Peroxide Patents (Class 423/582)
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Patent number: 10517977Abstract: A device and method for decontaminating the interior of a biosafety cabinet using a drug considered to be safe for humans is provided. A device for decontaminating the interior of a biosafety cabinet includes an ultrasonic atomizer for atomizing a peracetic acid disinfectant using ultrasound and releasing droplets; a diffusion fan; a circulation fan; a temperature-humidity sensor; and a controller.Type: GrantFiled: July 10, 2015Date of Patent: December 31, 2019Assignee: NITTA CORPORATIONInventor: Akio Sakaki
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Patent number: 9540298Abstract: [Problem] To provide a process for producing an aromatic dihydroxy compound, in which a hydroquinone compound is highly selectively produced while suppressing formation of by-products derived from a solvent and maintaining a high yield based on hydrogen peroxide when a phenol compound is allowed to react with hydrogen peroxide. [Solution] A process for producing an aromatic dihydroxy compound, including allowing a phenol compound to react with hydrogen peroxide in the presence of a titanosilicate, a C4-C5 alcohol containing a tertiary or quaternary carbon, and water and/or methanol, the amount of the water and/or methanol being 5 to 90 mass % based on the total mass of the reaction liquid.Type: GrantFiled: September 11, 2014Date of Patent: January 10, 2017Assignee: MITSUI CHEMICALS, INC.Inventors: Yuya Goto, Takashi Nabeta
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Patent number: 9433697Abstract: The present invention relates to odor-inhibiting compositions comprising water-absorbing polymer particles and metal peroxides, and to the production thereof.Type: GrantFiled: December 8, 2014Date of Patent: September 6, 2016Assignee: BASF SEInventors: Volker Braig, Thomas Daniel, Rupert Konradi, Herbert Platsch, Bettina Sobotka, Axel Jentzsch
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Patent number: 8951495Abstract: The present invention relates to odor-inhibiting compositions comprising water-absorbing polymer particles and metal peroxides, and to the production thereof.Type: GrantFiled: August 23, 2010Date of Patent: February 10, 2015Assignee: BASF SEInventors: Volker Braig, Thomas Daniel, Rupert Konradi, Herbert Platsch, Bettina Sobotka, Axel Jentzsch
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Patent number: 8877149Abstract: Combustion flue gas containing NOX and SOX is treated to remove NOX in a multistep system in which NOX is reduced in the flue gas stream via selective catalytic reduction or selective non-catalytic reduction with ammonia or an ammonia-forming compound, followed treatment with hydrogen peroxide to remove residual ammonia and, optionally, treatment with an alkali reagent to reduce residual NOX in the flue gas stream. The NOX-depleted flue gas stream may also be subjected to a desulfurization treatment for removal of SOX.Type: GrantFiled: February 9, 2012Date of Patent: November 4, 2014Assignee: Peroxychem LLCInventors: Henry A. Pfeffer, David E. Smith
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Publication number: 20140212669Abstract: An object of the present invention is to provide rounded zinc peroxide particles having a large particle diameter, the rounded zinc peroxide particles having excellent performance because they have an average particle diameter of 0.04 ?m or more, a small aspect ratio and a shape close to a spherical shape; rounded zinc oxide particles which are obtained by calcinating the rounded zinc peroxide particles and which have a small aspect ratio and a sharp particle size distribution; a method for production thereof; and a cosmetic and a heat releasing filler each containing the rounded zinc oxide particles. Provided are rounded zinc peroxide particles having an average particle diameter of 0.04 ?m or more and an aspect ratio of 2.0 or less, and rounded zinc oxide particles which are obtained by thermally decomposing the rounded zinc peroxide particles and which have an average particle diameter of 0.04 ?m or more and an aspect ratio of 2.0 or less.Type: ApplicationFiled: June 8, 2012Publication date: July 31, 2014Applicant: Sakai Chemical Industry Co., Ltd.Inventors: Satoru Sueda, Atsuki Terabe, Mitsuo Hashimoto, Koichiro Magara, Keita Kobayashi
