Abstract: This invention relates to a fixing bath containing a biologically degradable complexing agent of formula I ##STR1## wherein R.sup.1-4 represents hydrogen, C.sub.1 -C.sub.10 -alkyl, hydroxy-C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy-C.sub.1 -C.sub.10 -alkyl, carboxy-C.sub.2 -C.sub.10 -alkyl, dicarboxy-C.sub.1 -C.sub.10 -alkyl, carboxy-hydroxy-C.sub.1 -C.sub.10 -alkyl, hydroxy-C.sub.1 -C.sub.5 -alkyl-(oxy-C.sub.1 -C.sub.5 -alkyl).sub.n, or C.sub.1 -C.sub.5 -alkoxy-C.sub.1 -C.sub.5 -alkyl-(oxy-C.sub.1 -C.sub.5 -alkyl).sub.n,M represents hydrogen, lithium, sodium, potassium or ammonium, andn represents 1, 2, 3 or 4,the iron(III) complex salt of which does not impede electrolytic desilverisation during the regeneration of spent fixing bath.

Abstract: A conditioning or bleach accelerating solution is prepared by diluting a concentrate up to 25 times. The concentrate contains a formaldehyde bisulfite precursor salt at from 200 to 600 g/l, sulfite ions at 0 to 200 g/l, a bleach accelerating agent at from 1.5 to 25 g/l, and a metal ion chelating agent present at up to 60 g/l. The concentrate is free of sodium ions.

Abstract: An emulsification and dispersion method of a hydrophobic, photographically useful compound comprising dispersing a water-insoluble phase containing the hydrophobic, photographically useful compound in water or in a hydrophilic colloid composition, wherein the water-insoluble phase at a temperature at which the prepared dispersion is stored may have a viscosity of from 100 poise or more to less than 1,000,000 poise at the shear rate of 10 sec.sup.-1. According to the present invention, a silver halide photographic material comprising a fine dispersion of a hydrophobic, photographically useful compound and having an excellent production suitability can be obtained.

Abstract: There is disclosed a photographic composition having fixing capacity and a method for processing a silver halide photographic material using the same. The photographic composition having fixing capacity comprises at least one compound represented by the following formula (I):RSO.sub.2 M formula (I)wherein R represents a lower alkyl group having 1 to 3 carbon atoms, and M represents a hydrogen atom or a cationic group.

Abstract: A method for processing a silver halide photographic light-sensitive material is by an automatic processor having a processing chamber with a small volume.

Abstract: A method for processing silver halide photosensitive photographic material comprises the steps of developing an image-exposed silver halide photosensitive material and desilvering it with a processing solution having fixing function which contains a thiosulfate radical and a specified meso-ionic compound or a specified thiourea, an amount of ammonium ion in the solution being 0 to 50% based on the total counter cations in the solution. This method can provide processed silver halide photosensitive photographic material having excellent photographic properties while keeping a low stain concentration with even a small amount of a replenisher.

Abstract: A method of processing silver halide black-and-white photographic material in a processing machine which transports the material to be processed, through several processing tanks. The processing machine includes at least one tank with fixing ability and at least one tank which is either a wash or stabilizer tank. The wash or stabilizer tank furthest from the fixer tank(s) is replenished with wash or stabilizer solution. Outflow from the wash tank or stabilizer tank nearest the fixer tank(s) is passed to the nearest fixer tank together with a fixer replenishment solution to maintain the fixer's working composition. The total submersion time in the tank(s) having fixing ability is less than 25 seconds and the ratio of coated silver in the unprocessed photographic material (in g/m.sup.2) to the sum of the rates of addition to the fixer tank (in l/m.sup.2) of the wash outflow and fixer replenishment solution is greater than 10 g/l.

Abstract: Disclosed is a fixing solution for a silver halide light-sensitive material comprising a compound represented by Formula I:R--(B).sub.n --CH.sub.2 --COOH Formula Iwherein R represents an alkyl group or an aryl group, provided that the alkyl group or the aryl group is substituted by at least one selected from the group consisting of a hydroxyl group, an amino group, a sulfo group, a nitro group and a halogen group; B represents a chemical bond selected from the group consisting of an ester bond, an amide bond, an ether bond and a thioether bond; n represents zero or one.

