With Lubricants, Or Warning, Stabilizing Or Anti-corrosion Agents Or Persistent Gases Patents (Class 252/68)
  • Patent number: 11927373
    Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.
    Type: Grant
    Filed: January 26, 2023
    Date of Patent: March 12, 2024
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Sheng Peng, Mario Joseph Nappa
  • Patent number: 11905454
    Abstract: Disclosed are refrigerants comprising at least about 97% by weight of a blend of three compounds, said blend consisting of: from about 38% by weight to about 48% by weight difluoromethane (HFC-32), from about 6% by weight to about 12% by weight pentafluoroethane (HFC-125), from about 33% by weight to about 41% by weight trifluoroiodomethane (CF3I) and from about 2% by weight to about 16% by weight 2,3,3,3-tetrafluoropropene (HFO-1234yf) wherein the percentages are based on the total weight of the three compounds in the blend, and methods and systems which use same.
    Type: Grant
    Filed: March 1, 2021
    Date of Patent: February 20, 2024
    Assignee: HONEYWELL INTERNATIONAL INC.
    Inventors: Michael Petersen, Elizabet del Carmen Vera Becerra, Samuel F. Yana Motta, Ankit Sethi, Gustavo Pottker, Gregory Laurence Smith
  • Patent number: 11866634
    Abstract: A fluoropropene composition comprising E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, and 2,3,3,3-tetrafluoropropene, wherein the total amount of 1,1,3,3,3-pentafluoropropene and 2,3,3,3-tetrafluoropropene is 1.0 wt. % or less, based on the total weight of the fluoropropene composition. A method of producing the fluoropropene, composition and methods for using the fluoropropene composition are also disclosed.
    Type: Grant
    Filed: June 15, 2023
    Date of Patent: January 9, 2024
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Sheng Peng, Mario Joseph Nappa
  • Patent number: 11851602
    Abstract: The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
    Type: Grant
    Filed: August 23, 2021
    Date of Patent: December 26, 2023
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Andrew Edward Feiring, Viacheslav A Petrov, Barbara Haviland Minor, Mario Joseph Nappa, Nandini C Mouli, Thomas Joseph Leck, Jon Lee Howell
  • Patent number: 11834602
    Abstract: The present disclosure is to provide a composition comprising a refrigerant that has the characteristics of having a sufficiently low GWP, and having a coefficient of performance (COP) and a refrigerating capacity equivalent to or higher than those of R404A. The present disclosure provides a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), 1,1,2-trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoropropene (HFO-1234yf), wherein the total concentration of the three components is 99.5 mass % or more, based on the entire refrigerant, and the three components have a mass ratio that falls within a region surrounded by a figure passing through the following 5 points in a ternary composition diagram whose three vertices represent the three components: point A (HFO-1132(E)/HFO-1123/HFO-1234yf=42.5/1.0/56.5 mass %), point B (HFO-1132(E)/HFO-1123/HFO-1234yf=27.1/1.0/71.9 mass %), point C (HFO-1132(E)/HFO-1123/HFO-1234yf=1.0/30.4/68.
    Type: Grant
    Filed: July 28, 2021
    Date of Patent: December 5, 2023
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Shun Ohkubo, Mitsushi Itano, Yuuki Yotsumoto, Akihito Mizuno, Tomoyuki Gotou, Yasufu Yamada
  • Patent number: 11732932
    Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.
    Type: Grant
    Filed: January 26, 2023
    Date of Patent: August 22, 2023
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Sheng Peng, Mario Joseph Nappa
  • Patent number: 11591504
    Abstract: A composition including a lubricant based on polyol esters (POEs) or PVE and a refrigerant F including from 1 to 99% by weight of trans-1,3,3,3-tetrafluoropropene (trans-HFO-1234ze) and from 1 to 99% by weight of 1,1,1,2-tetrafluoroethane. Also, the use of the composition including a lubricant and refrigerant in refrigeration, air conditioning and heat pumps.
