Identified Precipitation Nuclei Or Image Receiving Layer Binder Containing Other Than Nominal Gelatin Patents (Class 430/231)
  • Patent number: 7829965
    Abstract: A structure and method for increasing the sensitivity of pixel sensors by eliminating a gap space formed between adjacent microlens structures in a pixel sensor array. Advantageously, exposure and flowing conditions are such that adjacent microlens structures touch (are webbed) at a horizontal cross-section, yet have a round lens shape in all directions. Particularly, exposure and flowing conditions are such that each touching microlens structure is formed to have a matched uniform radius of curvature at a horizontal cross-section and at a 45 degree cross-sections.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: November 9, 2010
    Assignee: International Business Machines Corporation
    Inventors: Timothy J. Hoague, Robert K. Leidy
  • Patent number: 7612489
    Abstract: A display filter for use with a plurality of microlenses in a display system includes an external light and electromagnetic (EM)-shielding portion having a photosensitive transparent resin layer with a photocatalyst, and an external light and EM-shielding pattern formed on regions of the photosensitive transparent resin layer to prevent external light from entering the display system and to prevent EM waves generated in the display device from exiting the display device, the regions corresponding to boundaries between the plurality of microlenses.
    Type: Grant
    Filed: May 16, 2005
    Date of Patent: November 3, 2009
    Assignee: Samsung Corning Precision Glass Co., Ltd.
    Inventors: Dae-chul Park, Yong-won Choi, Sang-cheol Jung, Wang-kyu Choi
  • Patent number: 6878513
    Abstract: A modified gelatin obtained by reacting (A) a gelatin and (B) a compound which contains a nitrogenous aromatic ring having a mercapto group to form covalent bond with a reactive group in the gelatin, an introduction amount of the compound in the gelatin being 1.0×10?6 mol to 2.0×10?3 mol per 100 g of the gelatin.
    Type: Grant
    Filed: December 27, 2001
    Date of Patent: April 12, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Terukazu Yanagi, Mamoru Sakurazawa, Naohiro Takeda, Yoichi Maruyama, Katsuyuki Takada
  • Patent number: 6692886
    Abstract: An object of the present invention is to provide a method for manufacturing an aluminum printing plate which is superior in fine line reproduction and has no occurrence of spot-like defect in the silver image part. According to the present invention, a method for manufacturing a lithographic printing plate is provided, wherein an aluminum plate subjected to at least graining treatment and anodizing treatment is rinsed with water, then coated with a liquid containing physical development nuclei, and subsequently coated with a silver halide emulsion layer.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: February 17, 2004
    Assignee: Mitsubishi Paper Mills Limited
    Inventor: Jun Yamada
  • Publication number: 20020177064
    Abstract: An object of the present invention is to provide a method for manufacturing an aluminum printing plate which is superior in fine line reproduction and has no occurrence of spot-like defect in the silver image part. According to the present invention, a method for manufacturing a lithographic printing plate is provided, wherein an aluminum plate subjected to at least graining treatment and anodizing treatment is rinsed with water, then coated with a liquid containing physical development nuclei, and subsequently coated with a silver halide emulsion layer.
    Type: Application
    Filed: March 8, 2002
    Publication date: November 28, 2002
    Inventor: Jun Yamada
  • Patent number: 6303262
    Abstract: Disclosed are a photomask material for preparing a photomask having excellent heat resistance, ultraviolet resistance and image strength, a photomask having the above properties and methods for the production thereof, and the present invention provides a photomask material, which comprises a glass substrate, a physical development nucleus layer and a photosensitive layer containing silver halide, the layers being consecutively formed on the transparent substrate, and a method for the production thereof, and a photomask, which comprises a transparent substrate, a physical development nucleus layer and a light shielding film formed of a predetermined pattern of a silver film derived from silver halide, the silver film being formed by the action of the physical development nucleus in said layer during development treatment, the physical development nucleus layer and the light shielding film being consecutively formed on the transparent substrate, and a method for the production thereof.
    Type: Grant
    Filed: June 17, 1999
    Date of Patent: October 16, 2001
    Assignee: Mitsubishi Paper Mills Ltd.
