Peroxide Patents (Class 423/582)
  • Patent number: 10517977
    Abstract: A device and method for decontaminating the interior of a biosafety cabinet using a drug considered to be safe for humans is provided. A device for decontaminating the interior of a biosafety cabinet includes an ultrasonic atomizer for atomizing a peracetic acid disinfectant using ultrasound and releasing droplets; a diffusion fan; a circulation fan; a temperature-humidity sensor; and a controller.
    Type: Grant
    Filed: July 10, 2015
    Date of Patent: December 31, 2019
    Assignee: NITTA CORPORATION
    Inventor: Akio Sakaki
  • Patent number: 9540298
    Abstract: [Problem] To provide a process for producing an aromatic dihydroxy compound, in which a hydroquinone compound is highly selectively produced while suppressing formation of by-products derived from a solvent and maintaining a high yield based on hydrogen peroxide when a phenol compound is allowed to react with hydrogen peroxide. [Solution] A process for producing an aromatic dihydroxy compound, including allowing a phenol compound to react with hydrogen peroxide in the presence of a titanosilicate, a C4-C5 alcohol containing a tertiary or quaternary carbon, and water and/or methanol, the amount of the water and/or methanol being 5 to 90 mass % based on the total mass of the reaction liquid.
    Type: Grant
    Filed: September 11, 2014
    Date of Patent: January 10, 2017
    Assignee: MITSUI CHEMICALS, INC.
    Inventors: Yuya Goto, Takashi Nabeta
  • Patent number: 9433697
    Abstract: The present invention relates to odor-inhibiting compositions comprising water-absorbing polymer particles and metal peroxides, and to the production thereof.
    Type: Grant
    Filed: December 8, 2014
    Date of Patent: September 6, 2016
    Assignee: BASF SE
    Inventors: Volker Braig, Thomas Daniel, Rupert Konradi, Herbert Platsch, Bettina Sobotka, Axel Jentzsch
  • Patent number: 8951495
    Abstract: The present invention relates to odor-inhibiting compositions comprising water-absorbing polymer particles and metal peroxides, and to the production thereof.
    Type: Grant
    Filed: August 23, 2010
    Date of Patent: February 10, 2015
    Assignee: BASF SE
    Inventors: Volker Braig, Thomas Daniel, Rupert Konradi, Herbert Platsch, Bettina Sobotka, Axel Jentzsch
  • Patent number: 8877149
    Abstract: Combustion flue gas containing NOX and SOX is treated to remove NOX in a multistep system in which NOX is reduced in the flue gas stream via selective catalytic reduction or selective non-catalytic reduction with ammonia or an ammonia-forming compound, followed treatment with hydrogen peroxide to remove residual ammonia and, optionally, treatment with an alkali reagent to reduce residual NOX in the flue gas stream. The NOX-depleted flue gas stream may also be subjected to a desulfurization treatment for removal of SOX.
    Type: Grant
    Filed: February 9, 2012
    Date of Patent: November 4, 2014
    Assignee: Peroxychem LLC
    Inventors: Henry A. Pfeffer, David E. Smith
  • Publication number: 20140212669
    Abstract: An object of the present invention is to provide rounded zinc peroxide particles having a large particle diameter, the rounded zinc peroxide particles having excellent performance because they have an average particle diameter of 0.04 ?m or more, a small aspect ratio and a shape close to a spherical shape; rounded zinc oxide particles which are obtained by calcinating the rounded zinc peroxide particles and which have a small aspect ratio and a sharp particle size distribution; a method for production thereof; and a cosmetic and a heat releasing filler each containing the rounded zinc oxide particles. Provided are rounded zinc peroxide particles having an average particle diameter of 0.04 ?m or more and an aspect ratio of 2.0 or less, and rounded zinc oxide particles which are obtained by thermally decomposing the rounded zinc peroxide particles and which have an average particle diameter of 0.04 ?m or more and an aspect ratio of 2.0 or less.
    Type: Application
    Filed: June 8, 2012
    Publication date: July 31, 2014
    Applicant: Sakai Chemical Industry Co., Ltd.
