Coating Process Making Radiation Sensitive Element Patents (Class 430/935)
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Patent number: 6376165Abstract: A method of preparing a photothermographic material, comprising a support having thereon at least a layer, the method comprising the steps of: coating a coating solution containing an organic silver salt, a photosensitive silver halide and a reducing agent on the support to form a coated material and subjecting the coated material to a thermal treatment at a temperature of 40 to 120° C. under a tension of 0.01 to 30 kg/cm2.Type: GrantFiled: September 15, 2000Date of Patent: April 23, 2002Assignee: Konica CorporationInventors: Hidetoshi Ezure, Kenji Ohnuma, Yuji Hosoi
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Publication number: 20020031724Abstract: A direct-to-plate method for obtaining a high quality lithographic printing plate is disclosed. The method comprises the application of a continuous layer of a radiation sensitive solution onto a lithographic substrate by means of an ink-jet printhead. Hereby waste of coating solution and contamination of the environment are avoided.Type: ApplicationFiled: July 24, 2001Publication date: March 14, 2002Inventors: Eric Verschueren, Luc Leenders, Joan Vermeersch, Ludo Joly
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Patent number: 6319317Abstract: A spreading state of an outline of the outer periphery of a coating solution is detected by a detecting sensor, and the rotation speed or the like of a wafer as a substrate is controlled so that a spreading speed of the outline becomes not more than a predetermined speed with no danger of producing a scratchpad. Alternatively, the width in the radius direction of a scratchpad is measured, and the rotation speed or the like of the wafer is controlled so that the width in the radius direction becomes not more than a predetermined value. Thereby, occurrence of the scratchpad is prevented or the degree thereof is decreased, thereby avoiding uncoating of the coating solution on the substrate and reducing the amount of the coating solution used.Type: GrantFiled: April 18, 2000Date of Patent: November 20, 2001Assignee: Tokyo Electron LimitedInventor: Hideyuki Takamori
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Publication number: 20010041311Abstract: A coating and developing apparatus for coating a substrate with a plurality of color resists and for developing it after exposure, comprises: a scrubbing unit for scrubbing the substrate; a coating unit having a plurality of resist discharge nozzles for respectively discharging a plurality of color resists on the scrubbed substrate; and a developing unit for developing the substrate coated with the color resists after exposure. Accordingly, reduction in size of apparatus and space savings can be achieved, and manufacturing cost can also be reduced.Type: ApplicationFiled: June 7, 2001Publication date: November 15, 2001Inventors: Shinichiro Araki, Shinko Matsumoto, Noriyuki Anai
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Patent number: 6273984Abstract: A method of curl control for lamination of a polymer sheet to each side of a core material comprising providing a bottom polymer sheet, bringing said bottom sheet into contact with a heat source, providing said core material, bringing said core material into contact with said bottom polymer sheet while simultaneously applying a binder between said bottom sheet and said core to form a laminate, providing a top polymer sheet, bringing said top sheet into contact with said laminate and while simultaneously applying a binder between said top sheet and said laminate to form a composite wherein each sheet to core modulus ratio is greater than 1 and wherein said composite has a desired curl.Type: GrantFiled: November 20, 1998Date of Patent: August 14, 2001Assignee: Eastman Kodak CompanyInventors: Robert P. Bourdelais, Thaddeus S. Gula, Peter T. Aylward
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Patent number: 6245500Abstract: A method of cooling a photographic coating composition in a sol state is disclosed. The composition that includes photographic emulsion, an emulsified material or gelatin solution, or comprising combinations thereof is continuously cooled by employing heat exchanger, and after being transformed into a gel state, the resulting product is placed into a storage vessel.Type: GrantFiled: May 25, 1999Date of Patent: June 12, 2001Assignee: Konica CorporationInventor: Yasuo Nishi
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Patent number: 6235458Abstract: A method for heat-treating a photographic film while conveying, which comprises the steps of: passing the photographic film through from 2 to 100 rolls disposed so that gaps between the adjacent rolls are within the range of from 0.1 cm to 50 cm; and heat-treating the photographic film during the conveyance, wherein the photographic film comprises a support having coated thereon at least one layer. Also disclosed is a method for heat-treating a photographic film, which comprises the steps of: heat-treating a photographic film; and winding the heat-treated film, wherein the heat-treated film is cooled before the winding, the cooling rate in the temperature range from the glass transition temperature (Tg) of the film +40° C. to the Tg −10° C. being at 0.01° C./second to 10° C./second. Further disclosed is a photographic film having a width direction and a lengthwise direction, and having a thickness unevenness along the film's width direction is from 2 &mgr;m to 300 &mgr;m.Type: GrantFiled: July 29, 1998Date of Patent: May 22, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Kiyokazu Hashimoto