Abstract: A processing solution for processing an exposed silver halide photographic light-sensitive material comprises a compound represented by the following formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represent --COOM.sub.1, --OH, --PO.sub.3 M.sub.1 M.sub.2 or --CONH.sub.2 in which M.sub.1 and M.sub.2 each represent a hydrogen ion, an alkali metal ion or another cation; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent a hydrogen atom, a lower alkyl group or a hydroxyl group; n.sub.1, n.sub.2, n.sub.3 and n.sub.4 each represent an integer of 0, 1 or 2, provided that none of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are hydrogen atoms when n.sub.1 +n.sub.2 =1 and n.sub.3 +n.sub.4 =1; and X represents a substituted or unsubstituted alkylene group having 2 to 6 carbon atoms or --(B.sub.1 O)m-B.sub.2 -- in which B.sub.1 and B.sub.2 each represent a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms, and m is an integer of from 1 to 4.

Abstract: The present invention provides a method for making an offset printing plate according to the silver salt diffusion transfer process comprising the steps of:image-wise exposing an imaging element comprising in the order given on a hydrophilic surface of a support (i) an image receiving layer containing physical development nuclei and (ii) a photosensitive layer comprising a photosensitive silver halide emulsion said photosensitive layer being in water permeable relationship with said image receiving layer,applying an aqueous alkaline solution to the imaging element in the presence of (a) developing agent(s) and (a) silver halide solvent(s) to form a silver image in said image receiving layer,treating the imaging element to remove the layer(s) on top of the image receiving layer, thereby exposing the imaged surface of the support by uncovering said silver image formed in said image receiving layer,characterized in that said aqueous alkaline solution comprises less than 0.

Abstract: A silver halide color photographic material having at least one silver halide emulsion layer on a support is color developed after imagewise exposure, followed by desilverization, wherein the photographic material has a total dry film thickness of 8 to 22 .mu.m, the concentration of ammonium ions contained in a processing solution having fixing ability used in desilverization is 0 to 50 mol % based on the total cations, and the processing solution having fixing ability contains at least one kind of thioether compound, thereby improving desilverization performance in continuous processing and preventing yellow stains from increasing.

Abstract: A redox amplification photographic process comprises a sulfite fixing step after development-amplification and prior to peroxide bleaching.

Abstract: A method for continuously processing an exposed silver halide photographic light sensitive material comprises the steps of:developing said material with a developing solution, the developing solution being replenished with a first water and a solid developing composition containing a developing agent and a first sulfite according to a processing amount of said material; andfixing the developed material with a fixing solution, the fixing solution being replenished with a second water and a solid fixing composition containing a fixing agent and a second sulfite according to a processing amount of said material, and no other processing being carried out between said developing and said fixing,wherein the second sulfite is replenished in an amount of 0 to 0.05 mol per liter of the second water.

Abstract: A solution for bleaching or bleach-fixing an exposed and developed silver halide color photographic light-sensitive material contains a ferric complex salt of a compound represented by the following Formula (A-I), (A-II) or (A-III), and a compound represented by the following Formula (B): ##STR1##

Abstract: This invention provides a process for removal of silver halide from a silver halide photographic recording material by a processing solution with fixing ability (a fixer) containing thiosulfate as a fixing agent conducted in the presence of a thioether compound incorporated within a fixer formulation. It further provides a fixer formulation for use in said process. The fixer contains a maximum ammonium ion concentration of 0.9M.

Abstract: The present invention provides a fixer composition and a method of processing an exposed photographic silver halide element comprising the steps of developing by means of a developer comprising a silver halide developing agent and treating the developed element with a fixer composition, wherein the fixer composition comprises a silver halide solvent, a sulfite ion source, an aluminum salt hardening agent, a buffering agent, a sequestering agent and an .alpha.-ketocarboxylic acid compound in an amount of more than 2 grams per liter corresponding to the formula:R--CO--COOHwherein R represents a hydrogen atom or an organic group.

