Abstract: The present application discloses a preparation method for quantum dots (QDs). The method includes providing initial QD cores, and mixing the initial QD cores with an organic carboxylic acid to bond the organic carboxylic acid to the surface of the initial QD cores; preparing a shell layer on the surface of the initial QD cores in a shell-growth reaction system containing an organic carboxylic acid; and mixing and heating the solution system, obtained after a completion of shell-layer growth reaction, with an organic amine, an organic phosphine, or a mixed solution of the organic amine and the organic phosphine.

Abstract: A process for producing sulfuric acid and cement clinker may use calcium sulfate that is formed as a solid by-product and separated off in phosphoric acid production in a reaction of raw phosphate with sulfuric acid to form phosphoric acid. The process comprises treating calcium sulfate separated from the phosphoric acid with an acid to obtain a suspension comprising purified calcium sulfate, separating the purified calcium sulfate in solid form from the liquid phase of the suspension, mixing the purified calcium sulfate with admixtures and reducing agents to obtain a raw meal mixture for cement clinker production, burning the raw meal mixture to obtain the cement clinker, with formation of sulfur dioxide as offgas, and subjecting the sulfur dioxide formed to offgas purification and feeding the sulfur dioxide as raw material to sulfuric acid production to produce the sulfuric acid. The sulfuric acid produced may be used as starting material in phosphoric acid production.

Abstract: A reagent system for treating heavy metal-contaminated materials is provided and includes an oxidizer, a soluble phosphate, and an alkaline hydroxide source, such as a caustic soda or lime. A method of treating mine waste bearing one or more heavy metals is also provided and includes the step of admixing a reagent system with heavy metal-containing material to preferentially reduce the leachability of heavy metals and form precipitates and complexes of low metal solubility that remain stable within the host solid matrix for long durations in acidic and abrasive conditions.

Abstract: A cadmium free quantum dot not including cadmium and including: a semiconductor nanocrystal core comprising indium and phosphorous, a first semiconductor nanocrystal shell disposed on the semiconductor nanocrystal core and comprising zinc and selenium, and a second semiconductor nanocrystal shell disposed on the first semiconductor nanocrystal shell and comprising zinc and sulfur, a composition and composite including the same, and an electronic device.

Abstract: Methods for purifying reaction precursors used in the synthesis of inorganic compounds and methods for synthesizing inorganic compounds from the purified precursors are provided. Also provided are methods for purifying the inorganic compounds and methods for crystallizing the inorganic compounds from a melt. ? and X-ray detectors incorporating the crystals of the inorganic compounds are also provided.

Abstract: Atomic layer deposition (ALD) processes for forming Group VA element containing thin films, such as Sb, Sb—Te, Ge—Sb and Ge—Sb—Te thin films are provided, along with related compositions and structures. Sb precursors of the formula Sb(SiR1R2R3)3 are preferably used, wherein R1, R2, and R3 are alkyl groups. As, Bi and P precursors are also described. Methods are also provided for synthesizing these Sb precursors. Methods are also provided for using the Sb thin films in phase change memory devices.

Abstract: Disclosed is a composite pellet used as a raw material in a kiln process for the production of phosphoric acid, which is of a core-shell structure with an inner ball encapsulated with a shell, the inner ball mainly consists of a inner ball material and a binding agent, and the shell mainly consists of a cladding material and a binding agent; the inner ball material mainly consists of a carbonaceous reductant powder, and phosphate ore powder and silica powder, the inner ball is combined with the shell through the binding agent to form the core-shell shaped structure. The preparation of the composite pellets comprises the steps of preparing the inner ball, preparing the cladding material, forming, drying and solidifying composite green pellets etc. The composite pellets prepared by the present invention have a smaller range of formulation fluctuation, more stable quality, higher strength and better performance.

Abstract: There is provided a method of preparing transition metal phosphide comprising the step of mixing a solution of a transition metal precursor and a phosphorous precursor under conditions to form the transition metal phosphide. There is also provided a transition metal phosphide particle made according to the method as defined herein. There is additionally provided a method of preparing a transition metal phosphide-based electrode used for producing hydrogen in the electrolysis of water.

