Sulfur Or Sulfur Compound Containing Patents (Class 430/629)
  • Patent number: 7241562
    Abstract: This invention relates to a color silver halide photographic element comprising gelatin, a support bearing at least one dye image forming unit selected from a dye image forming unit comprising at least one red sensitive silver halide emulsion layer having associated therewith a dye-forming coupler, a dye image forming unit comprising at least one green sensitive silver halide emulsion layer having associated therewith a dye-forming coupler, and a dye image forming unit comprising at least one blue sensitive silver halide emulsion layer having associated therewith a dye-forming coupler; and a polymer represented by Formula 1.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: July 10, 2007
    Assignee: Eastman Kodak Company
    Inventors: Sidney J. Bertucci, David M. Teegarden, David E. Decker, Thomas H. Whitesides, Larry D. Edwards
  • Patent number: 7115359
    Abstract: A photothermographic material having a support provided on at least one side of the support light-sensitive silver halide particles, an organic silver salt and a reducing agent, as well as a leuco dye of a specific structure and a compound of a specific structure.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: October 3, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventors: Yasushi Usagawa, Takeshi Habu
  • Patent number: 6897014
    Abstract: Disclosed is a silver halide photographic light-sensitive material, which comprises at least one polymer compound having a nitrogen-containing aromatic ring having a mercapto group represented by the formula Z—SH wherein Z represents a nitrogen-containing aromatic ring as a partial structure. This silver halide photographic light-sensitive material can stably contain silver halide grains of a high aspect ratio showing high sensitivity and superior planarity, shows superior pressure resistance and can be stably prepared.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: May 24, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Terukazu Yanagi, Makiko Yokoi, Mamoru Sakurazawa, Yoshihisa Tsukada, Seiji Hatano
  • Publication number: 20040043341
    Abstract: A photothermographic material is disclosed, comprising on a support a light-sensitive emulsion containing a light-insensitive organic silver salt and a light-sensitive silver halide, a reducing agent for silver ions and a binder, wherein the photothermographic material further comprises a compound represented by the following formula (A-1) or (B) and a compound represented by the following formula (A-2).
    Type: Application
    Filed: August 13, 2003
    Publication date: March 4, 2004
    Applicant: Konica Corporation
    Inventors: Kiyokazu Morita, Ayumu Nishijima
  • Publication number: 20040018458
    Abstract: The present invention provides a photothermographic material including a support having disposed on one surface of the support, at least one image forming layer containing a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent, a development accelerator and a binder, and at least one protective layer on the identical surface, wherein 50% by mass or more of the binder contained in the image forming layer is a water soluble binder, and the reducing agent is contained in the form of a solid dispersion.
    Type: Application
    Filed: May 15, 2003
    Publication date: January 29, 2004
    Inventor: Hajime Nakagawa
  • Patent number: 6620577
    Abstract: Photothermographic imaging materials having increased photospeed are provided by certain selenium chemical sensitizers that are added during the formulation of a photothermographic emulsion. These selenium chemical sensitizers can be used alone or in combination with other sulfur, tellurium, or gold chemical sensitizers as well as with oxidatively decomposed sulfur-containing compounds.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: September 16, 2003
    Assignee: Eastman Kodak Company
    Inventors: Doreen C. Lynch, Andrea L. Opatz, Henry J. Gysling, Sharon M. Simpson
  • Patent number: 6548238
    Abstract: The stability of the dyes which are obtained after processing a color photographic material is improved by the addition of a polyvinylcaprolactam.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: April 15, 2003
    Assignee: AGFA-Gevaert
    Inventors: Beate Weber, Bernd Spachmann, Heinz Wiesen
  • Patent number: 6475715
    Abstract: A photothermographic material is disclosed, comprising on a support an organic silver salt, a light-sensitive silver halide, a reducing agent, and a compound represented by the following formula, 6-aryl-2,4-bis(tribromomethyl)-s-triazine or a 6-heteroaryl-2,4-bis(tribromomethyl)-s-triazine.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: November 5, 2002
    Assignee: Konica Corporation
    Inventors: Katsura Hirai, Kiyoshi Fukusaka
  • Patent number: 6383731
    Abstract: The object of the present invention is to provides a novel polyhalogenomethylsulfonyl compound which can be used for providing a thermally processed image recording material which has a high sensitivity, gives less fog, and has a good stock stability and a good image storage stability of dark and high temperature or light storage. According to the present invention, there is provided a polyhalogenomethylsulfonyl compound represented by the following formula (1), or salts thereof, or hydrates or solvates thereof: wherein Z1 and Z2 each independently represents a halogen atom; A represents a hydrogen atom or a halogen atom; and R1 represents an alkyl group having from 2 to 12 carbon atoms, which may have one or more substituents, an alkenyl group having from 2 to 12 carbon atoms, which may have one or more substituents, or an alkinyl group having from 2 to 12 carbon atoms, which may have one or more substituents.