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Patent number: 6228570Abstract: An photographic element comprising: a support with two sides; at least one sensitized layer on one side of the support; at least one transparent magnetic layer on another side of the support, opposite the sensitized layer; and a lubricant layer deposited on the transparent magnetic layer,wherein the lubricant layer is a fluorinated polymer selected from the group consisting of fluoropolymer resins, polytetrafluoroethylene, fluorinated ethylene polymer, fluorinated ethylene propylene, perfluoroalkoxy copolymer resins, and amorphous fluoropolymers.Type: GrantFiled: December 1, 1999Date of Patent: May 8, 2001Assignee: Eastman Kodak CompanyInventors: Dennis R. Freeman, Christine J. Landry-Coltrain
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Patent number: 6225040Abstract: There is provided a method for preparing a biaxially oriented polyester sheet or web, with improved antistatic properties, comprising the steps of (i) stretching said polyester sheet or web first in one direction and second in a direction perpendicular thereto (ii) coating said hydrophobic polyester sheet or web, either before stretching or between said first and second stretching operation, on one or both sides, with a transparent antistatic primer layer, wherein the coating composition of said transparent antistatic primer layer comprises (1) a dispersion of a polythiophene with conjugated polymer backbone and a polymeric polyanion compound and (2) a latex polymer having hydrophilic functionality. The primer layer is coated from an aqueous composition and does not show a substantial change in resistivity depending on relative humidity or wet processing.Type: GrantFiled: December 15, 1994Date of Patent: May 1, 2001Assignee: Agfa-GevaertInventors: Bavo Muys, Dirk Quintens, Jozef Boeykens, Etienne Van Thillo, Geert Defieuw
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Patent number: 6190828Abstract: A method for making a lithographic printing master is disclosed. The method comprises a step of providing a hydrophilic cylindrical surface, e.g. an aluminium plate mounted on the plate cylinder of a printing press, with an image recording composition by transfer from a donor material. The donor material comprises a support and a transfer layer which comprises hydrophobic thermoplastic polymer particles dispersed in a hydrophilic binder and a compound capable of converting light to heat. The transfer is obtained by friction between the donor layer and the cylindrical surface and/or by moistening the cylindrical surface with an aqueous liquid. The method is especially suited for on-press coating and on-press imaging in computer-to-press procedures.Type: GrantFiled: April 19, 2000Date of Patent: February 20, 2001Assignee: Agfa-Gevaert, N.V.Inventors: Eric Verschueren, Joan Vermeersch
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Patent number: 6187517Abstract: The present invention provides a gelatin-based aqueous-coatable overcoat for a photographic element that allows for appropriate diffusion of photographic processing solutions. The overcoat comprises 10 to 50% by weight gelatin and 50 to 90% by weight of hydrophobic particles (by weight of dry laydown of the entire overcoat) having an average diameter of 10 to 500 nm. A proteolytic enzyme is applied to the clement in reactive association with the overcoat layer. A photographic element according to one embodiment of the invention can be exposed and processed using normal photofinishing equipment, with no modifications, to provide an imaged element together with a protective, water-resistant layer.Type: GrantFiled: June 9, 2000Date of Patent: February 13, 2001Assignee: Eastman Kodak CompanyInventors: Thomas H. Whitesides, Hwei-Ling Yau, Amy Jasek
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Patent number: 6180325Abstract: A method for exposing photo-sensitive printing plates comprises applying a patterned coating to the printing plate to form a mask. The coating may be sprayed onto the printing plate and patterned by laser ablation. The method avoids the need to stock printing plates with integral masking layers. In preferred implementations the printing plate is exposed to actinic radiation without dismounting it from the apparatus in which the coating is applied. This minimizes the likelihood that the coating could be damaged in handling. The coating may be a thin sprayed on layer of carbon in a suitable binder.Type: GrantFiled: June 23, 1999Date of Patent: January 30, 2001Assignee: Creo SRLInventor: Daniel Gelbart
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Patent number: 6165699Abstract: A photographic polyester support having an adjacent subbing layer which comprises a polymer or copolymer of glycidyl acrylate and/or glycidyl methacrylate followed by a gelatin layer and which is annealed. Such a composite has been found to provide improved adhesion properties without chemical degradation of the subbing layer under annealing conditions.Type: GrantFiled: December 17, 1999Date of Patent: December 26, 2000Assignee: Eastman Kodak CompanyInventors: Charles L. Bauer, Cathy A. Fleischer