    Inventors: Satoru Sueda, Atsuki Terabe, Mitsuo Hashimoto, Koichiro Magara, Keita Kobayashi
  • Patent number: 8715612
    Abstract: Zinc peroxide nanoparticles, used for arsenic and chromium removal, were synthesized using zinc acetate di-hydrate as precursors in ammonical water medium at room temperature.
    Type: Grant
    Filed: August 6, 2013
    Date of Patent: May 6, 2014
    Assignee: Council of Scientific & Industrial Research
    Inventors: Nahar Singh, Rashmi, Sukhvir Singh, Renu Pashricha, Prabhat Kumar Gupta, Daya Soni
  • Publication number: 20140045183
    Abstract: Provided are a method and a kit for detecting 5-hydroxymethylcytosine in a nucleic acid. The method is a method for detecting 5-hydroxymethylcytosine in a nucleic acid, comprising the steps of: (1) oxidizing 5-hydroxymethylcytosine in a nucleic acid sample by treating the nucleic acid sample with a tungstic acid-based oxidizing agent comprising peroxotungstic acid, tungstic acid, a salt thereof, or a combination thereof with a reoxidizing agent; and (2) determining the position of the oxidized 5-hydroxymethylcytosine in the nucleic acid sample.
    Type: Application
    Filed: April 16, 2012
    Publication date: February 13, 2014
    Applicant: RIKEN
    Inventors: Akimitsu Okamoto, Kaori Sugizaki, Akiko Nakamura, Hiroyuki Yanagisawa, Shuji Ikeda
  • Publication number: 20130203178
    Abstract: The method for detection of cyanide in water is a method for the detection of a highly toxic pollutant, cyanide, in water using ZnO2 nanoparticles synthesized locally by an elegant Pulsed Laser Ablation technique. ZnO2 nanoparticles having a median size of 4 nm are synthesized from pure zinc metal target under UV laser irradiation in a 1-10% H2O2 environment in deionized water. The synthesized ZnO2 nanoparticles are suspended in dimethyl formamide in the presence of Nafion, and then ultrasonicated to create a homogenous suspension, which is used to prepare a thin film of ZnO2 nanoparticles on a metal electrode. The electrode is used for cyanide detection.
    Type: Application
    Filed: March 14, 2013
    Publication date: August 8, 2013
    Inventors: MOHAMMED ASHRAF GONDAL, QASEM AHMED QASEM DRMOSH, Z.H. YAMANI, TAWFIK ABDO SALEH
  • Publication number: 20120225356
    Abstract: A galvanic element containing a substantially transition metal-free oxygen-containing conversion electrode, a transition metal-containing cathode, and an aprotic lithium electrolyte. The substantially transition metal-free oxygen-containing conversion. electrode materials contain lithium hydroxide and/or lithium peroxide and/or lithium oxide, and in the charged state additionally contain lithium hydride, and are contained in a galvanic element, for example a lithium battery, as the anode. Methods for producing substantially transition metal-free oxygen-containing conversion electrode materials and galvanic elements made of substantially transition metal-free oxygen-containing conversion electrode materials are also provided.
    Type: Application
    Filed: November 18, 2010
    Publication date: September 6, 2012
    Inventor: Ulrich Wietelmann
  • Patent number: 8147785
    Abstract: Combustion flue gas containing NOX and SOX is treated to remove NOX in a multistep system in which NOX is reduced in the flue gas stream via selective catalytic reduction or selective non-catalytic reduction with ammonia or an ammonia-forming compound, followed treatment with hydrogen peroxide to remove residual ammonia and, optionally, treatment with an alkali reagent to reduce residual NOX in the flue gas stream. The NOX-depleted flue gas stream may also be subjected to a desulfurization treatment for removal of SOX.
