Dissolvable Or Removable Patents (Class 430/513)
  • Patent number: 11186719
    Abstract: The present disclosure embodies compounds of Formula I, methods of use thereof, and kits thereof: that are useful in connection with the detection of analytes of all types (e.g., biological molecules such as proteins, organic molecules, natural or synthetic molecules). The disclosure is particularly applicable to detection of proteins and nucleic acids using all types of membrane-based assays by techniques such as Western blotting, Dot blotting, Southern blotting, and Northern blotting.
    Type: Grant
    Filed: May 7, 2019
    Date of Patent: November 30, 2021
    Assignee: LI-COR, INC.
    Inventors: Silvano Sanchini, Rose Skopp, Vassil Elitzin, Nisha Padhye, Teresa Urlacher
  • Patent number: 11086200
    Abstract: A camera module comprising a polymer composition that includes a polymer matrix containing a liquid crystalline polymer and a mineral filler is provided. The liquid crystalline polymer contains repeating units derived from naphthenic hydroxycarboxylic and/or dicarboxylic acids in an amount of about 10 mol. % or more of the polymer. Further, the polymer composition exhibits a melt viscosity of from about 30 to about 400 Pa-s, as determined at a shear rate of 400 seconds?1 and at a temperature 15° C. higher than the melting temperature of the composition in accordance with ISO Test No. 11443:2005.
    Type: Grant
    Filed: March 10, 2020
    Date of Patent: August 10, 2021
    Assignee: Ticona LLC
    Inventor: Young Shin Kim
  • Patent number: 8449293
    Abstract: A method for patterning a substrate with extreme ultraviolet (EUV) radiation is provided. The method includes contacting a surface of the substrate with at least one surface modification agent that reacts with and bonds to the surface 402 of the substrate 401 to provide a modified surface. A layer of photoresist is formed on the modified surface, followed by exposing the layer of photoresist to a pattern of EUV radiation. The surface modification agent has a general formula: X-L-Z, where X is a leaving group; L is a linkage group including a substituted or un-substituted carbon chain having 1 to 20 carbons, a sulfur moiety, a silicon moiety, or combinations thereof; and Z is at least one of an acid functional group, a photoactive acid generator group or a halide.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: May 28, 2013
    Assignee: Tokyo Electron Limited
    Inventors: Benjamin M. Rathsack, Steven Scheer, Mark H. Somervell
  • Patent number: 8142988
    Abstract: Organic coating composition are provided including antireflective coating compositions that can reduce reflection of exposing radiation from a substrate back into an overcoated photoresist layer and/or function as a planarizing or via-fill layer. Preferred compositions of the invention comprise contain a crosslinker component that is resistant to sublimination or other migration crosslinker from the composition coating layer during lithographic processing.
    Type: Grant
    Filed: March 20, 2006
    Date of Patent: March 27, 2012
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Anthony Zampini, Edward K. Pavelchek
  • Patent number: 7439011
    Abstract: A photothermographic material including, on one side of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, and, on the other side of the support, a non-photosensitive back side layer. The total quantity of an alkaline earth metal contained in the non-photosensitive back side layer is 1×10?5 mol/m2 to 1×10?3 mol/m2.
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: October 21, 2008
    Assignee: FUJIFILM Corporation
    Inventor: Rikio Inoue
  • Patent number: 7419774
    Abstract: Disclosed is a photothermographic material comprising a support having disposed on a surface thereof, a non-photosensitive silver source, a photosensitive silver halide, and a reducing agent, and having disposed another surface thereof at least one non-photosensitive layer, wherein at least one of the non-photosensitive layers contains at least one type of gelatin having an isoelectric point of from 5.0 to 9.5; and a method for processing the photothermographic material.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: September 2, 2008
    Assignee: FUJILFILM Corporation
    Inventor: Rikio Inoue
  • Patent number: 7223528
    Abstract: The present invention provides a photothermographic material having, on at least one side of a support, at least an image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, and a reducing agent for the organic silver salt, and at least one non-photosensitive layer, wherein the material contains a water-soluble magenta dye, and also provides an image forming method.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: May 29, 2007
    Assignee: Fujifilm Corporation
    Inventors: Seiichi Yamamoto, Masaharu Sugai, Rikio Inoue
  • Patent number: 7138223
    Abstract: A photothermographic material including, on one side of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, and, on the other side of the support, a non-photosensitive back side layer. The total quantity of an alkaline earth metal contained in the non-photosensitive back side layer is 1×10?5 mol/m2 to 1×10?3 mol/m2.
