Coating Process Making Radiation Sensitive Element Patents (Class 430/935)
  • Patent number: 6376165
    Abstract: A method of preparing a photothermographic material, comprising a support having thereon at least a layer, the method comprising the steps of: coating a coating solution containing an organic silver salt, a photosensitive silver halide and a reducing agent on the support to form a coated material and subjecting the coated material to a thermal treatment at a temperature of 40 to 120° C. under a tension of 0.01 to 30 kg/cm2.
    Type: Grant
    Filed: September 15, 2000
    Date of Patent: April 23, 2002
    Assignee: Konica Corporation
    Inventors: Hidetoshi Ezure, Kenji Ohnuma, Yuji Hosoi
  • Publication number: 20020031724
    Abstract: A direct-to-plate method for obtaining a high quality lithographic printing plate is disclosed. The method comprises the application of a continuous layer of a radiation sensitive solution onto a lithographic substrate by means of an ink-jet printhead. Hereby waste of coating solution and contamination of the environment are avoided.
    Type: Application
    Filed: July 24, 2001
    Publication date: March 14, 2002
    Inventors: Eric Verschueren, Luc Leenders, Joan Vermeersch, Ludo Joly
  • Patent number: 6319317
    Abstract: A spreading state of an outline of the outer periphery of a coating solution is detected by a detecting sensor, and the rotation speed or the like of a wafer as a substrate is controlled so that a spreading speed of the outline becomes not more than a predetermined speed with no danger of producing a scratchpad. Alternatively, the width in the radius direction of a scratchpad is measured, and the rotation speed or the like of the wafer is controlled so that the width in the radius direction becomes not more than a predetermined value. Thereby, occurrence of the scratchpad is prevented or the degree thereof is decreased, thereby avoiding uncoating of the coating solution on the substrate and reducing the amount of the coating solution used.
    Type: Grant
    Filed: April 18, 2000
    Date of Patent: November 20, 2001
    Assignee: Tokyo Electron Limited
    Inventor: Hideyuki Takamori
  • Publication number: 20010041311
    Abstract: A coating and developing apparatus for coating a substrate with a plurality of color resists and for developing it after exposure, comprises: a scrubbing unit for scrubbing the substrate; a coating unit having a plurality of resist discharge nozzles for respectively discharging a plurality of color resists on the scrubbed substrate; and a developing unit for developing the substrate coated with the color resists after exposure. Accordingly, reduction in size of apparatus and space savings can be achieved, and manufacturing cost can also be reduced.
    Type: Application
    Filed: June 7, 2001
    Publication date: November 15, 2001
    Inventors: Shinichiro Araki, Shinko Matsumoto, Noriyuki Anai
  • Patent number: 6273984
    Abstract: A method of curl control for lamination of a polymer sheet to each side of a core material comprising providing a bottom polymer sheet, bringing said bottom sheet into contact with a heat source, providing said core material, bringing said core material into contact with said bottom polymer sheet while simultaneously applying a binder between said bottom sheet and said core to form a laminate, providing a top polymer sheet, bringing said top sheet into contact with said laminate and while simultaneously applying a binder between said top sheet and said laminate to form a composite wherein each sheet to core modulus ratio is greater than 1 and wherein said composite has a desired curl.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: August 14, 2001
    Assignee: Eastman Kodak Company
    Inventors: Robert P. Bourdelais, Thaddeus S. Gula, Peter T. Aylward
  • Patent number: 6245500
    Abstract: A method of cooling a photographic coating composition in a sol state is disclosed. The composition that includes photographic emulsion, an emulsified material or gelatin solution, or comprising combinations thereof is continuously cooled by employing heat exchanger, and after being transformed into a gel state, the resulting product is placed into a storage vessel.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: June 12, 2001
    Assignee: Konica Corporation
    Inventor: Yasuo Nishi
  • Patent number: 6235458
    Abstract: A method for heat-treating a photographic film while conveying, which comprises the steps of: passing the photographic film through from 2 to 100 rolls disposed so that gaps between the adjacent rolls are within the range of from 0.1 cm to 50 cm; and heat-treating the photographic film during the conveyance, wherein the photographic film comprises a support having coated thereon at least one layer. Also disclosed is a method for heat-treating a photographic film, which comprises the steps of: heat-treating a photographic film; and winding the heat-treated film, wherein the heat-treated film is cooled before the winding, the cooling rate in the temperature range from the glass transition temperature (Tg) of the film +40° C. to the Tg −10° C. being at 0.01° C./second to 10° C./second. Further disclosed is a photographic film having a width direction and a lengthwise direction, and having a thickness unevenness along the film's width direction is from 2 &mgr;m to 300 &mgr;m.
