Deoxidant Or Oxygen Scavenging Patents (Class 252/188.28)
  • Patent number: 11612936
    Abstract: A method for preparing an oxygen-free passivated titanium or titanium-alloy powder product by means of gas-solid fluidization is provided.
    Type: Grant
    Filed: March 27, 2020
    Date of Patent: March 28, 2023
    Assignee: University of Science and Technology Beijing
    Inventors: Fang Yang, Yanru Shao, Yang Zhou, Zhimeng Guo, Yanli Sui, Qian Qin, Cunguang Chen
  • Patent number: 11431013
    Abstract: An air supply system for a fuel cell includes: a fuel cell stack in which multiple unit cells are stacked and that generates electricity through chemical reactions, an air channel to supply incoming air containing oxygen to the fuel cell stack and to transfer air discharged from the fuel cell stack to the outside of the air supply system, and a gas adsorption unit that is disposed on the air channel, positioned near an outlet of the fuel cell stack, and adsorbs oxygen contained in the air introduced into the air channel.
    Type: Grant
    Filed: September 23, 2020
    Date of Patent: August 30, 2022
    Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION
    Inventor: Young Min Kim
  • Patent number: 11338983
    Abstract: The disclosure relates to oxygen scavenging compositions, methods of making the compositions, articles prepared from the compositions, and methods of making the articles. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Grant
    Filed: August 22, 2014
    Date of Patent: May 24, 2022
    Assignee: PLASTIPAK PACKAGING, INC.
    Inventors: Shenshen Li, Matthew Dauzvardis, Richard Hoch
  • Patent number: 11077424
    Abstract: The present invention provides an oxygen scavenger composition comprising a granule having: an ? layer containing a water retention agent, a swelling agent, a metal salt and water; a ? layer containing iron; and a ? layer containing a porous support, wherein the granule forms a layer structure in order of the ? layer, the ? layer and the ? layer from an inside to an outside of the granule.
    Type: Grant
    Filed: January 24, 2017
    Date of Patent: August 3, 2021
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Ken Sugimoto, Yoshinobu Miyabe, Shinichi Ikeda, Kouta Kagimoto, Ryoujyu Narikawa
  • Patent number: 10775291
    Abstract: Devices for determining the absorption capacity of a metal-based oxygen absorber, preferably in the form of a sachet, comprising: a detector for detecting an electromagnetic field while the metal-based oxygen absorber is placed therein or moved relative thereto, preferably in uniform manner; and an evaluation unit which, on the basis of the measurement signal detected by the detector, determines the absorption capacity of the metal-based oxygen absorber, wherein the device further comprises a position and/or orientation sensing device which detects a position and/or an orientation of the metal-based oxygen absorber relative to the electromagnetic field; and wherein the evaluation unit corrects the measurement signal on the basis of the detected position and/or orientation of the metal-based oxygen absorber. In addition, a method for determining the absorption capacity of a metal-based oxygen absorber is disclosed.
    Type: Grant
    Filed: January 8, 2019
    Date of Patent: September 15, 2020
    Assignee: B. BRAUN AVITUM AG
    Inventor: Stefan Döring
  • Patent number: 10618718
    Abstract: Described herein are oxygen scavengers, oxygen scavenging polymeric compositions, and oxygen scavenging articles. The polymeric compositions comprising the oxygen scavengers may have utility in packaging, sealing, wrapping, and storing oxygen-sensitive substances, e.g., to preserve freshness of foods, beverages, and the like.
    Type: Grant
    Filed: February 1, 2019
    Date of Patent: April 14, 2020
    Assignee: APG Polytech, LLC
    Inventors: D. Jeffrey Black, Gianluca Ferrari, Robert Morford, Wenxia Zhu, Daniel Batzel, Adam Safir
  • Patent number: 10557094
    Abstract: A method for inhibiting corrosion on internal metal surfaces of an overhead condenser of a crude distillation unit in which hydrocarbons, water and amine hydrochlorides condense, the method includes adding to the overhead condenser an amine composition in an amount and at a rate sufficient to maintain the pH of water condensate in the condenser above a pH of about 5, the amine composition made of a mixture of four amines wherein the amines are monoethanloamine, methoxypropyl amine, morpholine and cyclohexylamine present in a weight ratio ranging from about 25:30:25:20 to about 30:40:15:15. Further, a system and method assess the corrosion rate and optimize the dosage of neutralizing amine composition during the operating conditions of overhead condensing system.