    Type: Grant
    Filed: August 20, 2001
    Date of Patent: May 7, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaru Takasaki, Katsuyuki Watanabe, Hisashi Okamura
  • Patent number: 6255045
    Abstract: This invention relates to a photographic element comprising a support, a radiation sensitive silver halide emulsion layer and a water dispersible polymeric disulfonamidophenol that is substantially immobile in the element. The invention provides color photographic elements that exhibit improved stability, color reproduction and robustness in terms of processing variations; particularly variations in red density due to sensitizing dye.
    Type: Grant
    Filed: March 13, 2000
    Date of Patent: July 3, 2001
    Assignee: Eastman Kodak Company
    Inventors: Tienteh Chen, Stephen P. Singer, Ronald E. Leone
  • Patent number: 6171767
    Abstract: 1-Sulfonyl-1H-benzotriazole compounds have been found to be useful as antifoggants and print stabilizers in photothermographic elements. The photothermographic elements may be used in medical imaging films or as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
    Type: Grant
    Filed: April 28, 1999
    Date of Patent: January 9, 2001
    Assignee: Eastman Kodak Company
    Inventors: Steven H. Kong, Kumars Sakizadeh, Gary E. Labelle, EmmaLee J. Spahl, Paul G. Skoug
  • Patent number: 6165701
    Abstract: A base film for photographic films formed from a copolyester comprising 97 to 100 mol % of 2,6-naphthalenedicarboxylic acid and 0 to 3 mol % of a dicarboxylic acid other than 2,6-naphthalenedicarboxylic acid and (i) 87 to 99.8 mol % of ethylene glycol, 0.2 to 10 mol % of bis[4-(.omega.-hydroxyalkoxy)phenyl]sulfone and 0 to 3 mol % of a glycol other than ethylene glycol and bis[4-(.omega.-hydroxyalkoxy)phenyl]sulfone or (ii) 97 to 100 mol % of ethylene glycol, 0 to 3 mol % of a diol other than ethylene glycol and 1 to 7 mol % of an oxycarboxylic acid. This base film has an endothermic peak having a peak top temperature, measured by a differential scanning calorimeter, of 120 to 160.degree. C. and showing an endothermic energy of 0.3 mJ/mg or more.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: December 26, 2000
    Assignee: Teijin Limited
    Inventors: Mitsuru Teramoto, Manabu Kimura, Shinya Watanabe, Koji Furuya, Kenji Suzuki
  • Patent number: 6027872
    Abstract: A photothermographic element comprising a photosensitive silver halide, an organic silver salt, a reducing agent, and a compound of formula (I) on a support has a high sensitivity and storage stability.Z.sup.1 --(W.sup.1).sub.m1 --L.sup.1 --S--S--L.sup.2 --(W.sup.2).sub.m2 --Z.sup.2 (I)L.sup.1 and L.sup.2 are divalent aliphatic hydrocarbon groups, W.sup.1 and W.sup.2 are divalent linking groups containing 0, S or N, Z.sup.1 is hydrogen, halogen, aliphatic hydrocarbon, aromatic or heterocyclic group, Z.sup.2 is an aromatic or heterocyclic group, m.sub.1 =0, 1, 2 or 3, and m.sub.2 =0, 1, 2 or 3.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: February 22, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ryo Suzuki, Tsutomu Arai, Katsuyuki Watanabe, Shigeo Hirano, Minoru Sakai
  • Patent number: 5989802
    Abstract: Recording materials and a method of manufacturing said materials by coating hydrophilic colloidal layer compositions on a support by slide-hopper or curtain-coating techniques, followed by drying, said materials comprising a support and one or more light-sensitive and/or heat-sensitive layer(s) having a hydrophilic colloidal coating composition comprising no gelatin(in the case of (photo)thermographic materials) or gelatin in low amounts in order to provide a ratio by weight of gelatin to silver halide expressed as an equivalent amount of silver nitrate in the range from 0.05 to 0.4 (in the case of a light-sensitive silver halide photographic material) and thickening agents composed of synthetic clay and anionic macromolecular polyelectrolytes and wherein said synthetic clay is present in an amount of at least 85% by weight versus a total amount of thickening agents.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: November 23, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Hubert Vandenabeele
  • Patent number: 5932404
    Abstract: The present invention is a silver halide photographic material including at least one layer which contains; a polymer comprising as constituent components thereof a repeating unit having a photographically useful group and at least one repeating unit having an imidazole group; and a compound having at least one functional group which reacts with an imidazole group and at least one other functional group capable of reacting with an imidazole group and a primary amine group, the amount of the compound being sufficient to insure adequate fixation of said polymer.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: August 3, 1999