Abstract: An image forming method is disclosed, comprising exposing a silver halide photographic material through a transparent, high definition-screening original and developing the photographic material with a developer to form a halftone dot image, wherein:the photographic material forms a halftone dot image having a dot area of 57% or less when exposed, through the transparent original comprising a halftone dot image having a dot area of 50%, in two times an amount that gives a halftone dot having a dot area of 50%; and the photographic material has a maximum density of 3.0 or more and a contrast of 8.0 or more;and wherein the photographic material is exposed to light having an emission peak at a wavelength of 360 to 450 nm and developed with a developer having a pH of 10.5 or less.

Abstract: An improved image forming method is disclosed which comprises contacting both an originating photographic element and a display photographic element with substantially similar processing solutions. The originating photographic element is characterized in that it contains at least 50 mole percent silver chloride grains and no more than 2 mole percent silver iodide, based on total silver forming the grain projected area. The grains are tabular grains bounded by {100} faces having adjacent edge ratios of less than 100 and each having an aspect ratio of at least 2.

Abstract: A substantially sulfur-free ammonium thiosulfate containing product can be produced by spray drying an aqueous solution containing ammonium thiosulfate and effective stabilizing amounts of both a carbonate component and a sulfite component under effective conditions to provide a substantially sulfur-free product. The carbonate component is selected from among ammonium carbonate or bicarbonate, an alkali metal carbonate or bicarbonate, or an alkaline metal carbonate or bicarbonate while the sulfite component is an ammonium sulfite or bisulfite, alkali metal sulfite or bisulfite, or an alkaline metal sulfite or bisulfite.

Abstract: There is disclosed a photographic composition having fixing capacity and a method for processing a silver halide photographic material using the same. The photographic composition having fixing capacity comprises a photographic composition having fixing capacity, which comprises at least one compound represented by the following formula (I) and at least one compound represented by the following formula (II):RSO.sub.2 SM formula (I)wherein R represents an aliphatic group, an aromatic group, or a heterocyclic group, and M represents a hydrogen atom or a cationic group,R.sup.1 SO.sub.2 M.sup.1 formula (II)wherein R.sup.1 represents an aliphatic group, an aromatic group, or a heterocyclic group, and M.sup.1 represents a hydrogen atom or a cationic group.

Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of exposing and developing an imaging element comprising on a support a silver halide emulsion layer and an image-receiving layer in the presence of a silver halide solvents corresponding to the following formula:Z.sup.1 --(R.sup.1 --X.sup.1).sub.n --(R.sup.2 --X.sup.2)--L--(X.sup.3 --R.sup.3)--(X.sup.4 --R.sup.4).sub.m --Z.sup.2 (I)wherein X.sup.1, X.sup.2, X.sup.3 and X.sup.4 each independently represents --S--, --NH-- or --N(R.sup.5 --Z.sup.3)--, R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each independently represents an alkylene, an alkenylene or an alkynylene, n and m each independently represents an integer from 0 to 4, Z.sup.1, Z.sup.2 and Z.sup.

Abstract: A diagnostic method for testing agitation of a photographic processing solution in a processing tank for a photographic processing apparatus of the type having a nozzle and adapted in use to impinge the photographic processing solution onto a photographic emulsion includes the steps of charging the processing tank with a solution containing a silver solvent, processing the photographic emulsion, and testing the processed photographic emulsion for patterns of silver remaining in the photographic emulsion, wherein such patterns are indicative of nozzle obstructions and thereby agitation levels present in the processing tank.

Abstract: A solid processing composition for providing fixer or bleach-fixer of a silver halide photographic light-sensitive material is disclosed, wherein the composition comprises a sugar alcohol and at least one of a thiosulfate salt and a thiocyanate salt.

Abstract: A lithographic printing plate is prepared from a silver halide photosensitive material in accordance with a silver complex diffusion transfer process. The photosensitive material is exposed and developed with a diffusion transfer processing solution containing a mesoionic compound as a silver halide complexing agent. The printing plate has good ink receptivity and minimized plate wear. The processing solution is free from the problems of corrosion and waste solution disposal.

