Abstract: A method and a test fixture for evaluating a junction between an electrical lead trace and a busbar are described, and include an electric power supply disposed to supply electric power to the electrical lead trace and an electric monitoring device disposed to monitor electrical potential across the junction. A mechanical stress-inducing device is disposed to apply mechanical stress proximal to the junction. The electric monitoring device monitors the electrical potential across the junction of the electrical lead trace coincident with the mechanical stress-inducing device applying mechanical stress proximal to the junction when the electric power supply is supplying electric power to the electrical lead trace. Electrical integrity of the junction is evaluated based upon the monitored electrical potential across the junction.

Abstract: Disclosed is a method and apparatus for reducing electromagnetic noise pick up in a Liquid Metal Cleanliness Analyzer (LiMCA), used to detect and measure particles in molten metal. A first electrode inserted in the molten metal is electrically insulated from second and third electrodes, also inserted in the molten metal. Molten metal and particles pass between the first electrode and the second and third electrodes through a passage in the electrical insulation. The second and third electrodes have a configuration with respect to the first electrode sufficient to establish symmetrical current loops between the first electrode and the second and third electrodes when a current is supplied to the second and third electrodes. The current is supplied from an ultra-capacitor. Electromagnetic noise in the symmetrical current loops is detected and is added in opposition to reduce the amplitude of the electromagnetic noise.

Abstract: A synergistic improvement of a precious metal assaying device with its associated electronic decoding algorithms further employing a precise feed of an electrolyte from a disposable flexing cartridge and through porous media for conveying electrolyte to create a reproducible electrochemical contact by a wetting action between a reference electrode in the assaying device and an external specimen under test where the electrolyte is passed through a novel slit diaphragm permitting efflux of electrolyte and reflux of unused electrolyte that results in a self-cleaning flush of the assaying device. The synergistic slit diaphragm permits the flow of electrolyte from the flexing cartridge in response to the positive pressure and the cleansing return of unused electrolyte on negative pressure of the cartridge, thereby solving a contamination problem which was a major shortcoming in such assaying devices.

Abstract: A method for analyzing a metal material includes electrolyzing a metal sample in an electrolytic solution, immersing a remaining portion of the metal sample taken out of the electrolytic solution in a dispersible solution to separate at least one substance selected from the group consisting of precipitates and inclusions attached to the remaining portion of the metal sample, filtering the dispersible solution containing the at least one separated substance through filters having straight pores and a porosity of 4% or more to obtain residues trapped on the filters and filtrates, and analyzing at least one of the residues and the filtrates.

Abstract: A DYNAMIC PRECIOUS METAL ASSAY DEVICE is described which is based on the methodology of the parent patent DYNAMIC PRECIOUS METAL ASSAY METHOD, U.S. Pat. No. 4,799,999 and achieves a highly accurate gold assay with a range extended to over 24 karats. The specified device requires a manual expulsion of a small amount of electrolyte from a disposable cartridge into a miniature galvanic cell which is formed at the lower tip of the device pencil. Placing the said tip against a gold specimen under test, thereby wetting it, and then by initiating the charging cycle and interpolating algorithm in the external electronics results in a professionally accurate assay of the gold specimen under test. The superior performance of this device is attributed to the novel replaceable electrolytic cartridge and miniature galvanic cell which wets a specimen through a porous interface. This improved device is very stable, rugged and is easily maintained.

Abstract: A precious metal testing apparatus determines the percentage content of precious metal in a specimen being tested by detecting the change in the rate of current flow through a resistive layer formed on the specimen by an application of a corrosive electrolyte on the specimen. The electrical circuit forms a fixed resistance circuit and a variable resistance circuit due to the formation of a growing resistive layer on the specimen such that the flow of current through the variable resistance circuit decreases as the flow of current through the fixed resistance circuit increase. The detection of the rate of change in current flow as a result of the increasing growth of the resistive layer can be compared to a look-up table that provides a corresponding percentage of precious metal in the specimen. Calibration of the testing apparatus can be accomplished with a specimen of known purity of the precious metal.