    Type: Grant
    Filed: May 12, 2010
    Date of Patent: April 3, 2012
    Assignee: FMC Corporation
    Inventors: Henry A. Pfeffer, David E. Smith
  • Patent number: 7993495
    Abstract: A method is provided for decontaminating a surface that is susceptible to contamination by a contaminant by applying to the surface a coating which produces a decontaminating agent for the contaminant in response to a signal, connecting the electroactive coating to a source of a signal, and when the surface is contaminated, applying the signal to the electroactive coating, thereby producing one or more decontaminating agents which neutralize or destroy the contaminant. Coatings for practicing the method and articles that have been protected by the novel coatings are also provided.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: August 9, 2011
    Assignee: Crosslink Polymer Research, a division of Lumimove, Inc.
    Inventors: Patrick J. Kinlen, Yiwei Ding, James K. Bashkin, Shifeng Hou
  • Patent number: 7754445
    Abstract: The invention relates to a method for the enzymatic production of a curing agent in its fluid state, e.g. liquid, comprising, in free phase, at least one oxygenated chemical species. Said method consists in bringing into contact at least one enzymatic catalysts agent, comprising at lease one peroxidase-type enzyme; an oxidizable substrate in aqueous phase that can be oxidized by the action of an oxygen donor, by catalysis by said enzymatic catalysis agent, generating said oxygenated chemical species in free phase; and said oxygen donor.
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: July 13, 2010
    Assignee: TMI Europe
    Inventor: Herve Casez
  • Patent number: 7264747
    Abstract: A microporous diffuser includes a first elongated member including at least one sidewall having a plurality of microscopic openings. The sidewall defines an interior hollow portion of the member. The diffuser has a second elongated member having a second sidewall having a plurality of microscopic openings, the second member being disposed through the hollow region of the first member. The diffuser includes an end cap to seal a first end of the microporous diffuser and an inlet cap disposed at a second end of microporous diffuser for receiving inlet fittings.
    Type: Grant
    Filed: January 9, 2006
    Date of Patent: September 4, 2007
    Inventor: William B. Kerfoot
  • Patent number: 7261942
    Abstract: Method for producing novel photochemically-active metal oxide-containing aqueous compositions such as TiO2 compositions coated or sprayed and dried under ambient conditions to form novel photochemically-active, colorless coatings having strong wetability and adhesion to clear substrates such as window glass. Preferably the present compositions include a suitable wetting agent or combination of agents to improve the wetability of the Titanium peroxide-containing amorphous film, allowing thinner films to be readily applied. Also the inclusion of an acrylic aliphatic urethane polymer can replace wholly or partially the titanium peroxide sol and provide additional film forming and wetability properties. The acrylic urethane polymer reduces or eliminates the amount of titanyl peroxide that is required and thereby reduces or eliminates the yellow color.
    Type: Grant
    Filed: March 3, 2005
    Date of Patent: August 28, 2007
    Assignee: Prizmalite Industries Inc.
    Inventor: John Andrews
  • Publication number: 20070140949
    Abstract: This invention relates to a method for generating peroxides in petroleum streams and extracting oxidized sulfur and nitrogen compounds. Peroxides are generated in-situ by combining the petroleum stream with a high neutralization number (HNN) crude and adding an oxygen-containing stream. Alternatively, the oxidation of sulfur and nitrogen compounds may be accomplished by adding peroxides in the presence of oil soluble metal catalysts. The peroxides oxidize nitrogen and sulfur compounds in the petroleum stream to more polar compounds which are solvent extracted.
    Type: Application
    Filed: December 16, 2005
    Publication date: June 21, 2007
    Inventors: Thomas R. Palmer, William J. Murphy
  • Patent number: 6884752
    Abstract: Method for producing novel photochemically-active metal oxide-containing aqueous compositions such as TiO2 compositions coated or sprayed and dried under ambient conditions to form novel photochemically-active, colorless coatings having strong wetability and adhesion to clear substrates such as window glass. Preferably the present compositions include a suitable wetting agent or combination of agents to improve the wetability of the Titanium peroxide-containing amorphous film, allowing thinner films to be readily applied. Also the inclusion of an acrylic aliphatic urethane polymer can replace wholly or partially the titanium peroxide sol and provide additional film forming and wetability properties. The acrylic urethane polymer reduces or eliminates the amount of titanyl peroxide that is required and thereby reduces or eliminates the yellow color.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: April 26, 2005
    Assignee: Prizmalite Industries, Inc.
