Abstract: A method includes treating a reservoir with a damaged near wellbore region (NWR), including introducing a liquid foam treatment into a wellbore proximate to the damaged NWR, where the liquid foam treatment has a solution medium and nanobubbles, transmitting an acoustic wave towards the damaged NWR such that the nanobubbles collapse, causing fluid flow pathways to form for hydrocarbon production. A system includes a solution generation tool for generating a liquid foam treatment, where the liquid foam treatment has a solution medium and nanobubbles, where the nanobubbles migrate along a concentration gradient, and an acoustic signal generator transmits an acoustic signal. The system also includes a downhole tool signally coupled to the acoustic signal generator fluidly coupled to the solution generation tool, and the downhole tool transmits an acoustic wave into an NWR and introduces the liquid foam treatment into the wellbore proximate to the NWR.

Abstract: The flow of well treatment fluids may be diverted from a high permeability zone to a low permeability zone within a fracture network within a subterranean formation by use of a mixture comprising a dissolvable diverter and a proppant. At least a portion of the high permeability zone is propped open with the proppant of the mixture and at least a portion of the high permeability zone is blocked with the diverter. A fluid is then pumped into the subterranean formation and into a lower permeability zone of the formation farther from the wellbore. The diverter in the high permeability zones may then be dissolved at in-situ reservoir conditions and hydrocarbons produced from the high permeability propped zones of the fracture network. The mixture has particular applicability in the enhancement of production or hydrocarbons from high permeability zones in a fracture network located near the wellbore.

Abstract: Well treatment fluids, and methods for treating wellbores or fracturing subterranean formations, which include acrylamide polymer or copolymer crosslinked with one or more crosslinkers and one or more iron-containing compounds are provided.

Abstract: Compositions and methods involving polyvalent cation reactive polymers for use as lost circulation materials in subterranean treatment operations are provided. In some embodiments, the methods include forming a treatment fluid including a base fluid, a source of a polyvalent cation, a polyvalent cation reactive polymer, and an acid precursor; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and allowing the treatment fluid to at least partially set.

Abstract: A geology materials organizer configured to receive and retain a plurality of elements configured to provide a method of testing a rock or mineral sample. The geology materials organizer of the present invention includes a case wherein the case has an interior volume having implements releasably secured therein. A plurality of mohs hardness picks are releasably secured within the case. The geology materials organizer further includes providing a streak plate and an acid dispenser that are operable to assist in performing additional test on rocks or mineral samples. The case of the present invention further includes a lid and a transparent map pocket. Disposed within the interior volume of the case are a plurality of mineral receptacles configured to receive an retain mineral samples. The geology materials organizer further includes an ultraviolet light and a magnet.

Abstract: De-oiled lost circulation materials and methods of using such materials to, for example, reduce fluid loss are provided. In some embodiments, such methods include introducing a first treatment fluid including a base fluid and a de-oiled plant material into a wellbore penetrating at least a portion of a subterranean formation including a loss zone; and allowing the de-oiled plant material to at least partially plug the loss zone.

Abstract: A method of acidizing a geological formation is provided. A method of determining an effectiveness of the acidizing with NMR spectroscopy is also provided. Various embodiments of the method of acidizing and the method of determining the effectiveness of the acidizing are specified.

Abstract: The complexity of a fracture network may be enhanced during a hydraulic fracturing operation by monitoring operational parameters of the fracturing job and altering stress conditions in the well in response to the monitoring of the operational parameters. The operational parameters monitored may include the injection rate of the pumped fluid, the density of the pumped fluid or the bottomhole pressure of the well after the fluid is pumped. The method provides an increase to the stimulated reservoir volume (SRV).

Abstract: An experimental test method for dynamic imbibition capacity of shale is provided. The method includes the following steps: core preparation; physical parameter test of shale; experimental loading conditions are determined according to formation stress, formation temperature and hydraulic fracturing parameters; and a dynamic imbibition saturation is defined to characterize a dynamic imbibition amount. Various factors, such as fracturing fluid flow, formation confining pressure, formation temperature and fluid pressure, are used to obtain change rules of dynamic imbibition with time under different construction parameters in shale fracturing process.

