Cupola Patents (Class 48/62R)
  • Patent number: 6048374
    Abstract: The subject invention pertains to unique and advantageous systems for gasifying and/or liquefying biomass. The systems of the subject invention utilize a unique design whereby heat from a combustion chamber is used to directly gasify or liquefy biomass. In a preferred embodiment, the biomass is moved through a reactor tube in which all the gasification and/or liquefaction takes place. Preferably, char exits the biomass reactor tube and enters the combustion chamber where the char serves as fuel for combustion. The combustion chamber partially surrounds the reactor tube and is in direct thermal contact with the reactor tube such that heat from the combustion chamber passes through the reactor wall and directly heats the biomass within the reactor tube.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: April 11, 2000
    Inventor: Alex E. S. Green
  • Patent number: 5976203
    Abstract: A synthesis gas generator with a combustion chamber and quench chamber for generating, cooling and cleaning gases, which are generated by partial oxidation in the combustion chamber of the synthesis gas generator. The combustion chamber (3) and the quench chamber (7) are separate chambers connected by a flow channel (6). Nozzle assemblies (10, 11) with nozzle heads (9, 34), which spray in a quenching medium (8), are arranged in the gas inlet area of the quench chamber (7). The quench zone within the quench chamber (7) is joined by a useful gas-quenching medium-mixing zone. A cone (20) is located at the outlet of the quench chamber. This cone is followed by a water bath (21). The useful gas leaves the synthesis gas generator after deflection by 180.degree. in the rear-side area of the cone (20) via gas outlet openings (23).
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: November 2, 1999
    Assignee: Metallgesellschaft Aktiengellschaft
    Inventors: Wolfgang Deeke, Wolfram Gruhlke, Jurgen Heering, Klaus Kohnen
  • Patent number: 5851497
    Abstract: A gasifier (10) for partially combusting a carbonaceous fuel mixture in the combustion chamber (13) of the gasifier (10). The latter includes a water bath (26) into which the hot effluent or the products of combustion are immersed, including a synthetic gas. The products of combustion are directed into the bath (26) by way of a constricted throat section (31). To avoid excessive erosion action and/or thermal shock to the throat section (31) as a result of exposure to the effluent's high temperatures, the throat section (31) is structured with an internal framework of pipes (32). The flamework (32) is communicated with a pressurized source of a cooling fluid (42), preferably water, whereby to cool the throat section (31) sufficiently to counteract the ill effects of exposure to contact with the high temperature effluent.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: December 22, 1998
    Assignee: Texaco Inc.
    Inventors: Donald Duane Brooker, James Samuel Falsetti, James Kenneth Wolfenbarger, Dinh-Cuong Vuong
  • Patent number: 5803937
    Abstract: A process and system for cooling a dust-laden raw or untreated gas from the gasification of a solid carbon-containing fuel in a pressurized reactor. The gas from the reactor is introduced into a quench pipe that has a cross-sectional area that is smaller than the cross-sectional area of the reactor, and to which is supplied a quenching medium for direct cooling. The gas emerging from the outlet end of the quench pipe is deflected essentially by 180.degree. and, counter to the flow of the gas in the quench pipe, is guided through a cooling section that surrounds the quench pipe and is incorporated in a water-steam circuit.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: September 8, 1998
    Assignee: L. & C. Steinmuller GmbH
    Inventors: Ralf-Uwe Hartermann, Arno Hendricks, Leszek Gawlowski, Hubert Scheid
  • Patent number: 5762657
    Abstract: A pyrolysis gasifier includes a first auger (26) which moves carbon from a carbon collection tank (24) through an air lock valve (30) to a carbon holding tank (28) The gasifier includes an inner cylindrical sleeve (80) which is configured such that there is a small air gap between it and an interior wall of the gasifier (16). The air lock valve (30) includes an inlet member (96) which connects the housing to a connecting tube from the first auger (26). A plate (100) within the housing is mounted such that in a closed position, the plate is sealingly positioned against a lower edge of the inlet member (96), while in an open position, the plate is away from the inlet member, permitting carbon to move into the carbon holding tank. A fuel spreader apparatus 53 is positioned at the top portion of the gasifier. It includes a stirring rod (44) and two opposed fuel paddle assemblies (67, 69) at the lower end thereof to spread the fuel over the cross-sectional area of the gasifier.
    Type: Grant
    Filed: February 4, 1997
    Date of Patent: June 9, 1998
    Assignee: Thermal Technologies, Inc.
