Gp Ii-iv-vi Compounds Patents (Class 148/DIG63)
  • Patent number: 5523241
    Abstract: Channel stops for MIS infrared photodetector devices in Hg.sub.1-x Cd.sub.x Te by lattice damage (454) between and automatically aligned to MIS gates (408). Also, field plates and guard rings are automatically aligned to MIS gates.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: June 4, 1996
    Assignee: Texas Instruments Incorporated
    Inventors: Chang-Feng Wan, Joseph D. Luttmer, Julie S. England, David E. Fleming
  • Patent number: 5454885
    Abstract: A typical source of cadmium and tellurium is as a by-product of copper mining. Although attempts are made to remove impurities such as copper prior to commercially supplying them for forming material like cadmium telluride, cadmium zinc telluride and cadmium telluride selenide for use as a substrate to support electronic circuitry, processing during formation of the circuitry causes the impurities from the substrate to segregate into the circuitry, resulting in unacceptable electrical performance of the circuitry. A method for purifying the substrate prior to circuitry formation includes forming a sacrificial layer of mercury telluride or mercury cadmium telluride on the substrate, annealing the combination at elevated temperature with an overpressure of mercury and removing the sacrificial layer along with a contiguous portion of the substrate, if desired. The sacrificial layer may be formed by vapor phase type processes or even by liquid phase epitaxy.
    Type: Grant
    Filed: December 21, 1993
    Date of Patent: October 3, 1995
    Assignee: Martin Marietta Corporation
    Inventors: Gregory K. Dudoff, Karl A. Harris, Lee M. Mohnkern, Richard J. Williams, Robert W. Yanka, Thomas H. Meyers, III
  • Patent number: 5028563
    Abstract: A PbTe/PbEuSeTe buried heterostructure tunable diode laser and array and the method for making the same. The active region layer is buried between two lead salt semiconductor layers containing europium and selenium that are mutually of opposite conductivity type and have substantially the same lattice constant as the active region layer. In addition, the europium and selenium containing lead chalcogenide layers have an energy band gap greater than the active buried layer and an index of refraction less than the active layer. The buried structure enhances electrical and optical confinement, reduces threshold currents, and provides a stable single mode laser. Strontium, calcium or tin may be used in place of the europium. The buried laser and array are produced using a two-step molecular beam epitaxy method.
    Type: Grant
    Filed: January 23, 1990
    Date of Patent: July 2, 1991
    Assignee: Laser Photonics, Inc.
    Inventors: Zeev Feit, Douglas Kostyk, Robert J. Woods
  • Patent number: 4870027
    Abstract: In a process for preparing an infrared sentitive photodiode comprising the teps of:(1) forming by vacuum deposition an epitaxial layer of a semiconductor alloy material selected from the group consissting of PbSe, PbTe, PbSe.sub.x Te.sub.1-x, Pb.sub.y Sn.sub.1-y Se, Pb.sub.y Sn.sub.1-y Te, Pb.sub.y Sn.sub.1-y Se.sub.x Te.sub.1-x, Pb.sub.z Cd.sub.1-z Se, Pb.sub.z Cd.sub.1-z Te, and Pb.sub.z Cd.sub.1-x Se.sub.x Te.sub.1-x, wherein 0<x<1, 0<y<1, and 0<z-1, to cover at least a portion of the surface of a substrate composed of an infrared transparent single crystal material selected from the group consisting of(a) alkali metal halides and(b) alkaline earth halides;(2) coating the epitaxial layer of semiconductor alloy material with a thin layer of a lead halide selected from the group consisting of PbCl.sub.2, PbBr.sub.2, PbF.sub.
