Heat Value Of Combustion (e.g., 'calorific Value') Patents (Class 374/36)
  • Patent number: 11474092
    Abstract: A method for determining properties of a hydrocarbon-containing gas mixture includes determining a thermal conductivity value, density measurement, viscosity measurement, and temperature and pressure. The method also includes determining a hydrogen content of the gas mixture on the basis of the thermal conductivity value and the temperature and pressure, determining a density measurement and associated temperature and pressure, and determining the mean molar mass or standard density on the basis of the density measurement and the temperature and pressure. The method further includes determining the mean molar mass or standard density of a hydrogen-free residual gas mixture based on the mean molar mass or standard density and the hydrogen fraction, determining the Wobbe index of the residual gas mixture based on the viscosity measurement and the temperature and pressure, and determining a calorific value based on the mean molar mass or standard density and the Wobbe index.
    Type: Grant
    Filed: October 10, 2017
    Date of Patent: October 18, 2022
    Assignee: ENDRESS+HAUSER FLOWTEC AG
    Inventors: Christof Huber, Patrick Reith, Anastasios Badarlis
  • Patent number: 10674866
    Abstract: Embodiments are directed to smoking food in an outdoor grill using a customized smoking routine. In one scenario, an electronic controller of an outdoor grill receives an input to initiate smoke generation according to a specified smoke generation pattern, including: adding a specified amount of combustible pellets to a combustion area within the outdoor grill, such that the combustible pellets begin to burn, measuring a current internal temperature of the outdoor grill and, if below a threshold value, adding a specified amount of additional combustible pellets to the combustion area sufficient to raise the temperature to another threshold value, allowing the internal temperature to cool a temperature below the first threshold value and, upon determining that the temperature of the outdoor grill has cooled below the first specified threshold value, adding additional combustible pellets to the combustion area sufficient to raise the temperature to at least the second threshold value.
    Type: Grant
    Filed: June 24, 2016
    Date of Patent: June 9, 2020
    Assignee: Traeger Pellet Grills LLC
    Inventor: Michael Colston
  • Patent number: 10671202
    Abstract: An apparatus and method for measuring a manual force that uses a pad that simulates human or animal body tissue and a sensor configured to receive the force. The pad can have the shape of a body part and can have different materials that have different hardnesses. The apparatus can have interchangeable pads and identify individual users for training purposes, such as for training massage therapists. The apparatus can indicate whether an applied force is within a predetermined range. Also a method of defining a standard or protocol for training and/or performing touch manipulations by applying a range force to one or more persons with an algometer and establishing a protocol based on data obtained from biosensors attached to the person in order to determine which forces produce a desired effect, such as a reflexive, mechanical, or relaxation effect. The apparatus can then be used to train a provider on how to follow the standard or protocol.
    Type: Grant
    Filed: April 25, 2018
    Date of Patent: June 2, 2020
    Assignee: Mendology, Inc.
    Inventors: Sarah E. Komala, Eric M. Komala
  • Patent number: 10161909
    Abstract: A system and method for substantially coincidental sample takeoff flow rate verification which detects unstable flow conditions in a pipeline, terminates fluid sample analysis during flow instability, and resumes sample takeoff when a steady flow state is re-established.
    Type: Grant
    Filed: October 19, 2016
    Date of Patent: December 25, 2018
    Assignee: Mustang Sampling LLC
    Inventors: Kevin Warner, Kenneth O. Thompson
  • Patent number: 9886533
    Abstract: A system is provided. The system comprises a computer system comprising at least one processor, a thermodynamic state solver application, and a thermodynamic system solver application. When executed by the at least one processor, the thermodynamic state solver application computes a flash equilibrium state solution for each of a plurality of nodes in a thermodynamic network and determines for each of the plurality of nodes at least one sensitivity of a first thermodynamic property with reference to at least one second thermodynamic property. When executed by the at least one processor, the thermodynamic system solver computes a pressure at each of the nodes and flows between the nodes based at least in part on the sensitivities, wherein a result based on the pressures and flows is determined.
    Type: Grant
    Filed: July 6, 2015
    Date of Patent: February 6, 2018
    Assignee: Schneider Electric Software, LLC
    Inventor: Ian H. Boys
  • Patent number: 9857321
    Abstract: The invention relates to a device (1) for determining the combustion value of a fuel. The device (1) comprises a fuel inlet (40) for supplying the fuel to be measured to the device (1). A gas inlet (50) is provided for supplying an oxygen-containing gas to the device (1). The device (1) further comprises a combustion unit connected to the fuel inlet (40) and the gas inlet (50), which combustion unit is provided with a combustion chamber (7) for combusting the fuel to be measured therein. A gas outlet (8) connected to the combustion chamber (7) makes it possible to discharge the combusted gas. The device (1) according to the invention comprises a flow measurement unit (14), preferably of the Coriolis type, disposed between the fuel inlet (40) and the combustion chamber (7).