    Type: Grant
    Filed: May 16, 2017
    Date of Patent: February 11, 2020
    Assignee: BHARAT PETROLEUM CORPORATION LTD.
    Inventors: Jaya Rawat, Ankur Verma, D. T. Gokak, Sanjay Bhargava
  • Patent number: 10518243
    Abstract: An electronic vaping device includes a housing extending in a longitudinal direction, a reservoir in the housing, the reservoir configured to store a pre-vapor formulation, a heater in the housing, the heater configured to heat the pre-vapor formulation, at least one portion formed of a material including at least one polymer and at least one oxygen sequestering agent, and a power supply.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: December 31, 2019
    Assignee: Altria Client Services LLC
    Inventors: Jason Andrew Macko, Georgios Karles
  • Patent number: 10207853
    Abstract: Described herein are oxygen scavengers, oxygen scavenging polymeric compositions, and oxygen scavenging articles. The polymeric compositions comprising the oxygen scavengers may have utility in packaging, sealing, wrapping, and storing oxygen-sensitive substances, e.g., to preserve freshness of foods, beverages, and the like.
    Type: Grant
    Filed: July 18, 2012
    Date of Patent: February 19, 2019
    Assignee: APG Polytech, LLC
    Inventors: D. Jeffrey Black, Gianluca Ferrari, Robert Morford, Wenxia Zhu, Daniel Batzel, Adam Safir
  • Patent number: 10208200
    Abstract: A composition comprising: a polyester base polymer; a blend of two distinct polyether-based oxygen scavenging additives, OS1 and OS2, wherein each of OS1 and OS2 is selected from the group consisting of a polyether diol, an ester end-capped derivative of a polyether diol, a polyether-polyester block copolymer, and an ether end-capped derivative of a polyetherdiol, wherein OS1 has a molecular weight of from 10,000 to 100,000 and OS2 has a molecular weight of from 200 to 5,000; and a transition metal catalyst.
    Type: Grant
    Filed: March 30, 2017
    Date of Patent: February 19, 2019
    Assignee: GRAHAM PACKAGING COMPANY, L.P.
    Inventors: Murali K. Akkapeddi, Brian A. Lynch
  • Patent number: 10035129
    Abstract: Oxygen-absorbing resin composition, not responsive to a metal detector, producing no odor after absorption of oxygen and has excellent oxygen-absorbing performance in a wide range of humidity conditions from low to high humidity. An oxygen-absorbing molded article, and a multilayer body, container, injection-molded article and medical containers also provided. The oxygen absorbing resin composition contains a polyester, comprising at least one constituent unit having a tetralin ring component compound, a transition metal catalyst, and a catalyst for producing the polyester. The oxygen-absorbing molded article of the present invention can be formed by molding the oxygen-absorbing resin composition into a film or a sheet. The multilayer body, container, injection-molded article, medical container, etc. of the present invention are obtained by using the oxygen-absorbing resin composition.
    Type: Grant
    Filed: November 22, 2012
    Date of Patent: July 31, 2018
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Satoshi Okada, Toshiya Takagi, Takashi Kashiba, Shinpei Iwamoto, Shinichi Ikeda, Fumihiro Ito, Shun Ogawa, Shota Arakawa, Kenichiro Usuda
  • Patent number: 9676171
    Abstract: A gas barrier laminate 10 having an inorganic barrier layer 3 and a water-trapping layer 5 that are formed on a plastic base material 1, the water-trapping layer 5 including a matrix of a cationic polymer (a) in which is distributed a hygroscopic agent (b) having such a hygroscopic property as to attain a humidity lower than a humidity that can be attained by using the matrix. The gas barrier laminate exhibits super barrier property against water despite of a structure of a small number of layers.