    Inventors: Leonard G. Beierle, Leroy Graff, John J. Fitzgerald
  • Patent number: 5755838
    Abstract: A coal gasifier has an inner wall surface made by metal of an inlet part of a heat recovery vessel, the inlet part having a inner cooling mechanism, and gas for peeling deposits on the inner wall surface is injected from plural gas injection holes, the injected gas forming a slewing flow and further being intermittently increased. And at least one cooling medium injection nozzle is provided at a side wall in the upper part of a gasification chamber.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: May 26, 1998
    Assignees: Hitachi, Ltd., Babcock-Hitachi Kabushiki Kaisha
    Inventors: Sinji Tanaka, Shuntaro Koyama, Masato Takagi, Eiji Kida, Fumiki Ueda, Tadayoshi Muramatsu
  • Patent number: 5730763
    Abstract: The invention relates to a process and an apparatus for gasifying liquid and/or fine-grain solid gasification substances and/or for reforming a gas, using a gasification agent, in a reaction (1). In the process the process heat is supplied by heat carrier particles which are heated within a substantially closed circuit in a heater (5) by combustion gases which are produced in a combustion chamber (3), and passed through the reactor (1) in counter-flow relationship with the gasification substance or the gas to be reformed and the gasification agent, and then returned to the heater (5) for renewed heating. In accordance with the invention the particles and the combustion gas form a fluidized bed above at least one grid (34, 34a, 34b, 34c, 34d, 34e) arranged in the heater (5).
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: March 24, 1998
    Assignee: Kortec AG
    Inventors: Mircea Tudor Manulescu, Jean-Paul Vandenhoeck
  • Patent number: 5630853
    Abstract: A coal slagging gasifier has a gasifying vessel over a quenching chamber partly filled with water below the surface of which a wall of a cylindrical, metal shield dips. The gasifying vessel has a hearth including a slag tap having a slag outlet with a lowermost opening at substantially the same horizontal level as an annular burner and a ring-shaped nozzle. The burner which surrounds the outlet is spaced therefrom and inset into a recess surrounding the outlet, and the nozzle surrounds the burner. Outlet ports from the nozzle project through a ceiling of the shield to direct a flow of combustion sustaining gas vertically downwards into the quenching chamber from the outlet ports and towards the water. An opening in the centre of the shield ceiling exposes the interior of the shield to the burner and the slag tap outlet. The burner separately supplies fuel gas and combustion air.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: May 20, 1997
    Assignee: British Gas PLC
    Inventor: David F. Eales
  • Patent number: 5618321
    Abstract: A pyrolysis gasifier includes a first auger (26) which moves carbon from a carbon collection tank (24) through an air lock valve (30) to a carbon holding tank (28). The gasifier includes an inner cylindrical sleeve (80) which is configured such that there is a small air gap between it and an interior wall of the gasifier (16). The air lock valve (30) includes an inlet member (96) which connects the housing to a connecting tube from the first auger (26). A plate (100) within the housing is mounted such that in a closed position, the plate is sealingly positioned against a lower edge of the inlet member (96), while in an open position, the plate is away from the inlet member, permitting carbon to move into the carbon holding tank. A fuel spreader apparatus 53 is positioned at the top portion of the gasifier. It includes a stirring rod (44) and two opposed fuel paddle assemblies (67, 69) at the lower end thereof to spread the fuel over the cross-sectional area of the gasifier.
    Type: Grant
    Filed: September 15, 1994
    Date of Patent: April 8, 1997
    Assignee: Thermal Technologies, Inc.
    Inventors: Leonard G. Beierle, Leroy Graff, John J. Fitzgerald
  • Patent number: 5554202
    Abstract: Method and apparatus for deslagging a gasifier's combustion chamber which has accumulated a residual solidified slag as a result of the fuel being combusted. The gasifier is provided with means for liquefying the slag into a flowable state by heating the combustion chamber to a temperature of which the slag will flow. To epitomize the gasifiers' deslagging mode, the combustion chamber is provided with an array of strain monitoring or measuring load cells which are located to detect and collectively respond to movement at the combustion chamber floor whereby to control the slag removing procedure.
    Type: Grant
    Filed: March 21, 1995
    Date of Patent: September 10, 1996
    Assignee: Texaco Inc.
    Inventors: Donald D. Brooker, James S. Falsetti, James K. Wolfenbarger, Dinh-Cuong Vuong, Allen J. Pertuit
  • Patent number: 5486269
    Abstract: A method and reactor for thermally decomposing a carbonaceous raw material (6) to recover gas and, if applicable, solid or liquid chemicals, the raw material being fed into a chamber (2) for gasification under under-stoichiometric conditions, the gasification is carried out in a gasification zone (15) at a pressure from atmospheric pressure up to about 150 bar and at a temperature within the range 500.degree.-1600.degree. C. According to the invention a part of the thermal energy required to maintain the endothermic reactions in the gasification zone (15) is produced by combustion of a fuel (8) in a combustion zone (16) located close to and in gaseous contact with the gasification zone, the raw material and fuel being supplied through different nozzle channels (12 and 13, respectively). An oxygen-containing gas (17) is supplied in an amount sufficient to oxidize substantially all the fuel.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: January 23, 1996
    Assignee: Chemrec Aktiebolag
    Inventor: Bengt Nilsson
  • Patent number: 5445658
    Abstract: The gasification apparatus for gasification of finely divided combustible material under pressure includes a gasification reactor which produces a crude gas, a quenching pipe and a convection-heated boiler with a boiler housing, all mounted inside a pressurized vessel. A gas flow guiding device is provided above the quenching pipe for conducting a mixed gas flow containing the crude gas and a quenching gas from the quenching pipe into the convection-heated boiler which surrounds the quenching pipe concentrically. A gas outlet device is provided for the gas flow from the convection-heated boiler and from the pressurized vessel. The gasification reactor is supported at its bottom end in the pressurized vessel at anchoring points. The convection-heated surface elements of the convection-heated boiler are supported by the quenching pipe and the boiler housing but in a stress-free manner.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: August 29, 1995
    Assignee: Krupp Koppers GmbH
    Inventors: Rainer Durrfeld, Johannes Kowoll, Eberhard Kuske, Hans Niermann, Gerhard Wilmer, Joachim Wolff
  • Patent number: 5437699
    Abstract: The slag tap of a gasifier is offset from the geometrical axis. Coalescent, molten, residual ash from incomplete combustion is directed to a hearth where residence time provides further combustion and a reduction in the volume and temperature of the resulting slag. The reduced volume and temperature ash is then directed to a slag tap after which disposal is accomplished by conventional means.