    Type: Grant
    Filed: December 24, 2013
    Date of Patent: January 2, 2018
    Assignee: BERKIN B.V.
    Inventors: Joost Conrad Lötters, Theodorus Simon Josef Lammerink, Remco John Wiegerink, Albertus Johannes Mouris, Marco Gábor Pap, Meint Jelle De Boer, Remco Gerardus Petrus Sanders
  • Patent number: 9752519
    Abstract: A method of controlling an exhaust gas recirculation system of an internal combustion engine is disclosed. The engine includes a compressor, an intake manifold, an after-treatment system, a low pressure EGR system and a high pressure EGR system. The method temporarily adjusts a low pressure EGR ratio, keeping constant a total EGR rate, after verifying at least one among compressor parameters, after-treatment system parameters or intake manifold parameter.
    Type: Grant
    Filed: October 16, 2014
    Date of Patent: September 5, 2017
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Alberto Vassallo, Stefano Pellegrino, Salvatore Sannino
  • Patent number: 8931950
    Abstract: In one aspect, provided herein is a single crystal silicon microcalorimeter, for example useful for high temperature operation and long-term stability of calorimetric measurements. Microcalorimeters described herein include microcalorimeter embodiments having a suspended structure and comprising single crystal silicon. Also provided herein are methods for making calorimetric measurements, for example, on small quantities of materials or for determining the energy content of combustible material having an unknown composition.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: January 13, 2015
    Assignee: The Board of Trustees of the University of Illinois
    Inventors: William P. King, Jungchul Lee
  • Patent number: 8903662
    Abstract: There is disclosed a method for determining the heating value of a fuel, the fuel comprising at least one hydrocarbon including a first hydrocarbon present in the highest molar concentration, the method comprising: measuring the stoichiometric oxidation molar flow ratio of the fuel; determining the ideal molar heating value (HVm,i) from the measured stoichiometric oxidation molar flow ratio; measuring the molar concentration of the first hydrocarbon; and determining the real molar heating value (HVm,r) from the ideal molar heating value (HVm,i) and the molar concentration of the first hydrocarbon. An apparatus is also disclosed.
    Type: Grant
    Filed: October 24, 2008
    Date of Patent: December 2, 2014
    Assignee: ANU-BIZ BVBA
    Inventors: Johan Bats, Floris J. J. Huijsmans
  • Patent number: 8888361
    Abstract: A calorific value measuring system, includes a gas flowing in a pipe; the flow rate controlling device; a temperature measuring element in the pipe; a heater element, in the pipe, producing a plurality of temperatures; a measuring portion measuring a value from a temperature measuring element that is dependent on the temperature of the gas, and a value from the heater element at each of a plurality of temperatures; an equation storage device storing a calorific value equation using values from the temperature measuring element and values from the heater element at the plurality of temperatures as independent variables and uses the calorific value as the dependent variable; and a calorific value portion calculating a value for the calorific value of a gas through substituting a value from the temperature measuring element and a value from the heater element into the independent variables of the calorific value equation.
    Type: Grant
    Filed: May 2, 2012
    Date of Patent: November 18, 2014
    Assignee: Azbil Corporation
    Inventor: Yasuharu Ooishi
  • Publication number: 20140226694
    Abstract: A method for estimating a heating value of a biological material is disclosed. The method comprises: correlating amounts of radiation transmitted through a number of different reference materials, said radiation being electromagnetic radiation of at least two energy levels, with heating values for said reference materials obtained by calorimeter measurements; irradiating the biological material (102) with electromagnetic radiation of said at least two different energy levels;and measuring the amount of radiation (109a-c) transmitted through said biological material at said energy levels. The method further comprises determining, for each energy level, a transmission value through the biological material based on the radiation through said biological material; and determining, based on said determined transmission values and said correlation, an estimate of the heating value of said biological material. A corresponding apparatus (100) is also disclosed.
    Type: Application
    Filed: June 28, 2012
    Publication date: August 14, 2014
    Applicant: MANTEX AB
    Inventors: Ragnar Kullenberg, Fredrik Danielsson, Eric Landstrom
  • Patent number: 8800394
    Abstract: A transportable Sample Apparatus includes a vacuum flask (Dewar flask) and integral sample container. The Sample Apparatus may be used to capture a liquid phase LNG sample at a custody transfer point and to transport the sample to a laboratory for analysis. Vaporization of the liquid phase sample may take place at a variety of different locations. For example, vaporization may begin and/or be completed during transport from the collection point to the laboratory. In another example, vaporization may begin and be completed in the laboratory. In yet another example vaporization may begin during transport and be completed at the laboratory. The gas phase sample is typically analyzed by a gas chromatograph for Btu content, among other things. Prior to capture of the sample, the Sample Apparatus goes through a pre-cool cycle to chill a sample end cap and other components to a temperature compatible with capture of a cryogenic liquid sample which is about ?250° F.