    Inventor: John Andrews
  • Publication number: 20040127354
    Abstract: Method for producing novel photochemically-active metal oxide-containing aqueous compositions such as TiO2 compositions coated or sprayed and dried under ambient conditions to form novel photochemically-active, colorless coatings having strong wetability and adhesion to clear substrates such as window glass. Preferably the present compositions include a suitable wetting agent or combination of agents to improve the wetability of the Titanium peroxide-containing amorphous film, allowing thinner films to be readily applied. Also the inclusion of an acrylic aliphatic urethane polymer can replace wholly or partially the titanium peroxide sol and provide additional film forming and wetability properties. The acrylic urethane polymer reduces or eliminates the amount of titanyl peroxide that is required and thereby reduces or eliminates the yellow color.
    Type: Application
    Filed: December 31, 2002
    Publication date: July 1, 2004
    Inventor: John Andrews
  • Publication number: 20030161784
    Abstract: A titanium oxide precursor which is used for producing a fine-particle titanium oxide showing a high photocatalytic activity is provided. The titanium oxide precursor is an oxygen-atom-containing titanium compound other than anatase-form titanium oxide, and has a maximum exothermic peak at a temperature in the range of from about 30° C. to about 500° C. in a differential thermal analysis curve and shows decrease in weight in a thermogravimetry curve at about the same temperature at which the maximum exothermic peak is shown in the differential thermal analysis curve when subjected to a thermogravimetry and differential thermal analysis under the condition of a temperature rising rate of 20° C./min.
    Type: Application
    Filed: February 20, 2003
    Publication date: August 28, 2003
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kensen Okusako, Hiroyuki Ando
  • Publication number: 20030079981
    Abstract: A distilling apparatus and method use a two step distillation and purification process for processing a waste liquid, such as an impure sulfuric acid solution, to form a highly concentrated sulfuric acid solution. First, the waste liquid is stored in a concentrating column, where it is heated. A condenser, which uses the waste liquid as a cooling medium, condenses the vapor generated by the heater. The condensed vapor is passed through a filter, which separates impurities out of the waste liquid, prior to feeding the waste liquid back into the concentrating column. Water is then removed from the waste liquid via a distilling process. The resulting concentrated liquid is then fed to a purifying column, where it is again heated, to remove residue, and condensed, resulting in a highly pure waste liquid.
    Type: Application
    Filed: November 22, 2002
    Publication date: May 1, 2003
    Applicant: FUJITSU LIMITED
    Inventors: Hiroshi Osuda, Toru Matoba, Daisuke Adachi, Masataka Fukuizumi
  • Publication number: 20010016187
    Abstract: A process for producing oxidized organic chemical products such as propylene oxide from various organic chemical feedstocks utilizing as oxidant directly produced hydrogen peroxide (H2O2) intermediate oxidizing agent. The hydrogen peroxide intermediate is directly produced from hydrogen and oxygen feeds plus a suitable solvent in a first catalytic reaction step utilizing an active supported phase-controlled noble metal catalyst at reaction conditions of 0-100° C. temperature and 300-3,000 psig pressure. An organic chemical feedstock such as propylene together with the hydrogen peroxide intermediate and solvent solution are fed into a second catalytic reactor maintained at 0-150° C. temperature and 15-1,500 psig pressure and oxidized to produce a desired crude oxidized organic product such as propylene oxide, which is purified by distillation steps and recovered from the solvent solution.
    Type: Application
    Filed: December 8, 2000
    Publication date: August 23, 2001
    Applicant: Hydrocarbon Technologies, Inc.