    Type: Grant
    Filed: July 29, 1998
    Date of Patent: May 22, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kiyokazu Hashimoto
  • Patent number: 6228570
    Abstract: An photographic element comprising: a support with two sides; at least one sensitized layer on one side of the support; at least one transparent magnetic layer on another side of the support, opposite the sensitized layer; and a lubricant layer deposited on the transparent magnetic layer,wherein the lubricant layer is a fluorinated polymer selected from the group consisting of fluoropolymer resins, polytetrafluoroethylene, fluorinated ethylene polymer, fluorinated ethylene propylene, perfluoroalkoxy copolymer resins, and amorphous fluoropolymers.
    Type: Grant
    Filed: December 1, 1999
    Date of Patent: May 8, 2001
    Assignee: Eastman Kodak Company
    Inventors: Dennis R. Freeman, Christine J. Landry-Coltrain
  • Patent number: 6225040
    Abstract: There is provided a method for preparing a biaxially oriented polyester sheet or web, with improved antistatic properties, comprising the steps of (i) stretching said polyester sheet or web first in one direction and second in a direction perpendicular thereto (ii) coating said hydrophobic polyester sheet or web, either before stretching or between said first and second stretching operation, on one or both sides, with a transparent antistatic primer layer, wherein the coating composition of said transparent antistatic primer layer comprises (1) a dispersion of a polythiophene with conjugated polymer backbone and a polymeric polyanion compound and (2) a latex polymer having hydrophilic functionality. The primer layer is coated from an aqueous composition and does not show a substantial change in resistivity depending on relative humidity or wet processing.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: May 1, 2001
    Assignee: Agfa-Gevaert
    Inventors: Bavo Muys, Dirk Quintens, Jozef Boeykens, Etienne Van Thillo, Geert Defieuw
  • Patent number: 6190828
    Abstract: A method for making a lithographic printing master is disclosed. The method comprises a step of providing a hydrophilic cylindrical surface, e.g. an aluminium plate mounted on the plate cylinder of a printing press, with an image recording composition by transfer from a donor material. The donor material comprises a support and a transfer layer which comprises hydrophobic thermoplastic polymer particles dispersed in a hydrophilic binder and a compound capable of converting light to heat. The transfer is obtained by friction between the donor layer and the cylindrical surface and/or by moistening the cylindrical surface with an aqueous liquid. The method is especially suited for on-press coating and on-press imaging in computer-to-press procedures.
    Type: Grant
    Filed: April 19, 2000
    Date of Patent: February 20, 2001
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Eric Verschueren, Joan Vermeersch
  • Patent number: 6187517
    Abstract: The present invention provides a gelatin-based aqueous-coatable overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight gelatin and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat) having an average diameter of 10 to 500 nm. A proteolytic enzyme is applied to the clement in reactive association with the overcoat layer. A photographic element according to one embodiment of the invention can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: February 13, 2001
    Assignee: Eastman Kodak Company
    Inventors: Thomas H. Whitesides, Hwei-Ling Yau, Amy Jasek
  • Patent number: 6180325
    Abstract: A method for exposing photo-sensitive printing plates comprises applying a patterned coating to the printing plate to form a mask. The coating may be sprayed onto the printing plate and patterned by laser ablation. The method avoids the need to stock printing plates with integral masking layers. In preferred implementations the printing plate is exposed to actinic radiation without dismounting it from the apparatus in which the coating is applied. This minimizes the likelihood that the coating could be damaged in handling. The coating may be a thin sprayed on layer of carbon in a suitable binder.
    Type: Grant
    Filed: June 23, 1999
    Date of Patent: January 30, 2001
    Assignee: Creo SRL
    Inventor: Daniel Gelbart
  • Patent number: 6165699
    Abstract: A photographic polyester support having an adjacent subbing layer which comprises a polymer or copolymer of glycidyl acrylate and/or glycidyl methacrylate followed by a gelatin layer and which is annealed. Such a composite has been found to provide improved adhesion properties without chemical degradation of the subbing layer under annealing conditions.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: December 26, 2000
    Assignee: Eastman Kodak Company
    Inventors: Charles L. Bauer, Cathy A. Fleischer
  • Patent number: 6150075
    Abstract: A process of transferring a photographic image to a stone surface, such as slate tile, provides for the use of a gelatin subbing solution in a step of preparing the stone surface for the receipt of the image. Additional steps include application of polyacrylic coating and concrete staining material to the surface prior to exposing the surface to the gelatin subbing solution, and using conventional photo developing compounds for permanently affixing a transferred image to the stone surface. Mixing gelatin, chrome alum and water makes the gelatin subbing solution. For an "antique" look, the photograph can be exposed to a sulfide sepia toner prior to transfer of the image to the stone surface.