    Type: Grant
    Filed: April 19, 2011
    Date of Patent: August 12, 2014
    Assignee: Welker, Inc.
    Inventors: Michael A. Bombulie, Tracy D. Peebles
  • Publication number: 20140119400
    Abstract: A sample stream of the gas to be analyzed is fed into a combustor. The combustor mixes the gas with ambient air to an over-stoichiometric oxygen content and combusts the sample gas completely. A respective TDLS analyzer measures the CO2 and/or H2O concentration of the combustor's flue gas. In case that the sample gas contains relevant concentrations of CO2 and/or H2O, a second TDLS CO2 and/or H2O analyzer may be added which measures the CO2 and/or or H2O concentration upstream of the combustor. The measurement of methane and ethane or other hydrocarbon and mixtures thereof is also possible. The method and device allows the measurement of the heating value and/or the total organic carbon of a natural gas with high temporal resolution.
    Type: Application
    Filed: October 25, 2012
    Publication date: May 1, 2014
    Applicant: AXETRIS AG
    Inventors: Brian KINKADE, Joe GREGORIA
  • Publication number: 20140079090
    Abstract: A combustion calorimeter (1) has a housing (6) and therein a detachably mounted decomposition vessel (2) with sample holder (11) and ignition apparatus (12) in its reaction chamber (3). The wall (4) of the decomposition vessel (2) and also the upper decomposition wall (5) here have in the vertical use position a wall thickness that increases from the bottom to the top in order to conduct the heat generated in a combustion process if possible into the upper region of the decomposition vessel (2), where also at least one temperature sensor (7) can be arranged. Owing to the increase in thickness of the delimitation of the internal or reaction space (3), the heat can be distributed therein more favourably.
    Type: Application
    Filed: April 19, 2012
    Publication date: March 20, 2014
    Applicant: IKA - Werke GmbH & Co. KG
    Inventor: Hubert Pinhack
  • Patent number: 8613545
    Abstract: The present invention describes a scan adiabatic resistive calorimeter (SARC) 1 with ohm heating of the sample 20, which measures the heating enthalpy and is formed of an inner cylinder 11 and a couple of pistons 15 and 16, thus forming said elements a cylindrical chamber hermetically closed 10, which avoids that during its operation can be material losses by leaks. Pistons 15 and 16 have, in one of their ends an electrode 31 and 36 respectively and they pass the electrical heating flow through the sample 20. In reference to this electric flow, the applied power is calculated and therefore, the supplied heat to the sample 20, which is equal to the specific enthalpy. To assure that the whole of the electric flow is conducted through the sample 20, the inner cylinder 11 is electrically isolated.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: December 24, 2013
    Assignee: Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional
    Inventors: Alberto Herrera Gómez, José Martín Yáñez Limón, Guadalupe Barreiro Rodríguez, Carlos Alberto Contreras Servín
  • Patent number: 8563320
    Abstract: A use composition monitor determines the concentration of peracid and/or peroxide in a use composition using a kinetic assay procedure. A sample mixture containing a sample of the use composition, a diluent and at least one reagent is prepared and analyzed using, for example, an optical detector. A reduced-turbulence optical detector can be used to improve collected response data. A reduced-turbulence optical detector can include a cell body disposed about a length of transparent tubing. The cell body positions one or more emitter/receiver pairs about the transparent tubing. Thus, tube junctions are eliminated and sample flow within the tube is substantially turbulence free.
    Type: Grant
    Filed: February 15, 2012
    Date of Patent: October 22, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Eugene Tokhtuev, Christopher Owen, Anna Pilipchenko, Paul Schilling, Daniel Kamben
  • Publication number: 20130259084
    Abstract: A calorific value measuring system having a container filled with a mixed gas to be measured; a microchip includes a heating element producing heat at a plurality of heat producing temperatures, disposed within the container; a measuring portion measuring a value of an electric signal from the heating element contacting the mixed gas being measured, at each of the plurality of heat producing temperatures; an equation storage device storing a calorific value calculating equation that has, for independent variables, the electric signals from the heating element at the plurality of heat producing temperatures and, as the dependent variable, the calorific value; and a calorific value calculating portion calculating the value of the calorific value of the mixed gas being measured by substituting the measured values for the electric signal from the heating element into the independent variables in the calorific value calculating equation.
    Type: Application
    Filed: January 11, 2013
    Publication date: October 3, 2013
    Applicant: AZBIL CORPORATION
    Inventor: Yasuharu OOISHI
  • Publication number: 20120297788
    Abstract: A method of determining an exit temperature of a gas exiting a combustor of a gas turbine includes determining a mass flow and a temperature of fuel being delivered to the combustor; determining a mass flow and a temperature of air being delivered to the combustor, determining a temperature dependence of the specific heat capacity of a burnt mixture of the fuel and the air being delivered to the combustor; and determining an exit temperature of the burnt mixture exiting the combustor. The exit temperature is determined based on the determined mass flow and temperature of the fuel, the determined mass flow and temperature of the air, and the determined temperature dependence of the specific heat capacity of the burnt mixture.