    Inventors: Bing Zhou, Michael A. Rueter
  • Patent number: 6267944
    Abstract: A method of preparing a solution for titanium oxide film is provided such that said solution has the effect of a photocatalyst, by coating, or impregnating therewith a variety of substrates being positioned in a place where no ultraviolet light is emitted. Utilizing a solution for titania film provided by a mixture of a titanium peroxide solution made from a compound of a titanium hydrate gel and a peroxide solution, and a solution forming titanium peroxide particles by calcining said titanium peroxide solution at a temperature over 80° C., particles of capsicin, magnetite and tourmaline, as well as a silica solution are each compounded to said solution for titania film, such that an improved solution for titania film can be obtained having the photocatalystic effect without any exterior light source.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: July 31, 2001
    Assignee: Morioki Sangyo Company Limited
    Inventor: Yoshihar Mori
  • Patent number: 6087089
    Abstract: A composition, method, and test device for quantitatively determining the oxidant concentration of a test sample are disclosed. The test device includes a test pad having a suitable carrier matrix incorporating an indicator reagent composition capable of interacting with an oxidant to produce a detectable and measurable response for oxidant over a wide concentration range of oxidant. An indicator reagent composition contains: (a) an iodide salt, (b) a buffer, and (c) a water-soluble polymer, preferably a cellulose-based polymer. An indicator reagent composition is incorporated into a carrier matrix, like filter paper, to provide a test pad useful in a dry phase oxidant assay of a test sample, especially for test samples containing a high concentration of oxidant, like chlorine or a peroxide.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: July 11, 2000
    Assignee: Integrated Biomedical Technology, Inc.
    Inventor: Wen H. Wu
  • Patent number: 5851439
    Abstract: A coloring layer composition for a chromatic device of the present invention contains an oxide such as tungsten oxide or niobium oxide and so on as a solute, water and an organic solvent such as propanol. In the step of forming a reduction coloring layer, a film is formed by using a peroxotungstic acid solution containing 100 parts by weight of WO.sub.3.aNb.sub.2 O.sub.5.bH.sub.2 O.sub.2 .andgate.cH.sub.2 O (wherein a, b and c are each a positive number) as a solute, 20 to 120 parts by weight of water and 80 to 800 parts by weight of n-propanol as an organic solvent. At this time, a dip coating method is used, and the vertical pulling-up speed is less than 15 cm/min. The present invention can effectively prevent unevenness and separation of the reduction coloring layer.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: December 22, 1998
    Assignee: Kabushiki Kaisha Toyoda Jidoshokki Seisakusho
    Inventors: Toshiki Inoue, Yoshifumi Kato, Hisashi Shiraki, Takanori Murasaki
  • Patent number: 5820841
    Abstract: A method of making an inorganic salt-hydrogen peroxide complex includes the following steps: (a) mixing the inorganic salt with sufficient water for a time sufficient to form a soft paste, (b) mixing the paste with an aqueous hydrogen peroxide solution to form a hydrogen peroxide-containing paste, and (c) drying the hydrogen peroxide-containing paste. A hydrate method of making Na.sub.4 P.sub.2 O.sub.7.3H.sub.2 O.sub.2 includes the steps of: mixing sodium pyrophosphate decahydrate solid with an aqueous solution of hydrogen peroxide having a concentration of less than 30%, and drying the mixture. Compositions of matter include K.sub.2 HPO.sub.4.3H.sub.2 O.sub.2, KH.sub.2 PO.sub.4.H.sub.2 O.sub.2 Ca.sub.2 P.sub.2 O.sub.7.nH.sub.2 O.sub.2, Ca.sub.2 P.sub.2 O.sub.4.nH.sub.2 O.sub.2, Na.sub.2 SO.sub.4.nH.sub.2 O.sub.2, K.sub.2 SO.sub.4.nH.sub.2 O.sub.2, Na.sub.2 SiO.sub.3.nH.sub.2 O.sub.2 and Na.sub.2 SiO.sub.7.nH.sub.2 O.sub.2.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: October 13, 1998
    Assignee: Ethicon, Inc.
    Inventors: Xiaolan Chen, Paul Taylor Jacobs, Szu-Min Lin
  • Patent number: 5780257
    Abstract: Method for detecting peroxidase or hydrogen peroxide with high sensitivity. Both peroxidase and hydrogen peroxide are prepared such that one of them is overabundant to the other. Phenoxy radicals are produced from a p-substituted phenol compound by the action of peroxidase in the presence of hydrogen peroxide. The free radicals are trapped by a hydroxy amine compound, and stable radical species are produced. Electron spin resonances of the stable radical species are measured.