    Inventors: Kazuchiyo Takaoka, Noriyuki Kawai, Kenji Hyodo
  • Patent number: 6146807
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer in water permeable relationship with said image receiving layer, characterized in that said aluminum support, provided with said image receiving layer, is kept at a relative humidity of at least 45% in an area of a machine, the said area being ahead of a coating head used for coating said photosensitive layer.
    Type: Grant
    Filed: November 5, 1999
    Date of Patent: November 14, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marcus Jonkheere
  • Patent number: 6146808
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer, characterized in that said element before and/or after being coated with said image-receiving layer and before being coated with another layer is wetted with a fluidum with a conductivity of at least 1 .mu.S/cm at 25.degree. C. and then the wetted element is brought in contact with an earthed discharging means and dried before coating the following layer.
    Type: Grant
    Filed: November 5, 1999
    Date of Patent: November 14, 2000
    Assignee: AGFA-Gevaert, N.V.
    Inventor: Marcus Jonkheere
  • Patent number: 6103444
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer, said aluminum support before being coated with a silver halide emulsion layer being guided over rollers, said rollers being exclusively rollers with a metallic surface, characterized in that the mean length of contact of the support with a contact roller (in meter) in the unwinding area is not more than 0.140 m.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: August 15, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marcus Jonckheere
  • Patent number: 6096474
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer, said aluminum support before being coated with a silver halide emulsion layer being guided over rollers, said rollers being exclusively rollers with a metallic surface, characterized in that the mean length of contact of said support with said rollers per meter of unwinding length is more than 0.070 m.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: August 1, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marcus Jonckheere
  • Patent number: 6071668
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer, said aluminum support before being coated with a silver halide emulsion layer being guided over rollers, characterized in that at least 90% of said rollers has an electrical resistance lower than 10.sup.9 ohm.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: June 6, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marcus Jonckheere
  • Patent number: 6054247
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer, said aluminum support before being coated with a silver halide emulsion layer being guided over rollers, said rollers being exclusively rollers with a metallic surface, characterized in that the ratio of the number of rollers with a metallic surface to the unwinding length of the aluminum support (in meter) is at least 0.60.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: April 25, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marcus Jonckheere
  • Patent number: 6040109
    Abstract: According to the present invention there is provided a method for preparing an imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer comprising unhardened gelatin, characterized in that said aluminum support when being coated with said photosensitive layer is in contact with a guiding roller, heated at a temperature between 35 and 70.degree. C.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: March 21, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul Coppens, Marcus Jonckheere
  • Patent number: 6004718
    Abstract: A transfer material colored to a predetermined color is used when images are formed on a transfer material for use in thermal transfer comprising a substrate and a dye receiving layer by a thermal transfer process.When images are formed by an optional image forming method such as silver salt photographic process, ink jet process or thermal transfer process, a transfer material having sepia tone is used in each of the image forming processes thereby forming sepia tone images. Images having unique appearance can be formed easily upon forming images by a thermal transfer process. Images of sepia tone can be formed safely and conveniently.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: December 21, 1999
    Assignee: Sony Corporation
    Inventor: Satoru Shinohara
  • Patent number: 5989802
    Abstract: Recording materials and a method of manufacturing said materials by coating hydrophilic colloidal layer compositions on a support by slide-hopper or curtain-coating techniques, followed by drying, said materials comprising a support and one or more light-sensitive and/or heat-sensitive layer(s) having a hydrophilic colloidal coating composition comprising no gelatin(in the case of (photo)thermographic materials) or gelatin in low amounts in order to provide a ratio by weight of gelatin to silver halide expressed as an equivalent amount of silver nitrate in the range from 0.05 to 0.4 (in the case of a light-sensitive silver halide photographic material) and thickening agents composed of synthetic clay and anionic macromolecular polyelectrolytes and wherein said synthetic clay is present in an amount of at least 85% by weight versus a total amount of thickening agents.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: November 23, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Hubert Vandenabeele
  • Patent number: 5869217
    Abstract: A silver halide photographic material which has a layer containing a swellable inorganic stratifying compound.