    Type: Application
    Filed: December 29, 2010
    Publication date: November 29, 2012
    Inventor: Vili Panov
  • Patent number: 8272779
    Abstract: A calorimeter which includes a casing in which a sample is combusted, a jacket around the casing, and temperature sensors in an outer surface of the jacket.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: September 25, 2012
    Inventor: John Anthony Bonnard
  • Patent number: 8143070
    Abstract: A use composition monitor determines the concentration of peracid and/or peroxide in a use composition using a kinetic assay procedure. A sample mixture containing a sample of the use composition, a diluent and at least one reagent is prepared and analyzed using, for example, an optical detector. A reduced-turbulence optical detector can be used to improve collected response data. A reduced-turbulence optical detector can include a cell body disposed about a length of transparent tubing. The cell body positions one or more emitter/receiver pairs about the transparent tubing. Thus, tube junctions are eliminated and sample flow within the tube is substantially turbulence free.
    Type: Grant
    Filed: February 12, 2009
    Date of Patent: March 27, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Eugene Tokhtuev, Christopher Owen, Anna Pilipchenko, Paul Schilling, Daniel Kamben
  • Publication number: 20100316087
    Abstract: A calorimeter (1) with a decomposition chamber (3) with a combustion chamber (2), in which a receiving device (4) for a sample, an ignition device (5), and at least one supply line (6) for oxygen are provided. The decomposition chamber (3) is surrounded by a liquid or water jacket (7) into which at least one temperature sensor (8) extends. The liquid or water jacket (7) is surrounded by an outer container (9), which is a pressure container and which absorbs pressure generated during the combustion of a sample in the decomposition chamber (3) at the walls (10) thereof as a result of a tight sliding fit (15) by way of the water or the incompressible liquid. The decomposition chamber (3) therefore has an accordingly thin wall so that the heat generated during combustion of a sample can reach the temperature sensor or sensors (8) quickly.
    Type: Application
    Filed: November 20, 2008
    Publication date: December 16, 2010
    Applicant: IKA-WERKE GMBH & CO. KG
    Inventor: Hubert Pinhack
  • Publication number: 20100303125
    Abstract: A calorimeter which includes a casing in which a sample is combusted, a jacket around the casing, and temperature sensors in an outer surface of the jacket.
    Type: Application
    Filed: May 28, 2010
    Publication date: December 2, 2010
    Inventor: John Anthony BONNARD
  • Publication number: 20100258223
    Abstract: The present invention relates to a process for determining the sensitive or insensitive nature of a crystalline hexogen. Said process comprises: the formulation of said crystalline hexogen in a matrix; the analysis of a sample of said matrix charged with said crystalline hexogen by differential scanning calorimetry; said matrix consisting essentially of at least one liquid polymer that is suitable for the formulation of binders for energetic materials charged with nitro organic explosives; and of at least one adsorbent for the volatile organic compounds, which is stable at the operating temperature of the analysis and which has low affinity for water. The present invention also relates to the crystalline hexogen in such a matrix.
    Type: Application
    Filed: June 5, 2008
    Publication date: October 14, 2010
    Applicant: EURENCO
    Inventors: Christian Spyckerelle, Genevieve Eck, Jean Guillaumin
  • Patent number: 7488106
    Abstract: An automated apparatus for determining the calorific value of combustible substances employs an integrated, isothermal water reservoir to reduce the complexity of the apparatus and facilitates automation of the calorimeter by providing a convenient source of isothermal water. A moving divider is used to reconfigure the isothermal water reservoir to either provide for temperature equilibration prior to sample analysis or define a fixed volume of water during analysis in which high precision temperature measurements can be recorded. The apparatus includes mechanisms for controlling the moving divider, a sample holding combustion vessel, and loading, cleaning, and unloading the combustion vessel. This eliminates key analysis steps that had previously required manual intervention by an operator.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: February 10, 2009
    Assignee: Leco Corporation
    Inventor: Kevin R. Brushwyler
  • Publication number: 20090034580
    Abstract: The invention provides a method for measuring the heat release rate of a flame retardardant compound in a microscale combustion calorimeter.
    Type: Application
    Filed: July 30, 2008
    Publication date: February 5, 2009
    Inventors: Thomas S. Lin, Jeffrey Morris Cogen
  • Patent number: 7481575
    Abstract: A calorimeter includes a bucket cover which is used to reconfigure an isothermal water reservoir to provide for temperature equilibration prior to sample analysis and subsequently define a fixed volume of water during analysis in which high precision temperature measurements can be recorded. The apparatus includes mechanisms for sealing and controlling the cover, and for coupling the combustion vessel to the cover while minimizing the thermal contact between them. Improved thermal isolation between the fixed volume of water and the surrounding environment is also achieved.