    Type: Grant
    Filed: November 30, 1998
    Date of Patent: November 21, 2000
    Inventor: Ralph S. Klafert
  • Patent number: 6146808
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer, characterized in that said element before and/or after being coated with said image-receiving layer and before being coated with another layer is wetted with a fluidum with a conductivity of at least 1 .mu.S/cm at 25.degree. C. and then the wetted element is brought in contact with an earthed discharging means and dried before coating the following layer.
    Type: Grant
    Filed: November 5, 1999
    Date of Patent: November 14, 2000
    Assignee: AGFA-Gevaert, N.V.
    Inventor: Marcus Jonkheere
  • Patent number: 6146807
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer in water permeable relationship with said image receiving layer, characterized in that said aluminum support, provided with said image receiving layer, is kept at a relative humidity of at least 45% in an area of a machine, the said area being ahead of a coating head used for coating said photosensitive layer.
    Type: Grant
    Filed: November 5, 1999
    Date of Patent: November 14, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marcus Jonkheere
  • Patent number: 6127094
    Abstract: In accordance with the present invention, there are provided water-developable photopolymerizable compositions useful for the preparation of printing plates. Printing plates prepared employing invention compositions have excellent form stability, thereby enabling such plates to be handled without the need for excessive care. Once photopolymerized, printing plates of the invention have excellent physical properties, enabling their use in many very demanding applications, e.g., flexographic printing. Such applications require the photopolymerized resin to have excellent water resistance (so that exposure to water-based inks does not significantly alter resin properties), as well as high durability (so that the physical contacting associated with the printing process does not significantly degrade resin properties).
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: October 3, 2000
    Assignee: Napp Systems Inc.
    Inventors: Mark W. Victor, Allyson R. Maurer, Richard P. Homick
  • Patent number: 6127090
    Abstract: A process for producing a photosensitive resin printing plate comprising a step of forming a liquid photosensitive resin into a layer by applying the same to a substrate with a bucket, wherein a forming speed variation point for said layer is set at a position which is 30 to 80% of the forming distance of said layer, and wherein the liquid photosensitive resin is formed into a layer by successively reducing the forming speed thereafter.
    Type: Grant
    Filed: September 11, 1998
    Date of Patent: October 3, 2000
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Shinichi Kawatsuji, Mitsuhiro Watanabe
  • Patent number: 6071681
    Abstract: A method for producing a silver halide photographic light-sensitive material is disclosed, which comprises a support having thereon a silver halide emulsion layer and optionally another hydrophilic colloid layer. The method comprises the steps of (1) coating a coating solution of the silver halide emulsion layer or that of the hydrophilic colloid layer on the support, and (2) drying the coated layer, and the coating solution of the silver halide emulsion layer or that of the hydrophilic colloid layer comprises gelatin and a sugaralcohol.
    Type: Grant
    Filed: May 18, 1998
    Date of Patent: June 6, 2000
    Assignee: Konica Corporation
    Inventors: Kiyokazu Morita, Hideki Hoshino, Shinichi Suzuki
  • Patent number: 6071682
    Abstract: The present invention is photographic film base which includes a polymeric support having a first side and a second side and a glass transition temperature (Tg.sub.s). A polymeric layer is superposed on the first side of the polymeric support, the polymer layer having a glass transition temperature Tg.sub.L which is greater than the glass transition temperature of the support Tg.sub.s. The polymeric layer has a thickness of at least 2.5 percent of the thickness of the support.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: June 6, 2000
    Assignee: Eastman Kodak Company
    Inventors: Jehuda Greener, Paul D. Yacobucci, Beverly A. Contestable, Catherine A. Falkner
  • Patent number: 6048666
    Abstract: A radiation sensitive resin composition comprising an alkali-soluble resin such as a polyvinyl phenol or a phenol resin other than a polyvinyl phenol having a weight average molecular weight of 2,000 or higher, a cross-linking agent such as an amino resin having two or more active methylol groups in a molecule, a particulate rubbery material comprising a cross-linked polymer chemically modified with an epoxy compound, a liquid rubbery material having a number average molecular weight between 1,000 and 10,000 and a glass transition temperature of -20.degree. C. or lower, and a radiation polymerization initiator. The composition is best suited for use as a material for preparing an insulating layer interposed between two layers of conductive wiring that are arranged in an overlaying stack.