    Type: Grant
    Filed: July 24, 1997
    Date of Patent: February 9, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiaki Aono
  • Patent number: 5856063
    Abstract: An image forming method comprising the steps of: (i) imagewise exposing a silver halide light-sensitive material comprising a support having thereon at least a light-sensitive silver halide emulsion, a hydrophilic binder and a slightly water-soluble basic metal compound; (ii) laminating the silver halide material with a processing sheet comprising a compound which forms a complex with a metal ion constituting the basic metal compound, a physical development nucleus, a solvent for a silver halide and a matting agent, after or concurrently with the imagewise exposure; and (iii) conducting heat development in the presence of a reducing agent and water to form a silver image on at least one of the light-sensitive material and the processing sheet, wherein the processing sheet comprises an uppermost layer containing the physical development nucleus; the product of the weight ratio in the uppermost layer of the amount of the physical development nucleus to that of the binder and the reciprocal of the mean size (.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: January 5, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Takashi Nakamura, Kiyoteru Miyake
  • Patent number: 5731124
    Abstract: The present invention provides a method for preparing an aluminium foil comprising the steps of roughening an aluminium foil and subsequently anodizing said aluminium foil characterized in that after said anodization said aluminium foil is cleaned using an aqueous bicarbonate containing solution. The present invention further provides a mono-sheet silver salt diffusion transfer material having as a support the alumium foil obtainable from the above defined method. The step of cleaning in the bicarbonate containing solution improves the adhesion of an image receiving layer containing physical development nuclei to the aluminum foil as revealed from the increased amount of silver precipitated in the image receiving layer when the aluminum foil provided with an image receiving layer is used in a diffusion transfer reversal (DTR) process.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: March 24, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Marcus Jonckheere, Paul Coppens
  • Patent number: 5707775
    Abstract: The present invention provides an imaging element for making a lithographic printing plate according to silver salt diffusion transfer processing, said imaging element comprising on a support a silver halide emulsion layer and a receiving layer, said receiving layer comprising (i) physical development nuclei, (ii) an inorganic colloidal substance and (iii) a hydrophilic polymer being a homo- or copolymer of acrylamide or methacrylamide.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: January 13, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Lode Deprez, Ronny De Clercq
  • Patent number: 5707774
    Abstract: According to the present invention, a method is provided for preparing physical development nuclei for use in silver salt diffusion transfer processing, said physical development nuclei comprising a heavy metal sulphide, said method comprising the steps of:precipitating said heavy metal sulphide by bringing a water soluble heavy metal compound in reactive association with a water soluble sulphide in an aqueous liquid andsaid precipitation being carried out in the presence of a hydrophilic polymer so as to disperse said heavy metal sulphide, said hydrophilic polymer comprising a heterocyclic group, characterized in that said heterocyclic group is present in a recurring unit of said hydrophilic polymer, said recurring unit being comprised in said polymer in an amount between 0.1 mol % and 5 mol %.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: January 13, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Lode Deprez, Ronny De Clercq, Rene De Keyzer
  • Patent number: 5691105
    Abstract: The present invention provides a method for obtaining an imaging element suitable for use in a silver salt diffusion transfer process comprising the steps of coating a support with a layer comprising physical development nuclei and a photosensitive layer comprising a photosensitive silver halide emulsion, said photosensitive layer being in water permeable relationship with said image receiving layer, characterized in that said physical development nuclei consist of a substantially homogeneous solid solution of two or more different metals and are prepared by pulsed high flux radiolysis.According to the invention there is further provided a method for making a lithographic printing plate comprising the steps of image-wise exposing an imaging element prepared as defined above and subsequently developing a thus obtained image-wise exposed imaging element by means of an alkaline processing solution in the presence of a developing agent and a silver halide solvent.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: November 25, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Rene De Keyzer, Yves Van Meenen
  • Patent number: 5645972
    Abstract: The present invention provides a method for preparing an aluminum foil comprising the steps of roughening and anodizing an aluminum foil, posttreating said roughened and anodized aluminum foil with an aqueous bicarbonate solution and subsequently rinsing said posttreated foil with water characterized in that the temperature of said water ranges from 30.degree. C. to 55.degree. C.