    Type: Grant
    Filed: June 21, 2007
    Date of Patent: January 27, 2009
    Assignee: Leco Corporation
    Inventors: Kevin R. Brushwyler, John T. Hoss, Octavio R. Latino
  • Patent number: 7399118
    Abstract: The invention relates to a method and a device for measuring a gas consumption by means of a gas meter. A gas meter with thermal mass flow sensor for determining mass flow signals (SM) and with a calibration as energy meter for outputting energy value signals (SE) is known. According to the invention, a gas type is determined by the gas meter insofar as combustible and non-combustible gas mixtures are differentiated. The gas meter is operated, in the case of a non-combustible gas mixture, with calibration in mass or standard volume units (I/min) and, in the case of a combustible gas mixture, with calibration in energy units (kWh). Embodiments concern inter alia: measurement of a gas parameter (?, ?, c, ?) of the gas or determining the gas type; gas quality sensor with an identical construction to thermal flow sensor; measuring intervals lengthened in the case of non-combustible gas and shortened in the case of combustible gas.
    Type: Grant
    Filed: July 22, 2003
    Date of Patent: July 15, 2008
    Assignee: EMS-Patent AG
    Inventors: Daniel Matter, Rolf Luchsinger, Beat Kramer, Bruno Sabbattini
  • Patent number: 7246938
    Abstract: A heating value meter for gases has an outer cylindrical mantle with an outer thermostatic heating apparatus and at least one inlet for introduction of air and at least one inlet for introduction of test or calibration gas. The outer mantle has an outer heating mantle and a bottom part containing an outer sensor of the outer thermostatic apparatus. A cylindrical measuring block is located coaxially inside the outer mantle and is equipped with an axially inserted internal sensor of an electrical remote thermometer of an internal thermostatic apparatus. The heating mantle, the outer sensor, an electrical heating block and an internal sensor, are interconnected via the outer and internal thermostatic apparatus and are adjusted for maintaining a constant temperature by regulation of the electrical input to the electrical heating block, or by the input to the heating mantle where, in addition, the measuring apparatus is connected by an electric lead to the electrical heating block.
    Type: Grant
    Filed: November 11, 2003
    Date of Patent: July 24, 2007
    Assignees: RWE Transgas Net, S.R.O., Jiri Sevcik
    Inventor: Jirí Śevćík
  • Patent number: 7048434
    Abstract: Thermally analysis of layers and multiple layer structures used in the semiconductor processing arts is disclosed. A modulated calorimetric analysis may be used to determine a thermal signature that characterizes the chemical properties of a sample of material. The signature may include one or more thermal properties such as heat capacities. The signature may be used to compare and infer the suitability of a material for use in an integrated circuit manufacturing process. A thermal signature for a material that is not known to be suitable for manufacturing integrated circuits may be compared with a thermal signature for a standard material that is known to be suitable in order to determine whether the aforementioned material is suitable. Multiple layer structures may also be analyzed, compared, and inferred, and approaches for determining thermal signatures for any individual layer of the multiple layer structure are disclosed.
    Type: Grant
    Filed: September 17, 2002
    Date of Patent: May 23, 2006
    Assignee: Intel Corporation
    Inventors: Alex Tregub, Mansour Moinpour, David Fryer
  • Patent number: 6939001
    Abstract: An embodiment of the invention is disclosed that relates to a mechanism for passing a rigid medium under an image-forming mechanism. The mechanism includes a conveyor belt and a number of rollers. The rigid medium travels on the conveyor belt under the image-forming mechanism, for image formation on the rigid medium. The rollers move the conveyor belt.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: September 6, 2005
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Marius Buibas
  • Publication number: 20040028112
    Abstract: A micro-calorimeter apparatus comprises a thermostated housing (3,4,5); a pair of essentially flat heat sinks (9,10), suspended in said housing (2) and thermally floating relative to the environment inside the housing (3,4,5). The heat sinks (9,10) are arranged with their surfaces facing each other. A pair of Peltier elements (11) are thermally attached to said heat sinks (9,10), one element (11) on each heat sink (9,10), on said facing surfaces, forming a gap between them for the accommodation of a generally flat biosensor unit (12).
    Type: Application
    Filed: August 20, 2003
    Publication date: February 12, 2004
    Inventors: Thomas Carlsson, Kjell Rosengren
  • Patent number: 6551094
    Abstract: A method for determining a soot charge in a combustion chamber includes measuring a spatial distribution of at least one parameter characteristic of a combustion by monitoring a flame in the combustion chamber. The at least one parameter allows a conclusion concerning a soot charge in the combustion chamber during operation and the at least one parameter is a temperature and/or a carbon monoxide content. The soot charge is determined based on the measuring step and by using a comparison with given conversion curves. A device for determining a soot charge in a combustion chamber is also provided.