    Type: Grant
    Filed: February 6, 2014
    Date of Patent: June 13, 2017
    Assignee: TOYO SEIKAN GROUP HOLDINGS, LTD.
    Inventors: Shimpei Okuyama, Yusuke Obu, Shunya Nangou, Kota Mori
  • Patent number: 9533441
    Abstract: A packaging article for containing and holding food products includes a barrier layer for limiting permeability of oxygen through and into the article and an oxygen scavenging layer, which oxygen scavenging layer together with a second plastic material is contained within a cavity in a first plastic material forming walls, bottom(s) and lid(s) of the packaging article, which first plastic material is suitable for contact with food products. A method of manufacturing a packaging finished in one injection molding cycle includes placing the barrier layer in a mold, injecting the first plastic material suitable for contact with food products into the mold, and injecting the second plastic material with the oxygen scavenger into the mold.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: January 3, 2017
    Assignee: Superfos A/S
    Inventor: Benny E. Nielsen
  • Patent number: 9428692
    Abstract: The present invention provides a novel oxygen absorbent composition being capable of realizing an oxygen absorbent not responding to a metal detector, being suppressed in the increase of the odor intensity after the absorption of oxygen and having an excellent oxygen absorption performance over a wide range of humidity conditions from low humidity to high humidity, and provides an oxygen absorbent package using the oxygen absorbent composition.
    Type: Grant
    Filed: August 30, 2012
    Date of Patent: August 30, 2016
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Satoshi Okada, Toshiya Takagi, Takashi Kashiba, Shinpei Iwamoto, Shinichi Ikeda, Kenichiro Usuda
  • Patent number: 9107442
    Abstract: An extruded or molded article containing iron based oxygen scavenger, electrolytes, activated carbon, silica gel, or other water absorbing media, and optionally pore formers, is subjected to deformation to create voids or porosity, and subjected to water spraying or dipping to obtain a water activity of 0.4 or higher. The article is placed in a container or package containing oxygen sensitive articles.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: August 18, 2015
    Assignee: Multisorb Technologies, Inc.
    Inventor: Chieh-Chun Chau
  • Patent number: 9085752
    Abstract: The atmosphere control composition according to the present invention is an atmosphere control composition for use in the culture of cells, which comprises (a) an ascorbic acid component, (b) water, (c) a porous carrier, (d) an aldehyde-removing agent, (e) a transition metal catalyst and/or an alkaline earth metal hydroxide, wherein the aldehyde-removing agent comprises at least one component selected from the group consisting of ethylene urea, urea, arginine, lysine hydrochloride and a polyallylamine. According to the present invention, the atmosphere control composition feasible for preventing the generation of aldehyde can be provided without affecting the oxygen absorption ability and the carbon dioxide generation ability thereof.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: July 21, 2015
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Ayako Oura, Shigeki Imagawa, Makoto Yoshizawa
  • Patent number: 9068113
    Abstract: The present invention provides a composition comprising: a polyester base polymer; at least one non-polymeric oxidizable organic compound; at least one transition metal in a positive oxidation state, said metal being present in the composition in an amount of from about 10 to about 400 ppm, wherein the polyester base polymer comprises less than about 40 ppm phosphorous. The compositions of the present invention do not exhibit an induction period prior to the onset of oxygen scavenging upon formation into a container.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: June 30, 2015
    Assignee: GRAHAM PACKAGING COMPANY, L.P.
    Inventors: Murali K. Akkapeddi, Brian A. Lynch, Timothy Schnetzka
  • Publication number: 20150144838
    Abstract: An oxygen-absorbing resin composition copolymerized polyolefin compound including a copolymerized polyolefin compound and a transition metal catalyst, wherein the copolymerized polyolefin compound is a copolymerized polyolefin compound including at least one of constitutional unit (a) selected from the group consisting of the constitutional units represented by the general formula (1), and at least one of the constitutional unit (b) having an indane ring, selected from the group consisting of the constitutional units represented by the general formulas (2) and (3).