    Type: Grant
    Filed: October 19, 1990
    Date of Patent: August 1, 1995
    Inventor: Charles V. Sternling
  • Patent number: 5407455
    Abstract: A reactor for gasification of cellulose-waste liquors, especially black liquor. The reactor includes a reactor cladding a supply for liquor and combustion air in the upper part of the reactor, an outlet opening for gases and other material in the lower part, and a heat-insulating lining at the cladding and bottom part. The lining is arranged at a distance from the surrounding wall, thereby forming a gap for gas or air having a pressure exceeding that in the hearth of the reactor.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: April 18, 1995
    Assignee: Chemrec AB
    Inventor: Bengt Nilsson
  • Patent number: 5310411
    Abstract: The process and apparatus for transforming combustible pollutants and waste materials into non-polluting, clean and useful energy, by completely removing the pollutants from raw materials while avoiding the formation of potential pollutants, involve the use of oxygen or a gas mixture containing oxygen, such as air, and steam.
    Type: Grant
    Filed: January 18, 1990
    Date of Patent: May 10, 1994
    Inventor: Valerio Tognazzo
  • Patent number: 5230716
    Abstract: A grate assembly for a coal gasifier of a moving-bed or fixed-bed type is provided for crushing agglomerates of solid material such as clinkers, tailoring the radial distribution of reactant gases entering the gasification reaction zone, and control of the radial distribution of downwardly moving solid velocities in the gasification and combustion zone. The clinker crushing is provided by pinching clinkers between vertically oriented stationary bars and angled bars supported on the upper surface of a rotating conical grate. The distribution of the reactant gases is provided by the selective positioning of horizontally oriented passageways extending through the grate. The radial distribution of the solids is provided by mounting a vertically and generally radially extending scoop mechanism on the upper surface of the grate near the apex thereof.
    Type: Grant
    Filed: July 14, 1992
    Date of Patent: July 27, 1993
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: John E. Notestein
  • Patent number: 5154732
    Abstract: A method and apparatus for gasifying or combusting solid, carbonaceous material a circulating fluidized bed reactor. Particles are separated from the product gas at least in two stages so that in the first stage, mainly coarser, so-called circulating particles are separted and returned to the reactor. In the second stage, fine carbonaceous particulates are separated from the gas and are made to agglomerate at a raised temperature. Coarser particles thus received are returned to the reactor through a return duct together with circulating particles. Adhesion of agglomerating particles to the walls of the duct is prevented preferably by leading hot particulates to the center of the duct and circulating particles to the walls of the duct.
    Type: Grant
    Filed: January 11, 1990
    Date of Patent: October 13, 1992
    Assignee: A. Ahlstrom Corporation
    Inventors: Bertel K. Hakulin, Jorma J. Nieminen
  • Patent number: 5136808
    Abstract: A gasifier for the gasification of a fuel material includes a chamber in which the material is converted into a gas and a molten slag. A quenching apparatus is provided for cooling and solidifying the molten slag. A nozzle extends between the chamber and the quenching apparatus. The nozzle includes an orifice having an inlet end for receiving the molten slag from the chamber and an outlet end for discharging the molten slag into the quenching apparatus. A recessed zone is provided between the outlet end of the orifice and the quenching apparatus. The recessed zone may be formed within the nozzle. An electric induction heating coil provides heat in the recessed zone to prevent the solidification of the slag at the outlet end of the orifice.
    Type: Grant
    Filed: May 10, 1990
    Date of Patent: August 11, 1992
    Inventor: Albert Calderon
  • Patent number: 5127772
    Abstract: The suspension density and mass flow rate of a particular solids and gas mixture transported to a reactor is controlled by using a radiation source and detector. The suspension density is measured and compared to a preselected value. The result is converted to a control signal which may be used to control venting from the vessel, and/or the amount of aeration gas supplied to the lower portion of the vessel, in order to maintain the suspension density at the preselected value and provide a constant mass flow rate.