    Assignee: Eastman Kodak Company
    Inventors: Tienteh Chen, Hwei-ling Yau, Dorothy T. Java
  • Patent number: 5888719
    Abstract: A color photographic material with a support and at least one spectrally sensitised silver halide emulsion layer containing at least one color coupler, which layer contains a polymer with repeat units of the structure I ##STR1## in which R.sub.1, R.sub.2, R.sub.3 are identical or different and mean hydrogen, alkyl or halogen,L means a chemical bond or a linking member andX means a group which reacts with NH.sub.2 --, COOH-- or OH-- groups in an addition or condensation reaction,in dispersed form with an average particle size of <300 nm, is distinguished by improved "dark fading" stability.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: March 30, 1999
    Assignee: AGFA-Gevaert AG
    Inventor: Gunter Helling
  • Patent number: 5871899
    Abstract: A silver halide color photographic element comprising a support, a silver halide emulsion and poly(alkylene oxide)s wherein greater than 50 percent of the poly(alkylene oxide)s have acidic functional end groups with an aqueous pKa.ltoreq.10, or end groups which will react to form acidic functional end groups with an aqueous pKa.ltoreq.10 during development, on both termini; and wherein the poly(alkylene oxide)s have a molecular weight ranging substantially between 1700 and 6000 AMU.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: February 16, 1999
    Assignee: Eastman Kodak Company
    Inventors: David A. Dickinson, George J. Burgmaier, Thomas R. Welter
  • Patent number: 5800977
    Abstract: A hydrophilic colloid is hardened with a vinyl-sulfone hardener in the presence of a borate compound in an amount sufficient to accelerate the rate of hardening. The borate compound is preferably a compound of Formula (I), or a salt, hydrate or precursor thereof:B(L).sub.n (I)wherein each L is independently --OH, --OR, --NH, --NR, or a substituted or unsubstituted alkyl group, substituted or unsubstituted aryl group, or substituted or unsubstituted heterocyclic group; R is a substituted or unsubstituted alkyl group or substituted or unsubstituted aryl group; and, n is 1, 2, or 3, with the proviso that at least one L is --OH. Preferred borate compounds are sodium and potassium borate, and hydrates thereof, and phenyl boronic acid.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: September 1, 1998
    Assignee: Eastman Kodak Company
    Inventors: Jeffrey Facer Taylor, Hwei-Ling Yau, Elmer Charles Flood, Lan Bach Thai, Susan A. Visser
  • Patent number: 5744292
    Abstract: There is disclosed a silver halide photographic light-sensitive material that comprises, in at least one photographic layer constituting the material, a dispersion containing fine grains of a solid dye represented by the following general formula (II), wherein the solid dye has been subjected to heat treatment at 40.degree. C. or higher, and wherein the dispersion further contains a specific water-soluble or water-dispersible polymer-compound that has a hydrophobic group bonding at a terminal of a copolymer of vinyl alcohol and vinyl ester: ##STR1## wherein D represents a residue of a compound having a chromophoric group; X represents a dissociating hydrogen atom, or a group having a dissociating hydrogen atom, which atom or group connects to the D directly or via a divalent connecting group; and y is an integer of 1 to 7. The photographic light-sensitive material prevents any change of viscosity with the lapse of time due to the dye in a state of dispersion solution containing fine grains of the dye.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: April 28, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Yoneyama
  • Patent number: 5698367
    Abstract: Disclosed is a lithographic printing plate having a silver halide emulsion layer and a layer containing physical development nuclei on a support, the improvement wherein a water-soluble polymer having a structural unit represented by the formula (I): ##STR1## wherein R.sup.1 represents H or alkyl; Q represents divalent linking group; R.sup.2 represents divalent linking group or direct bond; and A represents a functional group represented by the formula: --S--C(.dbd.N--R.sup.4)--NH--R.sup.3, --Z--X(.dbd.Y)--(R.sup.5).sub.m or --W--(SH).sub.n where respective substituents are defined in the specification is contained in the layer containing physical development nuclei.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: December 16, 1997
    Assignee: Mitsubishi Paper Mills, Limited
    Inventors: Akira Furukawa, Motozo Yamano, Satoshi Shimonodan
  • Patent number: 5674673
    Abstract: The invention concerns a color negative process wherein a photographic material comprising silver chloride or silver bromide and a DIR or DIAR coupler is processed in the presence of a polyester comprising intralinear thioether atoms.