Abstract: A method for analyzing a metallic material includes the steps of electrolyzing a metal sample in an electrolyte; removing the electrolyzed metal sample from the electrolyte; immersing the metal sample removed from the electrolyte into a dispersive solution that is different from the electrolyte to separate at least one selected from the group consisting of a precipitate and an inclusion deposited on the metal sample; and analyzing the at least one selected from the group consisting of a precipitate and an inclusion extracted into the dispersive solution.

Abstract: A method for analyzing a metal specimen includes an electrolysis step of electrolyzing a metal specimen containing a reference element and a target element in an electrolytic solution, a sampling step of sampling a portion of the electrolytic solution, an analysis step of analyzing the sampled electrolytic solution, a concentration ratio-calculating step of calculating the concentration ratio of the target element to the reference element in the electrolytic solution on the basis of the analysis results, and a content-calculating step of calculating the content of the target element present in the form of a solid solution by multiplying the content of the reference element in the metal specimen by the obtained concentration ratio.

Abstract: A water pollution sensor for detecting a heavy metal, the water pollution sensor including: a base member; a conductive layer formed at a portion of one of surfaces of the base member and consisting of a conductive material; an insulating layer formed on the conductive layer to enable a portion of the conductive layer to be exposed; and a bismuth layer formed on a portion of the exposed conductive layer and including bismuth powders.

Abstract: The present invention is generally directed to devices and methods for sensing a variety of biologically-related substances. In a device aspect, the present invention is directed to a multilayer device for sensing metal ions, biological molecules, or whole cells. The device comprises: a) one or more cavities that provide for the introduction of a sample to be analyzed and one or more channels that provide for exit of the sample, or one or more channels that provide for the introduction and exit of the sample; b) one or more single-walled carbon nanotubes presented to the one or more cavities or one or more channels; c) a plurality of electrodes electrically connected to the one or more single-walled carbon nanotubes; and, a reference gate electrode presented to the one or more cavities or one or more channels. In a method aspect, the present invention is directed to a method for sensing species such as a metal, biological cells, and one or more biological molecules using the device.

Abstract: A sampling system for measuring the presence and concentration of inorganic ion species, including, metals, metalloids and non-metals, in a liquid solution including a first sampling unit. The first sampling unit includes a potentiometric subsystem configured to gather environmental metrics of the liquid sample, a preparation subsystem, coupled to the potentiometric module, the preparation subsystem being configured to prepare and isolate contaminants of concern in a flow of a liquid sample into metal, metalloid, or non-metal ionic forms; and a voltammetric subsystem selectively coupled to the preparation subsystem, potentiometric subsystem and a sample source, the voltammetric subsystem being configured to identify and determine a concentration of metal, metalloid, or non-metal ionic species through stripping voltammetry. The system is configured to compare a value of a stripping signal of the sample with a predetermined value to determine if dilution of the sample is required.

Abstract: A precious metal testing apparatus and methods adapted to analyze impurities in a precious metal test sample is described. The testing apparatus contains a test probe that has a replaceable portion and that is connected to a meter to measure resistance. The replaceable portion contains or forms a reservoir that includes at least one electrolyte component, a conductive member, and a fibrous tip. The electrolyte component is fluidly associated with a fiber tip and the conductive member contacts an electrical contact located outside the reservoir. Methods of testing and instructions regarding such methods are also included.

Abstract: A method for analyzing a metal specimen includes an electrolysis step of electrolyzing a metal specimen containing a reference element and a target element in an electrolytic solution, a sampling step of sampling a portion of the electrolytic solution, an analysis step of analyzing the sampled electrolytic solution, a concentration ratio-calculating step of calculating the concentration ratio of the target element to the reference element in the electrolytic solution on the basis of the analysis results, and a content-calculating step of calculating the content of the target element present in the form of a solid solution by multiplying the content of the reference element in the metal specimen by the obtained concentration ratio.