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: April 22, 2003
    Assignee: Siemens Aktiengesellschaft
    Inventors: Felix Fastnacht, Thomas Merklein
  • Patent number: 6536946
    Abstract: The invention concerns a device (10) for measuring calorific energy contained in a fuel gas transported in a pipe (16) comprising a gas meter (12) measuring a volume V in pressure conditions P and temperature conditions T of a gas circulating in said pipe and an apparatus (14;52;63) to determine the gas calorific power H. The invention is characterized in that said apparatus for determining calorific power measures at least one physical variable proportional to the number of molecules of the gas different constituents in a given volume and is placed as near as possible to the gas meter so as to determine the calorific power H(P,T) in similar pressure P and temperature T conditions as those wherein the gas volume V(P,T) is measured, said device then determining the calorific energy H(P,T) V(P,T) contained in the gas.
    Type: Grant
    Filed: September 8, 2000
    Date of Patent: March 25, 2003
    Assignee: Schlumberger Industries, S.A.
    Inventors: Benoit Froelich, Didier Dominguez
  • Patent number: 6517237
    Abstract: An energy meter which measures a volume of gas supplied, which measures a calorific value of the gas supplied, and which calculates an energy value corresponding to the measured volume of gas supplied and the calorific value. The structure to measure the volume of the gas supplied and to calculate the energy value may be provided in a single unit. The structure to measure the calorific value of the gas supplied preferably includes a structure to measure the speed of sound in the gas and further preferably measures a first thermal conductivity of the gas at a first temperature and measures a second thermal conductivity of the gas at a second temperature which differs from the first temperature, and is arranged to produce the calorific value of the gas corresponding to the measured speed of sound in the first and second thermal conductivities.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: February 11, 2003
    Assignee: Lattice Intellectual Property Limited
    Inventors: Paul Steven Hammond, Robert Richard Thurston, Barry Leonard Price
  • Patent number: 6490908
    Abstract: The invention relates to a method and a device to determine the gas properties of combustible gas, in particular of natural gas, wherein a) at least part of the combustible gas is exposed to infrared radiation and the amount of infrared radiation absorbed by the combustible gas is determined for two wave lengths or spectral ranges, the two wave lengths or spectral ranges being selected so that the amounts of individual components of the combustible gas in their different percentages have an effect on the amounts absorbed and recorded, b) the thermal conductivity is recorded and c) the gas properties are determined from the three measurands. The term gas properties is understood to mean the gas composition, the gross heating value, the Wobbe number, the normal density and the methane number.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: December 10, 2002
    Assignee: Buhrgas Aktiengesellschaft
    Inventor: Peter Schley
  • Patent number: 6464391
    Abstract: A calorimeter that measures heat release rates of very small samples (on the order of one to 10 milligrams) without the need to separately and simultaneously measure the mass loss rate of the sample and the heat of combustion of the fuel gases produced during the fuel generation process. The sample is thermally decomposed in a small volume pyrolysis chamber. The resulting fuel gases are immedediately swept by an inert gas stream from the pyrolysis chamber into a combustion furnace in a plug-like flow. This plug flow substantially synchronizes the emerging fuel gases with the mass loss rate of the sample. Oxygen is metered into the fuel gas stream just before it enters the combustion furnace where the fuel gases are completely oxidized. The effluent from the furnace is analyzed to determine the amount of oxygen consumed per unit time and the heat release rate is computed without the need to separately measure the mass loss rate of the sample.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: October 15, 2002
    Assignee: The United States of America as represented by the Secretary of Transportation
    Inventor: Richard E. Lyon
  • Patent number: 6442996
    Abstract: A method and apparatus for measuring the calorific value of a gas. The apparatus includes a chamber to which a gas in question, for example natural gas, is supplied through an inlet and leaves through an outlet. The speed of sound SoS at ambient temperature is measured using any suitable method such as electronic control and a calculating device and an ultra-sound emitter and an ultra-sound receiver. The ambient temperatures Ta, is observed by a temperature sensor, and a thermal conductivity sensor measures the thermal conductivity of the gas at two different temperatures above the ambient temperature. One value ThCH, of the thermal conductivity is measured at 70° C. above ambient and the other value ThCL of the thermal conductivity is measured at 50° C. above ambient. The control calculates the calorific value CV of the gas according to the formula: CV=a·ThCH+b·ThCL+C·SoS+d·Ta+e·Ta2 +f, where a, b, c, d, e and f are constants.
    Type: Grant
    Filed: August 29, 2000
    Date of Patent: September 3, 2002
    Assignee: Lattice Intellectual Property Limited
    Inventors: Robert Richard Thurston, Paul Stephen Hammond, Barry Leonard Price
  • Publication number: 20020080849
    Abstract: A calorimeter that measures heat release rates of very small samples (on the order of one to 10 milligrams) without the need to separately and simultaneously measure the mass loss rate of the sample and the heat of combustion of the fuel gases produced during the fuel generation process. The sample is thermally decomposed in a small volume pyrolysis chamber. The resulting fuel gases are immediately swept by an inert gas stream from the pyrolysis chamber into a combustion furnace in a plug-like flow. This plug flow substantially synchronizes the emerging fuel gases with the mass loss rate of the sample. Oxygen is metered into the fuel gas stream just before it enters the combustion furnace where the fuel gases are completely oxidized.