    Type: Grant
    Filed: July 13, 2020
    Date of Patent: February 28, 2023
    Assignee: ARKEMA FRANCE
    Inventors: Wissam Rached, Beatrice Boussand
  • Patent number: 11555110
    Abstract: Provided is a heat-resistant resin composition which includes: a graft copolymer prepared by graft polymerization of a diene-based rubber polymer with an aromatic vinyl-based monomer and a vinyl cyan-based monomer; a first styrene-based copolymer including a maleimide-based unit and an aromatic vinyl-based unit; a second styrene-based copolymer including a vinyl cyan-based unit and an aromatic vinyl-based unit; and a third styrene-based copolymer including a vinyl cyan-based unit and an aromatic vinyl-based unit, wherein the second styrene-based copolymer and the third styrene-based copolymer include a vinyl cyan-based unit in mutually different amounts.
    Type: Grant
    Filed: December 4, 2018
    Date of Patent: January 17, 2023
    Assignee: LG CHEM, LTD.
    Inventors: Do Hyeong Kim, Ho Namgung, Seong Lyong Kim, Dae San Jung
  • Patent number: 11535809
    Abstract: The present invention relates to a lubricating composition, intended for a refrigerant system comprising a gas compression circuit, comprising: at least one first polyalkylene glycol exhibiting a hydroxyl number strictly of greater than 50 mg KOH/g and a kinematic viscosity, measured at 100° C. according to the standard ASTM D445, ranging from 5 to 10 mm2/s, and at least one second polyalkylene glycol with a kinematic viscosity, measured at 100° C., ranging from 100 to 500 mm2/s, said polyalkylene glycols A and B being present in a PAG(s) A/PAG(s) B ratio by weight of between 60/40 and 99/1. It also relates to the employment of such a lubricating composition in a refrigerant system comprising a gas compression circuit, in particular for an automobile air conditioning system, in combination with a coolant based on hydrocarbon compounds, such as R134a and/or HFO-1234yf.
    Type: Grant
    Filed: February 3, 2020
    Date of Patent: December 27, 2022
    Assignee: Total Marketing Services
    Inventors: Julien Argaud, Frédéric Michel
  • Patent number: 11525076
    Abstract: The present disclosure provides a composition comprising a refrigerant characterized by having a coefficient of performance (COP) and a refrigerating capacity equivalent to or higher than those of R404A, and having a sufficiently low GWP. Specifically, the present disclosure provides a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132 (E)) and 2,3,3,3-tetrafluoropropene (HFO-1234yf), wherein HFO-1132 (E) is present in an amount of 35.0 to 65.0 mass %, and HFO-1234yf is present in an amount of 65.0 to 35.0 mass %, based on the total mass of HFO-1132 (E) and HFO-1234yf, and wherein the refrigerant is for use in operating a refrigeration cycle in which the evaporation temperature is ?75 to ?5° C.
    Type: Grant
    Filed: August 14, 2020
    Date of Patent: December 13, 2022
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Shun Ohkubo, Mitsushi Itano, Yuuki Yotsumoto, Akihito Mizuno, Tomoyuki Gotou, Yasufu Yamada
  • Patent number: 11505648
    Abstract: The present disclosure provides amphiphilic fluorinated surfactant molecules for lowering the surface tension of aqueous, hydrocarbon, or solid phases in the presence of a fluorophilic continuous phase and for selectively interacting with biological and/or chemical molecules.
    Type: Grant
    Filed: April 20, 2016
    Date of Patent: November 22, 2022
    Assignee: RAN Biotechnologies, Inc.
    Inventor: Roger A. Nassar
  • Patent number: 11486620
    Abstract: In a refrigeration cycle apparatus, refrigerant circulates successively through a compressor, a condenser, an expansion valve, and an evaporator. The refrigeration cycle apparatus includes a detection unit, a heating unit, and a controller. The detection unit is configured to detect a temperature of refrigeration oil in the compressor. The heating unit is configured to heat the refrigeration oil. The controller is configured to operate the heating unit when the temperature detected by the detection unit is lower than a pour point of the refrigeration oil, and to stop the heating by the heating unit when the temperature detected by the detection unit reaches the pour point. Preferably, the heating unit includes a heater provided on an outer side of a compressor casing and at a lower portion of a motor unit.
    Type: Grant
    Filed: January 25, 2017
    Date of Patent: November 1, 2022
    Assignee: Mitsubishi Electric Corporation
    Inventors: Hiroki Ishiyama, Yusuke Shimazu
  • Patent number: 11466225
    Abstract: The invention relates to a lubricating oil composition and a refrigerant composition containing a polyalkylene glycol having a terpenoid end group, such as a farnesol end group.