Abstract: The invention provides for a fully electrically rechargeable metal anode battery systems and methods of achieving such systems. An electrically rechargeable metal anode cell may comprise a metal electrode, an air contacting electrode, and an aqueous electrolyte separating the metal electrode and the air contacting electrode. In some embodiments, the metal electrode may directly contact the liquid electrolyte and no separator or porous membrane is needed between the air contacting electrode and the electrolyte. Rechargeable metal anode cells may be electrically connected to one another through a centrode connection where a metal electrode of one cell and an air contacting electrode of a second cell are electrically connected. Air tunnels or pathways may be provided between individual metal anode cells arranged in a stack. In some embodiments, an electrolyte flow management system may also be provided to maintain liquid electrolyte at constant levels during charge and discharge cycles.

Abstract: Provided herein is a prohealing piezoelectric coating and the method of making and using the same.

Abstract: A method of fabricating a metal oxide sheet having a polycrystalline structure includes mixing a metal precursor material, a base material, and distilled water with each other to fabricate a preparation solution; adding an anionic surfactant into the preparation solution to forming a precursor solution; forming metal oxide nanoparticles in the precursor solution, wherein each of the metal oxide nanoparticles comprises a metal cation and an oxygen anion; and fabricating a metal oxide sheet by coupling the metal oxide nanoparticles to each other, wherein, in an aspect of a plane, the metal oxide sheet has a hexagonal shape and a polycrystalline structure.

Abstract: A hydrogen-free amorphous dielectric insulating film having a high material density and a low density of tunneling states is provided. The film is prepared by e-beam deposition of a dielectric material on a substrate having a high substrate temperature Tsub under high vacuum and at a low deposition rate. In an exemplary embodiment, the film is amorphous silicon having a density greater than about 2.18 g/cm3 and a hydrogen content of less than about 0.1%, prepared by e-beam deposition at a rate of about 0.1 nm/sec on a substrate having Tsub=400° C. under a vacuum pressure of 1×10?8 Torr.

Abstract: A system and method for passive capture of ammonia in an ammonia-containing liquid effluent. The invention allows for the passage of ammonia through microporous hydrophobic gas-permeable membranes and its capture in a circulated stripping solution with concomitant production of a concentrated non-volatile ammonium salt.

Abstract: A composite particle and a population of particles comprising a water-insoluble polyphosphate composition, methods of producing, and methods of using the same are provided. The polyphosphate composition may comprise at least one alkaline earth metal selected from calcium and magnesium and optionally at least one nutrient ion selected from the group consisting of potassium, ammonium, zinc, iron, manganese, copper, boron, chlorine, iodine, molybdenum, selenium or sulfur.

Abstract: Pharmaceutical compositions for long-term sustained release of bisphosphonate drugs are provided. In one embodiment, the composition includes an aqueous suspension of a solid which includes a salt of a bisphosphonate drug and a salt of pentavalent phosphorus oxoacid. The compositions can be used to treat a variety of bone diseases, including osteoporosis.

Abstract: Calcium peroxyphosphate compounds and dental compositions comprising these compounds that combine both whitening/stain removal of teeth with remineralization are disclosed. The calcium peroxyphosphate compounds are capable of releasing, in an aqueous environment, whitening and remineralization effective amounts of calcium ion, phosphate ion, and active oxygen. Preferred compounds are calcium peroxymonophosphate or calcium diperoxymonophosphate compounds. These compounds may be used in humans and other animals, including other mammals.

Abstract: Electrode active material of the invention is mainly an amorphous transition metal complex represented by AxMPyOz (where x and y are values which independently satisfy 0?x?2 and 0?y?2, respectively, and z=(x+5y+valence of M)/2 to satisfy stoichiometry; also, A is an alkali metal and M is a metal element selected from transition metals), and has a peak near 220 cm?1 in Raman spectroscopy. Applying the electrode active material of the invention to a nonaqueous electrolyte secondary battery increases the capacity of the nonaqueous electrolyte secondary battery.