Abstract: A processing method for silver halide photographic material is disclosed, in which at least one hydrophilic colloidal layer containing a dye of a solid fine grain dispersion. The processing method is carried out by processing the photographic material with a solution having a fixing ability containing at least one compound represented by formula (A):RSO.sub.2 SM (A)wherein R represents an aliphatic group, an aryl group or a heterocyclic group, and M represents a hydrogen atom or a cation group.

Abstract: A method of desilvering an imagewise and developed color silver halide element, said method comprising bleaching the photographic element with a peracid bleach and subsequently contacting the photographic element with a fixer solution comprising thiosulfate anion and sodium cation;wherein the Molar-minute fixing Time is less than about 0.2 Molar-minutes.times.m.sup.2 /g Ag.times.the grams of incorporated silver per square meter of the photographic element.

Abstract: A processing solution for a silver halide color photographic material, said solution containing at least one kind of compound represented by formula (I), (II), or (III); ##STR1## the substituents are defined in the instant specification.

Abstract: A method of treating a seasoned fixing solution comprising desilvering a fixing solution containing a chelating compound represented by Formula IMOOC(CH.sub.2)m(X)p((CH.sub.2).sub.n COOM).sub.q (I)where X is N, or C--OH;n and m are independently 0, 1, or 2;if X is N then p is 0 or 1 and q is 1 or 2;if X is C-OH then p is 0, 1 or 2 and q is 1 or 2; andM is a cationic counterion; andfurther containing a carryover amount of a bleaching agent which is a complex of ferric ion and a tridentate or a tetradentate ligand.

Abstract: A composition having a fixing ability for photography which is used as a bath having a fixing ability, for processing an exposed silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, said compositian being substantially free of thiosulfate ion and comprising as a fixing agent at least one thioether comcompound having at least one group selected from the group consisting of ##STR1## and a heterocyclic group, wherein M.sub.1, M.sub.2 and M.sub.3 may be the same or different, each represents a hydrogen atom or a counter cation; R.sub.1 to R.sub.19, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group or an alkenyl group; and X.sup..crclbar. represents a counter anion.

Abstract: A method for processing a color photographic material comprising a support having on at least one surface thereof at least one layer containing a light-sensitive silver halide emulsion and a non-diffusing oil-soluble coupler capable of forming a dye by coupling with the oxidation product of an aromatic primary amine developing agent, wherein the oil-soluble dye is a pyrrolotriazole cyan coupler and the color photographic material is processed after color development with a bath containing, as a fixing agent, at least one of nitrogen-containing heterocyclic compounds having a sulfide group, meso-ionic compounds and thioether compounds.

Abstract: A fixing solution having a pH.gtoreq.7 and comprising a fixing amount of sulfite and a fix accelerating amount of a thioether compound; wherein the fixing solution contains less than 0.05 moles/liter of thiosulfate and a method of processing an imagewise exposed and developed silver halide photographic element comprising fixing in said fixing solution a silver halide photographic element containing at least one emulsion or deposit of silver halide comprising greater than 90 mole % silver chloride.

Abstract: A method for processing a silver halide photographic material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, which comprises the steps of developing and fixing the image-wise exposed silver halide photographic material, wherein the fixing bath used in the fixing step contains at least one meso-ionic compound other than meso-ionic 1,2,4-triazolium-3-thiolate compounds, wherein said meso-ionic compound is a compound represented by formula (I): ##STR1## wherein M and A.theta. are as defined in the specification as a fixing agent. The fixing bath and subsequent baths have excellent stability against precipitation, and the processed photographic material having improved image stability can be obtained.

Abstract: A solid processing agent for a silver halide photographic light-sensitive material is disclosed, which comprises a compound represented by the following Formula (I): ##STR1## wherein R.sub.1 represents a halogen atom, an alkyl group or an alkenyl group, provided that a plural of R.sub.1 's may be the same or different; R.sub.2 represents a halogen atom, an alkyl group, an alkenyl group or an alkoxy group; R.sub.3 represents a lower alkyl group, provided that R.sub.1, R.sub.2 and R.sub.3 may be the same or different, m and n each represent an integer of 0 to 5; and X represents an anion.