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Patent number: 6150075Abstract: A process of transferring a photographic image to a stone surface, such as slate tile, provides for the use of a gelatin subbing solution in a step of preparing the stone surface for the receipt of the image. Additional steps include application of polyacrylic coating and concrete staining material to the surface prior to exposing the surface to the gelatin subbing solution, and using conventional photo developing compounds for permanently affixing a transferred image to the stone surface. Mixing gelatin, chrome alum and water makes the gelatin subbing solution. For an "antique" look, the photograph can be exposed to a sulfide sepia toner prior to transfer of the image to the stone surface.Type: GrantFiled: November 30, 1998Date of Patent: November 21, 2000Inventor: Ralph S. Klafert
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Patent number: 6146808Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer, characterized in that said element before and/or after being coated with said image-receiving layer and before being coated with another layer is wetted with a fluidum with a conductivity of at least 1 .mu.S/cm at 25.degree. C. and then the wetted element is brought in contact with an earthed discharging means and dried before coating the following layer.Type: GrantFiled: November 5, 1999Date of Patent: November 14, 2000Assignee: AGFA-Gevaert, N.V.Inventor: Marcus Jonkheere
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Patent number: 6146807Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer in water permeable relationship with said image receiving layer, characterized in that said aluminum support, provided with said image receiving layer, is kept at a relative humidity of at least 45% in an area of a machine, the said area being ahead of a coating head used for coating said photosensitive layer.Type: GrantFiled: November 5, 1999Date of Patent: November 14, 2000Assignee: Agfa-Gevaert, N.V.Inventor: Marcus Jonkheere
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Patent number: 6127094Abstract: In accordance with the present invention, there are provided water-developable photopolymerizable compositions useful for the preparation of printing plates. Printing plates prepared employing invention compositions have excellent form stability, thereby enabling such plates to be handled without the need for excessive care. Once photopolymerized, printing plates of the invention have excellent physical properties, enabling their use in many very demanding applications, e.g., flexographic printing. Such applications require the photopolymerized resin to have excellent water resistance (so that exposure to water-based inks does not significantly alter resin properties), as well as high durability (so that the physical contacting associated with the printing process does not significantly degrade resin properties).Type: GrantFiled: October 2, 1997Date of Patent: October 3, 2000Assignee: Napp Systems Inc.Inventors: Mark W. Victor, Allyson R. Maurer, Richard P. Homick
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Patent number: 6127090Abstract: A process for producing a photosensitive resin printing plate comprising a step of forming a liquid photosensitive resin into a layer by applying the same to a substrate with a bucket, wherein a forming speed variation point for said layer is set at a position which is 30 to 80% of the forming distance of said layer, and wherein the liquid photosensitive resin is formed into a layer by successively reducing the forming speed thereafter.Type: GrantFiled: September 11, 1998Date of Patent: October 3, 2000Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Shinichi Kawatsuji, Mitsuhiro Watanabe
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Patent number: 6071681Abstract: A method for producing a silver halide photographic light-sensitive material is disclosed, which comprises a support having thereon a silver halide emulsion layer and optionally another hydrophilic colloid layer. The method comprises the steps of (1) coating a coating solution of the silver halide emulsion layer or that of the hydrophilic colloid layer on the support, and (2) drying the coated layer, and the coating solution of the silver halide emulsion layer or that of the hydrophilic colloid layer comprises gelatin and a sugaralcohol.Type: GrantFiled: May 18, 1998Date of Patent: June 6, 2000Assignee: Konica CorporationInventors: Kiyokazu Morita, Hideki Hoshino, Shinichi Suzuki
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Patent number: 6071682Abstract: The present invention is photographic film base which includes a polymeric support having a first side and a second side and a glass transition temperature (Tg.sub.s). A polymeric layer is superposed on the first side of the polymeric support, the polymer layer having a glass transition temperature Tg.sub.L which is greater than the glass transition temperature of the support Tg.sub.s. The polymeric layer has a thickness of at least 2.5 percent of the thickness of the support.Type: GrantFiled: October 9, 1997Date of Patent: June 6, 2000Assignee: Eastman Kodak CompanyInventors: Jehuda Greener, Paul D. Yacobucci, Beverly A. Contestable, Catherine A. Falkner
