Liquid Extraction With Solvents Patents (Class 208/311)
  • Patent number: 10849949
    Abstract: The invention extends the utility of apparatus used to extract medicinal cannabis compounds into an eluate by separating a portion of medicinal cannabis compounds contained within a portion of eluate at a first extraction target level providing enough clean solvent to continue extraction operations. A high efficiency concentrator such as a rotary evaporator or a wiped film evaporator processes eluate from one or more tanks or extraction vessels creating clean solvent when extraction targets are met or when clean solvent is exhausted. This manages eluate concentration levels and limits the quantity of concentrated medicinal cannabis compounds on site at any moment in time. The invention enables a business model for keeping medicinal cannabis compounds within a legal system, and reduces pollution because law enforcement would no longer have to burn large quantities of cannabis plant matter.
    Type: Grant
    Filed: June 4, 2018
    Date of Patent: December 1, 2020
    Inventor: Robert J Rapp
  • Patent number: 10758579
    Abstract: Described herein, inter alia, are processes, methods, and compositions useful for the extraction of natural products from source materials.
    Type: Grant
    Filed: March 24, 2017
    Date of Patent: September 1, 2020
    Assignee: METAGREEN VENTURES
    Inventors: Randall B. Murphy, Loren Erik Snyder
  • Patent number: 10669165
    Abstract: According to one embodiment, a method for removing antimicrobial material from a composition includes providing a container that contains a plurality of carbon elements such as granules, rocks and sheets. The carbon elements are submerged with a liquid and a composition that includes an antimicrobial material is deposited in the container. The carbon elements are configured to remove the antimicrobial material from the composition. The level of the liquid in the container is monitored and controlled to maintain a submerged condition of the carbon elements.
    Type: Grant
    Filed: August 2, 2018
    Date of Patent: June 2, 2020
    Assignee: SAFE FOODS CORPORATION
    Inventors: Justin Massey, Tim Yeaman
  • Patent number: 10451602
    Abstract: A method of screening a hydrocarbon stream for potential toxicological hazards. The method involves providing a hydrocarbon stream; conducting 2-dimensional gas chromatography (2D-GC) analysis to quantify saturates and aromatic distribution in the hydrocarbon stream; identifying 2-8 ring aromatic distribution and weight percentage of 2-8 ring aromatic molecules in the hydrocarbon stream from the 2D-GC analysis; relating the weight percentage of 2-8 ring aromatic molecules in the hydrocarbon stream from the 2D-GC analysis to a mutagenicity index (MI), in which the MI is determined in accordance with ASTM Standard Method E 1687; and assessing a potential toxicological hazard of the hydrocarbon stream based on the weight percentage of 2-8 ring aromatic molecules in the hydrocarbon stream from the 2D-GC analysis and a MI threshold value. The 2-8 ring aromatic distribution preferably includes 3-6 ring aromatics, more preferably 3.5-5.5 ring aromatics.
    Type: Grant
    Filed: March 28, 2017
    Date of Patent: October 22, 2019
    Assignee: ExxonMobil Research And Engineering Company
    Inventors: Tracie L. Owens, Beatrice M. Gooding, Frank C. Wang, Yogi V. Shukla, Eugenio Sanchez, Charles L. Baker, Jr., Roland B. Saeger
  • Patent number: 10308881
    Abstract: Process for TDAE-1 and TDAE-2 production is initiated with production of DAE Feeds which have kinematic viscosity at 100° C. ranges 24-67 cSt, followed by mixing them with solvent to yield Mixture of DAE Feed with density ranges 0.75-0.85 kg/liter and further contacting the Mixture of DAE Feed with solvent, like furfural, NMP and DMSO to facilitate a counter current liquid-liquid extraction, wherein the TDAE-1 and TDAE-2 are produced at ratio of polar solvent to Mixture of DAE Feed ranges 1.7-2.0 and 0.5-1.7, respectively. The PCA content of TDAE-1 and TDAE-2 are less than 3% weight and 3-20% weight. The amount of 8 Grimmer polyaromatics hydrocarbon content in the TDAE-1 and TDAE-2 are the same, that is, less than 10 mg/kg including Benzo (a) pyrene substance as much as less than 1 mg/kg.
    Type: Grant
    Filed: December 5, 2016
    Date of Patent: June 4, 2019
    Assignees: PT Pertamina (Persero), PT Pura Barutama
    Inventors: Yana Meliana, Supriyantini Nunik, Joseph Tundang, Sudiyatmoko Bambang
  • Patent number: 9827850
    Abstract: Techniques for separating a fuel on-board a vehicle include mixing an input fuel stream and a fluid solvent; separating the mixture into a first liquid fuel stream and a second liquid fuel stream, the first liquid fuel stream including a first portion of the input fuel stream defined by a first auto-ignition characteristic value and the fluid solvent, the second liquid fuel stream including a second portion of the input fuel stream defined by a second auto-ignition characteristic value that is different than the first auto-ignition characteristic value; separating the first liquid fuel stream into the fluid solvent and the first portion of the input fuel stream; directing the first portion of the input fuel stream to a first fuel tank on the vehicle; and directing the second portion of the input fuel stream to a second fuel tank on the vehicle.