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Patent number: 8715612Abstract: Zinc peroxide nanoparticles, used for arsenic and chromium removal, were synthesized using zinc acetate di-hydrate as precursors in ammonical water medium at room temperature.Type: GrantFiled: August 6, 2013Date of Patent: May 6, 2014Assignee: Council of Scientific & Industrial ResearchInventors: Nahar Singh, Rashmi, Sukhvir Singh, Renu Pashricha, Prabhat Kumar Gupta, Daya Soni
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Publication number: 20140045183Abstract: Provided are a method and a kit for detecting 5-hydroxymethylcytosine in a nucleic acid. The method is a method for detecting 5-hydroxymethylcytosine in a nucleic acid, comprising the steps of: (1) oxidizing 5-hydroxymethylcytosine in a nucleic acid sample by treating the nucleic acid sample with a tungstic acid-based oxidizing agent comprising peroxotungstic acid, tungstic acid, a salt thereof, or a combination thereof with a reoxidizing agent; and (2) determining the position of the oxidized 5-hydroxymethylcytosine in the nucleic acid sample.Type: ApplicationFiled: April 16, 2012Publication date: February 13, 2014Applicant: RIKENInventors: Akimitsu Okamoto, Kaori Sugizaki, Akiko Nakamura, Hiroyuki Yanagisawa, Shuji Ikeda
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Publication number: 20130203178Abstract: The method for detection of cyanide in water is a method for the detection of a highly toxic pollutant, cyanide, in water using ZnO2 nanoparticles synthesized locally by an elegant Pulsed Laser Ablation technique. ZnO2 nanoparticles having a median size of 4 nm are synthesized from pure zinc metal target under UV laser irradiation in a 1-10% H2O2 environment in deionized water. The synthesized ZnO2 nanoparticles are suspended in dimethyl formamide in the presence of Nafion, and then ultrasonicated to create a homogenous suspension, which is used to prepare a thin film of ZnO2 nanoparticles on a metal electrode. The electrode is used for cyanide detection.Type: ApplicationFiled: March 14, 2013Publication date: August 8, 2013Inventors: MOHAMMED ASHRAF GONDAL, QASEM AHMED QASEM DRMOSH, Z.H. YAMANI, TAWFIK ABDO SALEH
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Publication number: 20120225356Abstract: A galvanic element containing a substantially transition metal-free oxygen-containing conversion electrode, a transition metal-containing cathode, and an aprotic lithium electrolyte. The substantially transition metal-free oxygen-containing conversion. electrode materials contain lithium hydroxide and/or lithium peroxide and/or lithium oxide, and in the charged state additionally contain lithium hydride, and are contained in a galvanic element, for example a lithium battery, as the anode. Methods for producing substantially transition metal-free oxygen-containing conversion electrode materials and galvanic elements made of substantially transition metal-free oxygen-containing conversion electrode materials are also provided.Type: ApplicationFiled: November 18, 2010Publication date: September 6, 2012Inventor: Ulrich Wietelmann
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Patent number: 8147785Abstract: Combustion flue gas containing NOX and SOX is treated to remove NOX in a multistep system in which NOX is reduced in the flue gas stream via selective catalytic reduction or selective non-catalytic reduction with ammonia or an ammonia-forming compound, followed treatment with hydrogen peroxide to remove residual ammonia and, optionally, treatment with an alkali reagent to reduce residual NOX in the flue gas stream. The NOX-depleted flue gas stream may also be subjected to a desulfurization treatment for removal of SOX.Type: GrantFiled: May 12, 2010Date of Patent: April 3, 2012Assignee: FMC CorporationInventors: Henry A. Pfeffer, David E. Smith
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Patent number: 7993495Abstract: A method is provided for decontaminating a surface that is susceptible to contamination by a contaminant by applying to the surface a coating which produces a decontaminating agent for the contaminant in response to a signal, connecting the electroactive coating to a source of a signal, and when the surface is contaminated, applying the signal to the electroactive coating, thereby producing one or more decontaminating agents which neutralize or destroy the contaminant. Coatings for practicing the method and articles that have been protected by the novel coatings are also provided.Type: GrantFiled: June 21, 2006Date of Patent: August 9, 2011Assignee: Crosslink Polymer Research, a division of Lumimove, Inc.Inventors: Patrick J. Kinlen, Yiwei Ding, James K. Bashkin, Shifeng Hou
