Abstract: A dental alloy contains palladium (Pd) and indium (In) for CAD/CAM machining. The dental alloy can further include one component selected from the group consisting of gold (Au), silver (Ag), nickel (Ni), cobalt (Co), and platinum (Pt). The dental alloy has a yield strength of 250 MPa to 450 MPa, breaking elongation of 2% to 8%, metal-ceramic adhesion of 20 MPa to 70 MPa, coefficient of linear thermal expansion of 14.0×10?6/K to 17.0×10?6/K, or density of 8 g/cm3 to 15 g/cm3.

Abstract: Electrode catalysts for fuel cells, a method of manufacturing the same, a membrane electrode assembly (MEA) including the same, and a fuel cell including the MEA are provided. The electrode catalysts include a first catalyst alloy containing palladium (Pd), cobalt (Co), and phosphorus (P), a second catalyst alloy containing palladium (Pd) and phosphorus (P), and a carbon-based support to support the catalysts.

Abstract: The disclosure provides an H2 separation membrane comprised of an alloy having the composition Cu(100-x-y)PdxMy, where x is from about 35 to about 50 atomic percent and where y is from greater than 0 to about 20 atomic percent, and where M consists of magnesium, yttrium, aluminum, titanium, lanthanum, or combinations thereof. The M elements act as strong stabilizers for the B2 phase of the alloy, and extend the critical temperature of the alloy for a given hydrogen concentration and pressure. Due to the phase stabilization and the greater temperature range over which a B2 phase can be maintained, the alloy is well suited for service as a H2 separation membrane, particularly when applicable conditions are established or cycled above about 600° C. over the course of expected operations. In certain embodiments, the B2 phase comprises at least 60 estimated volume percent of the alloy at a steady-state temperature of 400° C. The B2 phase stability is experimentally validated through HT-XRD.

Abstract: Methods for producing electronic grade metal nanostructures having low levels of contaminants are provided. Monolayer arrays, populations, and devices including such electronic grade nanostructures are described. In addition, novel methods and compositions for production of Group 10 metal nanostructures and for production of ruthenium nanostructures are provided, along with methods for recovering nanostructures from suspension.

Abstract: A supported catalyst includes a carbonaceous catalyst support and first metal-second metal alloy catalyst particles adsorbed on the surface of the carbonaceous catalyst support, wherein the difference between a D10 value and a D90 value is in the range of 0.1 to 10 nm, wherein the D10 value is a mean diameter of a randomly selected 10 wt % of the first metal-second metal alloy catalyst particles and the D90 value is a mean diameter of a randomly selected 90 wt % of the alloy catalyst particles. The supported catalyst has excellent membrane efficiency in electrodes for fuel cells due to uniform alloy composition of a catalyst particle and supported catalysts that do not agglomerate.

Abstract: Metallic glass alloys of palladium, copper, cobalt, and phosphorus, that are bulk-solidifying having an amorphous structure. Other embodiments are described and claimed.

Abstract: The present invention includes an apparatus, system and method for screening and making one or more electrocatalysts, electrocatalyst arrays, electrodes and catalysts for an oxygen reduction reaction with a Group VIII noble metal in contact with a component-M o form a Group VIII noble metal-M alloy, wherein component-M is one or more metals selected from Groups IIIA, IVA, VIII, IB, IIB, VB, VIB, VIIB and VIIIB of the Periodic Table.

Abstract: A palladium-boron composition and methods of making and using same are provided. In one aspect, the invention comprises an alloy comprising palladium and boron, the boron being in solid solution in the palladium and the alloy having a two-phase structure, wherein each phase of the two-phase structure has the same crystal structure as the other phase and has a different set of lattice parameters from the other phase such that the palladium is greatly hardened by the presence of the smaller phase crystals within the spaces between the larger phase crystals. The composition is carefully prepared by a process wherein palladium and an amount of boron sufficient to place the boron in solid solution, but insufficient to combine with the palladium, are placed together and repeatedly are melted, cooled and turned over until sufficiently mixed.