Abstract: The flow of a fluid may be diverted from a high permeability zone to a low permeability portion of a subterranean formation by use of particulates comprising dicarboxylic acid, ester or an anhydride of the formula: or an anhydride thereof, wherein R1 is —COO—(R5O)y—R4 or —H; R2 and R3 are selected from the group consisting of —H and —COO—(R5O)y—R4, provided both R2 and R3 are —COO—(R5O)y—R4 when R1 is —H and further provided only one of R2 or R3 is —COO—(R5O)y—R4 when R1 is —COO—(R5O)y—R4, R4 is —H or a C1-C6 alkyl group, R5 is a C1-C6 alkylene group, and each y is 0 to 5. The dicarboxylic acid, ester or anhydride may further be admixed with an aliphatic polyester having the general formula of repeating units: where n is an integer between 75 and 10,000 and R is selected from the group consisting of hydrogen, alkyl, aryl, alkylaryl, acetyl, heteroatoms, and mixtures; thereof.

Abstract: Formulations for fracturing fluids are prepared by mixing a granulated water-soluble friction reducing polymer with an invert polymer emulsion friction reducing formulation optionally in the presence of an organophilic clay, without the need for specialized field equipment. The mixture can be dosed into water to produce a fracturing fluid which is found to be technically highly advantageous and cost-effective.

Abstract: Systems and methods for sealing a lost circulation zone of a subterranean well include extending a drill string into the subterranean well. The drill string has an ultrasonic system, an actuator, and a fluid flow path. The actuator is instructed to transmit an on signal to the ultrasonic system to switch the ultrasonic system to an on condition with the ultrasonic system generating ultrasound waves directed towards the fluid flow path. A loss circulation material is delivered into the fluid flow path. The loss circulation material has an epoxy resin and a capsule containing a cross-linker. The capsule is formed of a capsule polymer operable to release the cross-linker upon exposure to an ultrasound irradiation. The loss circulation material is exposed to the ultrasound waves to irradiate the capsule polymer and release the cross-linker from the capsule. The loss circulation material is delivered to the lost circulation zone.

Abstract: A method of treating a subterranean formation penetrated by a wellbore comprises introducing into the subterranean formation a treatment fluid comprising encapsulated particles having a core of a crosslinking agent and a shell of a chitosan encapsulant disposed on the core; releasing the crosslinking agent from the encapsulated particles with an acid; reacting the released crosslinking agent with the chitosan encapsulant or a derivative thereof forming a polymerized chitosan; and consolidating a plurality of particles in the subterranean formation with the polymerized chitosan.

Abstract: Methods for treating subterranean formations are provided. In one embodiment, the methods comprise providing a treatment fluid comprising an aqueous base fluid and a surfactant comprising an ethoxylated amine or derivative thereof; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and producing fluids from the wellbore during or subsequent to introducing the treatment fluid into the wellbore.

Abstract: A method of acidizing a geological formation is provided. A method of determining an effectiveness of the acidizing with NMR spectroscopy is also provided. Various embodiments of the method of acidizing and the method of determining the effectiveness of the acidizing are specified.

Abstract: Various embodiments disclosed relate to crosslinked polymers including sulfonic acid groups or salts or esters thereof as viscosifiers and fluid loss additives for subterranean treatment. In various embodiments, the present invention provides a method of treating a subterranean formation. The method includes placing in a subterranean formation a composition including a crosslinked viscosifier polymer including an ethylene repeating unit including an —S(O)2OR1 group wherein at each occurrence R1 is independently chosen from —H, substituted or unsubstituted (C1-C20)hydrocarbyl, and a counterion.

Abstract: Compositions herein may include an aqueous fluid, a crosslinked polyvinylpyrrolidone (PVP), and a betaine based polymer. Methods herein may include pumping a selected amount of a fluid loss pill into a formation, the fluid loss pill including a crosslinked PVP and a betaine based polymer.