    Type: Grant
    Filed: March 4, 2019
    Date of Patent: October 11, 2022
    Assignee: SHRIEVE CHEMICAL PRODUCTS, INC.
    Inventors: Elizabeth Dixon, Christopher Seeton
  • Patent number: 11453833
    Abstract: The present invention relates to esters of at least one polyol and of a mixture of fatty acids comprising at least one C5-C12 saturated fatty acid and at least one C10-C12 unsaturated fatty acid.
    Type: Grant
    Filed: January 29, 2020
    Date of Patent: September 27, 2022
    Assignee: ARKEMA FRANCE
    Inventors: Stéphanie Lebrun, Salomé Gravelat, Guillaume Le
  • Patent number: 11447676
    Abstract: To provide a working fluid for heat cycle having a low global warming potential, which can replace R410A, a composition for a heat cycle system comprising it, and a heat cycle system employing the composition. A working fluid for heat cycle, which comprises trifluoroethylene and 2,3,3,3-tetrafluoropropene, wherein the total proportion of trifluoroethylene and 2,3,3,3-tetrafluoropropene based on the entire amount of the working fluid is from 70 to 100 mass %, and the proportion of trifluoroethylene based on the total amount of trifluoroethylene and 2,3,3,3-tetrafluoropropene is from 35 to 95 mass %, a composition for a heat cycle system comprising the working fluid for heat cycle, and a heat cycle system employing the composition.
    Type: Grant
    Filed: December 7, 2021
    Date of Patent: September 20, 2022
    Assignee: AGC Inc.
    Inventor: Masato Fukushima
  • Patent number: 11421171
    Abstract: An object of the present invention is to provide an ester-based lubricating base oil for a fluid bearing that has a high viscosity index and excellent evaporation resistance, hydrolytic stability, and low-temperature fluidity. The present invention relates to a lubricating base oil for a fluid bearing containing a compound represented by general formula (1): wherein R1 represents a linear C2-C16 alkyl group, m represents an integer of 2 to 10, and n represents an integer of 4 to 14.
    Type: Grant
    Filed: December 17, 2019
    Date of Patent: August 23, 2022
    Assignee: NEW JAPAN CHEMICAL CO., LTD.
    Inventors: Yumi Mandai, Hirotsugu Mochida, Meguru Sugiyama
  • Patent number: 11384271
    Abstract: One aspect of the present invention is a refrigerating machine including a refrigerant circulation system including a compressor, a condenser, an expansion mechanism, and an evaporator, and the refrigerant circulation system being filled with a refrigerant and a refrigerating machine oil, wherein the refrigerating machine oil contains: a first base oil having a compatible region with the refrigerant in a range of a temperature of 30° C. or lower and an oil ratio of 1 to 80% by mass; and a second base oil having a kinematic viscosity at 40° C. lower than the first base oil and having a narrower compatible region with the refrigerant than the first base oil.
    Type: Grant
    Filed: April 2, 2019
    Date of Patent: July 12, 2022
    Assignee: ENEOS CORPORATION
    Inventors: Kentaro Yamaguchi, Yuya Mizutani, Satoshi Nagai, Hidetoshi Ogata
  • Patent number: 11370948
    Abstract: A composition including between 4 and 6 wt. % of difluoromethane, between 2.5 and 3.5 wt. % of pentafluoroethane, and between 91 and 93.5 wt. % of tetrafluoropropene. The use of the composition as replacement for R404A, R452A, R22, R134a, R245fa, R152a, R422, R502, R407A, R407F, R407C, R1234yf or R1234ze. A heat-transfer composition including the composition and at least one additive chosen from nanoparticles, stabilizing agents, surfactants, tracing agents, fluorescent agents, odorous agents, lubricants, and solubilizing agents.
    Type: Grant
    Filed: March 20, 2018
    Date of Patent: June 28, 2022
    Assignee: ARKEMA FRANCE
    Inventor: Wissam Rached
  • Patent number: 11365335
    Abstract: An object of the present invention is to provide a mixed refrigerant having three types of performance; i.e., a refrigerating capacity (also referred to as cooling capacity) and a coefficient of performance (COP) that are equivalent to those of R410A, and a sufficiently low GWP. Provided as a means for achieving the object is a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).