Abstract: The invention relates to a high-hardness palladium alloy for manufacturing semi-finished products to be used in goldsmith's art or jewels to be obtained by the lost wax casting method, which comprises, in the following concentrations, expressed in thousandths by weight (%) palladium from 948 to 990%; copper from 0.0 a 50%; indium from 0.0 to 50%; gallium from 1 to 48%; aluminium from 0.8 to 49.5%; ruthenium from 0.0 to 50%; rhenium from 0.0 to 50%; silicon from 0.1 to 1.2%; platinum from 0.0 to 40%; nickel from 0.0 to 50%; iridium from 0.0 to 40%. In the manufacturing process of the above alloy, the component elements of said alloy are placed in a crucible, respectively made of zirconia, boron nitride or other ceramic material, and are melted using the induction method and using a protective atmosphere, respectively of argon, nitrogen or other inert gas.

Abstract: A method for producing a copper/palladium colloid catalyst useful for Suzuki couplings.

Abstract: A hard precious metal alloy member is constituted of a gold alloy, which has a gold Au content of from 37.50 to 98.45 wt %, and contains a hardening additive in a range of not less than 50 ppm but less than 15,000 ppm, wherein the hardening additive is constituted of gadolinium Gd only, or gadolinium Gd and at least one element selected from the group consisting of rare-earth elements other than Gd, alkaline-earth elements, silicon Si, aluminum Al, and boron B.

Abstract: An electrode having an excellent corrosion resistance and long service life even in a severe corrosive environment such as in NaCl solutions for anode electrolysis in which chlorine gas or the like is produced at a high potential from the alloy surface. The electrode of the invention is provided using a precious metal-based amorphous alloy which has a good plasticity processibility and is applicable to a large-sized component. The object is implemented by provision of an electrode material for anode electrolysis which utilizes a precious metal-based amorphous alloy which satisfies the general formula NM.sub.100-a-b-c Ni.sub.a Cu.sub.b P.sub.c wherein NM comprises one or two precious metal elements selected from Pd and Pt; a, b and c being atomic percent, satisfy that 30.ltoreq.a+b.ltoreq.45,3.ltoreq.b/a.ltoreq.7, and 18.ltoreq.c.ltoreq.25, respectively; Pt is contained from 10 to 30 atom percent (at. %); and wherein a temperature width .DELTA.Tx in the supercooled liquid region (.DELTA.

Abstract: A bonding wire for a semiconductor device contains high purity Pd or Pd alloy as a base metal and 25-10000 atppm of low boiling element III having a boiling point lower than a melting point of the base metal and soluble in Pd, or contains high purity Pd or Pd alloy as a base metal and 5-500 atppm of low boiling point element IV having a boiling point lower than a melting point of the base metal and insoluble in Pd, or high purity Pd or Pd alloy as a base metal, and 5-10000 atppm of low boiling point element III and low boiling point element IV, the low boiling point element III having a boiling point lower than a melting point of the base metal and being soluble in Pd, the low boiling point element IV having a boiling point lower than a melting point of the base metal and being insoluble in Pd, the low boiling elements III and IV being present in a concentration so that (content of the low boiling point element III)/25 + (content of the low boiling element IV)/5.gtoreq.1.gtoreq.

Abstract: Palladium based dental alloys do not show unaesthetic discolorations after ceramic firing if said alloys contain 66-85% by weight palladium, 1-20% by weight gold; 0-4% by weight silver; 0-4% by weight of at least one of platinum, iron and/or cobalt; 0.5-7% by weight of each of gallium, tin and indium, whereby the amount of said components total 9-14% by weight; 0-2% by weight germanium and/or zinc; and 0-1% by weight iridium, ruthenium and/or rhenium.

Abstract: A noble metal dental casting alloy for use in making dental restorations comprises 35-70 percent by weight palladium, 25-50 percent by weight silver, 0.5-10 percent by weight manganese, and 1-30 percent of at least one modifier element selected from (i) the group of gold, platinum, copper, tin, gallium, zinc, indium and cobalt in amounts of up to 15 percent by weight each, and (ii) the group of ruthenium, rhenium, aluminum, germanium, lithium, silicon, iridium, boron, tantalum and niobium in amounts of up to 5 percent by weight each. The alloy has a solidus temperature of at least 1100.degree. C., a liquidus temperature of not more than 1400.degree. C., tensile elongation of at least 2 percent, thermal expansion coefficient of at least 14.0.times.10.sup.-6 per .degree.C., Vickers hardness of at least 150, and offset yield strength at 0.2 percent of at least 250 MPa.