Abstract: A method for recovery of oil housed in a reservoir comprising injecting an aqueous solution or slurry of a carbonate salt into a wellbore and allowing the aqueous solution or slurry of the carbonate salt to enter into the reservoir. An aqueous solution of an acid is then injected into the wellbore and allowed to enter into the reservoir. The carbonate salt and the acid are allowed to react with each other and form carbon dioxide (CO2) gas, inside the reservoir, which mixes with the reservoir oil and thereby reduces the viscosity of the oil within the reservoir. The method also provides for a rapid effervescence of carbon dioxide that may enhance oil recovery by improving oil flow to the wellbore by increasing reservoir pressure, increasing rock permeability from sand production, causing oil swelling, inducing foamy oil creation and/or removing formation skin damage.

Abstract: A method for recovery of oil housed in a reservoir comprising injecting an aqueous solution or slurry of a carbonate salt into a wellbore and allowing the aqueous solution or slurry of the carbonate salt to enter into the reservoir. An aqueous solution of an acid is then injected into the wellbore and allowed to enter into the reservoir. The carbonate salt and the acid are allowed to react with each other and form carbon dioxide (CO2) gas, inside the reservoir, which mixes with the reservoir oil and thereby reduces the viscosity of the oil within the reservoir. The method also provides for a rapid effervescence of carbon dioxide that may enhance oil recovery by improving oil flow to the wellbore by increasing reservoir pressure, increasing rock permeability from sand production, causing oil swelling, inducing foamy oil creation and/or removing formation skin damage.

Abstract: Embodiments to enhance recovery of hydrocarbons from a formation by altering wettability at a surface of the formation towards more water-wet are provided. One embodiment comprises providing a formation, providing an aqueous stream for injecting into the formation, adding a reducing agent to the aqueous stream, and injecting the aqueous stream with the reducing agent into the formation to alter a surface charge of the surface of the formation to become more water-wet to enhance recovery of hydrocarbons from the formation. The reducing agent is responsive to characteristics of the formation, characteristics of brine of the formation, and characteristics of hydrocarbons of the formation. The embodiment also comprises injecting a second aqueous stream into the formation after injection of the aqueous stream with the reducing agent. The second aqueous stream comprises surfactant, mobility control agent, the reducing agent, or a combination thereof.

Abstract: Shear thinning fluids may be useful as calibration fluids for calibrating rheometers with bob/rotor eccentricity and at lower shear rates, which may be particularly useful for calibrating rheometers at well sites that are used for measuring the rheological properties of complex fluids (e.g., wellbore fluids like drilling fluids, cementing fluids, fracturing fluids, completion fluids, and workover fluids). Additionally, high shear rate calibrations may also be performed with shear thinning calibration fluids. Newtonian fluids may be used for high shear rate calibrations in alternate of or in addition to the shear thinning calibration fluid.

Abstract: A method of evaluating the effectiveness of matrix acidizing treatment in a subterranean formation surrounding a wellbore that involves injecting a plurality of cationic salts into multiple sections of the subterranean formation before acidizing treatment, followed by collecting the cationic salts at the surface of the wellbore after producing the wellbore. A permeability recovery factor is calculated from a concentration ratio of the injected salt to the collected salt. The permeability recovery factor shows the effectiveness of the acidizing treatment. The permeability recovery factor also indicates the contribution of each individual section of the formation to the total production flow.

Abstract: A remedial method for repairing a damaged cement sheath, especially for use in wells in which fluids with a pH lower than 6 are injected, stored or extracted, comprises placing an acid swellable composition adjacent to the cement sheath. In the event of cement-matrix failure, or bonding failure between the cement/casing interface or the cement/borehole-wall interface, the composition may be injected into or adjacent to the cement sheath so that the material swells when contacted by acid gases, including carbon dioxide and hydrogen sulfide. The swelling seals voids in the cement matrix, or along the bonding interfaces, thereby restoring zonal isolation.

Abstract: The current application discloses compositions and methods for treating a subterranean formation. CO2 swellable elastomers can be used in a treatment fluid to at least partially block a high permeability region, therefore improving the performance of an operation such as matrix stimulation, acidizing, and acid fracturing.

Abstract: The invention provides a method made of steps of injecting into a wellbore, a composition comprising a solvent, a surfactant, a foaming gas, a foam enhancer, a crosslinkable polymer, and a crosslinking agent capable of crosslinking the polymer, wherein the foam enhancer increases the foam half-life of the gel composition compared to the gel composition without the foam enhancer; and allowing viscosity of the composition to increase and form a gel.