Abstract: The present invention relates to a multi-functional sensor system that simultaneously measures cathode and anode electrode potentials, dissolved ion (i.e. oxide) concentration, and temperatures in an electrochemical cell. One embodiment of the invented system generally comprises: a reference(saturated) electrode, a reference(sensing) electrode, and a data acquisition system. Thermocouples are built into the two reference electrodes to provide important temperature information.

Abstract: A mercury-free, electrochemical sensor is described that includes a self-assembled monolayer on a mesoporous support (SAMMS) composite and a fluoropolymer component that is deposited on a measurement surface. The SAMMS component provides outstanding metal preconcentration. The fluoropolymer component acts as an antifouling binder. The sensor can detect various metals at a low detection level in the presence of fouling agents and without sample pretreatment. The sensor is also able to detect mixtures of metals simultaneously with excellent single and inter-electrode reproducibility. Service lifetimes are excellent.

Abstract: A method is described of treating aluminium-metal alloys with organic or inorganic bases by exposing them to an aqueous solution of the base, removing the aqueous base and washing the treated alloy material, the leaching process being monitored, during the time of exposure to the base, on the basis of the potential which is established at a measuring electrode as a result of the treated aluminium-metal alloy and the hydrogen which may be formed during the reaction.

Abstract: An electrochemical sensing method comprising: (a) providing an electrochemical cell having a working electrode and a pseudo reference electrode; (b) providing a sample comprising a metal, the sample being in contact with the working electrode and the metal being capable of being oxidised or reduced at the working electrode when the metal is bound to the working electrode; (c) preconditioning the working electrode by (i) applying a time varying preconditioning potential between the working and pseudo reference electrodes; and/or (ii) baking the working electrode; and/or (iii) air-ageing the working electrode; and (d) applying a measuring potential between the working and pseudo reference electrodes and, during application of said measuring potential, measuring the current generated by oxidation/reduction of the metal at the working electrode.

Abstract: A precious metal assay method which includes the steps of forming an electrolytic cell comprising an anode specimen and a reference cathode, driving a ramp input into the electrolytic cell, measuring a resulting current through the electrolytic cell over a period of the ramp input. The assay value may be determined by comparing the locality, slope and peak or area of a current response of the resulting current against the localities, slopes and peaks or areas of a list of current responses of known precious metal compositions from an empirical look-up table and displaying the assay value on an electronics display.

Abstract: Electrochemical methods and materials for the detection of arsenic. In one aspect, arsenic is detected using a working electrode comprising particulate platinum. In another aspect, arsenic is detected using an electrode comprising indium tin oxide and particulate gold. Also provided are methods for the production of electrodes which involve the electrodeposition of gold onto indium tin oxide.

Abstract: Designs, fabrication and applications of nanostructures made of an alloy of two or more different metal elements to provide a unique identification code based on the composition of the alloy. Such compositionally encoded nanostructures can be in various geometries including but not limited to nanoparticles, nanowires and nanotubes. In one example, a single-step electroplating process may be used to form alloy nanowires without separate electroplating steps.

Abstract: Disclosed is a method of in-situ monitoring a reduction process of uranium oxides by lithium metal, wherein a conversion yield of uranium metal from uranium oxides upon production of uranium metal through a reaction of uranium oxides (UOx, x?3) with lithium metal in the presence of a high-temperature molten salt is measured according to an electrochemical analysis based on an oxidation of an oxygen ion and a reduction of a lithium ion dissociated from lithium oxide obtained as a by-product of the reaction, by use of a measuring device composed of a potentiostat/galvanostat and a reactor provided with an anode and a cathode. The in-situ monitoring method of the current invention is advantageous in terms of fast and simplified measuring techniques, by directly measuring the reduction process of uranium oxides at the anode and cathode connected to the potentiostat/galvanostat in the presence of the high-temperature molten salt.