    Type: Grant
    Filed: August 16, 1995
    Date of Patent: October 7, 1997
    Assignee: Eastman Kodak Company
    Inventors: Jacques Roussilhe, John Martin Higgins
  • Patent number: 5569576
    Abstract: A photographic material is disclosed containing on at least one side of the support at least one light-sensitive silver halide emulsion layer characterised in that the light-sensitive layer and/or at least one non-light sensitive layer in water-permeable relationship with the light-sensitive layer comprises at least one compound having the general formula (I)R[O--CH.sub.2 --CH.sub.2 --S--(LINK.sup.1 --S).sub.x --CH.sub.2 --CH.sub.2 --O--(LINK.sup.2)].sub.y --OR (I)wherein each of LINK.sup.1 and LINK.sup.2 which may be the same or different represents a divalent linking group; R represents H, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or an acyl group; x is 0, 1 or 2, and y varies from 2 to 20.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: October 29, 1996
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jean-Marie Dewanckele, Geert Vercruysse, Ralf B uscher
  • Patent number: 5529892
    Abstract: Light-sensitive silver halide photographic element comprising a support bearing at least a light-sensitive silver halide emulsion layer and at least a protective layer being further away from the support than every silver halide emulsion layer, said protective layer containing a gelatin having a viscosity lower than 20 milliPascal per seconds in 10 weight % aqueous solution at 40.degree. C., said gelatin being hardened with a carbamoyl pyridinium salt compound having the following formula: ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl group, an aryl group or an aralkyl group, or R.sub.1 and R.sub.2, together, constitute the atoms required to form a heterocyclic ring with the nitrogen atom to which they are bonded,R.sub.3 represents hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a carbamoyl group, or a ureido group, andR.sub.4 represents an alkylene group or a single chemical bond between the pyridinium nucleus and the --SO.sub.3 -- group.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: June 25, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Sergio Massirio, Giovanni Giusto, Domenico Marinelli
  • Patent number: 5503967
    Abstract: The present invention relates to a silver halide photographic material comprising a support and at least one silver halide emulsion layer coated thereon, wherein said silver halide emulsion layer comprises from 5 to 15% by weight of a water-soluble, electrically conductive copolymer (1) containing carboxylic groups and sulfonic groups and wherein a hydrophilic colloid layer comprising a combination of a fluorinated surfactant (2), a non-ionic polyoxyethylene surfactant (3) and an anionic polyoxyethylene surfactant (4) is coated on said at least one silver halide emulsion layer.
    Type: Grant
    Filed: August 17, 1995
    Date of Patent: April 2, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Fulvio Furlan, Renzo Torterolo
  • Patent number: 5478715
    Abstract: A silver halide photographic material comprising a support and a silver halide emulsion layer provided thereon. The silver halide emulsion is prepared by nuclear formation, crystal growth and chemical sensitization. All or a part of the nuclear formation or the crystal growth is conducted in the presence of a hexa-coordinated cyano-complex to introduce the complex into crystal lattice of the silver halide. The density of the hexa-coordinated cyano-complex contained in surface parts of silver halide grains is in the range of 10.sup.-4 to 10.sup.-2 mol per 1 mol of silver. The surface parts of silver halide grains has a thickness of not more than 20.ANG. from the surfaces of the grains. The chemical sensitization is conducted using a gold sensitizer. The silver halide emulsion is prepared using a synthetic polymer as a protective colloid in place of gelatin. In the cases in which gelatin is used, it is present in an amount of not more than 10 g per 1 mol of silver.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: December 26, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomoyuki Ohzeki, Shinji Ikari
  • Patent number: 5420004
    Abstract: An internal latent image type positive silver halide emulsion has improved sensitivity reduction in low illuminance exposures. A color diffusion transfer light-sensitive material incorporates the emulsion and has reduced sensitivity reduction. The internal latent image type positive silver halide emulsion is prepared using a polymer having a repetitive unit derived from an ethylenically unsaturated monomer having at least one thioether structure on a side chain as a deflocculating agent to form silver halide grains and subjecting the grain surfaces to a chemical sensitization in the presence of a polymer having a repetitive unit represented by the following Formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a substituted or unsubstituted alkyl group and Q represents a group selected from the group consisting of groups represented by the following Formula (1) to Formula (4): ##STR2## wherein q represents an integer of 2 to 4; ##STR3## wherein R.sup.2 and R.sup.