    Type: Grant
    Filed: April 8, 2003
    Date of Patent: November 21, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Rikio Inoue
  • Patent number: 7112399
    Abstract: Photothermographic materials are coated with thermally developable imaging layers on both sides of the support. Such materials can be arranged in association with one or more phosphor intensifying screens capable of providing emission at a predetermined wavelength in imaging assemblies. These imaging assemblies can be exposed to X-radiation and thereby form a latent image in the photothermographic material that can eventually be heat developed and used for medical diagnosis. The photothermographic materials contain an opaque material that acts as a crossover control agent that absorbs radiation at the predetermined wavelength, for example at 300 to 450 nm, and has limited absorption at higher wavelengths. When the photothermographic material is heated, the opaque material loses its opacity. Additional crossover control agents, such as UV-absorbing compounds, can also be added to the support or to an antihalation layer.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: September 26, 2006
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Dickerson, Alphonse D. Camp
  • Patent number: 6974662
    Abstract: Improved compounds and base precursors that undergo thermal decomposition are disclosed. Thermal base precursors, and in particular, a novel class of salts of arylsulfonylacetic acids as bleaching agents or promoting for photothermographic use are disclosed. Compositions employing these thermal base precursors are suitable for use in acutance and antihalation systems, bleachable filter dye materials, and in promoting unblocking of various components such as blocked developers, especially in photothermographic elements.
    Type: Grant
    Filed: August 4, 2003
    Date of Patent: December 13, 2005
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, Wojciech K. Slusarek, David H. Levy
  • Patent number: 6746807
    Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one filter layer, wherein the filer layer comprises a heat-bleachable composition comprising a benzothiazine arylidiene filter dye, which filter dye is in the presence of an effective amount of a base precursor.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: June 8, 2004
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, Margaret J. Helber, Teresa J. Hosmer, David H. Levy
  • Patent number: 6746830
    Abstract: A silver halide photosensitive material having a substrate, a heat-responsive-discolorable coloring layer and a photosensitive layer coated thereon and having a silver halide, dye-providing compound and a binder, the heat-responsive-discolorable coloring layer containing a heat-responsive-discolorable coloring composition, which is colored at a temperature lower than its discoloration initiation temperature (T) of 60 to 200° C.; which is substantially discolored at a temperature equal to or higher than T; and which does not recover its color once discolored, even when its temperature is lowered to a temperature lower than T again, and the heat-responsive-discolorable coloring composition containing a polymer having a glass transition temperature of 60 to 200° C.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: June 8, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Jun Arakawa, Takahiro Ishizuka
  • Publication number: 20040096758
    Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one filter layer, wherein the filer layer comprises a heat-bleachable composition comprising a benzothiazine arylidiene filter dye, which filter dye is in the presence of an effective amount of a base precursor.