Abstract: A measurement device is provided for determining the oxygen activity in molten metal or slag with a measurement head, which is arranged on one end of a carrier tube and on which an electrochemical measurement cell is arranged. The electrochemical measurement cell has a solid electrolyte tubule, which is closed on one side and which contains on its closed end a reference material and an electrode, which projects from the opposite end of the solid electrolyte tubule. The solid electrolyte tubule has on its outer surface a coating made from a mixture of zirconium silicate with a fluoride. The measurement head may also have a thermo-element, and the device may be used to determine the concentration of silicon and/or carbon in the melt, based on the oxygen activity measurement.

Abstract: A measurement device is provided for determining the oxygen activity in molten metal or slag with a measurement head, which is arranged at one end of a carrier tube and on which an electrochemical measurement cell is arranged. The electrochemical measurement cell has a solid electrolyte tube, which is closed at one end and which contains a reference material and an electrode at its closed end. The electrode projects from the opposite end of the solid electrolyte tube. The outer surface of the solid electrolyte tube has a coating of a mixture of calcium zirconate with a fluoride. The measurement device can be used for calculating the sulfur, silicon and/or carbon content of the molten metal or slag from reaction of the sulfur with the calcium zirconate, which releases oxygen, and measurement of the resulting change in oxygen activity of the melt or slag at the outer surface of the solid electrolyte tube.

Abstract: The invention relates to the analysis of the performance and properties of electrochemical processes, and specifically, to electrolytic solutions and electrode processes. The invention discloses a device and a method for obtaining qualitative and quantitative information for the kinetics of the electrode reactions, the transport processes, the thermodynamic properties of the electrochemical processes taking place in the cell. When a deposition reaction takes place, the device provides also valuable information about the relationship between the current density and deposit properties including but not limited to the deposit color, luster, and other aspects of its appearance. The device disclosed herein typically is comprised of a multiplicity of cathodic or anodic regions where one or more electrochemical reactions take place simultaneously, but at a different rate.

Abstract: The present invention relates to an electrochemical sensor for determining the concentration of a group IA metal in a fluid such as molten metal. The sensor comprises a substantially pure quantity of the group 1A metal as a reference electrode (13) contained in a sensor housing (3), and a solid electrolyte constituting at least part of the sensor housing (3). The electrolyte is in electrical contact with the reference electrode (13) and the sensor is capable of operating at temperatures in excess of 973K. In a preferred arrangement, the sensor comprises a two part elongate conductor (15), a first part (17) of which extends from the reference electrode (13) into a refractory seal (11a), and a second part (19) of which extends from within the refractory seal (11a) externally of the sensor, the two parts (17, 19) being welded together.

Abstract: An electrochemical sensor to measure the activity of a metallic component in a molten metal, comprising the molten metal as the measuring electrode, a reference electrode containing the metallic component to be measured, separated from each other by a liquid ion-conducting halide comprising the metallic component to be measured and immobilized in a non-conducting porous support fabricated from a material inert or almost inert to the molten metal, the halide and the reference electrode material, and whereby the reference electrode further comprises an external connection comprising an electric wire held in an electric isolating material which is chemically inert or almost inert to the molten metal and the reference electrode material, characterized in that the sealing of the reference electrode which is adapted to be sealed is done by a high temperature cement and by the molten metal itself and by a gas tight sealing of the external connection above the melt, and the reference electrode is introduced by a melt

Abstract: A pretreatment method for element analysis of metal samples removes contaminants on the surface of the metal sample by sputtering while at least one electrode for sputtering is cooled. A pretreatment apparatus for element analysis of metal samples for performing the method includes a cathode for holding the metal sample, anodes arranged to counter the cathode for sputtering, and a pretreatment chamber to store the cathode, anodes and metal sample under an inert gas atmosphere. The apparatus includes a cooling device for cooling at least one of the electrodes. The cathode and the anodes may be interchanged in the apparatus.