    Type: Application
    Filed: July 9, 2013
    Publication date: May 28, 2015
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Shinpei Iwamoto, Satoshi Okada, Shinichi Ikeda
  • Patent number: 9028712
    Abstract: There are provided an oxygen scavenger composition and the like, which are excellent in economy in which the amount of oxygen absorbed per unit volume of the oxygen scavenger composition is large, and rusting at high humidity is inhibited. The oxygen scavenger composition of the present invention comprises (A) an iron powder, (B) a metal bromide and/or a metal iodide, and (C) a thiosulfate.
    Type: Grant
    Filed: June 8, 2012
    Date of Patent: May 12, 2015
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Takashi Nakata
  • Patent number: 9018284
    Abstract: The present invention provides a composition comprising: a base polymer; at least one compound having the structure of Formula I or II wherein Ar is an o-, m-, or p-phenylene moiety, a substituted phenylene moiety, or a naphthalene moiety; R1 and R2 are independently selected from the group consisting of: hydrogen, alkyl, alkenyl, and aryl; and X is O or —(CH2)n—; n=0, 1, or 2; and p=0, 1, or 2; and; and at least one transition metal in a positive oxidation state, said metal being present in the composition in an amount of from about 10 to about 400 ppm, wherein said compound is present in an amount of from about 0.10 to about 10 weight percent of the composition.
    Type: Grant
    Filed: May 6, 2011
    Date of Patent: April 28, 2015
    Assignee: Graham Packaging Company, L.P.
    Inventors: Murali K. Akkapeddi, Brian A. Lynch
  • Patent number: 9011727
    Abstract: Blending an electrically active, anodically coloring, electrochromic polymer with a non-electrochromic, non-electrically conductive binder polymer greatly enhances the performance of the anodically coloring, electrochromic polymer in an electrochromic device over time. In addition to improved physical characteristics of the blend, e.g., film build, durability etc, the coloristic properties, including color space and color strength, of the device comprising the blend are more durable than when using the neat polymer, and in certain instances, the color space and color intensity provided by the blend is superior to that available from the neat polymer.
    Type: Grant
    Filed: April 7, 2009
    Date of Patent: April 21, 2015
    Assignee: BASF SE
    Inventors: Nancy Cliff, David Yale, Deanna Rodovsky, Jennifer Jankauskas
  • Publication number: 20150090932
    Abstract: An oxygen absorbing agent composition including at least one type of a compound having an indane skeleton represented by the following general formula (1) and a transition metal catalyst:
    Type: Application
    Filed: May 13, 2013
    Publication date: April 2, 2015
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Satoshi Okada, Shinichi Ikeda, Kenichiro Usuda, Shinpei Iwamoto
  • Publication number: 20150064686
    Abstract: The preservation or extension of the life of oxygen perishable products such as fresh or cooked meats; fresh vegetables and fruits; dried vegetables, fruits and meats; packaged pharmaceuticals or biologicals; open and enclosed marketing display cases of meats, fruits and vegetables; and packaging, warehousing and transportation of meats, fruits, and vegetables is obtained by subjecting such products to an atmosphere obtained from gas permeable packets of an oxygen scavenging composition comprising a sodium carbonate mineral and one or more carboxylic acids. When the environment surrounding the oxygen perishable product is subjected to the packets of gaseous permeable oxygen scavenging compositions, oxygen is taken in by the scavenging composition and also the presence of carbon dioxide in the surrounding environment is enhanced thereby minimizing or eliminating the effect the oxygen on the oxygen perishable products.
    Type: Application
    Filed: August 29, 2014
    Publication date: March 5, 2015
    Inventor: Peter E. Fuller
  • Publication number: 20150050578
    Abstract: The present disclosure relates to an oxide-ion conductor having the general formula La2Ge1?xCrxMgO6?0.5x, where 0<x<1 and M=Cr, Sc, Ga and In or a mixture thereof. The present disclosure further relates to composite materials containing such oxide-ion conductors and to devices containing such oxide-ion conductors or composites.