    Type: Grant
    Filed: June 26, 2020
    Date of Patent: June 21, 2022
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Mitsushi Itano, Daisuke Karube, Yuuki Yotsumoto, Kazuhiro Takahashi, Shun Ohkubo
  • Patent number: 11359122
    Abstract: A method for heating and/or air-conditioning in a motor vehicle interior by means of a reversible refrigeration loop in which a refrigerant fluid circulates, said fluid including: between 4 and 6 wt. % of difluoromethane (HFC-32); between 2.5 and 3.5 wt. % of pentafluoroethane (HFC-125); and between 91 and 93.5 wt. % of tetrafluoropropene, preferably 2,3,3,3-tetrafluoropropene.
    Type: Grant
    Filed: March 20, 2018
    Date of Patent: June 14, 2022
    Assignee: ARKEMA FRANCE
    Inventor: Wissam Rached
  • Patent number: 11352532
    Abstract: A refrigeration apparatus includes a heat source unit, a utilization unit, and a liquid refrigerant pipe and gas refrigerant pipe. The utilization unit has utilization unit internal pipelines. The liquid refrigerant pipe and the gas refrigerant pipe connect the heat source unit and the utilization unit internal pipelines. A refrigerant circulates through the heat source unit, the utilization unit, the liquid refrigerant pipe, and the gas refrigerant pipe. The refrigerant contains a compound represented by a molecular formula having one or more carbon-carbon unsaturated bonds. A disproportionation inhibitor for reducing a disproportionation reaction of the refrigerant is applied to at least a part of inner surfaces of the liquid refrigerant pipe, the gas refrigerant pipe, and the utilization unit internal pipelines.
    Type: Grant
    Filed: August 24, 2020
    Date of Patent: June 7, 2022
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Masaru Tanaka, Shigeharu Taira, Tomoyuki Haikawa, Yoshiki Shimizu
  • Patent number: 11345840
    Abstract: An apparatus and method wherein potential ozone layer-damaging chlorodifluoromethane (Refrigerant R-22) is substituted with a mix of less environmentally damaging refrigerants pentafluoroethane and tetrafluoroethane in chlorodifluoromethane-based air-cooling systems mainly in residential cooling. While less environmentally damaging than chlorodifluoromethane, the substitute refrigerant has a temperature-pressure relationship similar to that of chlorodifluoromethane, making the substitute refrigerant suitable for use with chlorodifluoromethane-based air-cooling systems. In this event, it is mixed with a relatively small percentage of a lubricating oil which is compatible with both the unit refrigerant and typical R-22 system design.
    Type: Grant
    Filed: July 6, 2020
    Date of Patent: May 31, 2022
    Assignee: R421A LLC
    Inventors: Kenneth M. Ponder, Steffan Thomas
  • Patent number: 11339314
    Abstract: To provide a composition for a heat cycle system comprising trifluoroethylene (HFO-1123), which has a low global warming potential and excellent cycle performance of HFO-1123 and which has high durability, and a heat cycle system employing the composition, which has less influence over global warming and has both high cycle performance and durability. A composition for a heat cycle system, which comprises a working fluid for heat cycle containing trifluoroethylene, and a radical scavenger, and a heat cycle system employing the composition for a heat cycle system.
    Type: Grant
    Filed: June 12, 2019
    Date of Patent: May 24, 2022
    Assignee: AGC Inc.
    Inventor: Hidekazu Okamoto
  • Patent number: 11312890
    Abstract: Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF?CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.
    Type: Grant
    Filed: April 19, 2021
    Date of Patent: April 26, 2022
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Barry Asher Mahler, Mario Joseph Nappa
  • Patent number: 11286409
    Abstract: Provided is a composition containing a refrigerant that has a refrigerating capacity equivalent to that of widely used R404A, and a low GWP. The composition contains a refrigerant that contains difluoromethane (R32), pentafluoroethane (R125), 1,1,1-trifluoroethane (R143a), and 1,1,1,2-tetrafluoroethane (R134a) in specific concentrations.
    Type: Grant
    Filed: December 7, 2018
    Date of Patent: March 29, 2022
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Mitsushi Itano, Hitomi Kuroki, Shun Ohkubo, Tatsumi Tsuchiya, Kenji Gobou
  • Patent number: 11266585
    Abstract: Cosmetic lipophilic composition comprising less than 20% by weight of an aqueous component and an oily component characterized in that the oily component comprises at least one ester selected from neopentylglycol dipelargonate, glycerol tripelargonate, pentaerythritol tetrapelargonate or mixtures thereof.