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Patent number: 6048666Abstract: A radiation sensitive resin composition comprising an alkali-soluble resin such as a polyvinyl phenol or a phenol resin other than a polyvinyl phenol having a weight average molecular weight of 2,000 or higher, a cross-linking agent such as an amino resin having two or more active methylol groups in a molecule, a particulate rubbery material comprising a cross-linked polymer chemically modified with an epoxy compound, a liquid rubbery material having a number average molecular weight between 1,000 and 10,000 and a glass transition temperature of -20.degree. C. or lower, and a radiation polymerization initiator. The composition is best suited for use as a material for preparing an insulating layer interposed between two layers of conductive wiring that are arranged in an overlaying stack.Type: GrantFiled: June 3, 1998Date of Patent: April 11, 2000Assignee: JSR CorporationInventors: Kazuaki Niwa, Masako Suzuki, Toshiyuki Ota, Hozumi Sato, Hideki Chiba
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Patent number: 6043009Abstract: The invention relates to a photographic element comprising a paper base, at least one photosensitive silver halide layer, and a layer of microvoided biaxially oriented polyolefin sheet between said paper base and said silver halide layer.Type: GrantFiled: December 10, 1998Date of Patent: March 28, 2000Assignee: Eastman Kodak CompanyInventors: Robert P. Bourdelais, Douglas N. Haydock, Thaddeus S. Gula, Peter T. Aylward
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Patent number: 6040109Abstract: According to the present invention there is provided a method for preparing an imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer comprising unhardened gelatin, characterized in that said aluminum support when being coated with said photosensitive layer is in contact with a guiding roller, heated at a temperature between 35 and 70.degree. C.Type: GrantFiled: February 22, 1999Date of Patent: March 21, 2000Assignee: Agfa-Gevaert, N.V.Inventors: Paul Coppens, Marcus Jonckheere
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Patent number: 6037108Abstract: A support for an imaging element is described, which support comprises a polyester polymeric film having coated thereon a subbing layer comprising gelatin and a multi-hydric organic compound having at least three hydroxyl groups, which gelatin subbing layer coated support has been subjected to a heat treatment to reduce the core-set curling tendency of the polymeric film. Imaging elements for use in an image-forming process is also described, which elements comprise a gelatin subbing layer coated polyester polymeric film support as described above, and an image-forming layer coated on the subbed support. A method for forming a heat-tempered, gelatin-subbed support for an imaging element is also described, comprising coating a subbing layer comprising gelatin and a multi-hydric organic compound having at least three hydroxyl groups on a polyester polymeric film, and subjected the coated film to heat treatment to reduce the core-set curling tendency of the polymeric film.Type: GrantFiled: April 27, 1998Date of Patent: March 14, 2000Assignee: Eastman Kodak CompanyInventors: Janglin Chen, Richard A. Castle, Yongcai Wang
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Patent number: 5981159Abstract: A photographic element is disclosed comprising a support bearing at least one light sensitive silver halide emulsion layer comprising a dispersion of a dye-forming coupler and a water-insoluble polymer, wherein the polymer has a glass transition temperature of less than 75.degree. C. and is formed from at least 30 wt % monomer units which provide the polymer with functional groups that are hydrogen bond donors. The combination of such relatively low T.sub.g polymers with couplers in photographic elements leads to both decreased pressure sensitivity and improved image-dye light stability, as well as a decreased tendency toward dye smear or thermal induced change. The advantages of the invention are particularly useful for yellow coupler dispersions used in photographic color paper elements on reflective supports, although they will also be useful for motion picture print film and other projection or display films on transparent or diffuse supports.Type: GrantFiled: December 23, 1997Date of Patent: November 9, 1999Assignee: Eastman Kodak CompanyInventors: Ralph Bendt Nielsen, David Francis Bates, Brian Thomas
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Patent number: 5972591Abstract: The invention is generally accomplished by providing a photographic element and a process of its formation wherein a gelatin silver halide emulsion is provided with a thickener comprising a copolymer of the structure whereinA comprises about 10 to about 20 parts by weight of said copolymer, andB comprises about 80 to about 90 parts by weight of said copolymer.It is particularly preferred that the copolymer be provided in a hardener layer to minimize the amount of gelatin needed and thus reduce the reaction of hardener with gelatin. The invention finds a preferred use in curtain coating wherein there is a greater need for high viscosity materials, particularly at the bottom of a group of layers in order to minimize distortions of the layers as they are applied in the curtain coating process.Type: GrantFiled: December 30, 1993Date of Patent: October 26, 1999Assignee: Eastman Kodak CompanyInventors: Marianne Yarmey, Wayne Arthur Bowman, Stephen Joseph Kozak, Gary Francis Mitchell, Glenn Thomas Pearce, Melvin David Sterman