    Type: Grant
    Filed: September 18, 1987
    Date of Patent: July 7, 1992
    Assignee: Shell Oil Company
    Inventor: Thomas S. Dewitz
  • Patent number: 5059404
    Abstract: Resonant tubes of a pulse combustor are immersed in a bed of solid particles in a reaction zone to provide indirect heat from the pulsating combustion gases to the solid particles of the bed. The bed is maintained in an agitated state by a gas or vapor flowing through the bed. Reactant materials are introduced into the agitated bed and undergo reaction at enhanced rates resulting from heat transfer coefficients at least about twice as high as those of steady flow combustors and an intense acoustic pressure level propagated from the pulsating combustor into the reaction zone. The apparatus is useful, for example, to steam reform heavy hydrocarbons and to gasify carbonaceous material, including biomass and black liquor to produce combustible gas at relatively low temperatures, with steam being usilized as the bed fluidizing medium. Black liquor gasification, utilizing sodium carbonate as bed solids, results in liquor energy and chemical content recovery without smelt production.
    Type: Grant
    Filed: February 14, 1989
    Date of Patent: October 22, 1991
    Assignee: Manufacturing and Technology Conversion International, Inc.
    Inventors: Momtaz N. Mansour, Kanda-Swamy Durai-Swamy, David W. Warren
  • Patent number: 5011507
    Abstract: The present process is directed to the cooling and cleaning of hot crude synthesis gas leaving a gas generator (solid hydrocarbon gasification reactor) wherein the hot crude synthesis gas leaving the top of the gas generator in an upflow direction is quenched by injection of cold purified synthesis gas. The gas velocity is then reduced and the gas stream is reversed in a downflow direction whereupon the gas velocity is increased again. The gas stream is again reversed in an upflow direction and the gas velocity is decreased whereafter the gas is indirectly cooled and flyash being separated therefrom.
    Type: Grant
    Filed: June 16, 1990
    Date of Patent: April 30, 1991
    Assignee: Shell Oil Company
    Inventors: Jacob H. Stil, Adrianus J. Ooms, Bernardus H. Mink
  • Patent number: 4979964
    Abstract: The slag tap of a gasifier is offset from the geometrical axis. Coalescent, molten, residual ash from incomplete combustion is directed to a hearth where residence time provides further combustion and a reduction in the volume and temperature of the resulting slag. The reduced volume and temperature ash is then directed to a slag tap after which disposal is accomplished by conventional means.
    Type: Grant
    Filed: June 22, 1989
    Date of Patent: December 25, 1990
    Assignee: Shell Oil Company
    Inventor: Charles V. Sternling
  • Patent number: 4960439
    Abstract: An arrangement for the gasification of fuels with oxygen or oxygen-containing gases and steam, includes a shaft-like vessel for receiving solid charging stock. A gas discharge duct is provided on the upper end of the vessel and a primary gas chamber is in connection with the shaft-like vessel on its lower end via a passage. In the primary gas chamber a burner is provided, which includes feedings for oxygen or oxygen-containing gases as well as for fuels. A trough for receiving slag is arranged below. the primary gas chamber and a supporting bottoms is provided between the trough and the shaft-like vessel, reaching into the primary gas chamber, for the formation of a dumping material bed of the solid charging stock facing the burner by one dumping surface. In order to be able to gasify low-quality fuels into a high-quality product gas, the primary gas chamber includes a charging opening for charging a charging stock to be gasified.
    Type: Grant
    Filed: August 12, 1988
    Date of Patent: October 2, 1990
    Assignee: Voest-Alpine Aktiengesellschaft
    Inventors: Paul Freimann, Gernot Staudinger
  • Patent number: 4950308
    Abstract: The apparatus for producing a product gas from a fine-grained carbon-bearing substance during a high-pressure gasification comprises a vertical gasifier and radiative cooling device, a vertical convective cooling device through which a flow occurs from top to bottom and a connecting pipe between a head of the gasifier and radiative cooling device and a head of the convective cooling device. The gasifier and radiative cooling device comprises a pipe-like shaft, a lower cinder outlet and an upper conical connecting piece for the connecting pipe. The shaft is constructed as an equal speed flow duct, which is not equipped for feeding a foreign cooling means, but is designed so that solidification of the accompanying cinders travelling with the product gas occurs by radiative cooling.
    Type: Grant
    Filed: July 13, 1989
    Date of Patent: August 21, 1990
    Assignee: Krupp Koppers GmbH
    Inventors: Michael Lang, Gerhard Wilmer, Michael Kuhn
  • Patent number: 4948387
    Abstract: This invention relates to a combination comprising two vertical cylindrical shaped high temperature pressure vessels coaxially connected. The upper vessel is a refractory lined free-flow partial oxidation gas generator for the production of gaseous mixtures comprising H.sub.2 +CO from liquid hydrocarbonaceous and solid carbonaceous fuels. The lower vessel houses a radiation gas cooler for cooling the raw gas stream which is produced in the upper vessel and which passes down through a coaxial vertical cylindrical annular shaped refractory throat located between said upper and lower vessels. A vertical steel cylindrical gas barrier provided with a flanged bottom surrounds the refractory throat passage so that substantially no gas escapes into a stagnant annular zone outside of said gas barrier. Further the refractory throat is vertically supported by said flanged gas barrier.