    Type: Grant
    Filed: November 21, 1995
    Date of Patent: July 8, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marcus Jonkheere
  • Patent number: 5633115
    Abstract: The present invention provides a method for preparing an image receiving element comprising an aluminum foil as support comprising the steps of roughening and anodizing said aluminum foil and applying an image receiving layer containing physical development nuclei on said aluminum foil characterized in that said roughened and anodized aluminum foil is posttreated with an aqueous solution containing one or more organic compounds having at least one cationic group.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: May 27, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Nikolaas de Jaeger, Walter Verdyck, Augustin Meisters
  • Patent number: 5629131
    Abstract: The present invention provides an image receiving material comprising a receiving layer containing physical development nuclei characterized in that said physical development nuclei are grown on a colloidal smectic clay. Said image receiving material may be provided wih a photosensitive silver halide emulsion layer or may form a separate receiving element.The image receiving materials of the present invention can also be used for making lithographic printing plates having good printing properties.
    Type: Grant
    Filed: April 29, 1996
    Date of Patent: May 13, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Rene De Keyzer, Yves Van Meenen
  • Patent number: 5618650
    Abstract: The present invention provides an imaging element comprising on a support a silver halide emulsion layer and an image receiving layer comprising physical development nuclei being in water permeable contact with said silver halide emulsion layer, characterized in that said image receiving layer comprises a colloidal clay.According to the invention there is further provided a method for making a lithographic printing plate comprising the steps of image-wise exposing an imaging element as defined above and subsequently developing a thus obtained image-wise exposed imaging element by means of an alkaline processing solution in the presence of a developing agent and a silver halide solvent.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: April 8, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ren e De Keyzer, Jos Vaes
  • Patent number: 5501150
    Abstract: Process for the manufacture of a lithographic printing plate comprising the steps of:(1) information-wise projecting droplets of liquid, onto a receiving material having a hydrophilic surface to form a silver image by bringing into working relationship on said hydrophilic surface a reducible silver compound (A), a reducing agent (B) for said silver compound and physical development nuclei (C) that catalyze the reduction of said silver compound to silver metal, and(2) hydrophobizing the silver image that has been obtained through said step (1) e.g. by overall contacting the printing surface with a hydrophobizing substance for said silver image or hydrophobizing said silver image by imagewise depositing said hydrophobizing substance thereon.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: March 26, 1996
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc Leenders, Leo Oelbrandt, Jan Van den Bogaert, Guido Desie
  • Patent number: 5468588
    Abstract: A method of manufacturing a photosensitive element which can be exposed and enveloped by diffusion transfer processes to form a lithographic printing plate, said method comprising the steps of:(a) providing a support layer,(b) coating a negative acting silver halide emulsion layer onto said support layer, and(c) coating a physical development nucleation layer comprising particles onto said silver halide emulsion layer,wherein the coating of said physical development nucleation layer is performed with a coating composition which is at a temperature above 0.degree. C. and below 30.degree. C.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: November 21, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Michael T. Macioch, Douglas M. Gates, Timothy M. Leary
  • Patent number: 5445915
    Abstract: The present invention provides an imaging element comprising on a support in the order given a base layer containing a matting agent having a number average diameter between 0.4 and 1 times the thickness of said base layer, a spectrally sensitized silver halide emulsion layer and a receiving layer containing physical development nuclei having an average diameter less than 6 nm and wherein the number of nuclei having a diameter larger than 4.5 nm is less than 15% of the total number of nuclei contained in said receiving layer and wherein substantially no matting agent is present in said receiving layer, silver halide emulsion layer or any other layer optionally being present between said receiving layer and silver halide emulsion layer.
    Type: Grant
    Filed: January 11, 1995
    Date of Patent: August 29, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Jos Vaes
  • Patent number: 5436110
    Abstract: The present invention provides an imaging element comprising in the order given (i) a hydrophilic grained and anodized aluminum support with an aluminum oxide barrier layer of at least 10 nm thickness, (ii) an image receiving layer containing physical development nuclei in an amount of at least 0.7 mg/m.sup.2 and (iii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer. The invention also relates to a method for making lithographic plates with said imaging element.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: July 25, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul Coppens, Guido Hauquier, Marcus Jonckheere, Willem Cortens, Augustin Meisters
  • Patent number: 5427889
    Abstract: The present invention provides a lithographic printing plate material which comprises a grained and anodized aluminum support and a silver halide emulsion layer between which physical development nuclei are provided wherein said aluminum support have 500 or more pits having a diameter of 0.03-0.30 .mu.m and an average diameter of 0.05-0.20 .mu.m per 100 .mu.m.sup.2.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: June 27, 1995
    Assignee: Mitsubishi Paper Mills Ltd.