    Type: Grant
    Filed: March 30, 2016
    Date of Patent: November 28, 2017
    Assignee: Saudi Arabian Oil Company
    Inventors: Esam Z. Hamad, Abdullah Sadek AlRamadan
  • Patent number: 9732018
    Abstract: A process for simultaneously hydrating and oligomerizing a hydrocarbon feed comprising mixed olefins incudes the steps of: (a) introducing the hydrocarbon feed in the presence of water into a fixed bed; (b) contacting the hydrocarbon feed with a catalyst within said fixed bed reactor, where the catalyst is of the type that hydrates the mixed olefins to form mixed alcohols and oligomerizes at least a portion of the mixed olefins into oligomers to produce a first product stream that includes an organic phase and an aqueous phase; (c) introducing the first product stream into a first separator which separates the organic phase from the aqueous phase; (d) introducing the separated organic phase into a second separator which separates unreacted olefins from mixed alcohols and one or more oligomers which comprise a final product stream; and (e) introducing the separated aqueous phase into a third separator which separates an alcohol-water azeotrope component from water.
    Type: Grant
    Filed: February 11, 2014
    Date of Patent: August 15, 2017
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Kareemuddin M Shaik, Wei Xu, Ibrahim A. Abba, Thamer Mohammed, Hiren Shethna, Kadhim Abbas Mohammed
  • Patent number: 9555562
    Abstract: A method for making a nano-scale film includes the steps of: (a) providing a suspension including an organic solvent and a number of nano-scale particles dispersed therein; (b) dropping/releasing the suspension into a liquid having a specific gravity greater than that of the nano-scale particles; and (c) forming a uniform film of nano-scale particles on the surface of the liquid.
    Type: Grant
    Filed: November 2, 2007
    Date of Patent: January 31, 2017
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Li-Na Zhang, Yao-Jun Zhang, Yi Ren, Kai-Li Jiang, Qun-Qing Li, Shou-Shan Fan
  • Patent number: 9303219
    Abstract: Embodiments of apparatuses and methods for treating a vacuum gas oil (VGO) hydrotreating feed are provided. In one example, a method comprises contacting the VGO hydrotreating feed with a first hydrotreating catalyst in the presence of hydrogen at first hydroprocessing conditions effective to form a first hydrotreated effluent. The first hydrotreated effluent is separated to form a hydrotreated VGO-containing stream and a hydrotreated diesel-containing stream. The hydrotreated VGO-containing stream is stripped and fractionated to form a VGO product stream. The hydrotreated diesel-containing stream is combined with a hydrotreated diesel-, naphtha-containing stream to form a combined stream. The combined stream is stripped to form a diesel product stream.
    Type: Grant
    Filed: December 26, 2013
    Date of Patent: April 5, 2016
    Assignee: UOP LLC
    Inventor: Vikrant Vilasrao Dalal
  • Patent number: 9199896
    Abstract: Systems and methods for producing aromatic products are provided. An aromatic stream is provided with aromatic compounds and olefins. The olefins are reacted with aromatic compounds to form colored bodies, and the aromatic stream is distilled to produce an overhead stream and reboiler stream. The colored bodies are in the reboiler stream, and the reboiler stream is passed through an absorbent to remove the colored bodies.
    Type: Grant
    Filed: July 30, 2013
    Date of Patent: December 1, 2015
    Assignee: UOP LLC
    Inventors: Jon Eric Prudhom, Jason L. Noe
  • Patent number: 9028680
    Abstract: A method and system for handling viscous liquid crude hydrocarbons is disclosed. The method involves (a) solvent deasphalting at least a portion of an asphaltene-containing liquid crude hydrocarbon feedstock to form an asphaltene fraction and a deasphalted oil (DAO) fraction essentially free of asphaltenes; (b) adjusting the density of the asphaltene fraction to substantially the same density of a carrier for the asphaltene fraction; (c) forming coated asphaltene particles from the asphaltene fraction of step (b); (d) slurrying the coated asphaltene particles with the carrier; and (e) transporting the slurry to a treatment facility or a transportation carrier.
    Type: Grant
    Filed: October 14, 2010
    Date of Patent: May 12, 2015
    Assignee: Chevron U.S.A. Inc.