    Type: Grant
    Filed: June 3, 1998
    Date of Patent: April 11, 2000
    Assignee: JSR Corporation
    Inventors: Kazuaki Niwa, Masako Suzuki, Toshiyuki Ota, Hozumi Sato, Hideki Chiba
  • Patent number: 6043009
    Abstract: The invention relates to a photographic element comprising a paper base, at least one photosensitive silver halide layer, and a layer of microvoided biaxially oriented polyolefin sheet between said paper base and said silver halide layer.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: March 28, 2000
    Assignee: Eastman Kodak Company
    Inventors: Robert P. Bourdelais, Douglas N. Haydock, Thaddeus S. Gula, Peter T. Aylward
  • Patent number: 6040109
    Abstract: According to the present invention there is provided a method for preparing an imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer comprising unhardened gelatin, characterized in that said aluminum support when being coated with said photosensitive layer is in contact with a guiding roller, heated at a temperature between 35 and 70.degree. C.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: March 21, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul Coppens, Marcus Jonckheere
  • Patent number: 6037108
    Abstract: A support for an imaging element is described, which support comprises a polyester polymeric film having coated thereon a subbing layer comprising gelatin and a multi-hydric organic compound having at least three hydroxyl groups, which gelatin subbing layer coated support has been subjected to a heat treatment to reduce the core-set curling tendency of the polymeric film. Imaging elements for use in an image-forming process is also described, which elements comprise a gelatin subbing layer coated polyester polymeric film support as described above, and an image-forming layer coated on the subbed support. A method for forming a heat-tempered, gelatin-subbed support for an imaging element is also described, comprising coating a subbing layer comprising gelatin and a multi-hydric organic compound having at least three hydroxyl groups on a polyester polymeric film, and subjected the coated film to heat treatment to reduce the core-set curling tendency of the polymeric film.
    Type: Grant
    Filed: April 27, 1998
    Date of Patent: March 14, 2000
    Assignee: Eastman Kodak Company
    Inventors: Janglin Chen, Richard A. Castle, Yongcai Wang
  • Patent number: 5981159
    Abstract: A photographic element is disclosed comprising a support bearing at least one light sensitive silver halide emulsion layer comprising a dispersion of a dye-forming coupler and a water-insoluble polymer, wherein the polymer has a glass transition temperature of less than 75.degree. C. and is formed from at least 30 wt % monomer units which provide the polymer with functional groups that are hydrogen bond donors. The combination of such relatively low T.sub.g polymers with couplers in photographic elements leads to both decreased pressure sensitivity and improved image-dye light stability, as well as a decreased tendency toward dye smear or thermal induced change. The advantages of the invention are particularly useful for yellow coupler dispersions used in photographic color paper elements on reflective supports, although they will also be useful for motion picture print film and other projection or display films on transparent or diffuse supports.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: November 9, 1999
    Assignee: Eastman Kodak Company
    Inventors: Ralph Bendt Nielsen, David Francis Bates, Brian Thomas
  • Patent number: 5972591
    Abstract: The invention is generally accomplished by providing a photographic element and a process of its formation wherein a gelatin silver halide emulsion is provided with a thickener comprising a copolymer of the structure whereinA comprises about 10 to about 20 parts by weight of said copolymer, andB comprises about 80 to about 90 parts by weight of said copolymer.It is particularly preferred that the copolymer be provided in a hardener layer to minimize the amount of gelatin needed and thus reduce the reaction of hardener with gelatin. The invention finds a preferred use in curtain coating wherein there is a greater need for high viscosity materials, particularly at the bottom of a group of layers in order to minimize distortions of the layers as they are applied in the curtain coating process.