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Patent number: 7754445Abstract: The invention relates to a method for the enzymatic production of a curing agent in its fluid state, e.g. liquid, comprising, in free phase, at least one oxygenated chemical species. Said method consists in bringing into contact at least one enzymatic catalysts agent, comprising at lease one peroxidase-type enzyme; an oxidizable substrate in aqueous phase that can be oxidized by the action of an oxygen donor, by catalysis by said enzymatic catalysis agent, generating said oxygenated chemical species in free phase; and said oxygen donor.Type: GrantFiled: May 31, 2002Date of Patent: July 13, 2010Assignee: TMI EuropeInventor: Herve Casez
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Patent number: 7264747Abstract: A microporous diffuser includes a first elongated member including at least one sidewall having a plurality of microscopic openings. The sidewall defines an interior hollow portion of the member. The diffuser has a second elongated member having a second sidewall having a plurality of microscopic openings, the second member being disposed through the hollow region of the first member. The diffuser includes an end cap to seal a first end of the microporous diffuser and an inlet cap disposed at a second end of microporous diffuser for receiving inlet fittings.Type: GrantFiled: January 9, 2006Date of Patent: September 4, 2007Inventor: William B. Kerfoot
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Patent number: 7261942Abstract: Method for producing novel photochemically-active metal oxide-containing aqueous compositions such as TiO2 compositions coated or sprayed and dried under ambient conditions to form novel photochemically-active, colorless coatings having strong wetability and adhesion to clear substrates such as window glass. Preferably the present compositions include a suitable wetting agent or combination of agents to improve the wetability of the Titanium peroxide-containing amorphous film, allowing thinner films to be readily applied. Also the inclusion of an acrylic aliphatic urethane polymer can replace wholly or partially the titanium peroxide sol and provide additional film forming and wetability properties. The acrylic urethane polymer reduces or eliminates the amount of titanyl peroxide that is required and thereby reduces or eliminates the yellow color.Type: GrantFiled: March 3, 2005Date of Patent: August 28, 2007Assignee: Prizmalite Industries Inc.Inventor: John Andrews
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Publication number: 20070140949Abstract: This invention relates to a method for generating peroxides in petroleum streams and extracting oxidized sulfur and nitrogen compounds. Peroxides are generated in-situ by combining the petroleum stream with a high neutralization number (HNN) crude and adding an oxygen-containing stream. Alternatively, the oxidation of sulfur and nitrogen compounds may be accomplished by adding peroxides in the presence of oil soluble metal catalysts. The peroxides oxidize nitrogen and sulfur compounds in the petroleum stream to more polar compounds which are solvent extracted.Type: ApplicationFiled: December 16, 2005Publication date: June 21, 2007Inventors: Thomas R. Palmer, William J. Murphy
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Patent number: 6884752Abstract: Method for producing novel photochemically-active metal oxide-containing aqueous compositions such as TiO2 compositions coated or sprayed and dried under ambient conditions to form novel photochemically-active, colorless coatings having strong wetability and adhesion to clear substrates such as window glass. Preferably the present compositions include a suitable wetting agent or combination of agents to improve the wetability of the Titanium peroxide-containing amorphous film, allowing thinner films to be readily applied. Also the inclusion of an acrylic aliphatic urethane polymer can replace wholly or partially the titanium peroxide sol and provide additional film forming and wetability properties. The acrylic urethane polymer reduces or eliminates the amount of titanyl peroxide that is required and thereby reduces or eliminates the yellow color.Type: GrantFiled: December 31, 2002Date of Patent: April 26, 2005Assignee: Prizmalite Industries, Inc.Inventor: John Andrews