    Type: Grant
    Filed: August 10, 1993
    Date of Patent: May 30, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Munehisa Fujita, Toru Sano
  • Patent number: 5356770
    Abstract: Color photographic materials and methods employ a substrate bearing a silver chloride emulsion. The silver chloride emulsion includes a diamino disulfide and a sulfinate. The diamino disulfide and the sulfinate are included in a weight ratio of from about 1:1 to about 1:20, and provide improved storage stability and reduced high temperature sensitivity during exposure.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: October 18, 1994
    Assignee: Eastman Kodak Compamn
    Inventors: Roger Lok, Jess B. Hendricks, III
  • Patent number: 5275931
    Abstract: A silver halide light-sensitive material containing at least silver halide grains, a dispersion medium, an antifoggant, and a hardening agent, wherein said antifoggant is an antifoggant having a reactive substituent capable of reacting with a functional group of the dispersion medium to form a covalent bond after adsorption on the silver halide grains and/or an antifoggant previously covalently bonded to the dispersion medium. The antifoggant is immobilized in a light-sensitive material while exerting its antifogging activity and is not therefore dissolved into a developing solution.
    Type: Grant
    Filed: November 24, 1992
    Date of Patent: January 4, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsuo Saitou, Hisashi Okamura, Tadashi Ikeda
  • Patent number: 5234807
    Abstract: The polymerization and copolymerization of photographically useful vinyl monomers can be effected by dissolving such monomers in an isotropic oil-in-water microemulsion or in an isotropic water-in-oil microemulsion, each comprising monomers or comonomers, surfactants and/or cosurfactants, water, and optionally electrolytes. The microemulsion may be characterized as transparent or nearly transparent to the eye at 1% (w/w) or greater monomer, ultrafine in particle (droplet) size (typically in the range of 30 to 900 .ANG. in diameter), and spontaneously formed upon combining all the components with moderate stirring. The polymerization process is subsequently initiated with free radical initiators or with ultraviolet light. The components are chosen so that photographically useful polymers or photographically useful latexes are obtained, and said polymers or latexes may be coated in a photographic element.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: August 10, 1993
    Assignee: Eastman Kodak Company
    Inventors: John Texter, Tienteh Chen, Edward Schofield
  • Patent number: 5213959
    Abstract: A silver halide light-sensitive material containing at least silver halide grains, a dispersion medium, an antifoggant, and a hardening agent, wherein said antifoggant is an antifoggant having a reactive substituent capable of reacting with a functional group of the dispersion medium to form a covalent bond after adsorption on the silver halide grains and/or an antifoggant previously covalently bonded to the dispersion medium. The antifoggant is immobilized in a light-sensitive material while exerting its antifogging activity and is not therefore dissolved into a developing solution.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: May 25, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsuo Saitou, Hisashi Okamura, Tadashi Ikeda
  • Patent number: 5212056
    Abstract: A multilayer silver halide color photographic element comprising at least one blue-sensitive silver halide emulsion layer comprising a blue spectral sensitizing dye and a supersensitizing amount of a disulfide compound of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, equal or different, each represents a hydrogen atom or a lower alkyl group, R.sub.5 represents a hydrogen atom, a formyl group or an acetyl group, R.sub.6 and R.sub.7, equal or different, each represents a hydrogen atom or a lower alkyl group, or R.sub.6 and R.sub.7 represent the elements needed to complete an unsaturated cyclic nucleus.The combination provides a blue-sensitive silver halide emulsion layer having high sensitivity, low fog and good resistance against fading of the latent image.
    Type: Grant
    Filed: March 25, 1992
    Date of Patent: May 18, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Walter Beltramini, Ivano Delprato
  • Patent number: 5041367
    Abstract: A photographic recording material is provided which has enhanced photographic properties, such as sharpness values without substantial decrease in photographic speed.
    Type: Grant
    Filed: March 5, 1990
    Date of Patent: August 20, 1991
    Assignee: Eastman Kodak Company
    Inventor: Henry J. Sniadoch
  • Patent number: 5035975
    Abstract: Disclosed is a light-sensitive material comprising a support and a light-sensitive layer provided thereon which contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound. The silver halide and the polymerizable compound are contained in oily droplets. The oily droplets are a core material of microcupsules. The oily droplet has a film therearound which is composed of a reaction product of a water-soluble polymer having a sulfinyl group with an ethylenically unsaturated polymerizable compound.