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Patent number: 5962193Abstract: The present invention discloses a method and apparatus for controlling air flow in a liquid coating apparatus by providing an adjustable housing that consists of an upper compartment and a lower compartment such that the height of the cavity contained therein can be adjusted. Subsequently, the spacing between a substrate to be coated and the interior wall of the upper compartment can be suitably adjusted to allow a desirable quantity of air flowing therethrough. The redeposition of liquid coating particles thrown off the substrate surface during a spin coating process and then bouncing back from the interior wall of the upper compartment onto the substrate surface can be prevented. The contamination of the substrate surface can therefore be eliminated or reduced.Type: GrantFiled: January 13, 1998Date of Patent: October 5, 1999Assignee: Taiwan Semiconductor Manufacturing Co. Ltd.Inventors: Kuang-Hung Lin, Dong-Hsu Cheng, Cheng-Wei Huang, Cheng-Ku Chen
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Patent number: 5955251Abstract: A method for producing an information recording medium is disclosed. The method comprising the steps of (1) applying a surface treatment on a surface of a film support so that the atomic percentage of oxygen at said surface is increased by 1.0 atomic-% to 10 atomic-% compared to the atomic percentage of oxygen at said surface before treatment, (2) providing a subbing layer comprising a water-soluble or water-dispersible polymer having a 2-oxazoline group represented by Formula A on said treated surface of the film support so that the subbing layer is directly adjoined to said surface, and (3) providing an information recording layer on said subbing layer, ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently a hydrogen atom, a halogen atom, an alkyl group, an aralkyl group, a phenyl group.Type: GrantFiled: April 15, 1998Date of Patent: September 21, 1999Assignee: Konica CorporationInventors: Hirokazu Koyama, Makoto Honda, Toshiaki Shibue
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Patent number: 5919598Abstract: A method for making multilayer resist structures for microlithographic processing using a thermosetting anti-reflective coating is disclosed for a broad range of exposure wavelengths, said coating containing an active curing catalyst, ether or ester linkages derived from epoxy functionality greater than 3.0, a dye-grafted hydroxyl-functional oligomer, and an alkylated aminoplast crosslinking agent, all present in a low-to-medium alcohol-containing solvent.Type: GrantFiled: August 6, 1996Date of Patent: July 6, 1999Assignee: Brewer Science, Inc.Inventors: Tony D. Flaim, Jim D. Meador, Xie Shao, Terry Lowell Brewer
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Patent number: 5910398Abstract: Photographic glass plates can be prepared by directly coating the appropriate layer formations onto a glass support. One element comprises a thin subbing layer (less than 2 .mu.m), an antihalation layer, a silver halide emulsion layer, and a protective overcoat layer that can also include a matting agent or lubricant. Another embodiment has the antihalation layer coated directly onto the support.Type: GrantFiled: June 13, 1996Date of Patent: June 8, 1999Assignee: Eastman Kodak CompanyInventors: Ronald James Schmidt, Lawrence Annello Savino
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Patent number: 5869219Abstract: The present invention discloses a method for coating a polyimide precursor on an electronic structure incorporating the use of a silicon coupling agent without any bubble defect in the film deposited. The method can be carried out by flowing at least one inert gas through a deposition chamber and thereby keeping the relative humidity in the chamber at below 25% to carry away the formation of any water molecules and water vapor to prevent the formation of bubbles in the film deposited.Type: GrantFiled: November 5, 1997Date of Patent: February 9, 1999Assignee: Taiwan Semiconductor Manufacturing Co. Ltd.Inventors: Chen-Cheng Kuo, Ho-Ku Lan, Hung-Chih Chen, Shih-Shiung Chen
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Patent number: 5830632Abstract: Photographic element are described comprising a support bearing a photographic silver halide emulsion layer having associated therewith a micro-precipitated dispersion of a high dye-yield coupler having the formula:COUP--(T).sub.m --L--DYEwhere COUP is the coupler moiety of the coupler capable of reacting at the coupling position with oxidized color developer to form a first dye, T is one or more timing groups with m=0, 1 or 2, L is a linking group selected from the group consisting of --OC(O)--, --OC(S)--, --SC(O)--, --SC(S)--, or --OC(.dbd.NSO.sub.2 R)--, where R is a substituted or unsubstituted alkyl or aryl group, and DYE is a second dye or precursor thereof comprising an electrically neutral chromophore. The invention also provides a photographic coupler dispersion, a photographic silver halide emulsion, and a process for forming an image in a photographic element in accordance with the invention.Type: GrantFiled: October 31, 1996Date of Patent: November 3, 1998Assignee: Eastman Kodak CompanyInventors: Krishnan Chari, David Thomas Southby, David Hoke