    Type: Application
    Filed: November 20, 2002
    Publication date: May 20, 2004
    Inventors: Ramanuj Goswami, Margaret J. Helber, Teresa J. Hosmer, David H. Levy
  • Patent number: 6730462
    Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one filter layer, wherein the filer layer comprises a heat-bleachable composition comprising a barbituric acid arylidene filter dye is in the presence of an effective amount of a base precursor.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: May 4, 2004
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, Margaret J. Helber, Cynthia A. MacMillan, Mary C. Brick
  • Patent number: 6727057
    Abstract: A heat-developable photosensitive material comprising at least one light-sensitive layer containing an organic silver salt, light-sensitive silver halide and a reducing agent and at least one light-insensitive layer on a support, wherein the heat-developable photosensitive material comprises a water-soluble metal phthalocyanine compound.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: April 27, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Suzuki, Yoshiharu Yabuki
  • Patent number: 6699651
    Abstract: Improved compounds and base precursors that undergo thermal decomposition are disclosed. Thermal-dye-bleach agents, and in particular, a novel class of salts of arylsulfonylacetic acids as bleaching agents for photothermographic use are disclosed. Photothermographic elements employing these thermal-dye-bleach agents are suitable for use as acutance and antihalation systems, bleachable filter dye materials, and in promoting unblocking of various components such as blocked developers, especially in in photothermographic elements.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: March 2, 2004
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, David H. Levy
  • Publication number: 20040033449
    Abstract: A photothermographic material including, on one side of a support, an image forming layer containing at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, and, on the other side of the support, a non-photosensitive back side layer. The total quantity of an alkaline earth metal contained in the non-photosensitive back side layer is 1×10−5 mol/m2 to 1×10−3 mol/m2.
    Type: Application
    Filed: April 8, 2003
    Publication date: February 19, 2004
    Inventor: Rikio Inoue
  • Patent number: 6558880
    Abstract: Photothermographic materials comprise heat-bleachable antihalation compositions in backside antihalation layers. These compositions comprise a hexaarybiimidazole and an oxonol dye that can be represented by the following Structure I: A1═L1—(L2═L3)p—(L4═L5)q—(L6═L7)r—A2−(M)k wherein A1 and A2 are the same or different activated methylene moieties, L1 through L7 independently represent a substituted or unsubstituted methine group, M represents a counterion, k is the number of M counterions necessary to provide neutral charge for Structure I, p, and q, are independently 0 or 1, and r is 0, 1, or 2. The antihalation composition is typically bleached when subjected to a temperature of at least 90° C. for at least 0.5 seconds.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: May 6, 2003
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, William D. Ramsden, Paul A. Zielinski, David G. Baird, LuAnn K. Weinstein, Margaret J. Helber, Doreen C. Lynch
  • Patent number: 6514677
    Abstract: Photothermographic materials comprise heat-bleachable antihalation compositions in antihalation layers. These compositions comprise a hexaarybiimidazole and one or more infrared radiation absorbing compounds that are represented by the following Structure I: A1—L1—A2  I wherein A1 represents a group derived from a dye base, a heterocyclic group, or an electron-donating aromatic group, A2 represents a group derived from a dye base, a heterocyclic group, a group derived from a dye acid, or an electron-donating aromatic group, and L1 represents a conjugated linking group that maintains electron delocalization between A1 and A2 to provide infrared absorbance. The antihalation composition is typically bleached when subjected to a temperature of at least 90° C. for at least 0.5 seconds.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: February 4, 2003
    Assignee: Eastman Kodak Company
    Inventors: William D. Ramsden, David G. Baird
  • Patent number: 6492076
    Abstract: This invention relates to a color photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one antihalation layer or filter layer, wherein the antihalation or filer layer comprises an aqueous heat-bleachable composition comprising at least one zwitterionic 1-aminopyridinium dye having a methine linkage terminated by a substituted or unsubstituted heterocyclic nucleus.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: December 10, 2002
    Assignee: Eastman Kodak Company
    Inventors: Ramanuj Goswami, Mark E. Irving, David H. Levy
  • Patent number: 6489086
    Abstract: Disclosed are an improved silver halide color photographic photosensitive material comprising a support having thereon a photosensitive layer containing at least one kind of photosensitive silver halide grain, a color developing agent, a coupler and a binder, and a non-photosensitive layer, wherein a one dye is contained as a dispersion of solid fine particles at least one of the layers the dye being represented by general formula (I) as follows: D−(X)y  General formula (I) wherein D represents a compound having a chromophore; X represents a dissociative proton or a group having a dissociative proton which is linked to D directly or via a divalent linking group; and y represents an integer of 1 to 7.