    Type: Grant
    Filed: December 30, 1993
    Date of Patent: October 26, 1999
    Assignee: Eastman Kodak Company
    Inventors: Marianne Yarmey, Wayne Arthur Bowman, Stephen Joseph Kozak, Gary Francis Mitchell, Glenn Thomas Pearce, Melvin David Sterman
  • Patent number: 5962193
    Abstract: The present invention discloses a method and apparatus for controlling air flow in a liquid coating apparatus by providing an adjustable housing that consists of an upper compartment and a lower compartment such that the height of the cavity contained therein can be adjusted. Subsequently, the spacing between a substrate to be coated and the interior wall of the upper compartment can be suitably adjusted to allow a desirable quantity of air flowing therethrough. The redeposition of liquid coating particles thrown off the substrate surface during a spin coating process and then bouncing back from the interior wall of the upper compartment onto the substrate surface can be prevented. The contamination of the substrate surface can therefore be eliminated or reduced.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: October 5, 1999
    Assignee: Taiwan Semiconductor Manufacturing Co. Ltd.
    Inventors: Kuang-Hung Lin, Dong-Hsu Cheng, Cheng-Wei Huang, Cheng-Ku Chen
  • Patent number: 5955251
    Abstract: A method for producing an information recording medium is disclosed. The method comprising the steps of (1) applying a surface treatment on a surface of a film support so that the atomic percentage of oxygen at said surface is increased by 1.0 atomic-% to 10 atomic-% compared to the atomic percentage of oxygen at said surface before treatment, (2) providing a subbing layer comprising a water-soluble or water-dispersible polymer having a 2-oxazoline group represented by Formula A on said treated surface of the film support so that the subbing layer is directly adjoined to said surface, and (3) providing an information recording layer on said subbing layer, ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently a hydrogen atom, a halogen atom, an alkyl group, an aralkyl group, a phenyl group.
    Type: Grant
    Filed: April 15, 1998
    Date of Patent: September 21, 1999
    Assignee: Konica Corporation
    Inventors: Hirokazu Koyama, Makoto Honda, Toshiaki Shibue
  • Patent number: 5919598
    Abstract: A method for making multilayer resist structures for microlithographic processing using a thermosetting anti-reflective coating is disclosed for a broad range of exposure wavelengths, said coating containing an active curing catalyst, ether or ester linkages derived from epoxy functionality greater than 3.0, a dye-grafted hydroxyl-functional oligomer, and an alkylated aminoplast crosslinking agent, all present in a low-to-medium alcohol-containing solvent.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: July 6, 1999
    Assignee: Brewer Science, Inc.
    Inventors: Tony D. Flaim, Jim D. Meador, Xie Shao, Terry Lowell Brewer
  • Patent number: 5910398
    Abstract: Photographic glass plates can be prepared by directly coating the appropriate layer formations onto a glass support. One element comprises a thin subbing layer (less than 2 .mu.m), an antihalation layer, a silver halide emulsion layer, and a protective overcoat layer that can also include a matting agent or lubricant. Another embodiment has the antihalation layer coated directly onto the support.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: June 8, 1999
    Assignee: Eastman Kodak Company
    Inventors: Ronald James Schmidt, Lawrence Annello Savino
  • Patent number: 5869219
    Abstract: The present invention discloses a method for coating a polyimide precursor on an electronic structure incorporating the use of a silicon coupling agent without any bubble defect in the film deposited. The method can be carried out by flowing at least one inert gas through a deposition chamber and thereby keeping the relative humidity in the chamber at below 25% to carry away the formation of any water molecules and water vapor to prevent the formation of bubbles in the film deposited.
    Type: Grant
    Filed: November 5, 1997
    Date of Patent: February 9, 1999
    Assignee: Taiwan Semiconductor Manufacturing Co. Ltd.
    Inventors: Chen-Cheng Kuo, Ho-Ku Lan, Hung-Chih Chen, Shih-Shiung Chen
  • Patent number: 5830632
    Abstract: Photographic element are described comprising a support bearing a photographic silver halide emulsion layer having associated therewith a micro-precipitated dispersion of a high dye-yield coupler having the formula:COUP--(T).sub.m --L--DYEwhere COUP is the coupler moiety of the coupler capable of reacting at the coupling position with oxidized color developer to form a first dye, T is one or more timing groups with m=0, 1 or 2, L is a linking group selected from the group consisting of --OC(O)--, --OC(S)--, --SC(O)--, --SC(S)--, or --OC(.dbd.NSO.sub.2 R)--, where R is a substituted or unsubstituted alkyl or aryl group, and DYE is a second dye or precursor thereof comprising an electrically neutral chromophore. The invention also provides a photographic coupler dispersion, a photographic silver halide emulsion, and a process for forming an image in a photographic element in accordance with the invention.