    Inventors: Gunther Hans Dieckmann, John Segerstrom, Cesar Ovalles, Estrella Rogel, Vasudevan Sampath, Donald L. Kuehne, Hariprasad Janakiram Subramani, Dennis John O'Rear
  • Patent number: 8992771
    Abstract: Disclosed herein are methods for isolating heavy saturated hydrocarbons from a subsurface shale formation comprising kerogen and an extractible organics component. These methods can be used to provide a bright stock product. The process comprises extracting an extractible organics component from subsurface shale formations comprising kerogen and the extractible organics component in an inorganic matrix and isolating a heavy hydrocarbon fraction comprising saturated beta-carotene. The methods utilize a hydrocarbon solvent to at least partially solubilize the extractible organics component. Among other factors, these processes are based on the discovery that the extractible organics is composed of a heavy hydrocarbon component containing saturated beta-carotene. The saturated beta-carotene product is a valuable commercial product. The presently disclosed processes are more environmentally benign, more economical, and more efficient in producing commercial products and in providing access to kerogen.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: March 31, 2015
    Assignee: Chevron U.S.A. Inc.
    Inventors: Marcus Oliver Wigand, Saleh Elomari, Robert Martin Carlson
  • Patent number: 8992767
    Abstract: Initial high sulfur levels of a hydrocarbon feedstock are reduced to desired low levels without the need for integration of substantial new equipment or hardware with existing hydroprocessing reactors. Ionic liquids are utilized as organic sulfur extraction agents and are added to and mixed with the hydrocarbon feedstock containing organosulfur compounds downstream of an existing cold separator vessel. The ionic liquid and hydrocarbon mixture is maintained in a contact vessel under conditions which promote the formation of ionic sulfur-containing derivatives that are soluble in the ionic liquid to be formed, thereby enabling extractive removal and separation of the organosulfur compounds from the feedstock.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: March 31, 2015
    Assignee: Saudi Arabian Oil Company
    Inventors: Omer Refa Koseoglu, Adnan Al-Hajji
  • Publication number: 20150065402
    Abstract: Compounds of biodegradable surfactants useful for optimizing the separation of impurities typical of hydrocarbons, and designed to intervene and stabilize the molecular structure of crude oil, with no significant alterations of the crude's intrinsec composition are disclosed. The biodegradable surfactants compounds coexist with a non-ionic surfactant and an organic mix in emulsion form with the purpose of isolating crude from the pipeline, reduce friction to improve crude flow and to enter the crude macromolecule to modify the hydrocarbon chain to reduce its density and thus its viscosity; including compounds of biodegradable surfactants that comprise sodium hydroxide 1N, potassium chloride, sulphonic acid, dodecanoic acid, nonylphenol, terpene-1 and water, preferably hard water.
    Type: Application
    Filed: November 5, 2014
    Publication date: March 5, 2015
    Inventors: Osmerio Enrique LABARCA FINOL, Rixio Egardo REYES LOPEZ
  • Patent number: 8940154
    Abstract: A system and process for the preparation of high quality gasoline through recombination of catalytic hydrocarbon includes fractionator and extractor. The upper part of the fractionator is equipped with light petrol pipeline, the lower part of the fractionator is equipped with heavy petrol pipeline, the middle part of the fractionator is equipped with medium petrol pipeline. The medium petrol pipeline is connected with a medium petrol extractor, the upper part of the medium petrol extractor is connected with the medium petrol raffinate oil hydrogenation unit through the pipeline, the lower part of the medium petrol extractor is connected with the medium petrol aromatic hydrocarbon hydrogenation unit through the pipeline.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: January 27, 2015
    Inventor: Ranfeng Ding
  • Patent number: 8932450
    Abstract: A process and apparatus to remove asphaltenic contaminants from bitumen, heavy oil or residue to produce lower viscosity petroleum products and high purity asphaltenes.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: January 13, 2015
    Assignee: Value Creation Inc.
    Inventor: Columba K. Yeung
  • Patent number: 8900447
    Abstract: A method and a product made by treating a sulfur-containing hydrocarbon heavy feed, e.g., heavy crude asphaltene reduction is disclosed herein. The method comprises the steps of: mixing the sulfur-containing hydrocarbon heavy feed with a hydrogen donor solvent and an acidified silica to form a mixture and oxidizing the sulfur in the mixture at a temperature between 50° C. and 210° C., wherein the oxidation lowers the amount sulfur in the sulfur-containing hydrocarbon heavy feed by at least 90%.