    Type: Application
    Filed: August 14, 2013
    Publication date: February 19, 2015
    Inventors: John B. Goodenough, Preetam Singh
  • Publication number: 20150001443
    Abstract: The present invention provides an oxygen selective adsorbent containing BaxSr(1?x)Mgy(CO3)(1+y) or BaxSr(1?x)CO3 particles, increasing transition oxygen partial pressure, and representing high thermal stability and excellent oxygen sorption cavity, by adding another metal such as Sr to Ba which is active element for oxygen adsorption, so as to be capable of desorbing oxygen under lower vacuum even at the same operating temperature as existing oxygen selective adsorbents, and a preparation method thereof.
    Type: Application
    Filed: June 26, 2014
    Publication date: January 1, 2015
    Inventors: Jong-Ho Park, Taesung Jung, Hee-Tae Beum, Jong-Kee Park, Sang-Sup Han, Dong Woo Cho
  • Publication number: 20140361218
    Abstract: The disclosure relates to transition metal compositions, methods of making the compositions, articles prepared from the compositions, and methods of making the articles. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Application
    Filed: August 22, 2014
    Publication date: December 11, 2014
    Applicant: PLASTIPAK PACKAGING, INC.
    Inventors: Kirk Behrendt, Matt Dauzvardis, Richard Hoch
  • Patent number: 8906299
    Abstract: A container (22) includes a shell (24) made from a polymer, for example PET, and incorporating a catalyst, for example a palladium catalyst. A closure (40) incorporates a plug which includes a source of hydrogen, for example a hydride. In use, with container (22) including a beverage and closure (40) in position, the headspace in the container will be saturated with water vapor. This vapor contacts the hydride associated with plug (42) and as a result the hydride produces molecular hydrogen which migrates into the polymer matrix of shell (24) and combines with oxygen which may have entered the container through its permeable walls. A reaction between the hydrogen and oxygen takes place, catalyzed by the catalyst, and water is produced. Thus, oxygen which may ingress the container is scavenged and the contents of the container are protected from oxidation.
    Type: Grant
    Filed: January 24, 2008
    Date of Patent: December 9, 2014
    Assignee: Colormatrix Holdings, Inc.
    Inventors: Mark Rule, Ronald J. Valus, Steven Burgess Tattum
  • Patent number: 8871352
    Abstract: An oxygen-scavenging composition is provided that includes an oxygen-scavenging polymer and a catalyst. The oxygen-scavenging polymer, which in preferred embodiments is suitable for use in packaging articles, is a dendritic polymer having one or more oxygen-scavenging groups.
    Type: Grant
    Filed: May 31, 2013
    Date of Patent: October 28, 2014
    Assignee: Valspar Sourcing, Inc.
    Inventors: Richard D. Joslin, Jeffrey Niederst, Paul E. Share, Grant Schutte
  • Publication number: 20140311099
    Abstract: An oxygen scavenging composition capable of providing good oxygen absorption capabilities wherein the oxygen scavenging agent is a sulfite salt with a Group I cation, combined with an acidifying agent and optionally a hygroscopic salt. The compositions can be formed into films, coatings, 3-dimensional solids, fibers, webs, and shaped products or structures which are incorporated into, applied to, or otherwise become a part of a container structure, including container closures, seals, gaskets, liners, and the like.
    Type: Application
    Filed: April 3, 2014
    Publication date: October 23, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: Julius Uradnisheck
  • Patent number: 8852683
    Abstract: A method of dry coating oxidizable particles with activating particles. The method includes accreting at least portions of the activating particles onto surfaces of the oxidizable particles by mechanically induced juxtapositions to form composite particles; and abrading the composite particles to more evenly distribute the activating component over surfaces of the activating particles.
    Type: Grant
    Filed: December 26, 2012
    Date of Patent: October 7, 2014
    Assignee: Multisorb Technologies, Inc.
    Inventor: Stanislav E. Solovyov
  • Publication number: 20140262917
    Abstract: An oxygen-scavenging composition is provided that includes an oxygen-scavenging component and an oxidation catalyst. In preferred embodiments, the oxygen-scavenging composition includes a thermoplastic polymer that may optionally include the oxygen-scavenging composition as a portion thereof. In preferred embodiments, the composition is suitable for use in packaging articles.