Abstract: Methods of making a degradable ball composition comprising a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, or a combination thereof comprising the steps of: forming a thermoplastic mass, and allowing the thermoplastic mass to cool as to form a degradable ball that is introduced in subterranean treatments by a carrier fluid.

Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with the presence of at least one mineral oil slurried together in combination with at least one particulate fluid loss control agent that may be an alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof. The mineral oil having the particulate fluid loss control agents slurried within it may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the slurry is added to the fluid after it has been substantially gelled. The mineral oil/particulate slurry may enhance the ability of a particulate fluid loss control agent to reduce fluid loss. The presence of the mineral oil may also eventually reduce the viscosity of the VES-gelled aqueous fluid.

Abstract: A method of servicing a wellbore in a subterranean formation comprising placing a wellbore servicing fluid in the wellbore and/or subterranean formation, wherein the wellbore servicing fluid comprises a hydrophobically modified relative permeability modifier, an oxygenated alkylating agent, and an aqueous base fluid, and allowing the wellbore servicing fluid to modify the permeability of at least a portion of the wellbore and/or subterranean formation.

Abstract: A method for extracting bitumen from a subterranean oil sand deposit including: drilling a portion of the deposit; fragmenting the drilled deposit; drilling of the fragmented deposit to allow for flooding, wherein one or more wells are drilled to provide access to the deposit and retrieval of extracted bitumen, to form a drilled fragmented deposit; flooding the drilled fragmented deposit with a first flood volume of fluid to permit the first flood volume of fluid to admix with the fragmented first portion, to re lease heavy oil from any inert material so that the heavy oil floats within the first flood volume of fluid in the drilled fragmented deposit to form a flooded first portion; recovering the heavy oil; and repeating the above for each additional portions.

Abstract: Methods and compositions that include a method of treating a subterranean formation comprising the steps of providing a carrier fluid comprising degradable balls that comprise a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, a fatty acid salt, or a combination thereof, and introducing the carrier fluid to the subterranean formation during a treatment.

Abstract: Methods for preventing or alleviating the loss of drilling fluids and other well treatment fluids into a subterranean formation during drilling or construction of boreholes therein include a drilling fluid including a lost circulation material. The lost circulation material includes a suspension of swelled particles of a pH sensitive polymeric material, the swelled particles capable of reversibly attaching to other swelled particles of the polymeric material. The pH of the aqueous solution is such that each particle of the swelled pH sensitive polymeric material is not attached to other swelled particles, and wherein upon lowering the pH of the suspension, the swelled particles attach to each other.

Abstract: Methods and fluids are provided that include, but are not limited to, a drilling fluid comprising an aqueous base fluid and a fluid loss control additive that comprises at least one polymeric micro gel and a method comprising: providing an aqueous based treatment fluid comprising a fluid loss control additive that comprises at least one polymeric micro gel; placing the aqueous based treatment fluid in a subterranean formation via a well bore penetrating the subterranean formation; allowing the fluid loss control additive to become incorporated into a filter cake located on a surface within the subterranean formation; allowing the filter cake to be degraded; and producing hydrocarbons from the formation. Additional methods are also provided.

Abstract: A silicate gel composition that is useful for sealing the face of a fracture of a formation. A method of sealing a face of a fracture of a formation with the silicate gel composition and diverting an acid treatment fluid.

Abstract: A method of servicing a wellbore comprising preparing a composition comprising a calcium aluminate cement, water, and a fluid loss additive wherein the fluid loss additive comprises an acid gelling polymer, placing the composition in the wellbore, and allowing the composition to set. A method of servicing a wellbore comprising placing into a wellbore having a bottom hole static temperature of greater than about 50° F. and/or a pH of from about 3 to about 9 a cement slurry comprising a calcium aluminate cement having an aluminum oxide content of greater than about 60 wt. % based on the total weight of the calcium aluminate cement and an acid-gelling polymer wherein the cement slurry has a fluid loss at 10 cc/10 min. to about 600 cc/30 min.