    Inventors: Masahiko Saikawa, Akira Kaneko, Keisuke Iguchi, Akio Yoshida, Yutaka Araki, Takenobu Yoshiki
  • Patent number: 5405730
    Abstract: The present invention provides an imaging element comprising in the order given (i) a hydrophilic grained and anodized aluminum support, (ii) an image receiving layer containing physical development nuclei and (iii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer characterized in that the sum of the surface areas of subsidences amounts to at least 50% of the total surface area area of the grained and anodized side of said support.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: April 11, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul Coppens, Marcus Jonckheere
  • Patent number: 5340692
    Abstract: The present invention provides an image receiving material comprising on a support an image receiving layer containing physical development nuclei characterised in that said image receiving material contains a nacreous pigment in said image receiving layer and/or in an optional layer between said support and said image receiving layer. Excellent contone images with an antique look can be obtained with such an image receiving material in a silver salt diffusion transfer process.
    Type: Grant
    Filed: September 13, 1993
    Date of Patent: August 23, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Leon Vermeulen, Robert Pauwels
  • Patent number: 5334483
    Abstract: The invention provides a diffusion transfer receiver comprising a support with a non-light-sensitive image receiving layer coated onto each face thereof, said image receiving layer in each case comprising a catalytic nuclei layer for physical development of transferred complexed silver halide and each composite comprising a diffusion modifying active component which is preferably a tone controlling compound. The composites of Side 1 and Side 2 are different constitutions so as to provide receivers suitable for different end users. For example Side 1 can be made suitable for creative designers while Side 2 can be made suitable for pre-sensitized plate-makers.The invention also provides a method for improving transmission density of a receiver sheet in a non-light-sensitive image receiving layer of a silver diffusion transfer process which method comprises utilizing in the receiver layer an S-thiuronium alkyl sulfonate transmission density enhancer.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: August 2, 1994
    Assignee: Eastman Kodak Company
    Inventors: Julie Baker, Colin J. Gray, Anthony M. Barnett
  • Patent number: 5273858
    Abstract: Method for making lithographic aluminum offset printing plates according to the DTR-process by photo-exposing a photosensitive monosheet layer assemblage comprising a hydrophilic aluminum foil, an intermediate layer comprising hydrophobic polymer beads prepared by polymerization of ethylenically unsaturated monomer(s) and having an average diameter not lower than 0.2 .mu.m, and a silver halide emulsion layer, applying an aqueous alkaline solution to the photo-exposed silver halide emulsion layer in the presence of a developing agent and a silver halide solvent to form a silver image and to allow unreduced silver halide or complexes formed thereof to diffuse imagewise from the developed silver halide emulsion layer to said aluminum foil to produce thereon a silver image, and separating said emulsion layer and said intermediate layer from the imaged aluminum foil. The invention also relates to the photosensitive monosheet layer assemblage used for making such printing plates.
    Type: Grant
    Filed: October 28, 1991
    Date of Patent: December 28, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul J. Coppens, Joan T. Vermeersch, Luc H. Leenders, Ludovicus H. Vervloet, Eric M. Hoes, Eddie R. Daems
  • Patent number: 5268259
    Abstract: A process for preparing a toner donor roll having an integral electrode pattern involving: (a) providing a cylindrically shaped insulating member; (b) coating the insulating member with a photoresist; (c) patterning the photoresist by exposure to light, resulting in a first photoresist portion corresponding to the electrode pattern and a second photoresist portion corresponding to the remainder of the photoresist; (d) removing the first photoresist portion, thereby exposing the portion of the insulating member to be overlaid with the electrode pattern; and (e) depositing conductive metal on the portion of the insulating member formerly overlaid with the first photoresist portion, resulting in the electrode pattern.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: December 7, 1993
    Assignee: Xerox Corporation
    Inventor: Donald S. Sypula
  • Patent number: 5213943
    Abstract: Method for making lithographic aluminium offset printing plates according to the DTR-process by photo-exposing a photosensitive monosheet layer assemblage comprising a hydrophilic aluminium foil, a water-swellable intermediate layer comprising a non-proteinic hydrophilic film-forming polymer, and a silver halide emulsion layer, applying an aqueous alkaline solution thereto in the presence of a developing agent and a silver halide solvent, allowing to reduce the photo-exposed silver halide, allowing the unreduced silver halide or complexes thereof to diffuse to said aluminium foil to form a silver image thereon, and separating said emulsion layer and said intermediate layer from the imaged aluminium foil. The invention also relates to the photosensitive monosheet layer assemblage used for making such printing plates.