    Type: Application
    Filed: March 13, 2013
    Publication date: September 18, 2014
    Applicant: VALSPAR SOURCING, INC.
    Inventors: Paul Share, Richard H. Evans
  • Publication number: 20140275347
    Abstract: A nano-clay material that exhibits improved compatibility with polymers is described. The nano-clay material may be mixed with polymers to produce a nano-clay polymer nanocomposite material including reduced levels of clay loading. Methods for making the nano-clay nanocomposite material and articles of manufacture from the nanocomposite material are also described.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: NANOSCIENCE ENGINEERING CORPORATION
    Inventors: Pranav Nawani, David E. Burnett, Roy G. Crawford
  • Publication number: 20140225034
    Abstract: The present invention provides a novel oxygen absorbent composition being capable of realizing an oxygen absorbent not responding to a metal detector, being suppressed in the increase of the odor intensity after the absorption of oxygen and having an excellent oxygen absorption performance over a wide range of humidity conditions from low humidity to high humidity, and provides an oxygen absorbent package using the oxygen absorbent composition.
    Type: Application
    Filed: August 30, 2012
    Publication date: August 14, 2014
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Satoshi Okada, Toshiya Takagi, Takashi Kashiba, Shinpei Iwamoto, Shinichi Ikeda, Kenichiro Usuda
  • Patent number: 8790543
    Abstract: A closure (40) for a container incorporates calcium hydride and a matrix material as a hydrogen-generating composition. In use, hydrogen is generated which reacts with oxygen permeating a container associated with the closure and a catalyst associated with the container catalyses reaction of the hydrogen and oxygen to produce water, thereby scavenging the oxygen. The composition of calcium hydride and matrix is also claimed.
    Type: Grant
    Filed: April 8, 2010
    Date of Patent: July 29, 2014
    Assignee: Colormatrix Holdings, Inc.
    Inventors: Adrian John Carmichael, Andrew Stuart Overend, Mark Rule, Ronald James Valus, James Stuart Leeming
  • Publication number: 20140187413
    Abstract: The present invention relates to nanocomposite materials comprising nanoclays as support of metal oxide particles which give the materials multi-functional properties. Said properties are obtained through the formulation of a specific type of additives based on layers of natural and/or synthetic clays which are intercalated with metal oxides with antimicrobial and/or oxygen sequestrating and/or catalytic and/or self-cleaning and/or anti-abrasive capacity; and which may optionally contain other organic, metal, inorganic compounds or combination thereof which may exercise a role of compatibilization and/or dispersion and/or increase in the functionality of the metal oxides and/or providing new functionalities, both passive of physical strengthening and active such as biocide character, antioxidant and chemical-species absorbers. Furthermore, the present invention discloses the use of said materials for multi-sector applications.
    Type: Application
    Filed: May 28, 2012
    Publication date: July 3, 2014
    Applicant: Nanobiomatters Research & Develpment, S. L.
    Inventors: Jose Maria Lagaron Cabello, Eugenia Nunez, Maria Busolo Pons, Maria Dolores Sanchez-Garcia
  • Patent number: 8758644
    Abstract: An oxygen-scavenging component and methods for producing the oxygen-scavenging component are provided. The oxygen-scavenging component, which in preferred embodiments is suitable for use in packaging articles, includes an oxygen-scavenging group preferably having at least one double bond. The oxygen-scavenging component may be combined with a polymer and/or an oxidation catalyst to form an oxygen-scavenging composition.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: June 24, 2014
    Assignee: Valspar Sourcing, Inc.
    Inventors: Paul Share, Jeffrey Niederst, Richard H. Evans, Grant Schutte
  • Publication number: 20140145109
    Abstract: Butadiene, isoprene, and terpene based materials are soluble in polymer matrices such as polyethylene terephthalate when the butadiene, isoprene, or terpene compound also contains allylic carbons afterwith at least one polar moiety which is non-reactive to the matrix polymer. These compounds can be oxygen scavengers when in the presence of cobalt or manganese compounds and have been found to have substantially reduced haze in the final package.