Abstract: A fluid loss pill that includes a crosslinked polymer gel, a brine, and solid salt particles disposed in said gel is described. Further, a method for reducing fluid loss that includes pumping a selected amount of a fluid loss pill into a wellbore leading to an oil-, condensate-, or gas-producing formation, the fluid loss pill including a crosslinked polymer gel, a brine, and solid salt particles disposed in said gel is described.

Abstract: Provided are methods of using fluid loss control additives that comprise a water-soluble polymer with hydrophobic or hydrophilic modification. In one embodiment, a method of providing at least some degree of fluid loss control during a subterranean treatment is provided. In an example of such a method, the method may comprise providing a treatment fluid comprising an aqueous liquid and a fluid loss control additive, the fluid loss control additive comprising a water-soluble polymer with hydrophobic or hydrophilic modification; and introducing the treatment fluid into a well bore that penetrates a subterranean formation, wherein there is at least a partial reduction in fluid loss into at least a portion of the subterranean formation from the treatment fluid and/or another aqueous fluid introduced into well bore subsequent to the treatment fluid.

Abstract: Methods for improving the quality of hydrocarbon fluids produced by in situ pyrolysis or mobilization of organic-rich rock, such as oil shale, coal, or heavy oil. The methods involve reducing the content of olefins, which can lead to precipitation and sludge formation in pipelines and during storage of produced oils. The olefin content is reduced by arranging wells and controlling well pressures such that hydrocarbon fluids generated in situ are caused to pass through and contact pyrolyzed zones in which coke has been left. This contacting chemically hydrogenates a portion of the olefins in the pyrolysis oil by reducing the hydrogen content of the coke.

Abstract: A method of treating a geologic formation including injecting into a wellbore a high viscosity composition which comprises a base fluid wherein the base fluid has an initial viscosity of 100 cP or greater and which exhibits a decrease in viscosity upon exposure to a viscosity reducing agent, and fibers wherein the fibers exhibit flocking upon a decrease in the viscosity of the base fluid, and injecting into the wellbore a viscosity reducing agent wherein the viscosity reducing agent is injected into the wellbore with or separately from the high viscosity composition is provided.

Abstract: Process fluids comprising more than 1 wt % polyacrylamide and a non-metallic crosslinker may be used to control lost circulation in subterranean wells. The process fluid is placed into a subterranean lost-circulation zone and allowed to crosslink, thereby forming a gel barrier that limits further flow of process fluid into the zone. The non-metallic crosslinker may preferably comprise one or more polylactams. A pH-adjusting agent may also be incorporated into the process fluid.

Abstract: The invention provides a method comprising providing a composition comprising a pH trigger and a polymer able to be hydrated in a defined pH zone; injecting the composition with a pH outside the defined pH zone; triggering the pH trigger to adjust the pH of the composition within the defined pH zone; and allowing viscosity of the composition to increase and form a plug.

Abstract: A method includes providing a treatment fluid that is a viscous fluid. The viscous fluid may be greater than 0.01 Pa-s, greater than 0.1 Pa-s, and/or a cross-linked polymer based fluid. The method further includes determining a fines migration composition soluble in an aqueous phase of the treatment fluid that is compatible with the treatment fluid, and that interacts to secure fines in an earth formation intersecting a wellbore within a fines reaction time. The method further includes adding an amount of the fines migration composition to the treatment fluid, and treating the earth formation with the treatment fluid. The method includes leaking off a portion of the treatment fluid into the earth formation, and providing a residence time of the leaked off portion of the treatment fluid in the earth formation, where the residence time meets or exceeds the fines reaction time.

Abstract: A well treatment composition is formed from a fluid mixture of a viscoelastic surfactant and a liquid carrier fluid. The fluid mixture has rheological properties wherein the mixture exhibits shear-thickening behavior when the shear rate is increased from a first shear rate to a second higher shear rate. The fluid mixture may further include a shear activation additive that interacts with the viscoelastic surfactant to facilitate the shear-thickening behavior. The method is accomplished by introducing the fluid mixture into a wellbore formed in a subterranean formation. In certain applications, the fluid mixture may be recycled by bringing the fluid mixture to the surface and reintroducing the fluid into the same or a different wellbore.