Abstract: A first solution is brought into contact with a surface of a sample so that impurities, which exist in the sample or on the surface of the sample, and the sample are dissolved in the first solution, and a voltage is applied across electrodes by putting the electrodes into the first solution so that substances including the impurities are deposited on the surface of the electrodes, and the deposited impurities are dissolved in a second solution so that impurities dissolved in the second solution are measured. As a result, an impurity measuring method and an impurity measuring device, which are capable of measuring a very small amount of impurities with high sensitivity, which exist in the sample or on the surface of the sample, are provided.

Abstract: The nature of a metal sample, such as the purity of precious metals and metal alloys, such as gold, is determined using a handheld probe having an electrode embedded in an electrolyte in a reservoir of the probe and arranged to conduct electrically with the sample through the electrolyte and a fibrous tip. The tip can resemble the point of a marker or writing instrument. The tip is in fluid communication with the reservoir containing the electrolyte, and preferably has the electrode embedded therein. An electrical connection with the electrode is made at the rear of the probe. For testing gold purity, the electrode is preferably a thin platinum wire extending through the reservoir and into the tip to just behind the tip surface. A battery is coupled to a calibration potentiometer whereby the voltage on a millivoltmeter is set to full scale when the probe is open circuited.

Abstract: A new electrochemical probe(s) design allowing for continuous (renewable) reagent delivery. The probe comprises an integrated membrane-sampling/electrochemical sensor that prevents interferences from surface-active materials and greatly extends the linear range. The probe(s) is useful for remote or laboratory-based monitoring in connection with microdialysis sampling and electrochemical measurements of metals and organic compounds that are not readily detected in the absence of reacting with the compound. Also disclosed is a method of using the probe(s).

Abstract: The nature of a metal sample, such as the purity of precious metals and metal alloys such as gold, is determined using a handheld probe having an electrode embedded in an electrolyte in a reservoir of the probe and arranged to conduct electrically with the sample through the electrolyte and a fibrous tip. The tip can resemble the point of a marker or writing instrument. The tip is in fluid communication with the reservoir containing the electrolyte, and preferably has the electrode embedded therein. An electrical connection with the electrode is made at the rear of the probe. For testing gold purity, the electrode is preferably a thin platinum wire extending through the reservoir and into the tip to just behind the tip surface. A battery is coupled to a calibration potentiometer whereby the voltage on a millivoltmeter is set to full scale when the probe is open circuited.

Abstract: A first solution is brought into contact with a surface of a sample so that impurities, which exist in the sample or on the surface of the sample, and the sample are dissolved in the first solution, and a voltage is applied across electrodes by putting the electrodes into the first solution so that substances including the impurities are deposited on the surface of the electrodes, and the deposited impurities are dissolved in a second solution so that impurities dissolved in the second solution are measured. As a result, an impurity measuring method and an impurity measuring device, which are capable of measuring a very small amount of impurities with high sensitivity, which exist in the sample or on the surface of the sample, are provided.

Abstract: A pen shaped electrochemical cell houses a nib shaped diaphragm dispensing aqueous ammonium bromide charged to a potential of about 3 volts. The device is used to coat an identifying reddish ink comprising gold bromide on a test electrode comprising gold.

Abstract: A photo-ablation technique is used to create apertures (4) in a layer (2) of electrically insulating material and allow electrically conducting material (3) exposed through the apertures to create a microelectrode. The microelectrode can be used for assay methods and in an assay unit.

Abstract: A simple robust sensor probe for determining the magnesium concentration in molten metal alloys in real-time. The probe provides needed process control information in molten metal technologies and has particular application to processes for removing magnesium impurities from scrap aluminum. The probe employs a specially constructed electrochemical concentration cell adapted for repeated immersions into vessels containing molten metal alloys. Specifically, the probe comprises two electrodes, both inert to a molten salt layer, to the molten metal (aluminum), and to magnesium. One electrode comprises an inverted molybdenum cup, a magnesium reference material, and a fibrous ceramic wick, e.g., yttrium oxide, for retaining molten salt therein in contact with the magnesium reference material when the sensor probe is first inserted into the molten salt layer and then into the molten aluminum layer.