    Type: Grant
    Filed: March 17, 2000
    Date of Patent: December 3, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsu Kamosaki, Keizo Kimura, Masashi Ogiyama
  • Patent number: 6451516
    Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic imaging layer, and at least one antihalation layer or a filter layer, wherein the antihalation or filer layer comprises an aqueous heat-bleachable composition comprising a 1-aminopyridinium filter dye having a methine linkage terminated by a substituted or unsubstituted heterocyclic nucleus of the type contained in cyanine dyes, which filter dye is in the presence of an effective amount of a thermal solvent.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: September 17, 2002
    Assignee: Eastman Kodak Company
    Inventors: Mark E. Irving, Ramanuj Goswami
  • Patent number: 6342343
    Abstract: A photothermographic material comprising on one surface side of the support at least one kind of photosensitive silver halide, a photo-insensitive organic silver salt, a reducing agent for a silver ion, and a binder, and having an electroconductive layer, wherein the surface resistivity (under the atmosphere of 25° C., 25% RH) is 1011&OHgr; or less, and the optical density at the exposure wavelength of the surface side containing the photosensitive silver halide is from 0.2 to 3.0.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: January 29, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Ichizo Toya
  • Patent number: 6316179
    Abstract: An infrared sensitized photothermographic silver halide element comprising a support layer having on at least one surface thereof a photothermographic composition comprising a binder, a light insensitive silver source, a reducing agent for silver ion and infrared radiation sensitive preformed silver halide grains having number average particle size of <0.10 micron with at least 80% of all grains with ±0.05 microns of the average, in combination with an antihalation layer having an absorbance ratio of IR absorbance (before exposure)/visible absorbance (after processing) >30, and an IR absorbance of at least 0.3 within the range of 750-1400 and an optical density of less than 0.03 in the visible region.
    Type: Grant
    Filed: October 24, 2000
    Date of Patent: November 13, 2001
    Assignee: Eastman Kodak Company
    Inventors: Steven M. Shor, James B. Philip, Jr.
  • Patent number: 6300053
    Abstract: A photothermographic element has on a support a photo-sensitive layer, and a first non-photosensitive layer containing (1) a base-bleachable dye or a salt thereof and (2) a binder. The first non-photosensitive layer or a second non-photosensitive layer disposed adjacent thereto contains (3) a base precursor and (4) a melting point depressant. The dye (1) becomes more bleachable and the processed image becomes more water resistant.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: October 9, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Itsuo Fujiwara, Ichizo Toya, Masaki Noro
  • Patent number: 6270931
    Abstract: A method of exposing an integral imaging element having: an integral lens sheet with opposed front and back surfaces; a light sensitive layer positioned behind the back surface; and an anti-halation layer between the light sensitive layer and the back surface; the method comprising the steps of: simultaneously exposing a major portion of the area of the light sensitive layer with light from behind the light sensitive layer, or simultaneously exposing the light sensitive layer to all of an integral image from behind the light sensitive layer.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: August 7, 2001
    Assignee: Eastman Kodak Company
    Inventor: Roger Roy Morton
  • Patent number: 6245499
    Abstract: In a photothermographic material comprising an organic silver salt, a silver halide, and a reducing agent, a hydrazine compound of a special structure and a sensitizing dye of a special structure are contained. The photothermographic material shows high Dmax and ultrahigh contrast.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: June 12, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Suzuki, Toshiaki Kubo, Yoshio Inagaki, Tsutomu Arai
  • Patent number: 6165706
    Abstract: A photothermographic element has on a support a photosensitive layer and a non-photosensitive layer containing (1) a base precursor, (2) a base-bleachable dye or a salt thereof, and (3) a binder. A constituent layer on the same side of the support as the non-photosensitive layer contains (4) a water-soluble polymer other than gelatin. The element is improved in coating surface quality and minimized in residual color.
    Type: Grant
    Filed: April 7, 1999
    Date of Patent: December 26, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Itsuo Fujiwara, Ichizo Toya
  • Patent number: 6033840
    Abstract: A radiation-sensitive medical diagnostic film for soft tissue imaging, particularly mammography, is disclosed. The film allows more rapid processing than films currently available for mammographic imaging and maintains acceptably high levels of image sharpness and low levels of mottle. The radiographic film records medical diagnostic images of soft tissue through (a) exposure by a single intensifying screen located to receive an image bearing source of X-radiation and (b) processing, including development, fixing and drying, in 90 seconds or less comprised of a film support transparent to radiation emitted by the intensifying screen and having opposed front and back major faces and an image-forming portion for providing, when imagewise exposed by the intensifying screen and processed, an average contrast in the range of from 2.5 to 3.5, measured over a density above fog of from 0.25 to 2.0.