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Patent number: 5824462Abstract: Disclosed are resin-coated paper having on one side of its base paper a first resin layer made of a resin composition obtained by melt-blending 90 to 65 parts by weight of a high-density polyethylene resin having a melt flow rate of 10.0 g/10 min to 40.0 g/10 min and a density of 0.960 g/cm.sup.3 or more and 10 to 35 parts by weight of a low-density polyethylene resin or a medium-density polyethylene resin, which has a melt flow rate of 0.2 g/10 min to 2 g/10 min, a density of 0.935 g/cm.sup.3 or less, a percentage of molecules with a molecular weight of 500,000 or more of 10% by weight or more and a critical shear rate of 0.5 (l/sec) or less, said resin composition obtained by the melt-blending having a critical shear rate of 10 (l/sec) or less; and a process for producing the resin-coated paper. The resin-coated paper is good in the molding processability of the resin layer, is excellent in the adhesion between the resin layer and the base paper, and contains only a small amount of a gel formed.Type: GrantFiled: September 13, 1996Date of Patent: October 20, 1998Assignees: Mitsubishi Paper Mills Limited, Mitsubishi Chemical CorporationInventors: Tetsuya Ashida, Touru Noda, Osamu Kojima, Tomoichi Morita, Nobushige Ikeya, Takuya Seri, Kohhei Nitta
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Patent number: 5824463Abstract: This invention describes a method for manufacturing a photographic support which includes providing a support and laminating a surface of the support with a polymer resin formulation containing from 0.001 to 1 weight percent antioxidant at a temperature of from 305.degree. to 360.degree. C. while exposing the polymer resin formulation to an ozone containing gas at a rate of greater than 0.1 mg/m.sup.2 of said support.Type: GrantFiled: March 24, 1997Date of Patent: October 20, 1998Assignee: Eastman Kodak CompanyInventor: Eric E. Arrington
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Patent number: 5821027Abstract: The present invention is a method of producing an imaging support which includes providing a support, simultaneously coating on a side of the support; a transparent magnetic recording layer including magnetic particles, a polymeric binder and an organic solvent, and a lubricating overcoat layer farthest from the support, the lubricating overcoat layer including a lubricant selected form the general formulas I, II or III:wherein general formula I comprises: ##STR1## wherein X is selected from the group consisting of esters, amides, ethers, or methylene, a is from 10 to 500, and b is from 4 to 3000, and the general formula I has a molecular weight at least 800;wherein general formula II comprises: ##STR2## wherein Y is selected from the group consisting of, --C-- and --N--, Z is selected from the group consisting of esters, amides, and a carbon-carbon bond, R is selected from the group consisting of methyl, and hydrogen or may be absent if Y equals nitrogen, c is from 1 to 2, d is from 4 to 3000, e is from 10 tType: GrantFiled: May 19, 1997Date of Patent: October 13, 1998Assignee: Eastman Kodak CompanyInventors: Christine J. Landry-Coltrain, Bradley K. Coltrain, Michael J. Corrigan, David B. Bailey
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Patent number: 5811227Abstract: A dispersing method carried out in a liquid feeding system includes passing a dispersing medium containing an oil droplet type emulsified material at a flow rate of not less than 5 cc/cm.sup.2.min through a filter with a plurality of pores having such a size as to permit an oil droplet type emulsified material having a predetermined particle diameter to pass therethrough to reduce the size of the coarse particles of the oil droplet type emulsified material to below a predetermined particle diameter. The dispersing method is particularly suitable for use in the production of photographic layers.Type: GrantFiled: October 9, 1996Date of Patent: September 22, 1998Assignee: Fuji Photo Film Co., Ltd.Inventors: Iskandar Gandasasmita, Fuyuhiko Mori, Kazuya Sano, Johannes A.W. van Engelen
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Patent number: 5807668Abstract: An improved method for increaseing the hardening in a photographic element is described. The hardener is an imidazolium compound of formula: ##STR1## and the imidazolium is used in conjunction with a hardening accelerator defined by: ##STR2## the substituents are listed in the specification.Type: GrantFiled: March 17, 1997Date of Patent: September 15, 1998Assignee: Sterling Diagnostic Imaging, Inc.Inventors: Ludovic U. Fodor, Timothy D. Weatherill, Rolf T. Weberg
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Patent number: 5804365Abstract: A thermally processable imaging element comprises a support bearing an imaging layer comprising a hydrophobic binder and a boron compound of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and are selected from substituted or unsubstituted alkyl groups, and substituted or unsubstituted aryl groups.Type: GrantFiled: March 7, 1997Date of Patent: September 8, 1998Assignee: Eastman Kodak CompanyInventors: Charles L. Bauer, Ralph B. Nielsen, Ronald Di Felice, Gordon D. Young