    Type: Grant
    Filed: June 5, 2013
    Date of Patent: December 2, 2014
    Assignee: Board of Regents, The University of Texas System
    Inventors: Karina Castillo, Jason Parsons, Russell R. Chianelli
  • Patent number: 8864983
    Abstract: The invention is directed to a process for cleaning bitumen froth by mixing a sufficient amount of naphtha with the bitumen froth to provide a naphtha-to-bitumen ratio within the range of about 4.0 (w/w) to about 10.0 (w/w) and separating substantially dry diluted bitumen from the water and solids. Also provided is a process for cleaning diluted bitumen by mixing a sufficient amount of naphtha with the diluted bitumen to provide a naphtha-to-bitumen ratio equal to or greater than about 1.8 (w/w) and separating marketable fungible raw bitumen from the water and solids.
    Type: Grant
    Filed: March 16, 2012
    Date of Patent: October 21, 2014
    Assignee: Syncrude Canada Ltd.
    Inventors: Yin Ming Samson Ng, Brian Knapper, Jim Kresta
  • Patent number: 8864981
    Abstract: Deasphalted residual oil (DAO) and the aromatics-rich extract that is derived from DAO have low polycyclic aromatics contents, relatively low aniline points, and high flash points. They form blending stocks that improve properties of mixed feedstocks to consistently produce environmentally qualified rubber processing oil (RPO) by extraction under low solvent-to-oil ratios and moderate extraction temperatures. Distilling a petroleum crude oil under atmospheric pressure generates a bottom residual oil which is then subject to vacuum distillation to yield a bottom residual oil. DAO is produced by removing the asphalt from the vacuum bottom residual oil through extraction with light paraffinic solvent. The extract of DAO is a co-product in the production of the bright stock of the lubricating oil through extraction. The feedstock is mixed with the extract from a petroleum fraction boiling in lube oil range.
    Type: Grant
    Filed: January 14, 2011
    Date of Patent: October 21, 2014
    Assignee: CPC Corporation, Taiwan
    Inventors: Chih-Cheng Chang, Jung-Huang Wu, Cheng-Tsung Hong, Jin-Shang Liou, Kuo-Min Wei, Hung-Chung Shen, Fu-Ming Lee
  • Patent number: 8852429
    Abstract: A method for processing froth treatment tailings, including separating the froth treatment tailings in order to produce a coarse mineral material fraction and a fine mineral material fraction therefrom, subjecting the coarse mineral material fraction to froth flotation in order to produce a heavy mineral concentrate and a coarse mineral material tailings therefrom, and subjecting the heavy mineral concentrate to solvent extraction in order to produce a debitumenized heavy mineral concentrate and a bitumen extract therefrom.
    Type: Grant
    Filed: March 11, 2010
    Date of Patent: October 7, 2014
    Assignee: Titanium Corporation Inc.
    Inventors: Kevin Moran, Francis Chachula
  • Patent number: 8734639
    Abstract: Petroleum resid, bitumen and/or heavy oil is upgraded by the separation of asphaltenes and/or resins from such resids, bitumen and/or heavy oils by contacting them with an ionic liquid with which the asphaltenes and/or resins interact.
    Type: Grant
    Filed: April 1, 2008
    Date of Patent: May 27, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Michael Siskin, Manuel A. Francisco, Rustom M. Billimoria
  • Patent number: 8709237
    Abstract: A process for treating bitumen froth with paraffinic solvent is provided which uses three stages of separation. Froth and a first solvent are directed to a first stage at a solvent/bitumen ratio for precipitating few or substantially no asphaltenes. A first stage underflow is directed to a second stage and a first stage overflow is directed to a third stage. A second stage underflow is directed to waste tailings and the second stage overflow joins the first stage overflow. A third stage underflow is recovered as an asphaltene by-product and a third stage overflow is recovered as a diluted bitumen product. At least a second solvent is added to one or both of the second or third stages for controlling a fraction of asphaltenes in the third stage underflow. Asphaltene loss to waste tailings is minimized and asphaltenes are now recovered as asphaltene by-product.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: April 29, 2014
    Assignee: Total E&P Canada Ltd
    Inventors: Geoff Stevens, Ray Reipas
  • Patent number: 8680358
    Abstract: A method for cross connecting the lean solvent supply lines between the liquid liquid extraction (LLE) and the extractive distillation (ED) processes thereby using the LLE column as the outlet for removing accumulated heavy hydrocarbons (HCs) and polymeric materials from the solvent loop of both processes to maintain their solvent performance. The unique capabilities of the LLE column in rejecting heavy HCs from the solvent into a raffinate product stream that leaves the system enable the removal of the accumulated heavy HCs and polymeric materials from the closed solvent loop of the ED process when their lean solvent loop are cross connected. Cross connection requires minimum equipment change. In the revamped system, the solvent recovery column (SRC) in LLE process supplies lean solvent for the extractive distillation column while the SRC of the ED process supplies lean solvent for LLE column.