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Publication number: 20040127354Abstract: Method for producing novel photochemically-active metal oxide-containing aqueous compositions such as TiO2 compositions coated or sprayed and dried under ambient conditions to form novel photochemically-active, colorless coatings having strong wetability and adhesion to clear substrates such as window glass. Preferably the present compositions include a suitable wetting agent or combination of agents to improve the wetability of the Titanium peroxide-containing amorphous film, allowing thinner films to be readily applied. Also the inclusion of an acrylic aliphatic urethane polymer can replace wholly or partially the titanium peroxide sol and provide additional film forming and wetability properties. The acrylic urethane polymer reduces or eliminates the amount of titanyl peroxide that is required and thereby reduces or eliminates the yellow color.Type: ApplicationFiled: December 31, 2002Publication date: July 1, 2004Inventor: John Andrews
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Publication number: 20030161784Abstract: A titanium oxide precursor which is used for producing a fine-particle titanium oxide showing a high photocatalytic activity is provided. The titanium oxide precursor is an oxygen-atom-containing titanium compound other than anatase-form titanium oxide, and has a maximum exothermic peak at a temperature in the range of from about 30° C. to about 500° C. in a differential thermal analysis curve and shows decrease in weight in a thermogravimetry curve at about the same temperature at which the maximum exothermic peak is shown in the differential thermal analysis curve when subjected to a thermogravimetry and differential thermal analysis under the condition of a temperature rising rate of 20° C./min.Type: ApplicationFiled: February 20, 2003Publication date: August 28, 2003Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Kensen Okusako, Hiroyuki Ando
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Publication number: 20030079981Abstract: A distilling apparatus and method use a two step distillation and purification process for processing a waste liquid, such as an impure sulfuric acid solution, to form a highly concentrated sulfuric acid solution. First, the waste liquid is stored in a concentrating column, where it is heated. A condenser, which uses the waste liquid as a cooling medium, condenses the vapor generated by the heater. The condensed vapor is passed through a filter, which separates impurities out of the waste liquid, prior to feeding the waste liquid back into the concentrating column. Water is then removed from the waste liquid via a distilling process. The resulting concentrated liquid is then fed to a purifying column, where it is again heated, to remove residue, and condensed, resulting in a highly pure waste liquid.Type: ApplicationFiled: November 22, 2002Publication date: May 1, 2003Applicant: FUJITSU LIMITEDInventors: Hiroshi Osuda, Toru Matoba, Daisuke Adachi, Masataka Fukuizumi
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Publication number: 20010016187Abstract: A process for producing oxidized organic chemical products such as propylene oxide from various organic chemical feedstocks utilizing as oxidant directly produced hydrogen peroxide (H2O2) intermediate oxidizing agent. The hydrogen peroxide intermediate is directly produced from hydrogen and oxygen feeds plus a suitable solvent in a first catalytic reaction step utilizing an active supported phase-controlled noble metal catalyst at reaction conditions of 0-100° C. temperature and 300-3,000 psig pressure. An organic chemical feedstock such as propylene together with the hydrogen peroxide intermediate and solvent solution are fed into a second catalytic reactor maintained at 0-150° C. temperature and 15-1,500 psig pressure and oxidized to produce a desired crude oxidized organic product such as propylene oxide, which is purified by distillation steps and recovered from the solvent solution.Type: ApplicationFiled: December 8, 2000Publication date: August 23, 2001Applicant: Hydrocarbon Technologies, Inc.Inventors: Bing Zhou, Michael A. Rueter