    Type: Grant
    Filed: September 7, 2016
    Date of Patent: March 8, 2022
    Assignee: NOVAMONT S.P.A.
    Inventors: Luigi Capuzzi, Francesca Digioia, Vanessa Bramati, Federica Carlomagno, Alessandra Cominetti
  • Patent number: 11225623
    Abstract: It is provided an ester for a refrigerator oil and of mixed alcohols and mixed monocarboxylic acids. The mixed alcohols include dipentaerythritol and tripentaerythritol in a mass ratio of 90/10 to 99.7/0.3, and the mixed monocarboxylic acids include n-pentanoic acid and 2-methyl butanoic acid in a mass ratio of 50/50 to 80/20. The ester has a kinematic viscosity of 50 to 150 mm2/s at 40° C.
    Type: Grant
    Filed: December 19, 2016
    Date of Patent: January 18, 2022
    Assignee: NOF CORPORATION
    Inventors: Takeshi Kajiki, Fumitaka Yoshikawa, Seita Ueda
  • Patent number: 11220620
    Abstract: Refrigerant compositions for an HVACR system that includes R1123, R32 and at least one more refrigerant. The refrigerant composition has a reduced GWP of about or less than 1500. Some of the refrigerant composition may be suitable for replacing R410A, R32, and/or R22. Methods for making the refrigerant composition including mixing an amount of R1123, and amount of R32, and an amount of at least one more refrigerant. Methods of retrofitting an existing refrigerant composition include adding an amount of at least one refrigerant to an existing refrigerant composition to produce a retrofitted refrigerant composition. The retrofitted refrigerant composition includes at least R1123 and R32.
    Type: Grant
    Filed: June 3, 2020
    Date of Patent: January 11, 2022
    Assignee: TRANE INTERNATIONAL INC.
    Inventors: Kenneth J. Schultz, Stephen A. Kujak
  • Patent number: 11142674
    Abstract: The present invention relates to a composition comprising: trifluoroethylene; pentafluoroethane; and at least one compound C chosen from the group constituted by difluoromethane, 1,1,1-trifluoropropene, trifluoroethane, 1,1,1,2-tetrafluoroethane, monofluoroethane, 1,1,1,4,4,4-hexafluorobut-2-ene, 3,3,4,4,4-pentafluorobut-1-ene, 2,4,4,4-tetrafluorobut-1-ene, 1,1,1,3,3-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 1,1,2,2-tetrafluoroethane, 1,1-difluoroethane, 1,1,1,3,3-pentafluorobutane, butane, 1,1,1,2,3,3,3-heptafluoropropane, 1-chlorotrifluoropropene, 2-methylbutane, pentane, propane, and mixtures thereof. The present invention also relates to the uses thereof in refrigeration, air conditioning and heat pumps.
    Type: Grant
    Filed: May 31, 2018
    Date of Patent: October 12, 2021
    Assignee: ARKEMA FRANCE
    Inventor: Wissam Rached
  • Patent number: 11130894
    Abstract: The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling to apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
    Type: Grant
    Filed: December 16, 2019
    Date of Patent: September 28, 2021
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Andrew Edward Feiring, Viacheslav A. Petrov, Barbara Haviland Minor, Mario Joseph Nappa, Nandini C. Mouli, Thomas Joseph Leck, Jon Lee Howell
  • Patent number: 11124685
    Abstract: The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.
    Type: Grant
    Filed: January 3, 2020
    Date of Patent: September 21, 2021
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Mario Joseph Nappa, Barbara Haviland Minor, Allen Capron Sievert
  • Patent number: 11085680
    Abstract: Compositions, methods, systems, and applications herein are directed to lubricant blends that balance solubility and viscosity of a refrigerant, where in some cases the lubricant blends herein help reduce solubility of a refrigerant. A lubricant blend includes a mixture of two or more different types of lubricants to reduce refrigerant solubility.
    Type: Grant
    Filed: April 6, 2020
    Date of Patent: August 10, 2021
    Assignee: TRANE INTERNATIONAL INC.