Abstract: A process for processing an imagewise exposed silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, comprising the steps of developing in a developing bath and processing in a bath having a fixing ability, wherein the bath having the fixing ability contains at least one mesoionic compound represented by formula (I): ##STR1## In a second embodiment, a process is disclosed for processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, comprising the steps of subjecting the material to color development, and then subjecting the material to blix in a blix bath, wherein the blix bath contains at least one mesoionic compound represented formula (III) or (IV): ##STR2##

Abstract: There is disclosed a novel diaminostilbene series compound, a method for forming an image using the same, and a composition comprising the same. The diaminostilbene compound is represented by the following formula (I): ##STR1## wherein L.sup.1 and L.sup.2, which are the same or different, each represent --OR.sup.1 or --N--R.sup.2 (R.sup.3), wherein the four substituents L.sup.1 and L.sup.2 have four or more substituents in total selected from substituents represented by the following formula (II);R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group, or an alkyl group having a substituent selected from substituents represented by the formula (II);R.sup.3 represents an alkyl group or an alkyl group having a substituent selected from substituents represented by the formula (II); andM represents a hydrogen atom, an alkali metal, an ammonium, or a pyridinium:formula (II)--SO.sub.3 M, --OSO.sub.3 M, --COOM, and --NR.sub.

Abstract: A lithographic printing plate is prepared from a photosensitive material comprising a silver halide emulsion layer and a physical development nucleus layer on a support in accordance with a silver complex diffusion transfer process. The photosensitive material is diffusion transfer processed in the presence of both a triazole, oxadiazole or similar compound and an organic thioether compound. The printing plate has good ink receptivity and minimized plate wear. The processing solution is free from the problems of corrosion and waste solution disposal.

Abstract: A method of fixing a photographic element with a fixing solution containing less than 20% ammonium thiosulphate wherein the photographic element has incorporated therein a fix accelerator precursor which is a silver salt of an amino thiol having a solubility of less than 1 g/l (as silver ion) when held for 23.degree. C. for 5 minutes in a colour developer solution at pH 10 having a sulphite concentration of 4.25 g/l and a bromide concentration of 1.2 g/l.

Abstract: There is disclosed a method for processing a silver halide photographic light sensitive material comprising the steps ofdeveloping the light sensitive material with a developing solution,treating the light sensitive material with a fixing capacity-having solution, and thentreating the light sensitive material with a processing solution (S), wherein part of or the whole of overflow from a tank containing the processing solution (S) is allowed to flow into a tank containing the fixing capability-having solution, and wherein solid processing chemicals are added to the fixing capacity-having solution or the overflow from the tank containing the processing solution (S).

Abstract: There is described a fixing bath for developed silver halide photographic material which comprises as the active silver halide solvent a combination of sodium thiosulphate and potassium thiosulphate, the molar ratio of sodium to potassium being from about 2:3 to about 3:2.

Abstract: An aqueous alkaline processing liquid for use in silver halide photography, wherein said liquid comprises one or more alkanolamines, the said alkanolamines consisting of one or more tertiary alkanolamines in a total amount in the range from 0.3 mol/l to 1.5 mol/l, and one or more secondary alkanolamines in an amount from 0 mol % to 30 mol % with respect to the amount of tertiary alkanolamine(s), and said liquid also contains sulphite ions in an amount in the range of 16 g/l to 30 g/l.

Abstract: A process and composition for processing a silver halide photographic material. The photographic material mat be a black and white photographic material or a color photographic material.

Abstract: A method for making flowable alkaline thiosulfate, flowable alkaline sulfite, or a combination of the two, by blending an alkaline thiosulfate, an alkaline sulfite, or a combination of the two, with an alkali metal arylsulfonate.formaldehyde in an amount effective to render the alkaline thiosulfate, the alkaline sulfite, or the combination freely flowable, and the product of this method. It has been found that the product of this method, such as freely flowable ammonium thiosulfate powder mixture, can be stored in a freely flowable condition for extended periods of time and can be dissolved into solution readily to form a clear non-turbid solution. The freely flowable ammonium thiosulfate powdered mixture of the present invention is particularly useful as a photographic fixative and bleach fixative for processing photographic elements.