    Type: Grant
    Filed: September 13, 1991
    Date of Patent: May 25, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul J. Coppens, Ludovicus H. Vervloet, Luc H. Leenders, Ronald Schuerwegen
  • Patent number: 5202218
    Abstract: The present invention provides a lithographic printing plate material for silver complex diffusion transfer process by scanning type exposure which comprises a film support and, provided thereon, at least a silver halide emulsion layer and a surface physical development nuclei layer, wherein water content in the whole lithographic printing plate material including the support is 1.5% or less. Preferably, the silver halide emulsion comprises about 95 mol % or more of silver chloride, 90% by weight or more of the silver halide grains have a size within .+-.40% of average grain size, the silver halide grains have an average grain size of about 0.3.mu.-about 1.0.mu., and the surface of the grains is replaced with about 0.1 mol %-about 3.0 mol % of an iodide per 1 mol of the silver halide.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: April 13, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akio Yoshida, Keisuke Iguchi, Hiroyuki Ishikura, Hiroshi Nishinoiri
  • Patent number: 5200295
    Abstract: A method for the production of a silver image by the silver complex diffusion transfer reversal process, said method comprising the following steps:(I) image-wise photo-exposing a silver halide emulsion layer of a photographic silver halide emulsion having in waterpermeable relationship with the silver halide at least one developing agent,(II) wetting with a practically neutral aqueous liquid the said photo-exposed silver halide emulsion layer and/or wetting with said liquid a development nuclei containing layer of an image-receiving material as defined hereinafter and contacting said materials thereby bringing said layers into waterpermeable relationship with each other, and(III) separating the contacted materials after formation in the image-receiving material of a silver image,wherein said image-receiving material contains in co-operable relationship: (i) physical development nuclei, (ii) a silver halide solvent being a silver complexing agent or precursor thereof, (iii) a watersoluble sulfite or sulfite p
    Type: Grant
    Filed: December 10, 1991
    Date of Patent: April 6, 1993
    Assignee: AGFA-Gevaert N.V.
    Inventors: Leon L. Vermeulen, Robert S. Pauwels, Jean-Marie O. Dewanckele
  • Patent number: 5200296
    Abstract: Provided is an image receiving material for silver complex diffusion transfer process which comprises a support, an image receiving layer provided on the support and an upper layer provided on the image receiving layer wherein physical development nuclei are distributed densely in the vicinity of the surface of the support and gradually diminishing towards the upper layer and a color toning agent is contained densely in the upper layer and gradually diminishing towards the surface of the support and the physical development nuclei and the color toning agent are thus mutually distributed. The image receiving material is produced by coating on a support a hydrophilic colloid coating solution for image receiving layer which contains physical development nuclei and contains substantially no color toning agent and thereon at least one hydrophilic colloid coating solution which contains at least one color toning agent and contains substantially no physical development nuclei.
    Type: Grant
    Filed: April 8, 1992
    Date of Patent: April 6, 1993
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Hiroaki Nagamatsu, Susumu Baba, Tatsuhito Taniguchi
  • Patent number: 5196290
    Abstract: The present invention provides a method for making a lithographic aluminium offset printing plate comprising the steps of:information-wise exposing an imaging element comprising on an aluminium support a layer of physical development nuclei and a silver halide emulsion layerdeveloping said information-wise exposed imaging element in the presence of a silver halide solvent to obtain a silver image in said layer of physical development nuclei andremoving all layers on top of said silver image to expose said silver image by means of washing with rinsing water characterized in that said rinsing water has a pH of 4 to 8 and is bufferred.