Abstract: Compositions including relatively low reactivity acids and having a pH of from about 2 to about 5, mixed with viscoelastic surfactants (VESs) and internal breakers may serve as fluids, in a non-limiting embodiment as drilling fluids, to open underground hydrocarbon reservoirs with carbonate contents of 10 wt % or above. The fluids initially have low viscosities. After the fluid flows out of the drill bit, the acids react with carbonates in the formation thereby increasing the pH of the fluids causing the VES to gel the fluid at the bottom of the hole and within the formation rock. Even when the subterranean formation contains naturally-occurring fractures, the viscosified fluid will reduce fluid loss into the formation. After drilling through the targeted formation, internal breakers in the viscosified fluids will break down the fluids to permit their removal, and production of the well with very little or no near well bore damage.

Abstract: Of the many compositions and methods provided herein, one method includes providing a drilling fluid comprising a base drilling fluid and a plurality of particulates, wherein the base drilling fluid without the particulates is characterized by N1(B) and wherein the base drilling fluid with the particulates is characterized by N1(A); and adjusting a concentration of the particulates in the drilling fluid by comparing the value of ?N1(F) to ?N1(P) so that ?N1(F)??N1(P), wherein ?N1(F)=|N1(A)|?|N1(B)|.

Abstract: A method of servicing a wellbore comprising identifying lost circulation zone within a wellbore; and placing in the wellbore a composition comprising a wax and a water-based mud wherein placement of the composition reduces or prevents a loss of fluids to the lost circulation zone. A wellbore servicing fluid comprising a water-based mud, a sized calcium carbonate particle and a wax.

Abstract: Disclosed herein are an acid emulsion fluid for use in sealing target portions of a hydrocarbon producing formation penetrated by a wellbore and the method of use thereof for fluid loss control.

Abstract: In some implementations, a method for reducing material loss includes adding, to a downhole fluid circulated through a drill string, encapsulants encapsulating one or more activators. One or more parameters in a wellbore associated with a fault in operating conditions are determined. One or more energy waves in the downhole fluid configured to release the one or more activators from the encapsulants are emitted.

Abstract: Subterranean formations may be stimulated by introducing into the formation a fluid containing a viscosifying agent and aphrons. The viscosifying agent may be a linear gel, crosslinked gel or a viscoelastic surfactant. The aphrons in the fluid move faster than the liquid phase of the fluid and thus move toward the front of the fluid as the fluid is being pumped into the formation. The bubble barrier and radial-flow pattern of the fluid rapidly reduce the shear rate and raise the fluid viscosity, severely curtailing fluid invasion into the formation especially in those formations where high leak-off potential exists.

Abstract: Alkaline earth metal compounds may be fluid loss control (FLC) agents for viscoelastic surfactant (VES) fluids used for fluid loss control pills, lost circulation material pills and kill pills in hydrocarbon recovery operations. The FLC agents may include, but not be limited to oxides and hydroxides of alkaline earth metal, and in one case magnesium oxide where the particle size of the magnesium oxide is between 1 nanometer to 0.4 millimeter. The FLC agent may alternatively be transition metal oxides and/or transition metal hydroxides. The FLC agent appears to associate with the VES micelles and together form a novel pseudo-filter cake quasi-crosslinked viscous fluid layer that limits further VES fluid flow into the porous media. The FLC agent solid particles may be added along with VES fluids. The pills may also contain internal breakers to reduce the viscosity thereof so that the components of the pill may be recovered.

Abstract: Methods of reducing the permeability of a subterranean formation to aqueous-based fluids using a water-soluble relative permeability modifier that comprises a reaction product of a hydrophilic compound and a hydrophilic polymer. In some methods the hydrophilic polymer may be selected from the group consisting of: a polyacrylamide, a polyvinylamine, a poly(vinylamine/vinyl alcohol), an alkyl acrylate polymer, and a combination thereof. In other methods the hydrophilic polymer may be selected from the group consisting of: a polyvinylamine; a poly(vinylamine/vinyl alcohol); a cellulose; a chitosan; a polyamide; a polyetheramine; a polyethyleneimine; a polyhydroxyetheramine; a polylysine; a polysulfone; a gum; a starch, and a combination thereof.