Abstract: The present disclosure is directed toward a composition and method of treating and preventing infection of pathogenic microorganisms and endopyhtic microorganisms in a plant through the use of phosphite compositions.

Abstract: A method of synthesizing transition metal phosphide. In one embodiment, the method has the steps of preparing a transition metal lignosulfonate, mixing the transition metal lignosulfonate with phosphoric acid to form a mixture, and subjecting the mixture to a microwave radiation for a duration of time effective to obtain a transition metal phosphide.

Abstract: Disclosed herein are near field transducers (NFTs) that include either silver, copper, or aluminum and one or more secondary elements.

Abstract: A device including a near field transducer, the near field transducer including gold (Au) and at least one other secondary atom, the at least one other secondary atom selected from: boron (B), bismuth (Bi), indium (In), sulfur (S), silicon (Si), tin (Sn), hafnium (Hf), niobium (Nb), manganese (Mn), antimony (Sb), tellurium (Te), carbon (C), nitrogen (N), and oxygen (O), and combinations thereof erbium (Er), holmium (Ho), lutetium (Lu), praseodymium (Pr), scandium (Sc), uranium (U), zinc (Zn), and combinations thereof and barium (Ba), chlorine (Cl), cesium (Cs), dysprosium (Dy), europium (Eu), fluorine (F), gadolinium (Gd), germanium (Ge), hydrogen (H), iodine (I), osmium (Os), phosphorus (P), rubidium (Rb), rhenium (Re), selenium (Se), samarium (Sm), terbium (Tb), thallium (Th), and combinations thereof.

Abstract: The invention relates to derivatives of (1-cyanocyclopropyl)phenylphosphinic acid of the formula (I) and to salts thereof, of the formula (II), for enhancing stress tolerance in plants to abiotic stress, preferably to drought stress, especially for enhancing plant growth and/or for increasing plant yield.

Abstract: A method for preparing semiconductor nanocrystals includes reacting one or more semiconductor nanocrystal precursors in a liquid medium in the presence of a boronic compound at a reaction temperature resulting in semiconductor nanocrystals. Semiconductor nanocrystals are also disclosed.

Abstract: There is disclosed a composition for converting electromagnetic energy to ultraviolet C (UVC) radiation or radiation of a shorter wavelength, the composition comprising at least one phosphor capable of converting an initial electromagnetic energy (A) to an electromagnetic energy (B) comprising UVC radiation or radiation of a shorter wavelength, and an organic or inorganic media containing said phosphor. There is also a method of sterilizing an article by exposing it to UVC radiation or radiation of a shorter wavelength for a time sufficient to deactivate or kill at least one microorganism and/or for a time sufficient to inhibit abnormal cell growth within the body, when said composition is in an implantable medical device. A method of coating an article with such compositions is also disclosed.

Abstract: There is disclosed various devices and articles comprising phosphors for converting electromagnetic energy to radiation having a shorter wavelength, the composition comprising at least one phosphor capable of converting an initial electromagnetic radiation having a wavelength (A) to an electromagnetic radiation having a shorter wavelength (B) comprising UV radiation or radiation of a shorter wavelength. There is also a method of sterilizing such devices and articles by exposing it to UV radiation or radiation of a shorter wavelength for a time sufficient to deactivate or kill at least one microorganism and/or for a time sufficient to inhibit abnormal cell growth within the body, when the composition is in an implantable medical device.

Abstract: New magnetic materials containing cerium, iron, and small additions of a third element are disclosed. These materials comprise compounds Ce(Fe12?xMx) where x=1-4, having the ThMn12 tetragonal crystal structure (space group I4/mmm, #139). Compounds with M=B, Al, Si, P, S, Sc, Co, Ni, Zn, Ga, Ge, Zr, Nb, Hf, Ta, and W are identified theoretically, and one class of compounds based on M=Si has been synthesized. The Si cognates are characterized by large magnetic moments (4?Ms greater than 1.27 Tesla) and high Curie temperatures (264?Tc?305° C.). The Ce(Fe12?xMx) compound may contain one or more of Ti, V, Cr, and Mo in combination with an M element. Further enhancement in Tc is obtained by nitriding the Ce compounds through heat treatment in N2 gas while retaining the ThMn12 tetragonal crystal structure; for example CeFe10Si2N1.29 has Tc=426° C.