    Inventors: Julie A. Majurin, Daniel A. Strange, Daryl Dean Steinke
  • Patent number: 11072734
    Abstract: A composition for a heat cycle system and a heat cycle system employing the composition are provided. The composition has favorable lubricating properties and contains a working fluid for heat cycle and a refrigerant oil. The working fluid has a low global warming potential and can replace R410A. The working fluid contains an unsaturated fluorinated hydrocarbon compound having a specific structure. The refrigerant oil has a breakdown voltage of at least 25 kV, a hydroxyl value of at most 0.1 mgKOH/g, and a kinematic viscosity at 40° C. of from 5 to 200 mm2/s and a kinematic viscosity at 100° C. of from 2 to 30 mm2/s.
    Type: Grant
    Filed: June 26, 2019
    Date of Patent: July 27, 2021
    Assignee: AGC Inc.
    Inventors: Masato Fukushima, Hiroaki Mitsuoka, Mai Tasaka, Daisuke Shirakawa, Hirokazu Takagi, Takeaki Arai
  • Patent number: 11046875
    Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.
    Type: Grant
    Filed: October 30, 2019
    Date of Patent: June 29, 2021
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Barbara Haviland Minor, Velliyur Nott Mallikarjuna Rao
  • Patent number: 11046876
    Abstract: The present invention relates to fluoroolefin compositions. The fluoroolefin compositions of the present invention are useful as refrigerants or heat transfer fluids and in processes for producing cooling or heat. Additionally, the fluoroolefin compositions of the present invention may be used to replace currently used refrigerant or heat transfer fluid compositions that have higher global warming potential.
    Type: Grant
    Filed: July 8, 2020
    Date of Patent: June 29, 2021
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Mario Joseph Nappa, Barbara Haviland Minor, Allen Capron Sievert
  • Patent number: 11034872
    Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.
    Type: Grant
    Filed: October 30, 2019
    Date of Patent: June 15, 2021
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Barbara Haviland Minor, Velliyur Nott Mallikarjuna Rao
  • Patent number: 11028300
    Abstract: A refrigerant composition includes R125 (pentafluoroethane), R134a (1,1,1,2-tetrafluoroethane), R600a (isobutane) and a polyol ester (POE) lubricant. In one exemplary embodiment, the refrigerant includes about 53-57 wt % R125, about 40-44 wt % R134a, about 1-5 wt % R600a and no more than about 1 wt % POE. In another embodiment, the refrigerant composition includes about 54-56% R125, about 41-43 wt % R134a, about 2-4% R600a and about 0.3-0.7 wt % POE. In yet another embodiment, the refrigerant composition includes about 54.63 wt % R125, about 41.72 wt % R134a, about 2.98 wt % R600a and about 0.67 wt % POE. Manufacturing the refrigerant composition includes charging a vessel with about 53-57 wt % R125, about 44 wt % R134a, about 1-5 wt % R600a to form as 100 wt % charge, and then injecting no more than about 1 wt % POE.
    Type: Grant
    Filed: September 16, 2020
    Date of Patent: June 8, 2021
    Inventors: David L. Couchot, Sankara N. Ramanan
  • Patent number: 11008496
    Abstract: This pertains to the technical field of lubricants, and particularly relates to a composition for preparing a wear-resistant drilling fluid lubricant, a preparation method of the wear-resistant drilling fluid lubricant and a drilling fluid. Vegetable oil, nanometer calcium borate, an ether compound and an amine compound may be used as raw materials to prepare drilling fluid lubricant with excellent abrasion resistance by reasonably controlling dosages of the raw materials. The lubricant provided can improve wear resistance, lubricating property, and high temperature resistance of bentonite slurry and water-based drilling fluid.
    Type: Grant
    Filed: November 14, 2019
    Date of Patent: May 18, 2021
    Assignees: YANGTZE UNIVERSITY, JINGZHOU JIAHUA TECHNOLOGY CO., LTD., CNPC RESEARCH INSTITUTE OF SAFETY AND ENVIRONMENTAL TECHNOLOGY CO., LTD.