Abstract: A palladium alloy of the form PdNbM where M is at least one element selected from the group consisting of silicon, iron, nickel, copper, cobalt, boron and aluminum is provided. The alloys exhibit oxidation resistance and electrical contact resistance and are particularly suited for electrical applications such as coatings for electrical contacts or connectors. In a preferred embodiment, the alloy contains from about 5 to about 10 atomic percent niobium.

Abstract: The invention relates to a novel palladium-based alloy.This palladium-based alloy comprises tin in an amount, preferably of 5 to 20% by weight, which is sufficient to impart an acceptable resistance to corrosion by molten glass, preferably being essentially equivalent to that of platinum-rhodium 10% alloys.An alloy of this type can be used in the glass industry for making components which come into contact with molten glass, which preferably essentially contains no oxides less stable than tin oxide, such as lead oxide, because it has an excellent resistance to corrosion by molten glass and is much less expensive than the platinum-rhodium 10% alloy normally used. Moreover, by the addition of at least one element selected from platinum (0-50% by weight), rhodium (0-20% by weight), iridium (0-20% by weight) and ruthenium 0-20% by weight), the mechanical strength at high temperature, especially the creep strength, is significantly improved.

Abstract: The invention relates to a novel palladium-based alloy.This palladium-based alloy comprises at least one additional element selected from indium, bismuth, silver and copper, in an amount sufficient to impart an acceptable resistance to corrosion by molten glass, preferably being essentially equivalent to that of platinum-rhodium 10% alloys.An alloy of this type can be used in the glass industry for making components which come into contact with molten glass, which preferably essentially contains no oxides less stable than the oxide of the additional element, such as lead oxide, because is has an excellent resistance to corrosion by molten glass and is less expensive than the platinum-rhodium 10% alloy normally used. Moreover, by the addition of at least one element selected from platinum (0-50% by weight), rhodium (0-20% by weight), iridium (0-20% by weight), ruthenium (0-20% by weight) and tin (0-20%), the mechanical strength at high temperature, especially the creep strength, is significantly improved.

Abstract: A dental alloy consists essentially of 60 to 85% by weight palladium, 5 to 20% by weight copper, 3 to 15% by weight gallium, and, as modifiers, 0.5 to 7% by weight gold, 0.005 to 0.02% by weight ruthenium, rhenium, iridium or a mixture of at least two of these metals, 1 to 5% by weight tin and 0 to 2% by weight nickel, wherein the sum of the modifiers is from 5.5 to 10% by weight. Dental restorations are produced by firing ceramic onto at least part of the surface of a casting of such an alloy.

Abstract: The subject of this invention is the development of new alloys along with new processing approaches for the utilization of the alloys. A particular class of alloys comprises at least one noble metal selected from the group comprising gold, palladium, silver and copper and an amount of between about 0.20 weight percent and about 0.80 weight percent of at least one metalloid selected from the group of metalloids consisting of boron, phosphorous, silicon and lithium. Rapid solidification technology in powder fabrication and the addition of metalloids have been combined to produce a new class of palladium based alloys. The metalloid additions greatly increase the hardness, enhance the fine grain structure and aid sintering densification. Net-shape forming is a benefit derived from the characteristics of the new alloys.

Abstract: Dental restorations are made of a palladium alloy which consists essentially of, on a weight basis, 50-85 percent palladium; 5-40 percent of at least one metal selected from the group consisting of copper and cobalt; 1-15 percent gallium; up to 5 percent of a modifier selected from the group consisting of nickel, gold, indium, ruthenium, tin and mixtures thereof; from 0.005 up to 1 percent, ordinarily less than about 0.2 percent, of an oxygen scavenging component which is a member selected from the group consisting of germanium, lithium, and mixtures thereof; and up to 0.5 percent of a grain refiner selected from the group consisting of rhenium and iridium. The alloy is free of boron.