    Type: Grant
    Filed: July 18, 1996
    Date of Patent: July 14, 1998
    Assignees: Yamagata Technopolis Foundation, JEOL Ltd.
    Inventors: Masaaki Aoyama, Masanobu Shiga
  • Patent number: 5702911
    Abstract: The present invention relates to an improved test composition for the diagnosis of gastric ulcers, duodenal ulcers, gastritis, gastric lymphoma and gastric carcinoma by the detection of the bacteria Helicobacter pylori and the enzyme catalase associated with such conditions. The new test composition differs from the prior art agar compositions in being an aqueous solution containing hydrogen peroxide, urea, monobasic sodium phosphate and bromthymol blue as an indicator, and in being far more rapid than the prior art test compositions.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: December 30, 1997
    Assignee: Chek-Med Systems, Inc.
    Inventor: Robert G. Whalen
  • Patent number: 5552131
    Abstract: A process and apparatus for the molecular oxygen oxidation of a secondary alcohol such as isopropanol to hydrogen peroxide is provided.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: September 3, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: John C. Jubin, Jr.
  • Patent number: 5154912
    Abstract: The peroxides which include the O.sup.17 isotope, especially the hydrogen peroxides and peroxides and hydroperoxides prepared therefrom, are well adapted as nonradioactive labeled compounds for use in the medicinal and biological arts.
    Type: Grant
    Filed: September 20, 1990
    Date of Patent: October 13, 1992
    Assignee: Atochem
    Inventors: Jean-Pierre Schirmann, Jean-Jacques Barieux
  • Patent number: 5061599
    Abstract: A radiation-sensitive material comprising a polyacid composed of tungsten and niobium, titanium and/or tantalum. A uniform film can be formed by an easy spin coating method. The polyacid has a radiation sensitivity higher than that of a polyacid comprising only tungsten.
    Type: Grant
    Filed: January 5, 1990
    Date of Patent: October 29, 1991
    Assignee: Hitachi, Ltd.
    Inventors: Tetsuichi Kudo, Akira Ishikawa, Hiroshi Okamoto, Katsuki Miyauchi, Takao Iwayanagi, Fumio Murai, Shinji Okazaki
  • Patent number: 5035478
    Abstract: A material for an optical component comprising polytungstic acid having peroxo groups, and an optical component, at least part of which is constituted of a thin film of the above-mentioned material. By using this material, a thin film of an inorganic material having an excellent stability is formed by the inexpensive wet painting method. An optical component using the above-mentioned thin film can be formed on an arbitrary substrate with high accuracy at a low temperature of about 100.degree. C. or below. The polytungstic acid may contain carbon as a heteroatom and/or may have Nb, Ti, V, Ta and/or Mo substituted for part of W.
    Type: Grant
    Filed: August 14, 1990
    Date of Patent: July 30, 1991
    Assignee: Hitachi, Ltd.
    Inventors: Akira Ishikawa, Yukio Ito, Hiroshi Okamoto, Tetsuichi Kudo, Katsuki Miyauchi
  • Patent number: 4962040
    Abstract: 2-Hydrazono-4,6-dinitrobenzthiazolones of the formula ##STR1## in which X.sub.1 represents hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -hydroxyalkyl, C.sub.1 -C.sub.4 -sulphoalkyl or C.sub.1 -C.sub.4 -sulphatoalkyl, andX.sub.2 represents hydrogen or --SO.sub.2 X.sub.3, whereX.sub.3 may represent hydrogen, C.sub.1 -C.sub.8 -alkyl or optionally substituted aryl andX.sub.1 also represents a double bond between the cyclic nitrogen atom and the carbon atom 2 according to the formula II below: ##STR2## where X.sub.2 has the meaning specified under the above formula. These hydrazones may be employed in the preparation of azo dyestuffs and as color formers for detecting of biological substances, and in the determination of H.sub.2 O.sub.2.
    Type: Grant
    Filed: August 10, 1989
    Date of Patent: October 9, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Hugl, Aloysius Engel, Klaus Wehling
  • Patent number: 4515664
    Abstract: Discloses electro-organic synthesis process using a water wetted gaseous feed. Also discloses the electro-organic synthesis of hydrogen peroxide; 1,4-naphthoquinone; and organic nitriles.