    Inventors: Mingbiao Xu, Fuchang You, Xingchun Li, Jiao Wu, Shanshan Hou, Man Shu
  • Patent number: 10988653
    Abstract: Provided is a lubricating oil composition for a refrigerator which uses a base oil including as the main component at least one kind of oxygen-containing compounds selected from polyoxyalkylene glycols, polyvinyl ethers, copolymers of poly(oxy)alkylene glycols or monoethers thereof and polyvinyl ethers, polyol esters, and polycarbonates. The lubricating oil composition for a refrigerator is used for a refrigerator that uses, as a refrigerant, a fluorine-containing organic compound, which is a refrigerant applicable to current car air conditioner systems or the like and has a specific polar structure, and has favorable sealing property, a low coefficient of friction factor in a sliding part, and excellent stability as well as excellent compatibility with the refrigerant.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: April 27, 2021
    Assignee: IDEMITSU KOSAN CO., LTD.
    Inventor: Masato Kaneko
  • Patent number: 10988651
    Abstract: Embodiments are described herein to provide refrigerant and/or refrigerant composition that is suitable for providing lubrication to, for example, moving parts of a chiller system. Embodiments are also described herein to provide an additive, such as a corrosion inhibitor and/or stabilizers, that can be added to the refrigerant to form refrigerant compositions that is suitable for providing lubrication to, for example, moving parts of a chiller system.
    Type: Grant
    Filed: January 11, 2019
    Date of Patent: April 27, 2021
    Assignee: TRANE INTERNATIONAL INC.
    Inventor: Stephen Anthony Kujak
  • Patent number: 10976079
    Abstract: A compressor including a refrigerant and a lubricant, wherein the lubricant comprises at least one compound selected from the group consisting of a mono-tertiary amine, a di-tertiary amine, a tri-tertiary amine, and a tetra-tertiary amine.
    Type: Grant
    Filed: April 30, 2019
    Date of Patent: April 13, 2021
    Assignee: Emerson Climate Technologies, Inc.
    Inventors: Louis Rebrovic, Kyaw Wynn
  • Patent number: 10954467
    Abstract: The invention relates to the use of a composition comprising a polyol ester-based lubricant and a refrigerant F comprising at least one tetrafluoropropene and at least one hydrofluorocarbon, in a heat transfer system containing a vapour compression circuit comprising an oil separator.
    Type: Grant
    Filed: October 9, 2017
    Date of Patent: March 23, 2021
    Assignee: ARKEMA FRANCE
    Inventor: Wissam Rached
  • Patent number: 10899690
    Abstract: The invention relates to a method for purifying 1,1,1,2,2-pentafluoropropane (245cb) using a first composition comprising 1,1,1,2,2-pentafluoropropane and at least one of the compounds selected from the group consisting of 1,1-difluoroethane (152a), 1,1,1,2-tetrafluoroethane (134a), trans-1,3,3,3-tetrafluoro-1-propene (1234ze-E), cis-1,3,3,3-tetrafluoro-1-propene (1234ze-Z), trans-1,2,3,3,3-pentafluoropropene (1225ye-E), cis-1,2,3,3,3-10 pentafluoropropene (1225ye-Z) and 3,3,3-trifluoropropene (1243zf), said method comprising the steps of: a) bringing said first composition into contact with at least one organic extraction agent in order to form a second composition; b) extractive distillation of said second composition in order to form i) a third composition comprising said organic extraction agent and said at least one of the compounds selected from the group consisting of 1,1-difluoroethane (152a), 1,1,1,2-tetrafluoroethane (134a), trans-1,3,3,3-tetrafluoro-1-propene (1234ze-E), cis-1,3,3,3-tetrafluoro-1-p
    Type: Grant
    Filed: December 14, 2016
    Date of Patent: January 26, 2021
    Assignee: Arkema France
    Inventors: Abdelatif Baba-Ahmed, Bertrand Collier, Dominique Deur-Bert, Laurent Wendlinger
  • Patent number: 10815174
    Abstract: A storage method of HCFO-1233zd (Z) according to an embodiment of the present invention, includes using a storage container having a liquid-contact portion thereof. The liquid-contact portion is formed of a material selected from the group consisting of epoxy-phenolic resin, phenolic resin, phenolic-butyral resin, stainless steel, iron phosphate, zinc phosphate and glass.
    Type: Grant
    Filed: January 31, 2019
    Date of Patent: October 27, 2020
    Assignee: CENTRAL GLASS COMPANY, LIMITED
    Inventors: Naoto Takada, Masahiko Tani, Hideaki Imura, Koji Ueda, Yoshio Nishiguchi, Fuyuhiko Sakyu
  • Patent number: 10781152
    Abstract: Various compositions, including particularly aerosol compositions, containing fluorinated olefins, including particularly tetra- and penta-fluorpropenes, in a variety of applications are disclosed.