    Type: Grant
    Filed: October 14, 1998
    Date of Patent: March 7, 2000
    Assignee: Eastman Kodak Company
    Inventor: Robert E. Dickerson
  • Patent number: 5998117
    Abstract: A silver halide photographic light-sensitive material is disclosed. The light-sensitive material comprises a support and one or more photographic constituent layers and at least one of said layers contains a dye capable of being decolored by reacting with a color developing agent.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: December 7, 1999
    Assignee: Konica Corporation
    Inventors: Motoaki Sugino, Nobuaki Kagawa, Shigeto Hirabayashi, Atsushi Tomotake, Satoshi Nakagawa
  • Patent number: 5989795
    Abstract: This invention relates to a photographic recording material comprising a support and a photosensitive chemically sensitized silver halide emulsion layer, containing a sensitizing dye selected from the group consisting of oxonal dyes, merocyanine dyes, and cyanine dyes having a net negative charge, and which has a pH value between about 2 to about 5 and a pAg value between about 1 to about 4.7.
    Type: Grant
    Filed: May 21, 1992
    Date of Patent: November 23, 1999
    Assignee: Eastman Kodak Company
    Inventors: Francis John Evans, Arthur Herman Herz
  • Patent number: 5922523
    Abstract: A photographic element contains a filter dye of the Formula (I): ##STR1## wherein R.sup.1 -R.sup.4 each independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heteroaryl group; L.sup.1, L.sup.2 and L.sup.3 each independently represent substituted or unsubstituted methine groups; M.sup.+ represents a proton or an inorganic or organic cation.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: July 13, 1999
    Assignee: Eastman Kodak Company
    Inventors: Margaret Jones Helber, William James Harrison, Elizabeth Ann Gallo
  • Patent number: 5876909
    Abstract: The problem of sensing the presence of radiographic elements using infrared sensors that occurs when a radiographic element contains one or more very thin tabular grain emulsions a total silver coating coverage of less than 30 mg/dm.sup.2 is addressed by placing particles in one or more non-emulsion hydrophilic colloid layers. The particles are removable during rapid access processing, have a mean equivalent circular diameter of from 0.3 to 1.1 .mu.m, and have an index of refraction at the wavelength of the infrared radiation that differs from the index of refraction of the hydrophilic colloid by at least 0.2.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: March 2, 1999
    Assignee: Eastman Kodak Company
    Inventors: Stephen A. Hershey, James C. Bolthouse, Robert E. Dickerson
  • Patent number: 5853967
    Abstract: A mammographic medical diagnostic radiographic element is disclosed having emulsion layers coated on opposite surfaces of a transparent film support. To facilitate rapid processing the emulsion layers are fully forehardened and less than 35 mg/dm.sup.2 of hydrophilic colloid is coated on each major surface. To reduce crossover and hydrophilic colloid, emulsions on the opposite sides of the support are each divided into two layers with the layer coated nearest the support containing a particulate dye capable of being decolorized during processing. Particulate dye and silver halide grains together account for between 30 and 70 percent of the total weight of the emulsion layers. Combined with the use of spectrally sensitized tabular grain emulsions crossover can be reduced to less than 15 percent while processing can be completed in less than 45 seconds. The distribution of hydrophilic colloid and silver halide grains chosen achieves low wet pressure sensitivity.