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Patent number: 6267944Abstract: A method of preparing a solution for titanium oxide film is provided such that said solution has the effect of a photocatalyst, by coating, or impregnating therewith a variety of substrates being positioned in a place where no ultraviolet light is emitted. Utilizing a solution for titania film provided by a mixture of a titanium peroxide solution made from a compound of a titanium hydrate gel and a peroxide solution, and a solution forming titanium peroxide particles by calcining said titanium peroxide solution at a temperature over 80° C., particles of capsicin, magnetite and tourmaline, as well as a silica solution are each compounded to said solution for titania film, such that an improved solution for titania film can be obtained having the photocatalystic effect without any exterior light source.Type: GrantFiled: August 31, 1999Date of Patent: July 31, 2001Assignee: Morioki Sangyo Company LimitedInventor: Yoshihar Mori
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Patent number: 6087089Abstract: A composition, method, and test device for quantitatively determining the oxidant concentration of a test sample are disclosed. The test device includes a test pad having a suitable carrier matrix incorporating an indicator reagent composition capable of interacting with an oxidant to produce a detectable and measurable response for oxidant over a wide concentration range of oxidant. An indicator reagent composition contains: (a) an iodide salt, (b) a buffer, and (c) a water-soluble polymer, preferably a cellulose-based polymer. An indicator reagent composition is incorporated into a carrier matrix, like filter paper, to provide a test pad useful in a dry phase oxidant assay of a test sample, especially for test samples containing a high concentration of oxidant, like chlorine or a peroxide.Type: GrantFiled: June 2, 1998Date of Patent: July 11, 2000Assignee: Integrated Biomedical Technology, Inc.Inventor: Wen H. Wu
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Patent number: 5851439Abstract: A coloring layer composition for a chromatic device of the present invention contains an oxide such as tungsten oxide or niobium oxide and so on as a solute, water and an organic solvent such as propanol. In the step of forming a reduction coloring layer, a film is formed by using a peroxotungstic acid solution containing 100 parts by weight of WO.sub.3.aNb.sub.2 O.sub.5.bH.sub.2 O.sub.2 .andgate.cH.sub.2 O (wherein a, b and c are each a positive number) as a solute, 20 to 120 parts by weight of water and 80 to 800 parts by weight of n-propanol as an organic solvent. At this time, a dip coating method is used, and the vertical pulling-up speed is less than 15 cm/min. The present invention can effectively prevent unevenness and separation of the reduction coloring layer.Type: GrantFiled: May 16, 1996Date of Patent: December 22, 1998Assignee: Kabushiki Kaisha Toyoda Jidoshokki SeisakushoInventors: Toshiki Inoue, Yoshifumi Kato, Hisashi Shiraki, Takanori Murasaki
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Patent number: 5820841Abstract: A method of making an inorganic salt-hydrogen peroxide complex includes the following steps: (a) mixing the inorganic salt with sufficient water for a time sufficient to form a soft paste, (b) mixing the paste with an aqueous hydrogen peroxide solution to form a hydrogen peroxide-containing paste, and (c) drying the hydrogen peroxide-containing paste. A hydrate method of making Na.sub.4 P.sub.2 O.sub.7.3H.sub.2 O.sub.2 includes the steps of: mixing sodium pyrophosphate decahydrate solid with an aqueous solution of hydrogen peroxide having a concentration of less than 30%, and drying the mixture. Compositions of matter include K.sub.2 HPO.sub.4.3H.sub.2 O.sub.2, KH.sub.2 PO.sub.4.H.sub.2 O.sub.2 Ca.sub.2 P.sub.2 O.sub.7.nH.sub.2 O.sub.2, Ca.sub.2 P.sub.2 O.sub.4.nH.sub.2 O.sub.2, Na.sub.2 SO.sub.4.nH.sub.2 O.sub.2, K.sub.2 SO.sub.4.nH.sub.2 O.sub.2, Na.sub.2 SiO.sub.3.nH.sub.2 O.sub.2 and Na.sub.2 SiO.sub.7.nH.sub.2 O.sub.2.Type: GrantFiled: September 19, 1996Date of Patent: October 13, 1998Assignee: Ethicon, Inc.Inventors: Xiaolan Chen, Paul Taylor Jacobs, Szu-Min Lin