    Type: Application
    Filed: February 17, 2012
    Publication date: May 29, 2014
    Inventors: Ricardo Knudsen, Aaron Murray
  • Patent number: 8721920
    Abstract: The instant invention concerns a composition comprising a base polymer, at least one compound of the formula E-(L-E)x wherein: E is and L is a linking group; and at least one transition metal in a positive oxidation state. The invention also concerns packages containing walls comprising such compositions, methods of forming such packages, and methods of packaging an oxygen-sensitive item within such a package.
    Type: Grant
    Filed: March 9, 2010
    Date of Patent: May 13, 2014
    Assignee: Plastipak Packaging, Inc.
    Inventors: Girish Nilkanth Deshpande, Venkat Govindarajan, John M. Rost, Alan Silverman
  • Publication number: 20140117280
    Abstract: An oxygen absorber is provided that contains at least one of compounds each having a particular structure, and the oxygen absorber exhibits an oxygen absorbing capability without a metal contained, and is suitable for removing oxygen inside a packaging material packaging foods or the like.
    Type: Application
    Filed: May 16, 2012
    Publication date: May 1, 2014
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Kentaro Ishii, Ryoji Otaki, Takafumi Oda, Shota Arakawa
  • Patent number: 8673173
    Abstract: Disclosed is an oxygen-absorbable solvent-soluble resin having both oxygen absorbability and adhesive properties. Specifically disclosed is an oxygen-absorbable solvent-soluble resin which comprises an acid component (A), an acid component (B) and a polyester having a constituent unit derived from a glycol component, wherein the ratio of the amount of the acid component (A) to the total amount of the acid components is 40 to 80 mol % and the ratio of the amount of the acid component (B) to the total amount of the acid components is 15 to 35 mol %. The acid component (A):tetrahydrophthalic acid or a derivative thereof, or tetrahydrophthalic anhydride or a derivative thereof; and the acid component (B):terephthalic acid.
    Type: Grant
    Filed: March 8, 2010
    Date of Patent: March 18, 2014
    Assignee: Toyo Seikan Kaisha, Ltd.
    Inventors: Yoichi Ishizaki, Yoshihiro Ohta, Yui Yamaguchi
  • Patent number: 8623392
    Abstract: An allergen inactivating agent for preventing allergic manifestations or alleviating symptoms by reducing antigenicity of an allergen through contact with the allergen includes dissolved chlorine dioxide as an active ingredient.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: January 7, 2014
    Assignee: Taiko Pharmaceutical Co., Ltd.
    Inventors: Hirofumi Morino, Takashi Shibata
  • Publication number: 20140004232
    Abstract: The subject of the invention are new forms of nanoiron or zero-valent iron doped with boron, prepared with the method based on the invention, with the ability to fix oxygen in any environment, even an anhydrous one. In the second aspect, the subject of the invention is the method of oxygen scavenging both in a packaging containing water, as well as in an anhydrous environment. In the third aspect, the subject of the invention are nanocomposites containing nanoiron prepared according to the invention, characterised by the ability to fix oxygen in an environment containing water, as well as in an anhydrous environment. In the fourth aspect, the subject of the invention are iron oxygen scavengers in packaging, based on nanoiron or zero-valent iron doped with boron, prepared with the method based on the invention, with the ability to fix oxygen in an environment containing water, as well as in an anhydrous environment.
    Type: Application
    Filed: December 29, 2011
    Publication date: January 2, 2014
    Applicant: UNIWERSYTET EKONOMICZNY W POZNANIU
    Inventors: Zenon Foltynowicz, Wojciech Kozak, Joanna Stoinska, Marta Urbanska, Karol Muc, Anna Dominiak, Katarzyna Kublicka
  • Patent number: 8609744
    Abstract: An oxygen-scavenging mixture comprising: (I) an oxidizable metal component; (II) an electrolyte component selected from the group consisting of KCl and CaCl2, and (III) a non-electrolytic, acidifying component.