    Type: Grant
    Filed: November 24, 1989
    Date of Patent: August 14, 1990
    Assignee: Texaco Inc.
    Inventors: Michael C. Martin, Erwin A. Reich
  • Patent number: 4919687
    Abstract: In a process and apparatus for the production of gas containing hydrogen and carbon monoxide from a solid fuel in a fluidized bed, the solid particles contained in the product gas are separated off in a cyclone separator and recycled to the fluidized bed by way of a recycling conduit. The recycling conduit is provided with injection nozzles for introducing gas flows into the recycling conduit in a pulse-like manner in order to loosen up the particles therein. The gas flows may be introduced into the recycling conduit in displaced relationship in respect of time in such a way that, of two adjacent injection locations, gas is injected through the injection location which is arranged at a greater spacing from the reactor at a later time than at the injector location which is closer to the reactor.
    Type: Grant
    Filed: May 17, 1989
    Date of Patent: April 24, 1990
    Assignee: Rheinische Braunkohlenwerke A.G.
    Inventors: Johannes Lambertz, Wolfgang H. Adlhoch, Alfred G. Mittelstadt, Wolfgang Hermann
  • Patent number: 4799937
    Abstract: A method of and apparatus for gasifying carbonaceous material in a circulating fluidized bed reactor having a lower reactor chamber and an upper reactor chamber interconnected by a throttled throat portion. Carbonaceous material is supplied to a first fluidized bed gasification zone maintained in the lower chamber and is gasified there by a gasifying agent and recycled hot particles separated from the product gas. The effluent from the first gasification zone is passed upwardly through the throttled throat portion to a second fluidized bed gasification zone of the spouting-bed type maintained in the upper chamber to complete gasification of unconverted carbon remaining in the particles entrained in the gaseous effluent from the first zone at a higher temperature than that of the first zone.
    Type: Grant
    Filed: September 22, 1987
    Date of Patent: January 24, 1989
    Assignee: A. Ahlstrom Corp.
    Inventor: Jorma J. Nieminen
  • Patent number: 4664678
    Abstract: An apparatus and process for control and maintenance of fluidized beds under non-steady state conditions. An ash removal conduit is provided for removing solid particulates from a fluidized bed separate from an ash discharge conduit in the lower portion of the grate supporting such a bed. The apparatus and process of this invention is particularly suitable for use in ash agglomerating fluidized beds and provides control of the fluidized bed before ash agglomeration is initiated and during upset conditions resulting in stable, sinter-free fluidized bed maintenance.
    Type: Grant
    Filed: September 17, 1985
    Date of Patent: May 12, 1987
    Assignee: Institute of Gas Technology
    Inventors: Amirali G. Rehmat, Jitendra G. Patel
  • Patent number: 4652430
    Abstract: An apparatus for the multi-stage refining of organic bulk materials according to the fluidized bed principle comprising a plurality of horizontally aligned cells (23) including an upper drying chamber (1), a middle degasification chamber (2) and a lower refining chamber (3) separated from each other by an individual gas permeable floor (19) or a gas impermeable floor (20). Adjacent cells are connected to each other by common discharge/charge chutes having vertical separation walls extending therein.
    Type: Grant
    Filed: September 26, 1984
    Date of Patent: March 24, 1987
    Assignee: VEB Schwermaschinenbau "Karl Liebknecht" Magdeburg
    Inventors: Wolfgang Michel, Heinz Paul, Dieter Kostler, Frank Wilhelm, Andreas Rummel, Gero Seher, Wilfried Henze, Ralf Hander, Jurgen Heinemann, Manfred Ossowski
  • Patent number: 4555249
    Abstract: A solid fuel gasifying unit is used to convert coal and other combustible organic solids to gaseous end products. Solid feed enters the vertical preheat zone of S-shaped gasifying unit and is mixed with a hot recycle reagent such as clay. The solid material fills the preheating zone of the unit to an elevation sufficient to create a gravitational particle flow which forces the solid particles in the lower end of the zone into the bottom of a vertical gasifying zone and through the remaining sections of the unit. In the gasifying zone, a fluidizing gaseous stream such as carbon dioxide or steam is injected to enhance the flow of the solid particles.Also disclosed is a gas fractionating unit and a relatively high pressure solid fuel gasifying unit which contain a reagent powder having a significant weight difference in reduced form as compared with the weight of the powder in oxidized form and which may be circulated through the unit under gravity flow during oxidation-reduction chemical processing.
    Type: Grant
    Filed: December 16, 1983
    Date of Patent: November 26, 1985
    Inventor: Arnold M. Leas
  • Patent number: 4553981
    Abstract: Effluent gas streams for steam reforming, partial oxidation or coal gasification operations are advantageously treated in shift conversion, scrubbing and pressure swing adsorption units for recovery of a purified, hydrogen-containing product gas stream. By recycling a portion of the waste gas removed from the pressure swing adsorption system to the shift conversion unit and/or to the effluent gas generation operation, enhanced product recovery is achieved without the necessity for employing low temperature shift or for achieving essentially complete removal of the carbon dioxide content of the gas being treated prior to its passage to said pressure swing adsorption system.