    Type: Grant
    Filed: May 27, 1992
    Date of Patent: March 23, 1993
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul J. Coppens, Ludovicus H. Vefvloet, Eric M. Hoes
  • Patent number: 5068165
    Abstract: Method for making lithographic aluminium offset printing plates according to the DTR-process by photo-exposing a photosensitive monosheet layer assemblage comprising a hydrophilic aluminium foil, a water-swellable intermediate layer comprising a non-protenic hydrophilic film-forming polymer, and a silver halide emulsion layer, applying an aqueous alkaline solution thereto in the presence of a developing agent and a silver halide solvent, allowing to reduce the photo-exposed silver halide, allowing the unreduced silver halide or complexes thereof to diffuse to said aluminium foil to form a silver image thereon, and separating said emulsion layer and said intermediate layer from the image aluminium foil. The invention also relates to the photosensitive monosheet layer assemblage used for making such printing plates.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: November 26, 1991
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul J. Coppens, Ludovicus H. Vervloet, Luc H. Leenders, Ronald Schuerwegen
  • Patent number: 5053308
    Abstract: A light-sensitive composition in which microcapsules having a core material comprising a silver halide emulsion are dispersed in a polymerizable compound, and a light-sensitive material comprising a light-sensitive layer containing the light-sensitive composition and a reducing agent provided on a support.
    Type: Grant
    Filed: July 20, 1990
    Date of Patent: October 1, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Keiji Takeda
  • Patent number: 5030545
    Abstract: A method of forming images by silver salt diffusion transfer in which a photosensitive element which contains an imagewise exposed photosensitive silver halide emulsion layer is developed in the presence of a silver halide solvent using an alkaline processing composition, wherein at least part of the unexposed silver halide of the emulsion layer is formed into a transferable silver complex salt, at least part of the transferable silver complex salt is transferred to an image receiving layer to yield an image in the image receiving layer, wherein non-photosensitive silver precipitation nuclei are included in the photosensitive element. It is possible to obtain images without metallic luster in a stable manner.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: July 9, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Osami Tanabe
  • Patent number: 4954417
    Abstract: A light-sensitive microcapsule comprising a core material containing a polymerizable compound and a shell material characterized in that the shell material contains therin silver halide in the form of grains. A light-sensitive material comprising a light-sensitive layer containing a great number of said microcapsules and a reducing agent provided on a support is also disclosed.
    Type: Grant
    Filed: April 11, 1989
    Date of Patent: September 4, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Tsumoru Hirano, Eiji Funatsu, Shunichi Ishikawa
  • Patent number: 4888267
    Abstract: An ecologically clean method for processing an imagewise exposed photographic material having a silver halide emulsion layer which method comprises the steps of:(A) developing the image-wise exposed photographic material by means of at least one diffusible developing agent in the absence of such an amount of silver halide solvent that would reduce the coverage of developed silver metal (Ag/m2) by more than 20% using an aqueous alkaline liquid.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: December 19, 1989
    Assignee: AGFA-Gevaert N.V.
    Inventor: Gino L. De Rycke
  • Patent number: 4859565
    Abstract: Method for making images by image-wise exposing a silver halide emulsion layer, developing it with an alkaline processing solution in the presence of a silver halide solvent, development nuclei, and a density- and tone-controlling compound, transferring silver complexes from the emulsion layer to a non-light-sensitive image-receiving layer and forming an image therein, said density- and tone-controlling compound being contained in said image-receiving layer and/or in said processing solution and corresponding to the general formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 (same or different) represent hydrogen, C.sub.1 -C.sub.8 alkyl, or Alk.sub.1 --X--Alk.sub.2 --Y--; Alk.sub.1 is (substituted) C.sub.1 -C.sub.8 alkyl; X is --O-- or --S--; Alk.sub.2 is (substituted) C.sub.1 -C.sub.8 alkylene; Y is a single bond, --O--, --S--, --CONH--, --SO.sub.2 NH--, or --NHCONH--; R.sup.3 can alternatively represent (substituted) C.sub.1 -C.sub.8 alkylthio; at least one of R.sup.1, R.sup.2, and R.sup.