    Type: Grant
    Filed: February 27, 2013
    Date of Patent: March 25, 2014
    Assignees: AMT International, Inc., CPC Corporation, Taiwan
    Inventors: Fu-Ming Lee, Tzong-Bin Lin, Kuang-Yeu Wu, Jyh-Haur Hwang, Tsung-Min Chiu, Ciputra Jap, Yung-Sheng Ho
  • Patent number: 8658029
    Abstract: Methods for preparing solvent-dry, stackable tailings. The methods may include a primary leaching or extraction process that separates most of the bitumen from a material comprising bitumen and produces first solvent-wet tailings. The first solvent-wet tailings are washed with a second solvent that removes the first solvent from the tailings. Second solvent remaining in the tailings is removed to thereby produce solvent-dry, stackable tailings.
    Type: Grant
    Filed: August 13, 2012
    Date of Patent: February 25, 2014
    Assignee: Marathon Oil Canada Corporation
    Inventors: Willem P. C. Duyvesteyn, Julian Kift
  • Patent number: 8658030
    Abstract: Provided herein are processes for deasphalting and extracting a hydrocarbon oil. The processes comprise providing an oil comprising asphaltenes and/or other impurities, combining the oil with a polar solvent an extracting agent to provide a mixture, and applying a stimulus to the mixture so that at least a portion of any asphaltenes and/or impurities in the oil precipitate out of the oil.
    Type: Grant
    Filed: September 30, 2009
    Date of Patent: February 25, 2014
    Assignee: General Electric Company
    Inventors: John Aibangbee Osaheni, Thomas Joseph Fyvie
  • Patent number: 8574426
    Abstract: The present invention involves a process for removing one or more polycyclic aromatic hydrocarbon compounds from a vacuum gas oil comprising contacting the vacuum gas oil with a vacuum gas oil-immiscible phosphonium ionic liquid to produce a mixture comprising the vacuum gas oil and the vacuum gas oil-immiscible phosphonium ionic liquid, and separating the mixture to produce a vacuum gas oil effluent and a vacuum gas oil-immiscible phosphonium ionic liquid effluent, the vacuum gas oil-immiscible phosphonium ionic liquid effluent comprising the polycyclic aromatic hydrocarbon compound.
    Type: Grant
    Filed: April 16, 2012
    Date of Patent: November 5, 2013
    Assignee: UOP LLC
    Inventors: Beckay J. Mezza, Alakananda Bhattacharyya, Haiyan Wang, Christopher P. Nicholas
  • Patent number: 8574427
    Abstract: A process for removing a refractory nitrogen compound from a hydroprocessed vacuum gas oil feed includes contacting the hydroprocessed vacuum gas oil feed comprising the nitrogen compound with a VGO-immiscible phosphonium ionic liquid to produce a hydroprocessed vacuum gas oil and VGO-immiscible phosphonium ionic liquid mixture, and separating the mixture to produce a hydroprocessed vacuum gas oil effluent having a reduced refractory nitrogen compound content relative to the vacuum gas oil feed.
    Type: Grant
    Filed: July 23, 2012
    Date of Patent: November 5, 2013
    Assignee: UOP LLC
    Inventors: Beckay J. Mezza, Haiyan Wang, Alakananda Bhattacharyya, Christopher P. Nicholas
  • Patent number: 8449764
    Abstract: In solvent-assisted bitumen extraction, a native marker, for example: sulfur, nickel, vanadium, iron copper, or manganese, is used to control the solvent to bitumen ratio in a process stream such as a stream from a froth separation unit (FSU) and/or to measure hydrocarbon loss in a tailings solvent recovery unit (TSRU).
    Type: Grant
    Filed: October 26, 2009
    Date of Patent: May 28, 2013
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Tapantosh Chakrabarty, Ken N. Sury
  • Patent number: 8440072
    Abstract: Method of removing metals from hydrocarbon feedstock using esters of carboxylic acids, and additives for the same, are provided, wherein hydrocarbon stream including crude oil containing metals and salts thereof, wherein metal is calcium and its salt is calcium naphthenate, is mixed with an effective metal-removing-amount of an aqueous extraction-solution of non-precipitating and non-fouling additive comprising a chemical compound selected from a group consisting of methyl or ethyl or propyl or isopropyl mono- and/or di-esters of any one of the carboxylic acids selected from the groups consisting of maleic acid, maleic anhydride, and fumaric acid, or an appropriate combination of said esters, or an appropriate combination of any of said esters with any of said carboxylic acids to form a hydrocarbonous phase and an aqueous phase containing the metal ions; and separating aqueous phase.