    Type: Grant
    Filed: July 27, 1988
    Date of Patent: September 26, 1989
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Tak-Kin Chu, Francisco Santiago
  • Patent number: 4853339
    Abstract: In a process of preparing an infrared sensitive photodiode comprising the eps of(1) forming by vacuum deposition an epitaxial layer of a semiconductor alloy material selected from the group consisting of PbS, PbSe, PbTe, PbS.sub.x Se.sub.1-x, PbS.sub.x Te.sub.1-x, PbSe.sub.x Te.sub.1-x, Pb.sub.y Sn.sub.1-y S, Pb.sub.y Sn.sub.1-y Se, Pb.sub.y Sn.sub.1-y Te, Pb.sub.y Sn.sub.1-y S.sub.x, Pb.sub.y Sn.sub.1-y S.sub.x Te.sub.1-x, Pb.sub.y Sn.sub.1-y Se.sub.x Te.sub.1-x, Pb.sub.z Cd.sub.1-z S, Pb.sub.z Cd.sub.1-z Se, Pb.sub.z Cd.sub.1-z Te, Pb.sub.z Cd.sub.1-z S.sub.x Se.sub.1-x, Pb.sub.z Cd.sub.1-z S.sub.x Te.sub.1-x, and Pb.sub.z Cd.sub.1-z Se.sub.x Te.sub.
    Type: Grant
    Filed: July 27, 1988
    Date of Patent: August 1, 1989
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Tak-Kin Chu, Francisco Santiago
  • Patent number: 4632711
    Abstract: A zinc selenide or zinc selenide-sulphide epitaxial crystal is grown at a growth temperature of about 180.degree.-320.degree. C. by organometallic chemical vapor deposition by using zinc alkyl and hydrogen selenide and/or hydrogen sulphide. An as-grown crystal presented an n conductivity type low resistivity and exhibited a narrow near-band gap emission peak. Besides a crystal of the same material as the epitaxial layer, crystals of group III-V, group IV, and so forth having the same or similar crystal structure as the epitaxial layer can be used as an underlayer for the growth.
    Type: Grant
    Filed: March 1, 1985
    Date of Patent: December 30, 1986
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shigeo Fujita, Yoshinobu Matsuda, Akio Sasaki
  • Patent number: 4568397
    Abstract: A method for growing a Group II-VI epitaxial layer on a substrate, said epitaxial layer having an electron mobility greater than 1.5.times.10.sup.5 cm.sup.2 /V-sec at 77.degree. K. and a carrier concentration less than 4.times.10.sup.15 (cm.sup.-3) is described. The method includes the steps of directing a plurality of vapor flows towards the substrate including a Group II metalorganic vapor having a mole fraction in the range of 3.0.times.10.sup.-4 to 4.5.times.10.sup.-4, a Group VI metalorganic vapor having a mole fraction in the range of 2.9.times.10.sup.-3 to 3.5.times.10.sup.-3 and a Group II elemental metal vapor having a mole fraction in the range of 2.6.times.10.sup.-2 to 3.2.times.10.sup.-2. The source of Group II metal is heated to at least 240.degree. C. while radiant energy is directed toward the reactor vessel to warm the zone of the reactor vessel between the Group II metal source and the substrate to at least 240.degree. C.
    Type: Grant
    Filed: September 12, 1984
    Date of Patent: February 4, 1986
    Assignee: Raytheon Company
    Inventors: William E. Hoke, Richard Traczewski, Peter J. Lemonias
  • Patent number: 4566918
    Abstract: A layer of Cd.sub.x Hg.sub.1-x Te is grown on a substrate by growing layers of HgTe t.sub.1 thick, and CdTe t.sub.2 thick alternately. The thicknesses t.sub.1 and t.sub.2 combined are less than 0.5 .mu.m so that interdiffusion occurs during growth to give a single layer of Cd.sub.x Hg.sub.1-x Te. The HgTe layers are grown by flowing a Te alkyl into a vessel containing the substrate and filled with an Hg atmosphere by an Hg bath. The CdTe layers are grown by flowing of Cd alkyl into the vessel where it combines preferentially with the Te on the substrate. Varying the ratio of t.sub.1 to t.sub.2 varies the value of x. Dopants such as alkyls or hydrides of Al, Ga, As and P, or Si, Ge, As and P respectively may be introduced to dope the growing layer.
    Type: Grant
    Filed: August 16, 1984
    Date of Patent: January 28, 1986
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Stuart J. C. Irvine, John B. Mullin, Jean Giess