Abstract: This disclosure is directed to systems and methods for sorting a native aggregate, such as a fluorescent nanoparticle aggregate, which includes multiple objects, some of which have different characteristics, into lower level ensembles, such as monochromatic nanoparticle ensembles. In one aspect, the system includes two detectors, one of which accepts all emitted wavelengths and another one which is preceded by a filter to permit transmission of a specific wavelength or range of wavelengths. In another aspect, the system includes multiple detectors, each detector configured to detect a given wavelength or range of wavelengths, such that no two detectors have overlapping wavelengths or ranges. In yet another aspect, the system includes an optical regulator in front of a detector. This disclosure is also directed to systems and methods for multiplexing and analyzing a target analyte using the monochromatic nanoparticle ensembles.

Abstract: A method for producing a low-dislocation InP single crystal suitably used for an optical device such as a semiconductor laser, and the low-dislocation InP single crystal wafer are provided. In a liquid-encapsulated Czochralski method in which a semiconductor raw material and an encapsulant are contained in a raw material melt containing part comprising a cylindrical crucible having a bottom, the raw material containing part is heated to melt the raw material, and a seed crystal is brought into contact with a surface of a melt of the raw material in a state of being covered with the encapsulant to grow a crystal while the seed crystal is raised; a crystal shoulder part is grown from the seed crystal by setting a temperature gradient in a crystal growth direction to 25° C./cm or less and setting a temperature-fall amount to 0.25° C./hr or more. Thus, an iron-doped or undoped InP single crystal wafer in which an area having a dislocation density of 500/cm2 or less occupies 70% or more is realized.

Abstract: The inventors demonstrate herein that various Zintl compounds can be useful as thermoelectric materials for a variety of applications. Specifically, the utility of Ca3AlSb3, Ca5Al2Sb6, Ca5In2Sb6, Ca5Ga2Sb6, is described herein. Carrier concentration control via doping has also been demonstrated, resulting in considerably improved thermoelectric performance in the various systems described herein.

Abstract: The present disclosure is directed toward a composition and method of treating and preventing infection of pathogenic microorganisms and endopyhtic microorganisms in a plant through the use of phosphite compositions.

Abstract: A method for the manufacture of a III-V compound in the form of nanoparticles, such as those used in semi-conductors. The reaction proceeds at atmospheric pressure in a reaction solution by the reaction of a III compound source and a V compound source. The reaction proceeds in solvent of high boiling point. The solvent contains a stabilizer and a base. The manufactured III-V compound is precipitated from the reaction solution, isolated, purified and analyzed.

Abstract: Molybdic oxide is recovered from molybdenite by a multistep process in which (A) the molybdenite is converted to soluble and insoluble molybdic oxide by pressure oxidation, (B) the insoluble molybdic oxide is converted to soluble molybdic oxide by alkaline digestion and then combined with the soluble molybdic oxide, and (C) the molybdenum values of the combined streams are extracted into an organic phase using a nonprimary amine. The extracted molybdenum values are recovered from the organic phase using aqueous ammonia to form ammonium dimolybdate (ADM) which is recovered as refined crystals from a two-step calcination process.

Abstract: A process of synthesizing nanocrystals, the process including contacting a first precursor, a ligand compound, and a second precursor in a solvent having a boiling point of less than or equal to about 150° C. and a polarity index of less than or equal to 5, and performing a thermal decomposition reaction between the first precursor and the second precursor at a higher pressure than atmospheric pressure and at a higher temperature than a boiling point of the solvent, wherein at least one of the first precursor and the second precursor is a metal-containing precursor.