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Patent number: 5798136Abstract: The present invention is a method of producing an imaging support which includes providing a support, simultaneously coating on a side of the support; a transparent magnetic recording layer comprising magnetic particles, a polymeric binder and an organic solvent, and a lubricating overcoat layer farthest from the support, the lubricating overcoat layer comprising wax particles having a size from 0.01 .mu.m to 0.5 .mu.m, and an organic solvent; and drying the magnetic recording layer and the lubricating overcoat layer.Type: GrantFiled: May 19, 1997Date of Patent: August 25, 1998Assignee: Eastman Kodak CompanyInventors: Christine J. Landry-Coltrain, Michael J. Corrigan, Gregory W. Keyes, James H. Griggs, Bradley K. Coltrain
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Patent number: 5789145Abstract: The present invention is a method for treating a polyester support such as polyethylene naphthalate or polyethylene terephthalate. The treatment is carried out at atmospheric pressure in a gas of helium and optionally nitrogen and/or oxygen. The treatment uses metallic electrodes and an atmospheric glow discharge results when the electrodes are connected to a generator and spaced about 1 to 2 mm apart. The process and apparatus improve adhesion of subsequently coated emulsions on the polyester support at high speeds and relatively low power by selecting a frequency of 40 kHz to 500 kHz.Type: GrantFiled: July 23, 1996Date of Patent: August 4, 1998Assignee: Eastman Kodak CompanyInventors: David A. Glocker, Mark M. Romach, Richard C. Soper
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Patent number: 5786135Abstract: The present invention describes an imaging element wherein one layer is coated from an aqueous coating solution having a film forming binder. The film forming binder includes a carboxylic acid containing vinyl polymer or copolymer having a glass transition temperature greater than 60.degree. C. and an acid number of from 60 to 260. The carboxylic acid groups of the vinyl polymer or copolymer are reacted with ammonia or amine to provide a pH of the coating composition of from about 7 to 10.Type: GrantFiled: September 11, 1996Date of Patent: July 28, 1998Assignee: Eastman Kodak CompanyInventors: Charles Chester Anderson, Yongcai Wang, James L. Bello, Mario D. DeLaura
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Patent number: 5773204Abstract: The invention concerns a process for coating a photographic support.The process consists of depositing on a support a succession of at least two layers, at least one of which consists of a photosensitive composition, the top layer, situated at the opposite side to the support, containing a given concentration of at least one surfactant, the process being characterized in that a surfactant present in the top layer is introduced into the layer adjacent to the top layer at a concentration equal to at least 25% of the concentration of the same surfactant in the said top layer.Type: GrantFiled: March 17, 1997Date of Patent: June 30, 1998Assignee: Eastman Kodak CompanyInventor: Jean Marie Baumlin
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Patent number: 5770352Abstract: The invention is accomplished by providing an aqueous dispersion of a photographic coupler by precipitation from a solvent solution by solvent and/or pH shift. A second aqueous dispersion of an activating permanent solvent for the photographic coupler is also provided. The dispersion of activating permanent solvent and photographic coupler are combined to form a combined dispersion with relatively low amounts of coupler solvent which may be then mixed with a gelatin dispersion of silver halide particles to form a photographic emulsion coating composition suitable for casting as a photographic element layer. The coupler is selected to have a logP greater than or equal to about 10 and the activating solvent is selected to have a logP greater than or equal to about 8 and a Tg less than or equal to about -80.degree. C. to provide stable, small size photographically active coupler dispersions without the need for nonionic water soluble polymers and with minimal amount of added solvent.Type: GrantFiled: April 18, 1996Date of Patent: June 23, 1998Assignee: Eastman Kodak CompanyInventor: Krishnan Chari
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Patent number: 5753390Abstract: A method is described for preparing a concentrated dispersion of a photographically useful compound ready-for-use in coating solutions of hydrophilic colloid layers of a silver halide photographic material, wherein said compound has at least one ionisable acid site on its molecule, the said method comprising the steps of deprotonising and solubilising the said compound in alkaline medium; microprecipitating the said compound and milling the microprecipitated compound obtained, coating the said dispersion of a photographically useful compound in non-light-sensitive and/or light-sensitive hydrophilic layers of a silver halide photographic material, wherein milling proceeds during and/or after the microprecipitating step.Type: GrantFiled: July 17, 1996Date of Patent: May 19, 1998Assignee: Agfa-Gevaert, N.V.Inventors: Pierre De Roo, Jan Gilleir