Abstract: There are disclosed a fixing solution for a light-sensitive silver halide color photographic material which comprises containing a water-soluble surfactant and a processing method using the same.

Abstract: A method for processing a silver halide color photographic material, which comprises processing an imagewise exposed silver halide color photographic material with a processing solution containing at least one chelate compound of a metal salt selected from the group consisting of salts of Fe(III), Mn(III), Co(III), Rh(II), Rh(III), Au(II), Au(III) and Ce(IV) with an organic acid represented by following general formula (I): ##STR1## wherein Z represents a nonmetallic atom group required to form a heterocyclic group; R represents a substituent; n represents 0 or an integer of from 1 to 10; Q.sub.1, Q.sub.2 and Q.sub.3 each represents a hydrogen atom, an aliphatic hydrocarbon group substituted by a carboxyl group, an aromatic hydrocarbon group substituted by a carboxyl group or a heterocyclic group substituted by a carboxyl group; and W represents a divalent linkage group containing at least one of an alkylene group or an arylene group.

Abstract: A method of processing a silver halide color photographic material using a carbamoyl or imidazole type organic metal complex bleaching agent of any of compounds of formulae (I), (II), (III), (IV), and (V) and a mercapto, mesoionic or thioether fixing agent of compounds of formulae (A), (B) and (C). A bleach-fixing composition containing the bleaching agent and fixing agent is also disclosed. The processing method provides good desilvering with little bleach fogging of the processed photographic material, and the processing composition has good stability. W in formula (III) below represents a divalent linking group.

Abstract: Silver halide black-and-white photosensitive material is processed with a fixer which contains 0.5 to 2.0 mol/liter of a thiosulfate and 0.003 to 0.3 mol/liter of a meso-ionic compound, the moles of the meso-ionic compound divided by the moles of the thiosulfate being from 0.003 to 0.2. The fixer accelerates fixing speed, enabling rapid processing of photographic material.

Abstract: A method for processing a silver halide photosensitive material comprises the steps of developing an exposed silver halide photosensitive material and treating it with a bath having a fixing function containing an N-oxide compound having a mercapto group in the molecule. When the bath having a fixing function is used, a stable fixing power and excellent desilverization effect can be obtained by processing a color photosensitive material with only a small amount of replenisher.

Abstract: A method of reducing the environmental impact of ammonium thiosulfate photographic fixers without increasing fixing time is provided. In the method of the invention, up to 60% molar of the total ammonium thiosulfate is replaced by an alkali metal thiosulfate.

Abstract: There is disclosed a method for rapidly processing a silver halide photographic material with an automatic processing machine for 20 to 60 seconds, the method being excellent fixability and drying characteristics. The fixing solution has:(a) a pH of 5.3 or more,(b) a sulfite ion concentration of 0.05 to 1.0 mole/liter, and(c) a content of an aluminium compound content of 0 to 0.01 mole/liter as a hardener. The coated amount of the gelatin contained in the protective layer provided on the side of the silver halide emulsion layers of the photographic material is 1.0 g/m.sup.2 or less.

Abstract: A method for making flowable alkaline thiosulfate, flowable alkaline sulfite, or a combination of the two, by blending an alkaline thiosulfate, an alkaline sulfite, or a combination of the two, with an alkali metal .?.arylsulfonate.formaldehyde.!. .Iadd.arylsulfonate.cndot.formaldehyde .Iaddend.in an amount effective to render the alkaline thiosulfate, the alkaline sulfite, or the combination freely flowable, and the product of this method. It has been found that the product of this method, such as freely flowable ammonium thiosulfate powder mixture, can be stored in a freely flowable condition for extended periods of time and can be dissolved into solution readily to form a clear non-turbid solution. The freely flowable ammonium thiosulfate powdered mixture of the present invention is particularly useful as a photographic fixative and bleach fixative for processing photographic elements.