    Type: Grant
    Filed: February 7, 1984
    Date of Patent: November 19, 1985
    Assignee: Union Carbide Corporation
    Inventor: Andrija Fuderer
  • Patent number: 4511450
    Abstract: A passive hydrogen oxygen generator in which the long wavelength infrared portion of the sun's spectrum heats water to provide circulation of the water within the generator. The shorter wavelength portion of the spectrum to which water is transparent is used in splitting water into hydrogen and oxygen by photoelectrolysis.
    Type: Grant
    Filed: March 5, 1984
    Date of Patent: April 16, 1985
    Inventor: Charles W. Neefe
  • Patent number: 4490157
    Abstract: A fluidized bed gasifier (10) for gasifying a first fuel (50) receives heat indirectly from a combusting fluidized bed (24) disposed at least partially within the gasifier fluidized bed (12). Fuel for the combusting bed (24) may be provided by removing a portion of the fluidized first fuel from the gasifier bed (12) and transporting (30,34) this removed portion into the combusting bed (12). Heat is transferred across the conductive walls of the combustor vessel (26). Product gas heating value is increased by separately removing (28) the products of combustion from the gasifier (10) and by recycling a portion of the product fuel gas (74) as the fluidizing gas (54) for the gasifier fluidized bed (12). A radiation shield (18) is also provided to reduce heat loss from the gasifier bed (12) and to remove elutriated material from the product fuel gas.
    Type: Grant
    Filed: January 10, 1983
    Date of Patent: December 25, 1984
    Assignee: Combustion Engineering, Inc.
    Inventor: John H. Fernandes
  • Patent number: 4487612
    Abstract: A slagging gasifier has a hearth comprising an annular solid cast structure formed from a high thermal conductivity metal such as copper and shaped to fit above a slag tap of the gasifier. The hearth is provided with one or more integrally formed passageways for circulating a coolant liquid therethrough and has an upper tundish surface with a slope of at least 10.degree. to the horizontal (preferably between 25.degree. and 45.degree.), across which tundish surface the molten slag flows downwardly and inwardly towards to slag tap. The annular structure may be formed from at least three sector-shaped cast parts secured together in situ in the gasifier.
    Type: Grant
    Filed: August 19, 1982
    Date of Patent: December 11, 1984
    Assignee: British Gas Corporation
    Inventors: Dennis Hebden, Charles T. Brooks
  • Patent number: 4473534
    Abstract: A high temperature (1000.degree. C. or higher) gas distributor for a fluidized bed, comprising a plurality of plates which are made of an oxide-based burned refractory material and which are reduced in thickness in the longitudinal direction thereof leaving both sides thicker, refractory supporting bricks holding in position both sides of the plates, and refractory holding bricks holding in position the above refractory supporting bricks and the ends of the plates.
    Type: Grant
    Filed: November 22, 1982
    Date of Patent: September 25, 1984
    Assignee: Director-General, Agency of Industrial Science and Technology
    Inventors: Kazuo Tanaami, Nobuo Matsuda
  • Patent number: 4472171
    Abstract: Method and/or system for removing liquid slag from a pressurized gasifier. Hot liquid slag is quenched in a quenching medium such as water. The quenched and solidified slag is crushed to a maximum particle size. The crushed slag and quenching medium are alternatively connected to opposite ends of a floating piston while the other end is connected to an outlet for disposal of the slag. The crushed slag and quenching medium are subjected to the gasifier pressure so that the piston acts to forceably eject the mixture through the outlet.
    Type: Grant
    Filed: May 31, 1983
    Date of Patent: September 18, 1984
    Assignee: Texaco Development Corporation
    Inventor: James E. Broderick
  • Patent number: 4459133
    Abstract: A sulfur-containing fuel is passed into a first fluidized bed (13) containing CaSO.sub.4 and CaO and an oxygen-transfer mediator (e.g. H.sub.2) whereby the fuel is converted to combustible gas (18), some CaSO.sub.4 being reduced to CaS and sulfur being fixed as CaS by reaction with CaO. Bed particles pass from the bottom layer of the first bed (13) into the bottom layer of the second bed (14) which is fluidized by air at conditions such that some, but not all of the CaS is selectively oxidized to CaSO.sub.4 with no liberation of sulfur moieties. Bed particles pass from the bottom layer of the second bed (14) to the bottom layer of a third bed (15) optionally after passage via a fourth bed (60, FIG. 2) between the second and third beds. In the third bed (15), particles are fluidized with air to convert CaS selectively to CaSO.sub.
    Type: Grant
    Filed: March 22, 1982
    Date of Patent: July 10, 1984
    Assignee: Exxon Research and Engineering Co.