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: November 3, 1998
    Assignee: Eastman Kodak Company
    Inventors: Krishnan Chari, David Thomas Southby, David Hoke
  • Patent number: 5824462
    Abstract: Disclosed are resin-coated paper having on one side of its base paper a first resin layer made of a resin composition obtained by melt-blending 90 to 65 parts by weight of a high-density polyethylene resin having a melt flow rate of 10.0 g/10 min to 40.0 g/10 min and a density of 0.960 g/cm.sup.3 or more and 10 to 35 parts by weight of a low-density polyethylene resin or a medium-density polyethylene resin, which has a melt flow rate of 0.2 g/10 min to 2 g/10 min, a density of 0.935 g/cm.sup.3 or less, a percentage of molecules with a molecular weight of 500,000 or more of 10% by weight or more and a critical shear rate of 0.5 (l/sec) or less, said resin composition obtained by the melt-blending having a critical shear rate of 10 (l/sec) or less; and a process for producing the resin-coated paper. The resin-coated paper is good in the molding processability of the resin layer, is excellent in the adhesion between the resin layer and the base paper, and contains only a small amount of a gel formed.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: October 20, 1998
    Assignees: Mitsubishi Paper Mills Limited, Mitsubishi Chemical Corporation
    Inventors: Tetsuya Ashida, Touru Noda, Osamu Kojima, Tomoichi Morita, Nobushige Ikeya, Takuya Seri, Kohhei Nitta
  • Patent number: 5824463
    Abstract: This invention describes a method for manufacturing a photographic support which includes providing a support and laminating a surface of the support with a polymer resin formulation containing from 0.001 to 1 weight percent antioxidant at a temperature of from 305.degree. to 360.degree. C. while exposing the polymer resin formulation to an ozone containing gas at a rate of greater than 0.1 mg/m.sup.2 of said support.
    Type: Grant
    Filed: March 24, 1997
    Date of Patent: October 20, 1998
    Assignee: Eastman Kodak Company
    Inventor: Eric E. Arrington
  • Patent number: 5821027
    Abstract: The present invention is a method of producing an imaging support which includes providing a support, simultaneously coating on a side of the support; a transparent magnetic recording layer including magnetic particles, a polymeric binder and an organic solvent, and a lubricating overcoat layer farthest from the support, the lubricating overcoat layer including a lubricant selected form the general formulas I, II or III:wherein general formula I comprises: ##STR1## wherein X is selected from the group consisting of esters, amides, ethers, or methylene, a is from 10 to 500, and b is from 4 to 3000, and the general formula I has a molecular weight at least 800;wherein general formula II comprises: ##STR2## wherein Y is selected from the group consisting of, --C-- and --N--, Z is selected from the group consisting of esters, amides, and a carbon-carbon bond, R is selected from the group consisting of methyl, and hydrogen or may be absent if Y equals nitrogen, c is from 1 to 2, d is from 4 to 3000, e is from 10 t
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: October 13, 1998
    Assignee: Eastman Kodak Company
    Inventors: Christine J. Landry-Coltrain, Bradley K. Coltrain, Michael J. Corrigan, David B. Bailey
  • Patent number: 5811227
    Abstract: A dispersing method carried out in a liquid feeding system includes passing a dispersing medium containing an oil droplet type emulsified material at a flow rate of not less than 5 cc/cm.sup.2.min through a filter with a plurality of pores having such a size as to permit an oil droplet type emulsified material having a predetermined particle diameter to pass therethrough to reduce the size of the coarse particles of the oil droplet type emulsified material to below a predetermined particle diameter. The dispersing method is particularly suitable for use in the production of photographic layers.
    Type: Grant
    Filed: October 9, 1996
    Date of Patent: September 22, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Iskandar Gandasasmita, Fuyuhiko Mori, Kazuya Sano, Johannes A.W. van Engelen
  • Patent number: 5807668
    Abstract: An improved method for increaseing the hardening in a photographic element is described. The hardener is an imidazolium compound of formula: ##STR1## and the imidazolium is used in conjunction with a hardening accelerator defined by: ##STR2## the substituents are listed in the specification.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: September 15, 1998
    Assignee: Sterling Diagnostic Imaging, Inc.