    Type: Grant
    Filed: May 21, 1998
    Date of Patent: December 29, 1998
    Assignee: Eastman Kodak Company
    Inventor: Robert E. Dickerson
  • Patent number: 5830624
    Abstract: A method for forming a resist pattern by coating a primary photoresist pattern having a small thickness and then coating a secondary photoresist pattern over the primary photoresist pattern. Alternatively, the resist pattern is formed by coating a primary photoresist film, exposing the primary photoresist film to light to define a light-exposed region in the primary photoresist film, coating a secondary photoresist film over the primary photoresist film, exposing the secondary photoresist film to light to define a light-exposed region in the secondary photoresist film, and developing the resulting structure to form primary and secondary resist patterns. The method achieves an improvement in the contrast of light, thereby obtaining a resist pattern having a vertical profile.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: November 3, 1998
    Assignee: Hyundai Electronics Industries Co., Ltd.
    Inventors: Sang Man Bae, Ki Ho Baik
  • Patent number: 5747232
    Abstract: In accordance with this invention, a photographic film especially suited for motion imaging film applications such as motion picture film or television film has on one side of a support material, in order, a process surviving, electrically conductive subbing layer, a photographic emulsion, and a protective overcoat; and on the opposite side a carbon black-containing backing layer, and optionally, a lubricant that overlies the backing layer. The carbon black-containing layer provides antihalation and antistatic protection for the unprocessed film. The conductive subbing layer retains its antistatic properties after processing so that the motion imaging film is protected from the generation of static charge after the carbon black-containing layer is removed during processing. The conductive subbing layer has a resistivity of less than 5.times.10.sup.9 .OMEGA./.quadrature. after film processing.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: May 5, 1998
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Mario D. DeLaura
  • Patent number: 5719015
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide light-sensitive layer and at least one light-insensitive layer, wherein the support comprises a poly(alkylene aromatic dicarboxylate) having a glass transition temperature of from 50.degree. C. to 200.degree. C. and is heat-treated at a temperature of not lower than 40.degree. C., but lower than the glass transition temperature for 0.1 to 1500 hours after molding the polymer into the support and before the coating of the silver halide light-sensitive layer, and said at least one light-insensitive layer contains a dispersion of crystallites of at least one dye represented by general formula (I):D--(X).sub.y (I)wherein D represents a moiety having a chromophoric group; X represents a dissociable proton or a group having a dissociable proton which is bonded to D either directly or through a bivalent bonding group; and y represents an integer of 1 to 7.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: February 17, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Kiyoshi Nakazyo
  • Patent number: 5693370
    Abstract: A method is described to provide a radiographic silver halide material by coating on at least one side of a support, covered with a hydrophobic subbing layer comprising as a latex copolymer vinylidene chloride, methylacrylate and itaconic acid, following hydrophilic layers: at least one gelatinous dye containing layer comprising one or more dyes, at least one silver halide emulsion layer, at least one protective antistress layer, and optionally an afterlayer, characterized in that said hydrophilic layers have a swelling ratio of not more than 200% and in that said hydrophilic layers are coated simultaneously by the slide-hopper coating or by the slide-hopper curtain coating technique.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: December 2, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marc Van den Zegel
  • Patent number: 5688636
    Abstract: A new type of yellow dyes with general formula Q--CO--CO--X is disclosed. They can be used in photographic materials as antihalation dyes, acutance dyes or filter dyes. Preferably they are incorporated in UV sensitive contact materials for pre-press applications.
    Type: Grant
    Filed: May 29, 1996
    Date of Patent: November 18, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventor: Eric Kiekens
  • Patent number: 5665528
    Abstract: A silver halide photographic material comprises at least one silver halide emulsion layer and at least one non-light-sensitive hydrophilic colloidal layer provided on a support. The silver halide emulsion layer or the hydrophilic colloidal layer contains a new dye represented by the formula (I): ##STR1## in which L is a single bond, a divalent aliphatic group, a divalent aromatic group or a combination thereof; A is an acidic nucleus; each of R.sup.1, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently is hydrogen or a substituent group; R.sup.2 is a substituent group; m is an integer of 0 to 4; n is 0 or 1; and X is an electron attractive group having a Hammett's substituent constant (.sigma..sub.m) of 0.3 to 1.5.