Abstract: Palladium alloys consisting of (a) 65 to 85% palladium, (b) 0 to 10% gold and/or 0 to 5% platinum, (c) 0.1 to 10% tin, (d) 1 to 10% gallium, (e) 1 to 12% copper, (f) 0.05 to 1.5% ruthenium and/or 0.05 to 0.7% rhenium as well as (g) 0.01 to 4% tungsten and/or 0.01 to 4% aluminum and/or 0.01 to 4% zinc are use to produce firmly seated and removable dentures. These alloys do not form oxide films when melted in air.

Abstract: Economical but readily workable palladium alloys for baking on dental ceramics consist of 60 to 80% palladium, 0 to 8% gold, 0 to 5% platinum, 0 to 1% ruthenium and/or rhenium, 2 to 20% copper, 1 to 12% tin and/or indium, 0.2 to 5% of at least one of the elements tungsten, molybdenum, niobium, and tantalum, and 0 to 15% cobalt, with the proviso that the sum of tin and indium must be between 5 and 14%.

Abstract: Reactive metal-precious metal ductile alloys containing controlled amounts of Cu and Ni and mixtures thereof are suitable for brazing ceramics, other non-metallic and metallic materials.

Abstract: A palladium alloy for use in making porcelain jacketed dental restorations having the following composition: 60-85 percent by weight palladium, 5-20 percent by weight copper, 3-15 percent by weight gallium, and a modifier metal selected from gold, indium, ruthenium, tin, nickel and mixtures thereof, the sum of the concentrations of the modifier metal percent in the alloy being greater than 5.5 percent by weight.

Abstract: Reactive metal-precious metal ductile alloys containing controlled amounts of Cu and Ni and mixtures thereof are suitable for brazing ceramics, other non-metallic and metallic materials.

Abstract: There are described noble metal alloys for dental purposes, especially for firing on dental porcelain which are low melting, do not discolor the porcelain, are repeatedly castable, and making possible brazing joints. These alloys containing 20 to 65% gold, 25 to 65% palladium, 0 to 7% gallium, 0.2 to 11% indium and/or tin, 0 to 2% copper, 0.05 to 1% ruthenium, iridium and/or rhenium, 0 to 1% vanadium, 0 to 1% iron and additionally 0.5 to 15% cobalt, with the proviso that the content of base metals must exceed 5%.

Abstract: Grain refined palladium-based dental alloys contain about 70-85 weight percent palladium, 7-15 weight percent copper, 2-8 weight percent gallium, 2-15 weight percent indium, 0.2-3.0 weight percent rhenium or ruthenium and an effective amount of boron up to about 0.15% which eliminates the formation of bubbles in porcelain during the porcelain firing process. In addition, there can be an effective amount of zinc up to about 0.5 weight percent. Alternately, in lieu of zinc, the boron is added in the form of calcium boride.

Abstract: Low gold dental alloys, especially for firing on dental porcelains, should be easily worked, result in no discolorations and bubble formation in the firing, and have a physiologically replaceable hardness and a low melting interval. These properties are shown by alloys having 20 to 35 wt. % gold and 45 to 65 wt. % palladium if they also contain(a) 6 to 15 wt. % copper and 0 to 10 wt. % nickel,(b) 0 to 12 wt. % indium, 0 to 12 wt. % tin, and 0 to 4 wt. % gallium, with the proviso that the sum of the content of indium and tin added to two and one-half times the gallium content must give a value between 5 and 15 wt. %,(c) 0.1 to 1 wt. % iridium and/or rhenium and/or ruthenium, and(d) optionally 0 to 1 wt. % aluminum, 0 to 1 wt. % tantalum, 0 to 1 wt. % titanium and/or 0 to 5 wt. % silver.

Abstract: A palladium alloy suitable for use with both high and low thermal expansion dental porcelains without causing discoloration of the porcelains. The alloy consists essentially of 70-90% palladium, 1-8% silver, 0-5% gold, 5-16% copper, 1-8% gallium, 0.01-0.8% silicon and 0.001-0.5% grain refiners.

Abstract: Cast alloys which should be suited for both the production of removable dental construction (model casting technique) and also for permanent crowns and bridges with ceramic facing (firing technique) must combine good firing properties and good tensile strength and strain values. Alloys of this type consist of 65-85% Pd, 0-10% Au and/or 0-5% Pt, 0.1-10% Sn, 1-10% Ga, 1-12% Cu as well as 0.5-1.5 Ru and/or 0.05-0.7% Re.