    Type: Grant
    Filed: April 28, 2009
    Date of Patent: December 17, 2013
    Assignee: BASF SE
    Inventors: Edoardo Menozzi, Enrico Galfré, Yijun Ye, Mauro Mazzini
  • Publication number: 20130306905
    Abstract: The present invention provides a composition comprising: a polyester base polymer; at least one non-polymeric oxidizable organic compound; at least one transition metal in a positive oxidation state, said metal being present in the composition in an amount of from about 10 to about 400 ppm, wherein the polyester base polymer comprises less than about 40 ppm phosphorous. The compositions of the present invention do not exhibit an induction period prior to the onset of oxygen scavenging upon formation into a container.
    Type: Application
    Filed: March 13, 2013
    Publication date: November 21, 2013
    Applicant: GRAHAM PACKAGING COMPANY, L.P.
    Inventors: Murali K. Akkapeddi, Brian A. Lynch, Timothy Schnetzka
  • Publication number: 20130285277
    Abstract: The disclosure relates to transition metal compositions, methods of making the compositions, articles prepared from the compositions, and methods of making the articles. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Application
    Filed: April 30, 2013
    Publication date: October 31, 2013
    Inventors: Kirk Behrendt, Matthew J. Dauzvardis, Richard L. Hoch
  • Publication number: 20130284617
    Abstract: To provide an oxygen-absorbing polyester resin composition which exhibits excellent oxygen-absorbing capability even in the absence of transition metal catalyst without affected by the glass transition temperature of a polyester resin that is contained as a base resin. The oxygen-absorbing polyester resin composition including a base resin (A) which is a polyester resin, an oxygen-absorbing component (B) which is a compound having an unsaturated alicyclic structure, and an oxidation promotion component (C) for promoting the oxidation of the oxygen-absorbing component (B), said oxidation promotion component (C) being a compound having a benzyl hydrogen.
    Type: Application
    Filed: January 12, 2012
    Publication date: October 31, 2013
    Applicant: TOYO SEIKAN GROUP HOLDINGS, LTD.
    Inventors: Toshiki Yamada, Yukiko Hirayama, Yoshiki Sawa
  • Patent number: 8562861
    Abstract: The present invention provides an oxygen-scavenging composition and articles formed therefrom. The oxygen-scavenging composition preferably includes an oxygen-scavenging polymer having an unsaturated bicyclic group, a based polymer, and an optional oxidation catalyst. The base polymer preferably includes a substituted or unsubstituted addition backbone, which may include heteratoms.
    Type: Grant
    Filed: October 10, 2008
    Date of Patent: October 22, 2013
    Assignee: Valspar Sourcing, Inc.
    Inventors: Paul Share, Jeffrey Niederst, Richard Evans, Grant Schutte
  • Patent number: 8562860
    Abstract: A method for activating hydrogen molecules dissolved in water and stabilizing the concentration of the hydrogen molecules is provided. The method for activating and stabilizing hydrogen molecules dissolved in water is characterized by allowing hydrogen ions to coexist with the hydrogen molecules.
    Type: Grant
    Filed: July 5, 2007
    Date of Patent: October 22, 2013
    Assignee: Spring Co., Ltd.
    Inventor: Osao Sumita
  • Publication number: 20130266752
    Abstract: The disclosure relates to oxygen scavenging molecules, compositions, methods of making the compositions, articles prepared from the compositions, and methods of making the articles. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
    Type: Application
    Filed: May 7, 2013
    Publication date: October 10, 2013
    Inventor: Girish N. Deshpande
  • Publication number: 20130264516
    Abstract: An oxygen-scavenging composition is provided that includes an oxygen-scavenging polymer and a catalyst. The oxygen-scavenging polymer, which in preferred embodiments is suitable for use in packaging articles, is a dendritic polymer having one or more oxygen-scavenging groups.
    Type: Application
    Filed: May 31, 2013
    Publication date: October 10, 2013
    Inventors: Richard D. Joslin, Jeffrey Niederst, Paul E. Share, Grant Schutte