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Patent number: 5780257Abstract: Method for detecting peroxidase or hydrogen peroxide with high sensitivity. Both peroxidase and hydrogen peroxide are prepared such that one of them is overabundant to the other. Phenoxy radicals are produced from a p-substituted phenol compound by the action of peroxidase in the presence of hydrogen peroxide. The free radicals are trapped by a hydroxy amine compound, and stable radical species are produced. Electron spin resonances of the stable radical species are measured.Type: GrantFiled: July 18, 1996Date of Patent: July 14, 1998Assignees: Yamagata Technopolis Foundation, JEOL Ltd.Inventors: Masaaki Aoyama, Masanobu Shiga
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Patent number: 5702911Abstract: The present invention relates to an improved test composition for the diagnosis of gastric ulcers, duodenal ulcers, gastritis, gastric lymphoma and gastric carcinoma by the detection of the bacteria Helicobacter pylori and the enzyme catalase associated with such conditions. The new test composition differs from the prior art agar compositions in being an aqueous solution containing hydrogen peroxide, urea, monobasic sodium phosphate and bromthymol blue as an indicator, and in being far more rapid than the prior art test compositions.Type: GrantFiled: August 15, 1996Date of Patent: December 30, 1997Assignee: Chek-Med Systems, Inc.Inventor: Robert G. Whalen
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Patent number: 5552131Abstract: A process and apparatus for the molecular oxygen oxidation of a secondary alcohol such as isopropanol to hydrogen peroxide is provided.Type: GrantFiled: June 30, 1994Date of Patent: September 3, 1996Assignee: ARCO Chemical Technology, L.P.Inventor: John C. Jubin, Jr.
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Patent number: 5154912Abstract: The peroxides which include the O.sup.17 isotope, especially the hydrogen peroxides and peroxides and hydroperoxides prepared therefrom, are well adapted as nonradioactive labeled compounds for use in the medicinal and biological arts.Type: GrantFiled: September 20, 1990Date of Patent: October 13, 1992Assignee: AtochemInventors: Jean-Pierre Schirmann, Jean-Jacques Barieux
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Patent number: 5061599Abstract: A radiation-sensitive material comprising a polyacid composed of tungsten and niobium, titanium and/or tantalum. A uniform film can be formed by an easy spin coating method. The polyacid has a radiation sensitivity higher than that of a polyacid comprising only tungsten.Type: GrantFiled: January 5, 1990Date of Patent: October 29, 1991Assignee: Hitachi, Ltd.Inventors: Tetsuichi Kudo, Akira Ishikawa, Hiroshi Okamoto, Katsuki Miyauchi, Takao Iwayanagi, Fumio Murai, Shinji Okazaki
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Patent number: 5035478Abstract: A material for an optical component comprising polytungstic acid having peroxo groups, and an optical component, at least part of which is constituted of a thin film of the above-mentioned material. By using this material, a thin film of an inorganic material having an excellent stability is formed by the inexpensive wet painting method. An optical component using the above-mentioned thin film can be formed on an arbitrary substrate with high accuracy at a low temperature of about 100.degree. C. or below. The polytungstic acid may contain carbon as a heteroatom and/or may have Nb, Ti, V, Ta and/or Mo substituted for part of W.Type: GrantFiled: August 14, 1990Date of Patent: July 30, 1991Assignee: Hitachi, Ltd.Inventors: Akira Ishikawa, Yukio Ito, Hiroshi Okamoto, Tetsuichi Kudo, Katsuki Miyauchi
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Patent number: 4962040Abstract: 2-Hydrazono-4,6-dinitrobenzthiazolones of the formula ##STR1## in which X.sub.1 represents hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -hydroxyalkyl, C.sub.1 -C.sub.4 -sulphoalkyl or C.sub.1 -C.sub.4 -sulphatoalkyl, andX.sub.2 represents hydrogen or --SO.sub.2 X.sub.3, whereX.sub.3 may represent hydrogen, C.sub.1 -C.sub.8 -alkyl or optionally substituted aryl andX.sub.1 also represents a double bond between the cyclic nitrogen atom and the carbon atom 2 according to the formula II below: ##STR2## where X.sub.2 has the meaning specified under the above formula. These hydrazones may be employed in the preparation of azo dyestuffs and as color formers for detecting of biological substances, and in the determination of H.sub.2 O.sub.2.Type: GrantFiled: August 10, 1989Date of Patent: October 9, 1990Assignee: Bayer AktiengesellschaftInventors: Herbert Hugl, Aloysius Engel, Klaus Wehling