    Type: Grant
    Filed: January 27, 1984
    Date of Patent: May 7, 1985
    Assignee: PPG Industries, Inc.
    Inventor: Malcolm Korach
  • Patent number: 4427644
    Abstract: Disclosed is a continuous process for the production of bivalent metal peroxides, comprising the steps of introducing into an intensive mixing apparatus a solid, anhydrous or hydrated oxide or hydroxide of a bivalent metal; simultaneously introducing into the intensive mixing apparatus a solution of hydrogen peroxide, whereby the solid bivalent metal compound and the peroxide are intensively mixed and react to produce a reaction mixture containing bivalent metal peroxide; transporting the reaction mixture directly to a rapid dryer; and rapidly drying the reaction mixture to produce the bivalent metal peroxide in solid form.
    Type: Grant
    Filed: July 6, 1981
    Date of Patent: January 24, 1984
    Assignee: Peroxid-Chemie GmbH
    Inventors: Werner Doetsch, Helmut Dillenburg, Paul-Wilhelm Fuchs, Helmut Honig
  • Patent number: 4400367
    Abstract: Disclosed is an adduct of the formula 4Na.sub.2 SO.sub.4.2H.sub.2 O.sub.2.KCl and a process for the preparation of this adduct by crystallizing the adduct out of a suspension containing from about 100 to 900 g of hydrogen peroxide per liter of solution and a quantity of sodium sulphate and potassium chloride which exceeds the saturation concentration of the adduct at the crystallization temperature, whereby the weight ratio of sodium sulphate to potassium chloride is in the range of from about 2:1 to 12:1. A continuous process is also disclosed for producing the adduct.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: August 23, 1983
    Assignee: Peroxid-Chemie GmbH
    Inventors: Werner Doetsch, Helmut Honig, Rudolf Siegel
  • Patent number: 4399633
    Abstract: Alkali metal or alkaline earth metal peroxides, for example, particularly, calcium peroxide, are produced by recovering a moist peroxide product from an aqueous mixture, formed by reacting hydrogen peroxide and a hydroxide or oxide of the alkali metal or alkaline earth metal, and drying the moist product by means of a pneumatic conveyer drier. The peroxide so produced is suitable for granulation. Alternatively, particulate substances, such as seed, are coated with the peroxide by blending with the moist peroxide product and passing the blend through the pneumatic conveyer drier.
    Type: Grant
    Filed: April 9, 1981
    Date of Patent: August 23, 1983
    Assignee: Interox Chemicals Limited
    Inventors: Douglas P. Haughey, Malcolm H. Millar
  • Patent number: 4231890
    Abstract: A bleaching composition which does not cause color change or fading of fabrics, which composition contains 50 to 98 weight % of a peroxide which releases oxygen in an aqueous solution, 1 to 49 weight % of nitrilotriacetic acid or salt thereof and 1 to 49 weight % of a water softener as critical components.
    Type: Grant
    Filed: November 2, 1978
    Date of Patent: November 4, 1980
    Assignee: Kao Soap Co., Ltd.
    Inventors: Kouichi Yagi, Yunosuke Nakagawa
  • Patent number: 4128491
    Abstract: A particulate alkali metal perborate having an outer layer of chemically bound calcium in an amount of from about 0.4 to 2.0% by weight of the total particle, to slow down the rate of dissolution. A process for preparing said slow-dissolving perborate.The slow-dissolving perborate is especially designed for mixing with detergent granules and has improved resistance against catalase attack under practical use conditions.
    Type: Grant
    Filed: October 27, 1977
    Date of Patent: December 5, 1978
    Assignee: Lever Brothers Company
    Inventor: Leo W. A. Melles
  • Patent number: 4116859
    Abstract: Oxygen-containing bleach products are prepared by reaction of a source of hydroperoxy groups, such as hydrogen peroxide or ozone, with a water-soluble multi-metal, inorganic, amide group-containing monomeric complex. Such complex is obtained by reacting, in the presence of aqueous ammonia, at least one non-alkaline metal with an alkali metal hydroxide in accordance with a reaction sequence which produces reactive NH.sub.2 groups.