Abstract: Disclosed is a catalyst including metal phosphide for preparation of biodiesel, and a method of preparing biodiesel from feedstock comprising vegetable oil through hydrotreating using the catalyst. When the catalyst including metal phosphide is used as a catalyst for preparation of biodiesel, preparation activity of hydrotreated biodiesel is high even without continuous supply of sulfiding agent, and hydrotreating and isomerization reactions occur at the same time, thus obtaining high-quality hydrotreated biodiesel having a low pour point.

Abstract: A method and apparatus are presented for reducing halide-based contamination within deposited titanium-based thin films. Halide adsorbing materials are utilized within the deposition chamber to remove halides, such as chlorine and chlorides, during the deposition process so that contamination of the titanium-based film is minimized. A method for regenerating the halide adsorbing material is also provided.

Abstract: A wavelength converting substance is made of semiconductor material. The wavelength converting substance is suitable for absorbing an exciting light with the wavelength range falling between 300 nanometers and 490 nanometers and converting the exciting light to an emitted light with wavelength range falling between 450 nanometers and 750 nanometers.

Abstract: The present invention relates to a method for the preparation of a lithium phosphate compound with an olivine crystal structure, which has a chemical formula of LixMyM?1-yPO4, wherein 0.1?x?1, 0?y?1. The nano-scale lithium phosphate ceramic powder was synthesized by using a self-propagating combustion with reactants of soluble salts and the proper oxidizing agents, followed by heat treatment of powder to obtain nano-scale lithium phosphate compound with an olivine crystal structure in a complete crystal phase. The method of the present invention uses low cost materials and simple processes. The uniform crystal product materials are beneficial to the industrial application.

Abstract: A method for recovering phosphorus as a compound containing phosphorus from lamp waste, which contains luminophores, wherein a part, more than 20 wt.-%, of the luminophores are luminophores containing phosphorus, the method may include: a) mechanically partitioning out of coarse components; b) partitioning out of luminophores containing phosphorus as a dissolving process; c) separating the phosphorus; d) optionally carrying out at least one purification; and e) performing optional final treatment.

Abstract: A composition for preparing a semiconductor nanocrystal, the composition including (i) a Group II and/or Group III precursor, (ii) a Group VI and/or Group V precursor, (iii) an acid anhydride or acyl halide, and (iv) a solvent.

Abstract: The method for synthesizing indium phosphide nanoparticles using indium trichloride as an indium raw material and tris(dimethylamino)phosphine as a phosphorus raw material, includes a preparation step of mixing the indium raw material, the phosphorus raw material, an organic solvent having a boiling point of 170° C. or higher, and a particle surface ligand to obtain a mixture solution and a synthesis step of synthesizing the indium phosphide nanoparticles by heating the mixture solution to 150° C. or higher but lower than 170° C. In the method, the particle surface ligand is an aliphatic amine having a carbon number of 18 or more, and the indium trichloride is an anhydride.

Abstract: To provide near-infrared-absorbing particles which have a high transmittance in the visible light region and a low transmittance in the near infrared region and which, when incorporated, can give a near-infrared-absorbing coating film wherein the transmittance sharply changes in the wavelength range of from 630 to 700 nm; a process for their production; and their dispersion. Near-infrared-absorbing particles consisting essentially of crystallites of A1/nCuPO4 and having a number average aggregated particle size is from 20 to 200 nm, wherein A is at least one member selected from the group consisting of alkali metals (Li, Na, K, Rb and Cs), alkaline earth metals (Mg, Ca, Sr and Ba) and NH4, and n is 1 when A is an alkali metal or NH4, or 2 when A is an alkaline earth metal.

Abstract: Highly luminescent nanostructures, particularly highly luminescent quantum dots, are provided. The nanostructures have high photoluminescence quantum yields and in certain embodiments emit light at particular wavelengths and have a narrow size distribution. The nanostructures can comprise ligands, including C5-C8 carboxylic acid ligands employed during shell formation and/or dicarboxylic or polycarboxylic acid ligands provided after synthesis. Processes for producing such highly luminescent nanostructures are also provided, including methods for enriching nanostructure cores with indium and techniques for shell synthesis.