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Patent number: 4515664Abstract: Discloses electro-organic synthesis process using a water wetted gaseous feed. Also discloses the electro-organic synthesis of hydrogen peroxide; 1,4-naphthoquinone; and organic nitriles.Type: GrantFiled: January 27, 1984Date of Patent: May 7, 1985Assignee: PPG Industries, Inc.Inventor: Malcolm Korach
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Patent number: 4427644Abstract: Disclosed is a continuous process for the production of bivalent metal peroxides, comprising the steps of introducing into an intensive mixing apparatus a solid, anhydrous or hydrated oxide or hydroxide of a bivalent metal; simultaneously introducing into the intensive mixing apparatus a solution of hydrogen peroxide, whereby the solid bivalent metal compound and the peroxide are intensively mixed and react to produce a reaction mixture containing bivalent metal peroxide; transporting the reaction mixture directly to a rapid dryer; and rapidly drying the reaction mixture to produce the bivalent metal peroxide in solid form.Type: GrantFiled: July 6, 1981Date of Patent: January 24, 1984Assignee: Peroxid-Chemie GmbHInventors: Werner Doetsch, Helmut Dillenburg, Paul-Wilhelm Fuchs, Helmut Honig
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Patent number: 4400367Abstract: Disclosed is an adduct of the formula 4Na.sub.2 SO.sub.4.2H.sub.2 O.sub.2.KCl and a process for the preparation of this adduct by crystallizing the adduct out of a suspension containing from about 100 to 900 g of hydrogen peroxide per liter of solution and a quantity of sodium sulphate and potassium chloride which exceeds the saturation concentration of the adduct at the crystallization temperature, whereby the weight ratio of sodium sulphate to potassium chloride is in the range of from about 2:1 to 12:1. A continuous process is also disclosed for producing the adduct.Type: GrantFiled: September 29, 1982Date of Patent: August 23, 1983Assignee: Peroxid-Chemie GmbHInventors: Werner Doetsch, Helmut Honig, Rudolf Siegel
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Patent number: 4399633Abstract: Alkali metal or alkaline earth metal peroxides, for example, particularly, calcium peroxide, are produced by recovering a moist peroxide product from an aqueous mixture, formed by reacting hydrogen peroxide and a hydroxide or oxide of the alkali metal or alkaline earth metal, and drying the moist product by means of a pneumatic conveyer drier. The peroxide so produced is suitable for granulation. Alternatively, particulate substances, such as seed, are coated with the peroxide by blending with the moist peroxide product and passing the blend through the pneumatic conveyer drier.Type: GrantFiled: April 9, 1981Date of Patent: August 23, 1983Assignee: Interox Chemicals LimitedInventors: Douglas P. Haughey, Malcolm H. Millar
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Patent number: 4231890Abstract: A bleaching composition which does not cause color change or fading of fabrics, which composition contains 50 to 98 weight % of a peroxide which releases oxygen in an aqueous solution, 1 to 49 weight % of nitrilotriacetic acid or salt thereof and 1 to 49 weight % of a water softener as critical components.Type: GrantFiled: November 2, 1978Date of Patent: November 4, 1980Assignee: Kao Soap Co., Ltd.Inventors: Kouichi Yagi, Yunosuke Nakagawa
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Patent number: 4128491Abstract: A particulate alkali metal perborate having an outer layer of chemically bound calcium in an amount of from about 0.4 to 2.0% by weight of the total particle, to slow down the rate of dissolution. A process for preparing said slow-dissolving perborate.The slow-dissolving perborate is especially designed for mixing with detergent granules and has improved resistance against catalase attack under practical use conditions.Type: GrantFiled: October 27, 1977Date of Patent: December 5, 1978Assignee: Lever Brothers CompanyInventor: Leo W. A. Melles