    Type: Grant
    Filed: January 10, 1977
    Date of Patent: September 26, 1978
    Inventor: George G. Merkl
  • Patent number: 4094758
    Abstract: The present invention relates to a process for preparing high purity inorganic higher oxides of the alkali and alkaline earth metals by subjecting the hydroxide of the alkali or alkaline earth metal to a radio frequency discharge sustained in oxygen. The invention is particularly adaptable to the production of high purity potassium superoxide (KO.sub.2) by subjecting potassium hydroxide to glow discharge sustained in oxygen under the pressure of about 0.75 to 1.00 torr.
    Type: Grant
    Filed: January 19, 1977
    Date of Patent: June 13, 1978
    Inventors: James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher, Pasupati Sadhukhan, Alexis T. Bell
  • Patent number: 4032623
    Abstract: A hydroperoxy-group-containing aluminum compound is prepared by a process which comprises:Contacting and reacting, at room temperature or below, and in the substantial absence of water, (a) a reactive metal comprising aluminum of a purity of at least 99.9% by weight permeated with a liquid metal selected from mercury, gallium and indium/gallium alloys with (b) a liquid reactant comprising (i) hydrogen peroxide in (ii) a liquid organic compound having no multiple carbon-to-carbon bonds.The aluminum compounds produced can be used, for example, as substrates for electronics, in the preparation of synthetic gems, ceramics and paint pigments. The aluminum compound is prepared in sheet for plate form, resembling mica in physical appearance.In an alternative embodiment, a metal or metal salt is added to the reactive system to yield a hydroperoxy-group-containing aluminum compound with the desired metal deposited thereon.
    Type: Grant
    Filed: August 16, 1976
    Date of Patent: June 28, 1977
    Inventor: George G. Merkl
  • Patent number: 4008167
    Abstract: A bleaching composition is disclosed characterized by containing (a) sodium percarbonate which has been heated at a temperature of 75.degree. to 135.degree. C for a time ranging from 5 to 30 minutes at 135.degree. C to 2 to 6 hours at 75.degree. C and (b) an activating agent for the sodium percarbonate.
    Type: Grant
    Filed: March 5, 1975
    Date of Patent: February 15, 1977
    Assignee: Kao Soap Co., Ltd.
    Inventors: Yunosuke Nakagawa, Masaaki Nishimura, Koitsu Sato
  • Patent number: 4005182
    Abstract: An adduct having the formula: 4Na.sub.2 SO.sub.4. 2H.sub.2 O.sub.2. NaCl, is prepared by reacting sodium sulfate with hydrogen peroxide in an aqueous solution, in the presence of sodium chloride in the reaction system.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: January 25, 1977
    Assignees: Kao Soap Co., Ltd., Nippon Peroxide Co., Ltd.
    Inventors: Yoshio Ito, Toshio Mashiko
  • Patent number: 3979313
    Abstract: A bleaching composition comprising a hydrogen peroxide adduct having the formula:4Na.sub.2 SO.sub.4.sup.. 2H.sub.2 O.sub.2.sup.. NaCland an activating agent.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: September 7, 1976
    Assignees: Kao Soap Co., Ltd., Nippon Peroxide Co., Ltd.
    Inventors: Yunosuke Nakagawa, Shigetsugu Sugiura, Kinjiro Matsunaga, Yoshio Ito
  • Patent number: 3953350
    Abstract: A bleaching composition is disclosed characterized by containing sodium percarbonate which was treated by subjecting it to heating at a temperature of 75.degree. to 135.degree.C, for a heating time ranging (1) from 2 to 6 hours at 75.degree.C to (2) 5 to 30 minutes at 135.degree.C.
    Type: Grant
    Filed: October 21, 1974
    Date of Patent: April 27, 1976
    Assignee: Kao Soap Co., Ltd.
    Inventors: Takashi Fujino, Masaaki Nishimura, Makoto Yamanaka