    Type: Application
    Filed: December 22, 2000
    Publication date: June 27, 2002
    Inventor: Richard E. Lyon
  • Patent number: 6371147
    Abstract: The subject of the present invention is: processes for the evaluation and the regulation, to a value P0, of the net (or gross) thermal power P of a flow of a combustible gas CG of composition close to that of a reference gas, said flow of gas passing through a flowmeter (7) of thermal mass technology, which is standardized, or standardized and calibrated, for said reference gas; a method of characterizing a flowmeter of thermal mass technology.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: April 16, 2002
    Assignee: L'Air Liquide, Societe Anonyme pour l'etude et l'Exploitation des Procedes Georges Claude
    Inventor: Louis Philippe
  • Patent number: 6342186
    Abstract: Ceramic liners for use with closed bomb devices are disclosed. The closed bomb devices measure performance properties of energetic materials, such as solid propellant, explosive, and pyrotechnic formulations. The closed bomb devices include a body and a ceramic liner. Alumina silicate and boron nitride are two currently preferred ceramic liner materials which have low compressibility, low thermal conductivity, and excellent durability.
    Type: Grant
    Filed: July 26, 1993
    Date of Patent: January 29, 2002
    Assignee: Cordant Technologies Inc.
    Inventors: Horace L. Wingfield, III, David R. Dillehay
  • Patent number: 6312154
    Abstract: The fuel heat content of fuel is measured on-line while a combustion turbine system is running by measuring data from the combustion turbine system during combustion of the fuel. The measured data are corrected using a standard correction algorithm. The fuel heat content of the fuel is determined using at least a portion of the corrected data. From the measurement of the fuel heat content, any changes in the fuel heat content are determined. Also, any changes in the control and operational parameters attributable to the change in fuel heat content are determined.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: November 6, 2001
    Assignee: General Electric Company
    Inventors: Louis Andrew Schick, Douglas Ancona Catharine, Stephen Duane Sanborn
  • Patent number: 6244097
    Abstract: The fuel gas or a substream of the fuel gas is passed through a volumetric flowmeter and the volumetric gas flow is measured. In addition, the pressure, temperature and the proportion of at least one inert gas as well as the density and the dielectric constant are measured under reference conditions. The amount of heat supplied to gas consumption devices can be determined from these six parameters reliably without complicated technology.
    Type: Grant
    Filed: April 27, 2000
    Date of Patent: June 12, 2001
    Assignees: N.V. Nederlandae Gasunie, Ruhrgas Aktiengesellschaft
    Inventors: Peter Schley, Manfred Jaeschke, Reiner Kleinrahm, Renee Janssen-van Rosmalen, Jan A. Schouten
  • Patent number: 5882115
    Abstract: The heating value of a sample gas is calculated by a microcontroller (12) from the heating value of a reference gas, and from flow ratios and power levels determined as the gas is combusted by a flameless combustion process. The combustible gas is mixed with a combustion supporting gas, such as air, and flowed to a body of material (26, 52) which is heated to a temperature sufficient for oxidation of the gas mixture. The size of spaces in a first embodiment of a heater device (9, 11, 25, 26) and in a second embodiment of a heater device (50) are limited to prevent formation of an open flame. In a preferred "lean mixture" embodiment, the gas-air mixture of the reference gas, and the gas-air mixture of the sample gas, respectively, are each adjusted until a selected power level of combustion at a temperature lower than the point of stoichiometric combustion is reached.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: March 16, 1999
    Assignee: Badger Meter, Inc.
    Inventors: William H. Vander Heyden, Ronald Arthur Berg
  • Patent number: 5820260
    Abstract: The heating value of a sample gas is calculated by a microcontroller (12) from the heating value of a reference gas, and from an oxidation energy ratio determined as the gas is combusted by a flameless combustion process. The combustible gas is mixed with a combustion supporting gas, such as air, in a volume chamber (4) and injected into a combustion device (8, 50) in which a body of inert material (26, 51, 53) is heated above the auto-ignition temperature of the gas mixture. The inert material (26, 51, 53) is arranged to have a void dimension that is small enough to prevent the formation of an open flame during combustion. The process is repeated with a sample gas. During the injection cycle, the microcontroller (12) receives signals which monitor the power of combustion. The microcontroller (12) calculates the heating value of the sample gas and generates an output signal to a visual display or other output device.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: October 13, 1998
    Assignee: Badger Meter, Inc.