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Patent number: 4116859Abstract: Oxygen-containing bleach products are prepared by reaction of a source of hydroperoxy groups, such as hydrogen peroxide or ozone, with a water-soluble multi-metal, inorganic, amide group-containing monomeric complex. Such complex is obtained by reacting, in the presence of aqueous ammonia, at least one non-alkaline metal with an alkali metal hydroxide in accordance with a reaction sequence which produces reactive NH.sub.2 groups.Type: GrantFiled: January 10, 1977Date of Patent: September 26, 1978Inventor: George G. Merkl
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Patent number: 4094758Abstract: The present invention relates to a process for preparing high purity inorganic higher oxides of the alkali and alkaline earth metals by subjecting the hydroxide of the alkali or alkaline earth metal to a radio frequency discharge sustained in oxygen. The invention is particularly adaptable to the production of high purity potassium superoxide (KO.sub.2) by subjecting potassium hydroxide to glow discharge sustained in oxygen under the pressure of about 0.75 to 1.00 torr.Type: GrantFiled: January 19, 1977Date of Patent: June 13, 1978Inventors: James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher, Pasupati Sadhukhan, Alexis T. Bell
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Patent number: 4032623Abstract: A hydroperoxy-group-containing aluminum compound is prepared by a process which comprises:Contacting and reacting, at room temperature or below, and in the substantial absence of water, (a) a reactive metal comprising aluminum of a purity of at least 99.9% by weight permeated with a liquid metal selected from mercury, gallium and indium/gallium alloys with (b) a liquid reactant comprising (i) hydrogen peroxide in (ii) a liquid organic compound having no multiple carbon-to-carbon bonds.The aluminum compounds produced can be used, for example, as substrates for electronics, in the preparation of synthetic gems, ceramics and paint pigments. The aluminum compound is prepared in sheet for plate form, resembling mica in physical appearance.In an alternative embodiment, a metal or metal salt is added to the reactive system to yield a hydroperoxy-group-containing aluminum compound with the desired metal deposited thereon.Type: GrantFiled: August 16, 1976Date of Patent: June 28, 1977Inventor: George G. Merkl
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Patent number: 4008167Abstract: A bleaching composition is disclosed characterized by containing (a) sodium percarbonate which has been heated at a temperature of 75.degree. to 135.degree. C for a time ranging from 5 to 30 minutes at 135.degree. C to 2 to 6 hours at 75.degree. C and (b) an activating agent for the sodium percarbonate.Type: GrantFiled: March 5, 1975Date of Patent: February 15, 1977Assignee: Kao Soap Co., Ltd.Inventors: Yunosuke Nakagawa, Masaaki Nishimura, Koitsu Sato
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Patent number: 4005182Abstract: An adduct having the formula: 4Na.sub.2 SO.sub.4. 2H.sub.2 O.sub.2. NaCl, is prepared by reacting sodium sulfate with hydrogen peroxide in an aqueous solution, in the presence of sodium chloride in the reaction system.Type: GrantFiled: July 7, 1975Date of Patent: January 25, 1977Assignees: Kao Soap Co., Ltd., Nippon Peroxide Co., Ltd.Inventors: Yoshio Ito, Toshio Mashiko
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Patent number: 3979313Abstract: A bleaching composition comprising a hydrogen peroxide adduct having the formula:4Na.sub.2 SO.sub.4.sup.. 2H.sub.2 O.sub.2.sup.. NaCland an activating agent.Type: GrantFiled: July 7, 1975Date of Patent: September 7, 1976Assignees: Kao Soap Co., Ltd., Nippon Peroxide Co., Ltd.Inventors: Yunosuke Nakagawa, Shigetsugu Sugiura, Kinjiro Matsunaga, Yoshio Ito
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Patent number: 3953350Abstract: A bleaching composition is disclosed characterized by containing sodium percarbonate which was treated by subjecting it to heating at a temperature of 75.degree. to 135.degree.C, for a heating time ranging (1) from 2 to 6 hours at 75.degree.C to (2) 5 to 30 minutes at 135.degree.C.Type: GrantFiled: October 21, 1974Date of Patent: April 27, 1976Assignee: Kao Soap Co., Ltd.Inventors: Takashi Fujino, Masaaki Nishimura, Makoto Yamanaka