    Type: Grant
    Filed: February 16, 1990
    Date of Patent: July 30, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ryuichi Takahashi, Taku Nakamura
  • Patent number: 5019494
    Abstract: A silver halide photographic material which comprises a support having thereon at least one hydrophilic colloid layer, wherein the hydrophilic colloid layer comprises (a) a binder comprising a dextran having a molecular weight of at least 100,000 and (b) an ionic polymer.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: May 28, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ichizo Toya, Ryoichi Nemori
  • Patent number: 4977059
    Abstract: A method for forming microcapsules by enwrapping an oily core material in a formaldehyde condensation product formed in situ wherein a dispersant is used of the formula (I): ##STR1## where: M is an alkali metal cation or a quaternary ammonium group,L is --(CH.sub.2).sub.p, --COO(CH.sub.2).sub.p, --C.sub.6 H.sub.4 -- or a direct bond;R, R.sup.2 and R.sup.6 are the same or different and represent a hydrogen atom or a methyl group;R.sup.1 is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or --SO.sub.3 M where M is defined as above; R.sup.3 is --COOR.sup.4, --CONHR.sup.4, --CO--R.sup.4, a pyridinyl group or quaternary salt thereof, --COOCH.sub.2 CH.sub.2 N(CH.sub.3).sub.2 --, --COOCH.sub.2 CH.sub.2 N.sub.4 (CH.sub.3).sub.3 Cl-- group having 1 to 12 carbon atoms, an aralkyl group, an aryl group, or --(CH.sub.2).sub.m --OOC--CR.sup.2 CH.sub.2, --(OCH.sub.2 CHhd 2).sub.m COO--CR.sup.2 CH.sub.2 or --(CH.sub.2).sub.m NHCO--CR.sup.2 CH.sub.2 ;x is about 0.4 to 0.8;y is about 0.2 to 0.6;z is about 0 to 0.
    Type: Grant
    Filed: May 12, 1989
    Date of Patent: December 11, 1990
    Assignee: The Mead Corporation
    Inventors: Rong-Chang Liang, William H. Simpson, Katherine A. Gyure, Kenneth P. Carpenter
  • Patent number: 4962016
    Abstract: A silver halide photographic light-sensitive material which has an excellent gradation and an excellent pressure resistance. The photographic material comprising a support and, provided thereon, a photographic component layer including a silver halide emulsion layer in which the sewlling degree of said photographic component layer is not higher than 150 and said silver halide emulsion layer is added with elementary sulfur.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: October 9, 1990
    Assignee: Konica Corporation
    Inventors: Shigeo Chino, Mitsuhiro Okumura
  • Patent number: 4939077
    Abstract: Photographic silver halide recording material comprising a support, at least one light-sensitive silver halide emulsion layer, a protective layer and optionally other layers, at least one layer which is arranged closer to the support than the protective layer containing a compound which in the form of the free acid corresponds to the following formula ##STR1## wherein R.sub.1 denotes alkylene, arylene, aralkylene or cycloalkylene,L denotes the residue of a polyester diol having an average molecular weight of from 500 to 20,000,m denotes 0 to 1,n denotes 0 to 30, preferably 0 to 10 and m+n.gtoreq.1,is distinguished by improved properties, in particular an improved maximum density.
    Type: Grant
    Filed: August 25, 1989
    Date of Patent: July 3, 1990
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Gunter Helling, Wolfgang Himmelmann
  • Patent number: 4916047
    Abstract: A silver halide light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, and containing a compound containing a repeating unit, said compound containing a repeating unit being connected at the repeating unit to a compound represented by formula (I) at the position of the PWR or Time moiety:PWR--Time.sub.t PUG (I)wherein PWR represents a moiety capable of releasing (Time.sub.t PUG upon reduction, and PUG represents a group which can fulfil a photographically useful function after the release; Time represents a moiety capable of releasing PUG through a reaction subsequent to the release from PWR in the form of --Time.sub.t PUG; and t represents 0 or 1.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: April 10, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Koya, Junichi Yamanouchi, Masaharu Toriuchi, Yoshisada Nakamura
  • Patent number: 4877720
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, at least one layer of the silver halide photographic material comprising at least one compound represented by formula (I):PWR--Time--.sub.t --POL (I)wherein PWR represents a group capable of releasing (Time--.sub.t POL upon reduction; Time represents a divalent organic group capable of releasing POL via a subsequent reaction after (Time--.sub.t POL is released from PWR; t is 0 or 1; and POL represents a polymer group.The compound represented by formula (I) is a useful functional polymer whose properties are drastically changed upon reduction and reveal photographically useful function.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: October 31, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Shigeru Ohno, Sumito Yamada
  • Patent number: 4727008
    Abstract: A dye-forming electrically activatable recording (EAR) element which is capable of forming at least two dye images comprises an electrically conductive support bearing on one side of the support at least a dye-forming layer (A) responsive to negative polarity charge exposure and at least one dye-forming layer (B) responsive to positive polarity charge exposure and, optionally, other dye-forming layers. A multicolor dye image can be formed in the dye-forming electrically activatable recording element by multistep imagewise charge exposure in which the exposure steps are reversed in electrical polarity at each step. The reversal of polarity of exposure at differing charge density levels enables formation of a dye image in at least one layer without formation of a dye image in another layer. Processing of the exposed dye-forming electrically activatable recording element is carried out by thermal processing or by means of processing solutions or baths.