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Patent number: 5736309Abstract: There is disclosed a method of manufacturing a photographic polyester film, comprising forming an unstretched film controlling; each of the temperature of the inlet of a melt extruder, at a temperature in the range from "the melting point of the polymer (Tm)"-10.degree. C. to the Tm+15.degree. C.; the temperature of the central part of a screw, at a temperature in the range from the Tm to the Tm+30.degree. C.; and the temperature of the outlet thereof, at a temperature in the range from the Tm+10.degree. C. to the Tm+35.degree. C., followed by biaxial stretching and heat-setting, and a photographic support manufactured by the method. The thus obtained photographic polyester support excels in photographic properties, adhesiveness, and mechanical strength, and that moreover hardly causes a core set curl and fog formation.Type: GrantFiled: July 10, 1997Date of Patent: April 7, 1998Assignee: Fuji Photo Film Co., Ltd.Inventor: Fumio Kawamoto
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Patent number: 5721088Abstract: This invention provides an improved electrodepositable photoimageable resist composition which includes a photosensitive composition and a microgel. The photosensitive composition can be either a negative-acting or a positive-acting photoresist. Moreover, with regard to each of these, the photoresist component can be either cationic or anionic. The microgel includes a plurality of crosslinked organic particles which can form a stable aqueous dispersion. Moreover, the microgel is present in an amount ranging from between about 0.1 to about 30 weight percent. These weight percentages are based upon the total weight of the resin solids in the photoimageable resist composition. At these concentrations, the microgels promote edge coverage, but do not significantly reduce the photosensitivity and developability properties of the photosensitive composition with which they are combined.Type: GrantFiled: December 20, 1995Date of Patent: February 24, 1998Assignee: PPG Industries, Inc.Inventors: James W. Martin, Charles F. Kahle, II
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Patent number: 5714308Abstract: The present invention is a method for treating a polyester support such as polyethylene naphthalate or polyethylene terephthalate. The treatment is carried out at near atmospheric pressure in a gas of helium and optionally nitrogen and/or oxygen. The treatment uses anodized aluminum electrodes and an atmospheric glow discharge results when the electrodes are connected to an RF generator and spaced about 2 mm apart. The process and apparatus improve adhesion of subsequently coated emulsions on the polyester support at high speeds and relatively low power by selecting a frequency of 40 kHz to 500 kHz.Type: GrantFiled: February 13, 1996Date of Patent: February 3, 1998Assignee: Eastman Kodak CompanyInventors: Mark M. Romach, David Appler Glocker
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Patent number: 5709984Abstract: A coating composition useful for forming an electrically conductive layer on a substrate is disclosed, said composition comprising a liquid medium containing: a) a vanadium oxide gel, b) a film-forming binder, and c) a conductivity-increasing amount of a volatile aromatic compound comprising an aromatic ring substituted with at least one hydroxy group or a hydroxy substituted substituent group. Further embodiments of the invention disclose a composite support for an imaging element, which composite support comprises a polymeric film having coated thereon an electrically conductive layer, wherein the electrically conductive layer has been formed by applying a coating of the coating composition of the invention, and drying the coating.Type: GrantFiled: October 31, 1996Date of Patent: January 20, 1998Assignee: Eastman Kodak CompanyInventors: Janglin Chen, Richard A. Castle, Karen E. Gleasman
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Patent number: 5695920Abstract: A coating composition that is useful for the preparation of an auxiliary layer of an imaging element, such as a photographic element, is comprised of an aqueous medium having dispersed therein film-forming polymeric particles and non-film-forming polymeric particles and is characterized in that the film-forming polymeric particles are acid-stable polyurethane particles. These coating compositions have excellent stability characteristics, provide auxiliary layers with improved chemical and physical properties when coated and dried to form a coalesced layer, and provide for reduced emission of volatile organic compounds during the drying process.Type: GrantFiled: April 22, 1996Date of Patent: December 9, 1997Assignee: Eastman Kodak CompanyInventors: Charles Chester Anderson, Brian Andrew Schell, Yongcai Wang
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Patent number: 5674660Abstract: An electrodepositable photoresist composition comprising an aqueous dispersion of: (a) a water-dispersible neutralized cationic polymeric material having a pendant unsaturation, (b) a nonionic unsaturated material and (c) a photoinitiator; characterized in that it can form smooth, thin and pinhole free coatings and further characterized in that the film is capable of being selectively insolubilized by patterned radiation exposure such that the unexposed portion of the film is soluble in dilute aqueous acid and the exposed portion is insoluble in said aqueous acid.Type: GrantFiled: June 30, 1994Date of Patent: October 7, 1997Assignee: PPG Industries, Inc.Inventors: Kurt G. Olson, Michael G. Sandala, Steven R. Zawacky, Charles F. Kahle, II, Masayuki Nakajima