    Type: Grant
    Filed: July 24, 2009
    Date of Patent: May 14, 2013
    Assignee: Dorf Ketal Chemicals (I) Private Limited
    Inventor: Mahesh Subramaniyam
  • Patent number: 8366917
    Abstract: A method of recovering minerals from hydrocarbonaceous materials can include forming a constructed permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be contacted with an agent sufficient to remove minerals therefrom. The agent is typically a solution containing a solvent, leachant, chelating agent and the like via which minerals can be removed having value, toxic minerals, radioactive minerals and the like.
    Type: Grant
    Filed: February 9, 2010
    Date of Patent: February 5, 2013
    Assignee: Red Leaf Resources, Inc
    Inventors: Todd Dana, James W. Patten
  • Patent number: 8323481
    Abstract: A method of sequestering carbon dioxide emissions during recovery of hydrocarbons from hydrocarbonaceous materials can include forming a constructed permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom. During heating, the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Additionally, during heating, any carbon dioxide that is produced can be sequestered. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: December 4, 2012
    Assignee: Red Leaf Resources, Inc.
    Inventors: Todd Dana, James W. Patten
  • Patent number: 8246811
    Abstract: Process for the production of a hydrocarbon fraction with a high octane number and a low sulfur content from a hydrocarbon feedstock, comprising at least the following stages: 1) a hydrodesulfurization stage of the hydrocarbon feedstock, and 2) at least one stage for extracting aromatic compounds on all or part of the effluent that is obtained from the hydrodesulfurization stage, whereby said extraction leads to a paraffin-enriched raffinate and an aromatic compound-enriched extract sent to a gasoline pool to improve its octane number, wherein a portion of the paraffinic raffinate can be used in a mixture with the aromatic extract; another portion can be used as a petrochemistry base either for producing aromatic compounds or for producing olefins.
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: August 21, 2012
    Assignee: IFP Energies Nouvelles
    Inventors: Quentin Debuisschert, Jacinthe Frecon, Robert L. Huggins
  • Patent number: 8226819
    Abstract: An extraction aid has been found which provides for enhanced contaminate removal, such as metals and amines, from crude oils that uses components that are desirable in desalting processes as the components are water soluble, have low toxicity, are highly biodegradeable and exhibit high thermal stability. According to one embodiment of the invention, an extraction aid that provides enhanced extraction properties is comprised of a blend of acids, particularly water soluble acids. More specifically, a combination of two acids chosen from the group consisting of acetic acid, sulfuric acid, glycolic acid, citric acid and methanesulfonic acid.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: July 24, 2012
    Assignee: General Electric Company
    Inventors: Alan E. Goliaszewski, Cato R. McDaniel
  • Patent number: 7972496
    Abstract: The present invention is related to a process oil using as a raw material a deasphalted oil obtained by deasphalting a vacuum residual oil of a crude oil and a manufacturing method of the process oil, the process oil having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (b) a viscosity (100° C.) of 40 to 70 mm2/s; (c) an aniline point of 85 to 100° C.; (d) a flash point of 250° C. or higher; (e) an aromatic hydrocarbon content of 40 to 55 mass %; and (f) a polar substance content of 10 to 15 mass %. The present invention is also related to a process oil and a manufacturing method of the process oil, the process oil obtained by mixing: an extract obtained by deasphalting and solvent-extracting a vacuum residual oil of a crude oil; and a lubricant base oil having a polycyclic aromatics (PCA) content of less than 3 mass %, and having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (i) a viscosity (100° C.
    Type: Grant
    Filed: May 29, 2006
    Date of Patent: July 5, 2011
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Meishi Tanaka, Masashi Nakamura, Kazuhiro Teshima, Akihito Abe, Masami Takasaki
  • Patent number: 7955522
    Abstract: An extraction aid has been found which provides for enhanced contaminate removal, such as metals and amines, from crude oils that uses components that are desirable in desalting processes as the components are water soluble, have low toxicity, are highly biodegradeable and exhibit high thermal stability. According to one embodiment of the invention, an extraction aid that provides enhanced extraction properties is comprised of a blend of acids, particularly water soluble acids. More specifically, a combination of two acids chosen from the group consisting of acetic acid, sulfuric acid, glycolic acid, citric acid and methanesulfonic acid.
    Type: Grant
    Filed: February 26, 2008
    Date of Patent: June 7, 2011
    Assignee: General Electric Company
    Inventors: Alan E. Goliaszewski, Cato R. McDaniel
  • Patent number: 7857964
    Abstract: The present invention relates to a method in which grades of oil are refined according to their object from a feed oil. This method has a solvent extraction process that obtains an extracted oil, and a hydrogenation process that subjects the obtained extracted oil to hydrogenation process in the presence of hydrogen and a catalyst to obtain a hydrorefined oil. The solvent extraction conditions are selected by using the poly-aromatic concentration as an index for calculating the concentration of heptane insoluble components in the residue of the extracted oil obtained by the solvent extraction process that cannot be fractionally distilled.