    Inventor: Gerald Moss
  • Patent number: 4457764
    Abstract: A flue-stream reactor for gasifying fossil fuels which contain ballast. The reactor comprises two cylindrical, cooled, and insulated reaction chambers which are disposed one after the other in the axial direction. The first reaction chamber is provided with an axial inlet for accommodating a gasification burner. The second reaction chamber is provided with an opening for the addition of gasification material. A cooled, coaxial channel provides communication between the two reaction chambers. The reactor further includes a radial discharge and a device for removing liquid and solid ash and slag.
    Type: Grant
    Filed: February 9, 1983
    Date of Patent: July 3, 1984
    Assignee: L & C Steinmuller GmbH
    Inventors: Rolf Dorling, Ulrich Premel
  • Patent number: 4455153
    Abstract: Processes and apparatus for storing solar energy in synthetic fuels are disclosed. The disclosed processes include the steps of introducing steam and carbonaceous material such as coal, lignite, peat, solid organic wastes, or heavy oils into a molten gasification medium such as one or more molten salts and supplying sufficient solar heat to the gasification medium to maintain it in the molten state at a temperature at which the carbonaceous material and steam react to produce a synthesis gas product including a synthetic fuel gas or gases. Disclosed processes include the step of adding solar absorptivity enhancing dopant material to the gasification medium. Disclosed processes include the step of supplying solar heat to the gasification medium by directing concentrated solar radiation onto the gasification medium, rather than directing the solar radiation onto a separate body of material for indirectly heating the gasification medium.
    Type: Grant
    Filed: September 4, 1979
    Date of Patent: June 19, 1984
    Inventor: Douglas Y. Jakahi
  • Patent number: 4437864
    Abstract: A plant for the gasification of fossil fuels which includes a reactor container and a further plant component attachable to the reactor container. The reactor container has a discharge opening and includes a connection part extending outwardly from the discharge opening. A fireproof lining, which determines the inner cross-sectional area of the container, is provided within the container. An intermediate ring is interposed between the connecting part of the reactor container and the further plant component for attaching the connecting part to the further plant component. This intermediate ring is provided with a fireproof lining having an area of reduced inner cross-section which is less than the inner cross-sectional area of the fireproof lining of the reactor container, the area of reduced cross-section being the smallest cross-sectional area in the connection between the reactor container and the further plant component.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: March 20, 1984
    Assignees: Karrena GmbH, Ruhrchemi AG, Ruhrkohle AG
    Inventors: Rainer Gorris, Josef Hibbel, Ulrich Gerhardus, Heinrich Scheve
  • Patent number: 4415339
    Abstract: Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char.
    Type: Grant
    Filed: April 6, 1981
    Date of Patent: November 15, 1983
    Assignee: The United States of America as represented by the Department of Energy
    Inventors: William R. Aiman, David W. Gregg
  • Patent number: 4405339
    Abstract: A fluidized bed apparatus and a process for the gasification of combustible materials such as biomass heavy hydrocarbon oils and coal. Two or more separate reaction zones connected in series as a closed loop are formed within a tubular housing, through which a bed of particulate heat transfer medium such as sand continuously and successively recirculates while being maintained in the fluidized state. One of the reaction zones serves as a cracking zone for the combustible material and another one of the reaction zones serves as a heat-up zone for thermally regenerating the heat transfer medium by partial or complete combustion of char produced in the cracking zone.
    Type: Grant
    Filed: July 30, 1981
    Date of Patent: September 20, 1983
    Assignee: Mittetu Chemical Engineering, Ltd.
    Inventor: Daizo Kunii
  • Patent number: 4400181
    Abstract: Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature.
    Type: Grant
    Filed: January 28, 1982
    Date of Patent: August 23, 1983
    Assignee: Hydrocarbon Research, Inc.
    Inventors: George J. Snell, Paul H. Kydd
  • Patent number: 4385905
    Abstract: A system is disclosed for the conversion of solid carbonaceous fuels to combustible gases having a high energy content. The system utilizes a two-stage reaction system where a particulate fuel is entrained in a high velocity, hot gas stream emanating from a fixed-bed char reactor, the particulate fuel delivered to a gasification reactor by the hot gas stream while being rapidly heated (fast pyrolized). The gases produced are drawn a fixed distance through a bed of char at the bottom of the gasification reactor, after which they are withdrawn from the reactor and cooled. To promote methanation, the generated gases, after passing through the fixed bed of char in the gasification reactor, exit the reactor through a dip leg within the reactor filled with a catalyst which promotes methanation.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: May 31, 1983
    Assignee: Everett Metal Products, Inc.
    Inventor: Gordon H. Tucker
  • Patent number: 4377394
    Abstract: An apparatus in which a downflowing high pressure stream of hot raw synthesis gas from the reaction zone of a free flow partial oxidation gas generator at a temperature in the range of about 1800.degree. to 3000.degree. F. is passed through a first gas diversion and residue separation chamber contained in a first pressure vessel where the velocity of the gas stream is reduced, solid material and molten slag are separated by gravity from the gas stream, and the direction is diverted into a thermally insulated side transfer line. The hot gas stream is then passed through a thermally insulated gas-solids impingement separation means contained in a second pressure vessel where its direction and velocity is changed and additional residue is separated. The hot gas stream is then passed upwardly through a radiant cooler where additional solid matter is removed by gravity and the gas temperature is reduced to a temperature in the range of about 900.degree. to 1800.degree. F.