    Inventors: Ludovic U. Fodor, Timothy D. Weatherill, Rolf T. Weberg
  • Patent number: 5804365
    Abstract: A thermally processable imaging element comprises a support bearing an imaging layer comprising a hydrophobic binder and a boron compound of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and are selected from substituted or unsubstituted alkyl groups, and substituted or unsubstituted aryl groups.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: September 8, 1998
    Assignee: Eastman Kodak Company
    Inventors: Charles L. Bauer, Ralph B. Nielsen, Ronald Di Felice, Gordon D. Young
  • Patent number: 5798136
    Abstract: The present invention is a method of producing an imaging support which includes providing a support, simultaneously coating on a side of the support; a transparent magnetic recording layer comprising magnetic particles, a polymeric binder and an organic solvent, and a lubricating overcoat layer farthest from the support, the lubricating overcoat layer comprising wax particles having a size from 0.01 .mu.m to 0.5 .mu.m, and an organic solvent; and drying the magnetic recording layer and the lubricating overcoat layer.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: August 25, 1998
    Assignee: Eastman Kodak Company
    Inventors: Christine J. Landry-Coltrain, Michael J. Corrigan, Gregory W. Keyes, James H. Griggs, Bradley K. Coltrain
  • Patent number: 5789145
    Abstract: The present invention is a method for treating a polyester support such as polyethylene naphthalate or polyethylene terephthalate. The treatment is carried out at atmospheric pressure in a gas of helium and optionally nitrogen and/or oxygen. The treatment uses metallic electrodes and an atmospheric glow discharge results when the electrodes are connected to a generator and spaced about 1 to 2 mm apart. The process and apparatus improve adhesion of subsequently coated emulsions on the polyester support at high speeds and relatively low power by selecting a frequency of 40 kHz to 500 kHz.
    Type: Grant
    Filed: July 23, 1996
    Date of Patent: August 4, 1998
    Assignee: Eastman Kodak Company
    Inventors: David A. Glocker, Mark M. Romach, Richard C. Soper
  • Patent number: 5786135
    Abstract: The present invention describes an imaging element wherein one layer is coated from an aqueous coating solution having a film forming binder. The film forming binder includes a carboxylic acid containing vinyl polymer or copolymer having a glass transition temperature greater than 60.degree. C. and an acid number of from 60 to 260. The carboxylic acid groups of the vinyl polymer or copolymer are reacted with ammonia or amine to provide a pH of the coating composition of from about 7 to 10.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: July 28, 1998
    Assignee: Eastman Kodak Company
    Inventors: Charles Chester Anderson, Yongcai Wang, James L. Bello, Mario D. DeLaura
  • Patent number: 5773204
    Abstract: The invention concerns a process for coating a photographic support.The process consists of depositing on a support a succession of at least two layers, at least one of which consists of a photosensitive composition, the top layer, situated at the opposite side to the support, containing a given concentration of at least one surfactant, the process being characterized in that a surfactant present in the top layer is introduced into the layer adjacent to the top layer at a concentration equal to at least 25% of the concentration of the same surfactant in the said top layer.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: June 30, 1998
    Assignee: Eastman Kodak Company
    Inventor: Jean Marie Baumlin
  • Patent number: 5770352
    Abstract: The invention is accomplished by providing an aqueous dispersion of a photographic coupler by precipitation from a solvent solution by solvent and/or pH shift. A second aqueous dispersion of an activating permanent solvent for the photographic coupler is also provided. The dispersion of activating permanent solvent and photographic coupler are combined to form a combined dispersion with relatively low amounts of coupler solvent which may be then mixed with a gelatin dispersion of silver halide particles to form a photographic emulsion coating composition suitable for casting as a photographic element layer. The coupler is selected to have a logP greater than or equal to about 10 and the activating solvent is selected to have a logP greater than or equal to about 8 and a Tg less than or equal to about -80.degree. C. to provide stable, small size photographically active coupler dispersions without the need for nonionic water soluble polymers and with minimal amount of added solvent.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: June 23, 1998
    Assignee: Eastman Kodak Company
    Inventor: Krishnan Chari
  • Patent number: 5753390
    Abstract: A method is described for preparing a concentrated dispersion of a photographically useful compound ready-for-use in coating solutions of hydrophilic colloid layers of a silver halide photographic material, wherein said compound has at least one ionisable acid site on its molecule, the said method comprising the steps of deprotonising and solubilising the said compound in alkaline medium; microprecipitating the said compound and milling the microprecipitated compound obtained, coating the said dispersion of a photographically useful compound in non-light-sensitive and/or light-sensitive hydrophilic layers of a silver halide photographic material, wherein milling proceeds during and/or after the microprecipitating step.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: May 19, 1998
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Pierre De Roo, Jan Gilleir
  • Patent number: 5736309
    Abstract: There is disclosed a method of manufacturing a photographic polyester film, comprising forming an unstretched film controlling; each of the temperature of the inlet of a melt extruder, at a temperature in the range from "the melting point of the polymer (Tm)"-10.degree. C. to the Tm+15.degree. C.; the temperature of the central part of a screw, at a temperature in the range from the Tm to the Tm+30.degree. C.; and the temperature of the outlet thereof, at a temperature in the range from the Tm+10.degree. C. to the Tm+35.degree. C., followed by biaxial stretching and heat-setting, and a photographic support manufactured by the method. The thus obtained photographic polyester support excels in photographic properties, adhesiveness, and mechanical strength, and that moreover hardly causes a core set curl and fog formation.