    Type: Grant
    Filed: February 19, 2002
    Date of Patent: December 28, 2010
    Assignee: JGC Corporation
    Inventors: Yoshinori Mashiko, Akira Sugimoto, Tsuyoshi Okada
  • Patent number: 7806965
    Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: October 5, 2010
    Inventor: Donald Leo Stinson
  • Publication number: 20100140144
    Abstract: A method for reducing one or more additives in a gaseous hydrocarbon stream (40) such as natural gas, comprising the steps of: (a) admixing an initial hydrocarbon feed stream (10) with one or more additives (20) to provide a multiphase hydrocarbon stream (30); (b) passing the multiphase hydrocarbon stream (30) from a first location (A) to a second location (B2); (c) at the second location (B2), passing the multiphase hydrocarbon stream (30) through a separator (22) to provide one or more liquid streams (50) comprising the majority of the one or more additives, and a gaseous hydrocarbon stream (40) comprising the remainder of the one or more additives; and (d) washing the gaseous hydrocarbon stream (40) in a decontamination unit (24) with a washing stream (60), wherein the washing stream (60) comprises distilled water, to provide an additive-enriched stream (70) and an additive-reduced hydrocarbon stream (80).
    Type: Application
    Filed: February 15, 2008
    Publication date: June 10, 2010
    Inventors: Paul Clinton, Marcus Johannes Antonius Van Dongen, Nishant Gupta
  • Patent number: 7727383
    Abstract: A highly effective liquid-liquid extraction process to remove nitrogen compounds and especially basic nitrogen compounds from aromatic light petroleum oils with excellent recovery employs de-ionized water, which can be acidified, as the extractive solvent. The product is an aromatic hydrocarbon with ultra-low amounts of nitrogen poisons that can deactivate acidic catalysts. The extracted oils are suitable feedstock for the subsequent catalytic processes that are promoted with the high performance solid catalysts, which are extremely sensitive to nitrogen poison.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: June 1, 2010
    Assignees: AMT International, Inc., CPC Corporation, Taiwan
    Inventors: Tzong-Bin Lin, Hung-Chung Shen, Kuang-Yeu Wu
  • Patent number: 7727766
    Abstract: There is disclosed a method of testing oil extraction processes including the steps of: 1) placing a sample to be tested in a sample holder which has a configurable temperature profile; 2) placing the sample holder in a pressure vessel; 3) increasing the pressure in the pressure vessel to simulate an over burden pressure; 4) configuring the temperature profile of the sample holder to match a desired temperature profile; 5) applying an oil extraction process to the sample; 6) measuring one or more parameters of the oil extraction process; 7) measuring the temperature of the sample to which the process is being applied; 8) configuring the sample holder to match the measured temperature profile. A device to test oil extraction processes on samples is disclosed. The device has a temperature configurable sample holder having sufficient temperature control to provide a desired heat profile to the sample.
    Type: Grant
    Filed: February 19, 2009
    Date of Patent: June 1, 2010
    Assignee: N-Solv Corporation
    Inventors: John Nenniger, Steve Conzuorgood, Lowy Gunnewiek, Bob Reid, Emil Nenniger
  • Patent number: 7622035
    Abstract: A method of deresinating a crude oil comprises contacting the crude oil with a carbon dioxide containing fluid, the crude oil having an initial API gravity and comprising an oil phase, resins, and asphaltenes, and wherein the carbon dioxide containing fluid enters the oil phase of the crude oil in a manner such that the resins and asphaltenes precipitate out of the crude oil such that the final API gravity of the crude oil is higher than the initial API gravity of the crude oil.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: November 24, 2009
    Assignee: North Carolina State University
    Inventors: Nael Naguib Zaki, Peter Kelley Kilpatrick, Ruben Guillermo Carbonell
  • Patent number: 7582204
    Abstract: The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: September 1, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Christophe Gueret, Raphaël Huyghe, Hugues Dulot, Patrick Euzen
  • Patent number: 7507869
    Abstract: Metal hydride compounds, which are prepared by mixing together from about 1 to about 10 parts by molecular weight of at least one metal selected from the group consisting of silicon, aluminum, tin, and zinc; from about 1 to about 3 parts by molecular weight of an alkali metal hydroxide; and from about 5 to about 10 parts by molecular weight of water and allowing this mixture to stand for a time sufficient to form a metal hydride, can be used for making fuel additives, treating sour gas, enhancing oil refining, extracting oil from tar sands and shale, increasing production of hydrogen from a hydrogen plant, treating oil and gas wells to enhance production, eliminate PCBs, cleaning soil contaminated by hydrocarbons and/or heavy metals, controlling odors, cleaning polluting stack emissions, extracting edible and essential oils, and eliminating bacteria, fungicides, and parasites from vegetation.