    Type: Grant
    Filed: July 28, 1980
    Date of Patent: March 22, 1983
    Assignee: Texaco Development Corporation
    Inventors: James R. Muenger, Edward T. Child, Albert Brent
  • Patent number: 4359326
    Abstract: A process and pressurized, gasification reactor apparatus for converting combustible carbon containing materials such as coal char and other carbonaceous solids or carbonaceous solids/heavy oil combinations to an intermediate heating value fuel gas. The gasification reactor includes an insulated fluidized bed reactor chamber, an upper reactor housing for a freely suspended bayonet bundle type heat exchanger for (a) superheating incoming saturated steam and (b) cooling outgoing high temperature product gas, and a lower reactor housing structure which includes a free-floating, conically-shaped perforated plenum chamber. The superheated steam and oxygen are premixed with the plenum chamber before being pressure directed into the fluidized bed reactor chamber for mixture and combustion with the incoming combustible carbon containing materials such as coal char. After reaction of the superheated steam, oxygen and coal char in the fluidized bed reactor at temperatures ranging from 900.degree. F. to 1750.degree. F.
    Type: Grant
    Filed: November 20, 1980
    Date of Patent: November 16, 1982
    Assignee: Hydrocarbon Research, Inc.
    Inventors: Franklin D. Hoffert, John D. Milligan, Jose M. Marina, Jose M. Fernandez
  • Patent number: 4343625
    Abstract: A high temperature solids gasification generator which employs finely divided solids, e.g. powdered coal, has a down flow and discharges into a plenum chamber below the generator. The plenum chamber has a restricted outlet at the bottom so that a pool of liquid slag will form, and there is a lateral outlet above the slag pool for effluent gas. The lateral outlet has its throat located offset farther from the axis of the plenum chamber than the inside radius of the chamber.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: August 10, 1982
    Assignee: Texaco Inc.
    Inventor: Walter C. Gates, Jr.
  • Patent number: 4328006
    Abstract: An apparatus in which the hot raw synthesis gas stream leaving the reaction zone of a free flow partial oxidation gas generator at a temperature in the range of about 1800.degree. to 3000.degree. F. is passed through a first gas diversion and residue separation zone where the velocity of the gas stream is reduced and its direction is diverted into a side transfer line. Solid material and molten slag separate by gravity from the gas stream. The hot gas stream is then introduced into a second gas diversion and residue separation zone, which comprises a plurality of high temperature resistant, thermally insulated cyclones, where the direction and velocity is changed and additional residue is separated. About 0.5 to 20 vol. % of the hot gas stream may be passed through bottom outlets in said first and second gas diversion zones in order to prevent bridging.
    Type: Grant
    Filed: July 10, 1980
    Date of Patent: May 4, 1982
    Assignee: Texaco Development Corporation
    Inventors: James R. Muenger, Edward T. Child, Albert Brent
  • Patent number: 4324563
    Abstract: A hot raw gas stream, as produced by the partial oxidation of a solid carbonaceous fuel such as coal, is partially cooled and cleaned to remove entrained solid matter and slag. A novel gas--gas quench cooling and solids separation apparatus is employed. The apparatus comprises a closed cylindrical insulated vertical pressure vessel containing a lower quench chamber in communication with an upper solids separation chamber. The hot raw gas stream is cooled in the lower chamber to a temperature below the initial deformation temperature of the entrained slag by impingement and direct heat exchange with an oppositely directed coaxial stream of cooled, cleaned, and compressed recycle quench gas. The stream of cooled gas leaving the turbulent lower chamber passes up through a choke-ring into the comparatively calmer upper chamber counter-currently with solid slag droplets which separate out by gravity.
    Type: Grant
    Filed: July 13, 1979
    Date of Patent: April 13, 1982
    Assignee: Texaco Inc.
    Inventors: Henry B. Jones, Randlow Smith
  • Patent number: 4306506
    Abstract: Apparatus for the conversion of solid fuels and solid organic waste materials by high temperature gasification into gaseous fuel called "producer gas." The apparatus comprises a stacked two-section gasifier defining sequentially descending drying, distillation, oxidation and reduction reaction zones through which a column of the solid fuel descends during its conversion to the gaseous fuel. The lower reactor section is of double-shell construction and defines the lower oxidation and reduction reaction zones. Means are provided for drawing air into the oxidation zone for burning reaction with carbonized fuel passing therethrough and for thereafter drawing reaction gases downwardly through the lower reduction zone of the gasifier and then through the annular space defined by the double-shell structure of the lower section in indirect counter-current heat exchange relationship with the fuel column portion in the oxidation and reduction zones.
    Type: Grant
    Filed: June 2, 1980
    Date of Patent: December 22, 1981
    Assignee: Energy Recovery Research Group, Inc.
    Inventor: Franz Rotter