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: April 7, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Fumio Kawamoto
  • Patent number: 5721088
    Abstract: This invention provides an improved electrodepositable photoimageable resist composition which includes a photosensitive composition and a microgel. The photosensitive composition can be either a negative-acting or a positive-acting photoresist. Moreover, with regard to each of these, the photoresist component can be either cationic or anionic. The microgel includes a plurality of crosslinked organic particles which can form a stable aqueous dispersion. Moreover, the microgel is present in an amount ranging from between about 0.1 to about 30 weight percent. These weight percentages are based upon the total weight of the resin solids in the photoimageable resist composition. At these concentrations, the microgels promote edge coverage, but do not significantly reduce the photosensitivity and developability properties of the photosensitive composition with which they are combined.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: February 24, 1998
    Assignee: PPG Industries, Inc.
    Inventors: James W. Martin, Charles F. Kahle, II
  • Patent number: 5714308
    Abstract: The present invention is a method for treating a polyester support such as polyethylene naphthalate or polyethylene terephthalate. The treatment is carried out at near atmospheric pressure in a gas of helium and optionally nitrogen and/or oxygen. The treatment uses anodized aluminum electrodes and an atmospheric glow discharge results when the electrodes are connected to an RF generator and spaced about 2 mm apart. The process and apparatus improve adhesion of subsequently coated emulsions on the polyester support at high speeds and relatively low power by selecting a frequency of 40 kHz to 500 kHz.
    Type: Grant
    Filed: February 13, 1996
    Date of Patent: February 3, 1998
    Assignee: Eastman Kodak Company
    Inventors: Mark M. Romach, David Appler Glocker
  • Patent number: 5709984
    Abstract: A coating composition useful for forming an electrically conductive layer on a substrate is disclosed, said composition comprising a liquid medium containing: a) a vanadium oxide gel, b) a film-forming binder, and c) a conductivity-increasing amount of a volatile aromatic compound comprising an aromatic ring substituted with at least one hydroxy group or a hydroxy substituted substituent group. Further embodiments of the invention disclose a composite support for an imaging element, which composite support comprises a polymeric film having coated thereon an electrically conductive layer, wherein the electrically conductive layer has been formed by applying a coating of the coating composition of the invention, and drying the coating.
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: January 20, 1998
    Assignee: Eastman Kodak Company
    Inventors: Janglin Chen, Richard A. Castle, Karen E. Gleasman
  • Patent number: 5695920
    Abstract: A coating composition that is useful for the preparation of an auxiliary layer of an imaging element, such as a photographic element, is comprised of an aqueous medium having dispersed therein film-forming polymeric particles and non-film-forming polymeric particles and is characterized in that the film-forming polymeric particles are acid-stable polyurethane particles. These coating compositions have excellent stability characteristics, provide auxiliary layers with improved chemical and physical properties when coated and dried to form a coalesced layer, and provide for reduced emission of volatile organic compounds during the drying process.
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: December 9, 1997
    Assignee: Eastman Kodak Company
    Inventors: Charles Chester Anderson, Brian Andrew Schell, Yongcai Wang
  • Patent number: 5674660
    Abstract: An electrodepositable photoresist composition comprising an aqueous dispersion of: (a) a water-dispersible neutralized cationic polymeric material having a pendant unsaturation, (b) a nonionic unsaturated material and (c) a photoinitiator; characterized in that it can form smooth, thin and pinhole free coatings and further characterized in that the film is capable of being selectively insolubilized by patterned radiation exposure such that the unexposed portion of the film is soluble in dilute aqueous acid and the exposed portion is insoluble in said aqueous acid.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: October 7, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Kurt G. Olson, Michael G. Sandala, Steven R. Zawacky, Charles F. Kahle, II, Masayuki Nakajima