Abstract: A dental alloy for porcelain-fused-to-metal restorations is provided which consists essentially of, on a weight basis, about 60-90% palladium, an effective amount of ruthenium up to about 2% for the purpose of grain-refining the alloy, an effective amount of copper up to about 30% for the purpose of lowering the melting point and raising the thermal expansion, up to about 15% indium, up to about 16% tin, up to about 12% zinc, up to about 5% gold, and from about 0.05 to about 0.25% boron or calcium boride, the total of said constituents being 100%, wherein the sum of the copper, indium, tin and zinc concentrations is greater than about 18%, the sum of the indium, tin and zinc concentrations is greater than about 10%, and the sum of the indium and zinc concentrations is greater than about 5%, such that said alloy exhibits a melting point between about 1100.degree. C. and 1400.degree. C. and a coefficient of thermal expansion of about 0.66 to 0.72 at 500.degree. C.

Abstract: A superconducting type II composite palladium alloy hydride material having a region containing a contiguous surface comprising a palladium alloy-palladium region wherein at least a portion of the alloy region contains hydrogen and at least a portion of the palladium region contains hydrogen.

Abstract: The retention of the beta brass phase structure (body-centered cubic) as gold atoms (molars) are substituted for copper atoms. Thus essentially the useful physical and working properties of the beta brasses are retained (hot forgeability, castability, some ductility etc.). As to chemical behavior, there is a definite nobleization effect of the beta brasses, i.e. all gold-containing beta golds are more tarnish resistant than the beta brasses, and the nobleization increases with gold content. However, of most importance from a commercial point of view, is that the low kt beta golds (4-kt, 6-kt) are more tarnish resistant than the 10-kt conventional jewelry alloys, and equal to those of 14-kt gold. In essence there is a tarnish resistance enhancement in going from alpha structure to beta structure kt for kt, in the jewelry range. Other noble metals (Pd, Pt, Ru, Rh, Os, Ir and Ag) may be used singly or in combinations with, or in lieu of, the gold.

Abstract: A dental alloy for use in porcelain-fused-to-metal restorations including palladium, cobalt, gallium, gold, aluminum, copper, zinc and ruthenium or rhenium. The cobalt controls the coefficient of thermal expansion of the alloy to permit the use of the alloy with commercially available porcelains having a variety of thermal coefficients. The zinc serves as a scavenger during formation and casting of the alloy. The aluminum protects the alloy from absorbing gases during torch melting and during the porcelain firing process. The ruthenium or rhenium provides grain refining for the alloy to increase its elongation, tensile strength, and thus toughness. The alloy with ruthenium or rhenium as a grain refining agent must be made in a protective environment to avoid the formation of bubbles in the procelain during the procelain firing process.

Abstract: A dental alloy for use in porcelain-fused-to-metal restorations including palladium, cobalt, gallium, gold, aluminum, copper and ruthenium or rhenium. The cobalt controls the coefficient of thermal expansion of the alloy to permit the use of the alloy with commercially available porcelains having a variety of thermal coefficients. The ruthenium of rhenium provides grain refining for the alloy to increase its elongation, tensile strength, and thus toughness. The alloy with ruthenium or rhenium as a grain refining agent must be made under vacuum or in an inert atmosphere to avoid the formation of bubbles in the porcelain during the porcelain firing process.

Abstract: A homogeneous fine grained palladium alloy consisting essentially of______________________________________ Weight Percent ______________________________________ Pd 70-82 Au 0.1-10 In 5-10 Cu 2-5 Ga 0.5-5 Sn 0.5-5 Co 0.9-2.7 Re 0.01-0.3 ______________________________________and between 0.08 and 0.25% of at least one metal selected from the group consisting of Ru and Ir.

Abstract: A palladium alloy for use in making porcelain coated dental restorations comprises 50-85 percent palladium, 5-40 percent copper and/or cobalt, 1-15 percent gallium, up to 5 percent of a modifier selected from nickel, gold, indium, ruthenium and tin, up to 0.5 percent rhenium and/or iridium, and up to 1 percent boron. The dental restorations obtained by firing porcelain against castings of this alloy exhibit freedom from discoloration, and excellent bond strength is obtained between the porcelain coating and the underlying alloy casting.