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: February 23, 1988
    Assignee: Eastman Kodak Company
    Inventors: Mark Lelental, Scott A. Brownstein
  • Patent number: 4716099
    Abstract: Liquid petroleum sulfonates are useful alone or in combination with less lipophilic anionic surfactants in the preparation of dispersions of water-insoluble photographic addenda, such as couplers and ultraviolet absorbers, in hydrophilic colloid compositions. Such dispersions are useful in photographic elements. Crystallization of the addenda is inhibited and, for some addenda, other advantages are obtained.
    Type: Grant
    Filed: June 2, 1986
    Date of Patent: December 29, 1987
    Assignee: Eastman Kodak Company
    Inventor: Michael J. Simons
  • Patent number: 4684608
    Abstract: A latex composition having utility in articles such as photographic elements is disclosed. The composition comprises loadable polymer particles having recurring units a, b and c wherein:component a is 10 to 100 weight percent of a tetrahydrofurfuryl monomer having the structure: ##STR1## in which R.sub.1 represents O or NH; andR.sub.2 represents H or lower alkyl of about 1 to 6 carbon atoms;component b is 0 to 20 weight percent of a hydrophilic monomer andcomponent c is 0 to 90 weight percent of a hydrophobic monomer.
    Type: Grant
    Filed: November 21, 1985
    Date of Patent: August 4, 1987
    Assignee: Eastman Kodak Company
    Inventors: James W. Brown, Tsang J. Chen, Michael A. Schen
  • Patent number: 4624903
    Abstract: Liquid petroleum sulfonates are useful alone or in combination with less lipophilic anionic surfactants in the preparation of dispersions of water-insoluble photographic addenda, such as couplers and ultraviolet absorbers, in hydrophilic colloid compositions. Such dispersions are useful in photographic elements. Crystallization of the addenda is inhibited and, for some addenda, other advantages are obtained.
    Type: Grant
    Filed: November 21, 1985
    Date of Patent: November 25, 1986
    Assignee: Eastman Kodak Company
    Inventor: Michael J. Simons
  • Patent number: 4600687
    Abstract: A photographic light-sensitive material having at least one layer containing a polymer having a repeating unit of the formula (I): ##STR1## wherein A is a monomer unit prepared by copolymerizing copolymerizable ethylenically unsaturated monomers; R.sub.1 is hydrogen or a lower alkyl group having 1 to 6 carbon atoms; Q is ##STR2## (wherein R.sub.1 is the same as defined above) or an arylene group having 6 to 10 carbon atoms; L is a divalent group having 3 to 15 carbon atoms and containing at least one linking group selected from the members consisting of ##STR3## (wherein R.sub.1 is the same as defined above) or a divalent group having 1 to 12 carbon atoms and containing at least one linking group selected from the members consisting of ##STR4## (wherein R.sub.1 is the same as defined above); R.sub.2 is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.
    Type: Grant
    Filed: April 22, 1985
    Date of Patent: July 15, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Mitsunori Hirano, Masasi Ogawa, Kunio Ishigaki
  • Patent number: 4594400
    Abstract: Thioxanthone carboxylic acid esters, thioesters and amides with reactive functional groups of the formula ##STR1## in which X, Y, Z, n and Q are as defined in the patent claim and Q is, for example, --OCH.dbd.CH.sub.2, --OCH.sub.2 CH.dbd.CH.sub.2, --SCH.sub.2 CH.dbd.CH.sub.2 or --NHCH.sub.2 CH.dbd.CH.sub.2 (n=1), --OH, --SH, --NH.sub.2, --COOH, --COCl or --OCO--C(R").dbd.CH.sub.2, in which R" is methyl or hydrogen (n=2), are suitable for the preparation of polymers with thioxanthone radicals in side chains. The compounds (I) and also the polymers which can be prepared therefrom can be employed as sensitizers for photocrosslinkable polymers or as initiators, if desired in a mixture with amines, for the photopolymerization of ethylenically unsaturated compounds or for the photochemical crosslinking of polyolefines.