    Type: Grant
    Filed: August 9, 1995
    Date of Patent: September 9, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koji Wariishi, Keisuke Matsumoto, Keiichi Suzuki
  • Patent number: 5635333
    Abstract: Reduction of reflection from an integrated circuit substrate during exposure of a photoresist layer on a surface such as an integrated circuit wafer is minimized by incorporating an antireflective coating between the photoresist layer and the integrated circuit substrate. The antireflective layer, after exposure and development of the photoresist layer, is preferably removed by exposing the non-masked antireflective layer to activating radiation while heating the coating to induce a solubilizing reaction in an antireflective coating and a curing reaction in an overlying photoresist mask. Thereafter, the exposed portions of the antireflective layer are removed by treatment with a suitable developer.
    Type: Grant
    Filed: December 28, 1994
    Date of Patent: June 3, 1997
    Assignees: Shipley Company, L.L.C., Sematech, Inc.
    Inventors: John S. Petersen, Kim R. Dean, Daniel A. Miller
  • Patent number: 5538836
    Abstract: A silver halide color photographic material having an excellent color reproducibility, high sensitivity and excellent graininess.The silver halide color photographic material contains at least one of each blue-sensitive emulsion, green-sensitive emulsion, red-sensitive emulsion layer and hydrophilic colloid layers, in which the hydrophilic colloid layer contains a compound of formula (I) and the silver halide emulsion layer, which gives an interlayer effect to said red-sensitive layer, contains a silver halide emulsion spectrally sensitized with a compound represented by formulae (II) and (III).
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: July 23, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumitaka Ueda, Junji Nishigaki, Tetsuo Nakamura
  • Patent number: 5491058
    Abstract: A film is disclosed for duplicating a silver image in a radiographic film. A single monodispersed fogged direct-positive emulsion layer is employed. To extend exposure latitude the emulsion layer contains micro-crystalline particles of a dye that competes with the fogged direct positive grains of the emulsion layer for absorption of exposing radiation and can be decolorized during photographic processing.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: February 13, 1996
    Assignee: Eastman Kodak Company
    Inventors: Ralph W. Jones, Catherine C. Wideman, Paul W. Twombly
  • Patent number: 5468598
    Abstract: A process for preparing a stable, solid particle dispersion of a substantially water-insoluble compound useful in imaging, comprises the steps of:(a) forming a coarse aqueous slurry of solid particles of said compound and a hydrophobic, water-soluble or water-dispersible polymer in an amount of 0.1 to 100% by weight based on the weight of said compound; and(b) milling said slurry for time sufficient to provide particles of the desired average particle size;wherein the polymer is an uncharged or weakly anionically charged water-soluble or water-dispersible homopolymer or copolymer in which at least 10 mole % of the repeat units contain an uncharged pendant group that terminates in (a) a CH.sub.3 unit, (b) a ring containing at least two contiguous CH.sub.2 units, or (c) an aromatic group.The resulting dispersion has dispersed solid particles of said compound having the desired small particle size and is stable toward particle agglomeration, particle growth and needle growth.
    Type: Grant
    Filed: April 18, 1994
    Date of Patent: November 21, 1995
    Assignee: Eastman Kodak Company
    Inventors: David D. Miller, Mary C. Brick, Mridula Nair
  • Patent number: 5464734
    Abstract: Disclosed is a silver halide photographic material containing a compound of formula (1) or (2): ##STR1## where DYE represents a methine dye residue; G and G.sup.- each represent a substituent for the methine dye residue, and are represented by formulae (3) and (4), respectively; and n represents an integer of from 1 to 6.--T.sup.1 --G.sup.1 NHG.sup.2 (3)--T.sup.1 --G.sup.1 N.sup.- G.sup.2 (4)where T.sup.1 represents a divalent linking group; G.sup.1 represents a carbonyl group, a sulfinyl group, or a sulfonyl group; G.sup.2 represents --CO--T.sup.2 --, --SO--T.sup.2, --SO.sub.2 --T.sup.2, or a cyano group; and T.sup.2 represents a monovalent group. The spectral sensitivity of the material is high, and the material has few residual color after processed.