    Type: Grant
    Filed: April 26, 1988
    Date of Patent: August 22, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Rene M. De Keyzer, Robert J. Pollet, Leon L. Vermeulen
  • Patent number: 4859566
    Abstract: Image receiving material suited for use in the silver complex diffusion transfer reversal process which material contains a water-impermeable support coated with (1) an image-receiving layer containing physical development nuclei dispersed in a waterpermeable binder and (2) a waterpermeable top layer free from development nuclei and containing a hydrophilic colloid, characterized in that:(i) the total solids coverage of said two layers (1) and (2) is at most 2 g/m2,(ii) in layer (1) the coverage of said nuclei is in the range of 0.1 mg/m2 to 10 mg/m2, and the coverage of binder is in the range of 0.4 to 1.3 g/m2, and(iii) in said top layer (2) the coverage of hydrophilic colloid is in the range of 0.1 to 0.9 g/m2.
    Type: Grant
    Filed: August 4, 1988
    Date of Patent: August 22, 1989
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Rene M. De Keyzer
  • Patent number: 4830949
    Abstract: An ecologically advantageous method for processing an exposed photographic silver halide emulsion layer-bearing material involves the steps of:(A) developing in an aqueous alkaline liquid an image-wise exposed silver halide emulsion layer of said material by means of at least one diffusible developing agent in the absence of such an amount of silver halide solvent that would reduce the coverage of developed silver metal (Ag/m2) by more than 20%,(B) bringing the emulsion layer side of said developed photographic material while still wet by the liquid from step (A) into contact with a water-absorbing processing layer of a receptor element that contains in an organic hydrophilic colloid binder a silver halide reducing agent and silver halide complexing agent and in waterpermeable relationship therewith physical development nuclei,(C) maintaining said photographic material and receptor compound into said receptor element until removal of undeveloped silver halide from the exposed silver halide emulsion layer is s
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: May 16, 1989
    Assignee: AGFA-Gevaert N.V.
    Inventor: Gino L. De Rycke
  • Patent number: 4798779
    Abstract: A process for forming an image by silver salt diffusion transfer comprising developing a light-sensitive element which comprises a support having provided thereon a light-sensitive silver halide emulsion layer which has been imagewise exposed to light by an alkaline processing composition in the presence of a silver halide solvent so that at least a part of silver halide unexposed in said emulsion layer is converted to a transferable silver complex salt, and then transferring at least a part of said silver complex salt to an image-receiving layer containing a silver precipitating agent to form an image on said image-receiving layer, wherein the concentration of said silver precipitating agent in said image-receiving layer is in the range of from 2.times.10.sup.-6 to 8.times.10.sup.-6 mol/m.sup.2 and at least one of said light-sensitive element and said alkaline processing composition contains at least one of a compound represented by formula (I) and a compound represented by formula (II) ##STR1## wherein R.
    Type: Grant
    Filed: January 29, 1987
    Date of Patent: January 17, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Idota, Yukio Karino, Hiroshi Hayashi, Hideki Tomiyama
  • Patent number: 4775614
    Abstract: An ecologically advantageous method for fixing a developed photographic silver halide emulsion layer material which involves the steps of:(A) developing an image-wise exposed silver halide emulsion layer with a developing agent in the presence of an aqueous alkaline liquid,(B) bringing the developed photographic material while still wet with the liquid of step (A) with its silver halide emulsion layer side in intimate contact with a water-absorbing layer of a receptor element, which layer comprises an organic hydrophilic colloid binder, a silver halide complexing agent, and in dispersed form a metal sulphide as silver ion scavenging agent,(C) maintaining said photographic material and receptor element in contact to allow the transfer of dissolved complexed silver compound into said receptor element, and(D) separating the photographic material from the receptor element, andwherein said water-absorbing layer contains said metal sulphide in colloidal form with an average grain size below 0.1 .mu.
    Type: Grant
    Filed: October 20, 1986
    Date of Patent: October 4, 1988
    Assignee: Agfa-Gevaert N.V.
    Inventor: Gino L. De Rycke