    Type: Grant
    Filed: September 19, 1984
    Date of Patent: June 10, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Vratislav Kvita, Hans Zweifel, Martin Roth, Louis Felder
  • Patent number: 4590151
    Abstract: Reticulation caused by swelling with processing solutions in photographic elements is reduced for elements containing at least two contiguous gelatin-containing layers wherein the uppermost layer has a lateral swell coefficient at least 10% greater than the lower gelatin-containing layer before polymer addition and wherein said uppermost layer comprises an essentially non-diffusible vinyl polymer having reactive groups which crosslink by reaction with primary amine or secondary amine groups on gelatin or a water-soluble, non-diffusible amine containing vinyl polymer and a hardener for gelatin. These elements are particularly useful in photographic products.
    Type: Grant
    Filed: November 29, 1982
    Date of Patent: May 20, 1986
    Assignee: Eastman Kodak Company
    Inventors: Thomas C. Arter, Ignazio S. Ponticello
  • Patent number: 4540658
    Abstract: A silver halide color photographic product with dye images having improved fastness to light is disclosed. The product has at least one dye image forming layer on a support and further includes at least one of the compounds of formula (I) or (II) in said dye image forming layer and/or an adjoining or an adjacent layer: ##STR1## wherein R is an alkyl group, an aryl group or a heterocyclic group; X is an alkylene group; and Y is an alkylene or arylene group; and ##STR2## wherein R.sub.1 is a hydrogen atom, an alkyl group or an aryl group; R.sub.2 and R.sub.3 are each an alkyl group; Y.sub.1 is an alkylene or arylene group; Z is an oxygen atom, a sulfur atom, a sulfonyl group, a carbonyl group or an alkylene group; and n is an integer of 1 to 20.
    Type: Grant
    Filed: June 24, 1983
    Date of Patent: September 10, 1985
    Assignee: Konishiroku Photo Industry Co. Ltd.
    Inventors: Masao Sasaki, Kaoru Onodera
  • Patent number: 4511643
    Abstract: A color diffusion transfer photographic element is disclosed. The element provides a transferred dye image in a mordant layer and includes a compound having recurrent units represented by the general formula (I): ##STR1## the substituents within the general formula (I) are defined within the specification. By utilizing the compound the images produced having improved preservability having specific improvements with respect to the elimination of yellow stains which are formed in white areas of the images after storage for a long period of time. Furthermore, the images formed do not deteriorate at high temperatures and the use of the compound does not decrease the D.sub.max in print images.
    Type: Grant
    Filed: September 22, 1983
    Date of Patent: April 16, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Ichizo Toya
  • Patent number: 4436811
    Abstract: Compounds of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, alkyl or alkoxy and R.sub.2 additionally represents a radical of the formula ##STR2## in which R.sub.1 and R.sub.3 have the abovementioned meanings, R.sub.4 is unsubstituted or substituted phenoxy or unsubstituted or substituted amino and R.sub.5 is hydrogen or a radical of the formula ##STR3## in which R.sub.1, R.sub.3 and R.sub.4 have the abovementioned meanings and R.sub.2 ' has the same meanings as R.sub.1 and R.sub.3 are suitable development accelerators in the development of exposed, photographic materials containing silver halide.They accelerate the reduction of the exposed silver salt to silver and increase the speed of photographic material.
    Type: Grant
    Filed: June 22, 1982
    Date of Patent: March 13, 1984
    Assignee: Ciba-Geigy AG
    Inventors: Mario Fryberg, Viktor Weiss
  • Patent number: 4400463
    Abstract: Radiation-sensitive photographic emulsions are disclosed comprised of a dispersing medium and silver halide grains the halide content of which is at least 50 mole percent chloride, based on silver. The silver halide grains include tabular grains having a thickness of less than 0.5 micron, a diameter of at least 0.6 micron, and an average aspect ratio greater than 8:1 which account for at least 50 percent of the total projected area of the silver halide grains. The tabular grains have two opposed substantially parallel major crystal faces lying in {111} crystal planes and exhibiting at least one of the following features: (1) at least one peripheral edge lying parallel to a <211> crystallographic vector lying in the plane of one of the major faces and (2) bromide and/or iodide incorporated in a central grain region. The tabular grains are formed in the presence of an aminoazaindene and a peptizer having a thioether linkage.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: August 23, 1983
    Assignee: Eastman Kodak Company
    Inventor: Joe E. Maskasky