    Inventors: William H. Vander Heyden, Ronald Arthur Berg
  • Patent number: 5816705
    Abstract: The heating value of a sample gas is calculated by a microcontroller (12) from the heating value of a reference gas, and from flow ratios and power levels determined as the gas is combusted by a flameless combustion process. The combustible gas is mixed with a combustion supporting gas, such as air, and flowed to a body of material (26, 52) which is heated to a temperature sufficient for oxidation of the gas mixture. The size of spaces in a first embodiment of a heater device (9, 11, 25, 26) and in a second embodiment of a heater device (50) are limited to prevent formation of an open flame. In a preferred "lean mixture" embodiment, the gas-air mixture of the reference gas, and the gas-air mixture of the sample gas, respectively, are each adjusted until a selected power level of combustion at a temperature lower than the point of stoichiometric combustion is reached.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: October 6, 1998
    Assignee: Badger Meter, Inc.
    Inventors: William H. Vander Heyden, Ronald Arthur Berg
  • Patent number: 5807749
    Abstract: A method and apparatus for determining the calorific value of a combustible gas including passing an amount of gas through a hydrocarbon detection device comprising interconnected first and second measuring cells, the first measuring cell including a catalyzing substance, wherein the first and second measuring cells provide a signal, the signal is integrated to determine a value, and the value is compared with calibrated values to determine the calorific value. In another embodiment, the Wobbe index of natural gas is determined further including determining the density of the gas and calculating the Wobbe index from the calorific value and density.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: September 15, 1998
    Assignee: Gastec N.V.
    Inventor: Johan Adrianus Tilmann Hornemann
  • Patent number: 5779362
    Abstract: A calorimeter is disclosed comprising a sample chamber (12) adapted to enclose a sample, a thermally conductive reference surface (14) surrounding and insulated from the sample chamber (12) and a casing (16) surrounding and insulated from the reference surface. Temperature transducers, in communication with a micro-computer, record the temperatures of the sample chamber (VS) and reference surface (V1) at periodic intervals. The micro-computer is programmed to calculate the theoretical temperature (VT) of the sample chamber from the measured values of the temperature of the reference surface (V1) and estimated values of the thermal power of the sample (I), the thermal resistance from the sample to the sample chamber (RS) and the thermal capacity of the sample (CS), and to optimize the fit between the theoretical calculations (VT) and the corresponding measured values (VS) of the temperature of the sample chamber.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: July 14, 1998
    Inventor: John Adrian Lightfoot
  • Patent number: 5707150
    Abstract: An apparatus for measuring the BTU content of a gas includes a source of combustion air, a detector and a sample loop or tube connected to a six-port switching valve. The switching valve allows accurate and repeatable quantities of the gas to be obtained and mixed with the combustion air. In a second embodiment, the apparatus includes a second switching valve to obtain samples of the gas at a second pressure and calculate the BTU content at the second pressure. By measuring the BTU content at two different pressures, a quantity related to the volumetric flow of the gas between the two pressures can also be calculated.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: January 13, 1998
    Assignee: Rosemount Analytical Inc.
    Inventor: Fred C. Sittler
  • Patent number: 5635626
    Abstract: Apparatus to measure the calorific value and/or the Wobbe index of fuel gas supplied along a pipe. A control can operate two outlet valves and cause an inlet valve to be locked in a closed position or be unlocked to stay in a normally open state until the gas pressure in a chamber of predetermined volume reaches a preset pressure difference above the pressure in the pipe. Under direction of the control, a pump moves fuel gas from the pipe into the chamber whilst the outlet valves are closed. Once the pressure in the chamber attains the preset difference, the inlet valve closes automatically to be held locked closed by the control. Certain properties of the gas in the chamber, such as thermal conductivity, specific heat capacity and speed of sound, are measured and corrected to STP conditions. The pump moves two samples of gas into the chamber at two sequential times, each time until the gas pressure therein attains the preset value and the inlet valve again closes automatically in a locked position.
    Type: Grant
    Filed: November 20, 1995
    Date of Patent: June 3, 1997
    Assignee: British Gas plc
    Inventors: Paul S. Hammond, Robert R. Thurston
  • Patent number: RE35639
    Abstract: The present invention is a method and apparatus for monitoring in real time the mass and energy flow rate of a gas through a pipeline. The invention determines the mass flow ratio of a pipeline gas flowing through a pipeline compared to sample gas tapped from the pipeline line when the volumetric flow of pipeline gas through the pipeline is measured by a linear flow meter. Sample gas tapped from the pipeline is flowed to a chamber having a section with a fixed volume until the pressure in the chamber section is substantially equal to the pipeline gas pressure. The sample gas is maintained at substantially the same temperature as the gas in the pipeline while the sample gas is in the chamber section. A timer measures the time interval for the sample gas to flow from the chamber section at a selected rate for a calculated pressure drop the selected rate being controlled by a flow controller. The mass flow ratio is computed using the measured time interval and a signal from the linear flow meter.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: October 21, 1997
    Assignee: Badger Meter, Inc.
    Inventors: William H. Vander Heyden, William H. Clingman, Jr., deceased