Abstract: A process for preparing a composition of mixed crystalline particles from columns 13-15 in which a liquid solution is produced by solubilization in a non-aqueous solvent medium of at least one first precursor chosen from coordination complexes including at least one element E1 from column 13, then the liquid solution is brought into contact with at least one second precursor chosen from the hydrides of at least one element E2 from column 15.

Abstract: A method of forming a metal chalcogenide material. The method comprises introducing a metal precursor and a chalcogenide precursor into a chamber, and reacting the metal precursor and the chalcogenide precursor to form a metal chalcogenide material on a substrate. The metal precursor is a carboxylate of an alkali metal, an alkaline earth metal, a transition metal, a post-transition metal, or a metalloid. The chalcogenide precursor is a hydride, alkyl, or aryl precursor of sulfur, selenium, or tellurium or a silylhydride, silylalkyl, or silylaryl precursor of sulfur, selenium, or tellurium. Methods of forming a memory cell including the metal chalcogenide material are also disclosed, as are memory cells including the metal chalcogenide material.

Abstract: A method for recycling organic waste material containing phosphorus oxides and metal oxides is particularly suited for recycling sewage sludge. The waste materials are mixed with chlorine carriers and then heat-treated at an air ratio of 0.85???1.6 and at least partially oxidized. The metal chlorides thus formed are drawn off and recovered and the fraction remaining after the metal chlorides have been drawn off is subjected to reduction in order to obtain elemental phosphorus.

Abstract: The present invention provides a metal material comprising an alloy that is represented by the compositional formula Mn3-xM1xSiyAlzM2a, wherein M1 is at least one element selected from the group consisting of Ti, V, Cr, We, Co, Ni, and Cu; M2 is at least one element selected from the group consisting of B, P, Ga, Ge, Sn, and Bi, where 0?x?3.0, 3.5?y?4.5, 2.5?z?3.5, and 0?a?1, the alloy having a negative Seebeck coefficient and an electrical resistivity of 1 m?·cm or less at a temperature of 25° C. or higher. The metal material of the present invention is a novel material that has good thermoelectric conversion capability in the intermediate temperature region and excellent durability, and that is useful as an n-type thermoelectric conversion material.

Abstract: Disclosed herein is a method for the preparation of metal phosphide nanocrystals using a phosphite compound as a phosphorous precursor. More specifically, disclosed herein is a method for preparing metal phosphide nanocrystals by reacting a metal precursor with a phosphite compound in a solvent. A method is also provided for passivating a metal phosphide layer on the surface of a nanocrystal core by reacting a metal precursor with a phosphite compound in a solvent. The metal phosphide nanocrystals have uniform particle sizes and various shapes.

Abstract: A method for the synthesis of rare earth containing phosphates of the LaPO4:Ce,Tb type comprising providing an initial charge of phosphate having a pH above 2 to a reactor; subsequently commencing introduction of a rare earth solution to the reactor, and subsequently, continuing to introduce both the phosphate and the rare earth solution to the reactor to form a mixture; whereby a rare earth phosphate precipitate is produced, at least a portion of which is precipitated while the pH of the mixture is less than 2.

Abstract: The present invention provides improved methods for producing the aluminum adjuvant AlPO4. In one aspect, the present invention provides a method for producing aluminum phosphate which comprises the steps of mixing a solution of aluminum chloride and a solution of sodium phosphate tribasic to produce an aluminum phosphate precipitate, wherein the improvement comprises settling the aluminum phosphate precipitate at a temperature in the range of about 50° C. to about 70° C. In another aspect, the present invention is directed to methods for producing aluminum phosphate within a closed system.

Abstract: A dichalcogenide thermoelectric material having a very low thermal conductivity in comparison with a conventional metal or semiconductor is described. The dichalcogenide thermoelectric material has a structure of Formula 1 below: RX2-aYa??Formula 1 wherein R is a rare earth or transition metal magnetic element, X and Y are each independently an element selected from the group consisting of S, Se, Te, P, As, Sb, Bi, C, Si, Ge, Sn, B, Al, Ga, In, and a combination thereof, and 0?a<2.