    Type: Grant
    Filed: September 21, 2017
    Date of Patent: September 22, 2020
    Assignee: HONEYWELL INTERNATIONAL INC.
    Inventors: Rajiv R. Singh, Hang T. Pham, Ian Shankland
  • Patent number: 10759920
    Abstract: The present disclosure relates to compositions comprising E-1,1,1,4,4,4-hexafluoro-2-butene and additional compounds that may be useful as refrigerants, heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, power cycle working fluids, extinguishing agents, and fire suppression agents in liquid or vapor form, and in methods for detecting leaks.
    Type: Grant
    Filed: February 3, 2016
    Date of Patent: September 1, 2020
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Mario Joseph Nappa, Xuehui Sun, Ivan Sergeyevich Baldychev, Sheng Peng, Konstantinos Kontomaris, Barbara Haviland Minor, Joseph Anthony Creazzo
  • Patent number: 10731065
    Abstract: The present invention provides a haloolefin-based composition comprising a highly-stable haloolefin in which decomposition and oxidization are inhibited, and the haloolefin-based composition being used for at least one application selected from the group consisting of heat transfer media, refrigerants, foaming agents, solvents, cleaning agents, propellants, and fire extinguishers. The present invention relates to a haloolefin-based composition comprising a haloolefin and water and being used for at least one application selected from the group consisting of heat transfer media, refrigerants, foaming agents, solvents, cleaning agents, propellants, and fire extinguishers. The haloolefin-based composition comprising a haloolefin and water is used for at least one application selected from the group consisting of heat transfer media, refrigerants, foaming agents, solvents, cleaning agents, propellants, and fire extinguishers.
    Type: Grant
    Filed: February 29, 2016
    Date of Patent: August 4, 2020
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Kazuhiro Takahashi, Tatsumi Tsuchiya, Yasufu Yamada
  • Patent number: 10723926
    Abstract: The present invention provides a working fluid composition for a refrigerating machine containing: a refrigerating machine oil containing: a first ester that is a polyol ester of dipentaerythritol and at least one fatty acid selected from fatty acids having 4 to 10 carbon atoms, and has a kinematic viscosity at 100° C. of 7.0 mm2/s or more; and a second ester that is a complex ester of a polyhydric alcohol containing at least one selected from neopentyl glycol, trimethylolpropane and pentaerythritol, a polybasic acid having 6 to 12 carbon atoms, and a monohydric alcohol having 4 to 18 carbon atoms or a fatty acid having 4 to 18 carbon atoms; and a refrigerant containing difluoromethane.
    Type: Grant
    Filed: July 26, 2016
    Date of Patent: July 28, 2020
    Assignee: JXTG NIPPON OIL & ENERGY CORPORATION
    Inventors: Takeshi Okido, Hiroko Shimpo, Yuya Mizutani, Hidetoshi Ogata
  • Patent number: 10705582
    Abstract: A freezer power calculation unit calculates power consumption Wc of a freezer, based on a heat exchanging amount Q of an electronic device and a performance coefficient COP_c of the freezer. An apparatus performance coefficient calculation unit calculates an apparatus performance coefficient ACOP, based on a calorific value Q of the electronic device, Wc, and power consumption Wf of an air conditioning blower unit. Note that the apparatus performance coefficient ACOP is a performance coefficient of an apparatus including an evaporator, a condenser, a heat exchanger, the freezer, and the air conditioning blower unit. A blower rotational speed control unit controls a rotational speed r of the air conditioning blower unit, based on the apparatus performance coefficient ACOP. A coolant temperature control unit controls a first coolant temperature Tin being a temperature of coolant COO flowing from the freezer, based on the apparatus performance coefficient ACOP.
    Type: Grant
    Filed: March 23, 2017
    Date of Patent: July 7, 2020
    Assignee: NEC CORPORATION
    Inventor: Masanori Sato
  • Patent number: 10683443
    Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.
    Type: Grant
    Filed: May 31, 2018
    Date of Patent: June 16, 2020
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Barbara Haviland Minor, Velliyur Nott Mallikarjuna Rao