    Type: Grant
    Filed: January 2, 2008
    Date of Patent: March 24, 2009
    Inventor: Ignacio Cisneros
  • Publication number: 20080047871
    Abstract: HSP crude oil is used as process stream in crude oil storage tanks to address sludge levels both by cleaning sludge accumulations and preventing any significant sludge build up when used on a regular basis. HSP crude oil is also used to optimize cleaning routines. Making HSP oil easily accessible by providing a designated HSP source will make tank maintenance more efficient and allow refineries to use the advantages of the HSP oil to the maximum extent.
    Type: Application
    Filed: August 23, 2006
    Publication date: February 28, 2008
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Glen B. Brons, Douglas S. Meyer, Mohsen N. Harandi, Randolph Perry, John W. Anthony, John S. Jackson
  • Patent number: 7288184
    Abstract: Disclosed is a process for removing acids in a system in which aromatic hydrocarbons are separated from a mixture with aliphatic hydrocarbons. The aromatic hydrocarbons are extracted from the mixture using an extracting solvent. The aromatic hydrocarbons are stripped from the extracting solvent with steam and the steam is condensed to form water which is separated from the aromatic hydrocarbons. The separated water is passed through a basic anion exchange column and is then heated to produce the steam.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: October 30, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Marcus Lambertus Hendricus van Nuland, John Joseph Monson
  • Patent number: 7244873
    Abstract: It has now been disclosed that by directing the effluent from an oligomerization reactor to a water wash column to remove alcohol modifier from the hydrocarbon stream before sending it to a fractionation column offers flexibility in providing a bottoms product of a desired vapor pressure without increasing the concentration of alcohol modifier in the overhead stream beyond alcohol concentration limits.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: July 17, 2007
    Assignee: UOP LLC
    Inventors: Ruth Buskus Kleinworth, Charles P. Luebke
  • Patent number: 7156981
    Abstract: A process for the producing edible protein-containing meal for human and animal consumption and high quality food grade oils from oil seed using iodotrifluoromathane as the solvent is shown. The meal has a significantly improved level of dietary available (absorbable) protein. The process involves the preparation of protein isolates by a procedure which is conducted at room temperature, thus decreases protein degradation and denaturing which is caused by elevated temperatures. The process also provides for extraction of substantially all oils and fats, which interfere with the formation of the protein micelle, from the protein meal providing a cleaner, purer product with high levels of absorbable protein. Such protein isolates can then be used as such or added to formulated foods in order to increase the total protein content of that food. The protein produced and the oils recovered have compositions which are also unique and unobtainable by prior processing methods.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: January 2, 2007
    Assignee: Bio Extraction Limited
    Inventors: Peter F. Wilde, Ronald E. Skinner, Richard F. Ablett
  • Patent number: 7041485
    Abstract: The invention relates to a method for preparing free polyunsaturated fatty acids and their oxidation metabolites, wherein, successively, the production of polyunsaturated fatty acids and of their oxidation metabolites is stimulated, in a red alga, by the action of an elicitor which is peptide, lipid or saccharide in nature, and then the polyunsaturated fatty acids produced and also their oxidation metabolites are extracted.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: May 9, 2006
    Assignee: Laboratoires Goemer S.A.
    Inventors: Kamal Bouarab, Jean-Pierre Salaun, Jean-Claude Yvin, Philippe Potin
  • Patent number: 6890424
    Abstract: The present invention relates to a method of extracting and concentrating oils from materials in which the oils are already dispersed. More particularly, the present invention is concerned with the extraction of fixed oils or mineral oils from materials using a process of solvent extraction which is performed under elevated pressure and temperature. The solvent medium may be HFC 134a alone, or HFC 134a in combination with a suitable co-solvent which can be determined in accordance with the invention.
    Type: Grant
    Filed: January 20, 2000
    Date of Patent: May 10, 2005
    Assignee: Naturol Limited
    Inventor: Peter Frederick Wilde
  • Patent number: 6890425
    Abstract: A method of refining a petroleum product to remove aromatics and to separate paraffinic oils and waxes is provided. The method involves the utilization of phase equilibria wherein crystallized or solidified waxes, normally present in the petroleum product, are used to remove oils from a liquid solvent phase containing dissolved aromatics present in the unrefined petroleum product. The wax containing the oils is separated from the aromatic-containing solvent and is further processed to separate the waxes and oils. For petroleum products containing little, if any, wax, additional wax may be added and recycled back for further use in removing oils from the petroleum product. The method has particular application in preparing lubricating oils having a high viscosity index, where the presence of aromatics and wax can be detrimental.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: May 10, 2005
    Assignee: Process Dynamics, Inc.
    Inventors: Michael D. Ackerson, Michael Steven Byars