    Type: Grant
    Filed: June 8, 1994
    Date of Patent: November 7, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Inagaki, Shuzo Suga
  • Patent number: 5445930
    Abstract: A novel silver halide photographic material is provided, comprising a hydrophilic colloidal layer containing at least one dye represented by the following formula (I): ##STR1## wherein Y.sup.1 and Y.sup.2 each represents a chalcogen atom, --CH.dbd.CH--, --N(R.sup.10)--, or --C (R.sup.10)(R.sup.11)--, in which R.sup.10 and R.sup.11 each represents an alkyl group; Z.sup.1 and Z.sup.2 each represents a nonmetallic atom group necessary for forming a benzo condensed or naphtho condensed ring; R.sup.1 and R.sup.2 each represents an alkyl group; the plurality of L groups may be the same or different and each represents a methine group, with the proviso that at least one of the plurality of L groups represents a methine group substituted by --OR.sup.12, --N(R.sup.12)(R.sup.13), --SR.sup.12 or --CH(R.sup.14)(R.sup.15), in which R.sup.12 represents an alkyl or aryl group substituted by an acidic substituent, R.sup.13 represents a hydrogen atom or an alkyl or aryl group substituted by an acidic substituent, and R.sup.
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: August 29, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toru Harada, Itsuo Fujiwara
  • Patent number: 5420003
    Abstract: A photographic element is disclosed comprised of a support and a sequence of superimposed blue, green and red recording silver halide emulsion layer units that produce images of the same hue upon imagewise exposure and photographic development. A first interlayer unit overlies the emulsion layer unit nearest the support and is capable of transmitting to it imagewise exposing radiation this emulsion layer unit is intended to record. A second interlayer unit underlies the emulsion layer unit farthest from the support and is capable of transmitting to the emulsion layer units lying nearer the support imagewise exposing radiation these emulsion layer units are intended to record. The imagewise exposed photographic element is photographically developed and fixed to produce a silver image in each of the emulsion layer units.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: May 30, 1995
    Assignee: Eastman Kodak Company
    Inventors: John Gasper, Gareth B. Evans, Christopher B. Rider, Michael J. Simmons
  • Patent number: 5418119
    Abstract: A photographic element is disclosed comprised of a sequence of superimposed blue, green and red recording silver halide emulsion layer units at least two of which produce images of the same hue upon processing. The photographic element is additionally comprised of, interposed between the two emulsion layer units, an interlayer unit for transmitting to the emulsion layer unit of the two units which is nearer the support, electromagnetic radiation that this emulsion layer unit is intended to record and capable, after processing, of reflecting electromagnetic radiation within at least one wavelength region.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: May 23, 1995
    Assignee: Eastman Kodak Company
    Inventor: Michael J. Simons
  • Patent number: 5401620
    Abstract: A silver halide photographic material for laser exposure comprising at least one silver halide emulsion layer on a support,wherein said support or photographic constituent layers of said material contain an antihalation dye which exhibits a spectral absorption density of 0.4 or more before development with respect to the wavelength corresponding to the laser used and a spectral absorption density of 0.2 or more after development when the fluctuations of the average visual density excluding the support density and emulsion fog density are 0.02 or less.
    Type: Grant
    Filed: March 18, 1993
    Date of Patent: March 28, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masahide Sasai, Naoki Arai
  • Patent number: 5395747
    Abstract: Certain poly(lactic acid) and poly(glycolic acid) polymers or copolymers, and certain carbonates, lactones, lactates, lactylates, lactides, glycolates, glycolylates, and glycolides have been found to stabilize thermal-dye-bleach constructions containing a dye in association with a thermally-generated-bleaching agent. Preferably, the thermally-generated-bleaching agent is a thermal-carbanion-generating agent such as a quaternary ammonium salt of a phenylsulfonylacetic acid or a thermal-nucleophile-generating agent such as an ammonium salt of a phenylsulfonylacetic acid. These materials have been found to be particularly effective when used in acutance and antihalation systems for photothermographic and photographic elements.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: March 7, 1995
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: Randall H. Helland, William D. Ramsden, Roger A. Mader