From Ketone-containing Phenolic Reactant Or With Ketone-containing Reactant Patents (Class 528/125)

Application number: 20130112409
Abstract: The invention pertains to improved proppant particles comprising an aromatic polycondensation polymer having a glass transition temperature (Tg) of at least 120° C. when measured according to ASTM 3418 [polymer (P)] and a method of treating a subterranean formation using said proppant particles.
Type: Application
Filed: November 2, 2012
Issued: May 9, 2013
Assignee: SOLVAY SPECIALTY POLYMERS USA, LLC
Inventor: SOLVAY SPECIALTY POLYMERS USA, LLC
Patent number: 8436106
Abstract: Cross-linkers and polymers produced using them are provided. The cross-linked polymers are suitable for use in applications where a broad temperature range may be encountered. In some examples, at least a first and a second polyetheretherketone chain may be cross-linked to each other through two or more Schiff base linkages. Articles using the cross-linked polymers are also described.
Type: Grant
Filed: July 24, 2008
Issued: May 7, 2013
Assignee: Schlumberger Technology Corporation
Inventors: Huilin Tu, Agathe Robisson
Patent number: 8431676
Abstract: The invention described herein relates to a polyarylene copolymer comprising a structural unit represented by formula (1?): where the structural variables are defined herein. The invention also relates to a solid polymer electrolyte, a proton conductive membrane and A proton conductive membrane for direct methanol fuel cell which contains the polyarylene copolymer.
Type: Grant
Filed: April 24, 2007
Issued: April 30, 2013
Assignee: JSR Corporation
Inventors: Yoshitaka Yamakawa, Yousuke Konno, Teruhiko Umehara
Application number: 20130102754
Abstract: The invention provides novel flame-retardant polymers and materials, their synthesis and use. More particularly, the flame-retardant polymers are deoxybenzoin-derived polymers.
Type: Application
Filed: October 18, 2012
Issued: April 25, 2013
Assignee: University of Massachusetts
Inventor: University of Massachusetts
Patent number: 8420767
Abstract: Disclosed herein is a polyarylene-based polymer, a preparation method for the same, and a polymer electrolyte membrane for fuel cell using the polymer. The polyarylene-based polymer, which is designed to have long side chains of a hydrophilic moiety and dense sulfonic acid groups, may improve the formation of ion channels when fabricating a polymer membrane and also ensures good chemical stability of the hydrophilic moiety and good dimensional stability against water. Further, the preparation method of the present invention simplifies production of the polymer, and polymer electrolyte membranes using the polymer exhibits improved properties as a polymer electrolyte membrane for a fuel cell, such as high proton conductivity, even under an atmosphere of low water uptake, and good dimensional stability against a long-term exposure to water.
Type: Grant
Filed: December 9, 2011
Issued: April 16, 2013
Assignee: Hyundai Motor Company
Inventors: Inchul Hwang, Nak Hyun Kwon, Young Taek Kim, Dong Il Kim, Ju Ho Lee, Jang-Bae Son
Patent number: 8394910
Abstract: A method of making a polymeric material is described, the method comprising contacting, for example polycondensing, a compound of formula with a compound of formula wherein each X is selected from a group comprising a chlorine and a fluorine atom, n represents 1, 2 or 3 and each Y1 is selected from a group comprising an alkali metal and a hydrogen atom.
Type: Grant
Filed: May 26, 2006
Issued: March 12, 2013
Assignee: Victrex Manufacturing Limited
Inventors: Brian Wilson, John Kevin Prescott, Graham Robert Webster
Patent number: 8383756
Abstract: A composition of matter for the recording medium of nanometer scale thermo-mechanical information storage devices and a nanometer scale thermo-mechanical information storage device. The composition includes: one or more polyaryletherketone copolymers, each of the one or more polyaryletherketone copolymers comprising (a) a first monomer including an aryl ether ketone and (b) a second monomer including an aryl ether ketone and a first phenylethynyl moiety, each of the one or more polyaryletherketone copolymers having two terminal ends, each terminal end having a phenylethynyl moiety the same as or different from the first phenylethynyl moiety. The one or more polyaryletherketone copolymers are thermally cured and the resulting cross-linked polyaryletherketone resin used as the recording layer in an atomic force data storage device.
Type: Grant
Filed: March 19, 2008
Issued: February 26, 2013
Assignee: International Business Machines Corporation
Inventors: Richard Anthony DiPietro, Urs T. Duerig, Jane Elizabeth Frommer, Bernd Walter Gotsmann, Erik Christopher Hagberg, James Lupton Hedrick, Armin W. Knoll, Teddie Peregrino Magbitang, Robert Dennis Miller, Russell Clayton Pratt, Charles Gordon Wade
Patent number: 8378054
Abstract: A process for preparing polyaryl ethers in which a polycondensation of the monomer building blocks is carried out using microwave irradiation leads to thermoplastic molding compositions having improved color properties.
Type: Grant
Filed: November 11, 2008
Issued: February 19, 2013
Assignee: BASF SE
Inventors: Martin Weber, Volker Warzelhan, Faissal-Ali El-Toufaili, Andreas Greiner, Heiner Stange, Seema Agrarwal
Patent number: 8372941
Abstract: A method for the purification of aromatic polyether polymers prepared by a halide displacement polymerization process comprises adsorbing the catalyst with an alkali metal halide to form an adsorbent component and then removing the adsorbent component. Mixtures resulting from this method are also discussed.
Type: Grant
Filed: December 21, 2007
Issued: February 12, 2013
Assignee: Sabic Innovative Plastics IP B.V.
Inventors: Beatriz Penalver Bernabe, Thomas Guggenheim, David Bruce Hall, Norman Johnson, Juan Justino Rodriguez Ordonez, David Woodruff
Patent number: 8373287
Abstract: A polymeric composition comprising a first polymer chosen from a poly(arylene ether) polymer including polymer repeat units of the following structure: —(O—Ar1—O—Ar2—O—)m—(—O—Ar3—O—Ar4—O)n- where Ar1, Ar2, Ar3, and Ar4 are identical or different aryl radicals, m is 0 to 1, n is 1 m; a polysulfone, a polyimide, a poly(etherketone), a polyurea, a polyurethane, and combinations thereof and a second polymer comprising a per(phenylethynyl) arene polymer derivative. Cured films containing the polymer can exhibit at least one of the following properties: Tg from 160° C. to 180° C., a dielectric constant below 2.7 with frequency independence, and a maximum moisture absorption of less than 0.17 wt %. Accordingly, the polymer is especially useful, for example, in interlayer dielectrics and in die-attach adhesives.
Type: Grant
Filed: August 10, 2009
Issued: February 12, 2013
Assignee: Greene, Tweed IP, Inc.
Inventors: William Franklin Burgoyne, Jr., Mark David Conner, Andrew Francis Nordquist, William Steven Collins
Application number: 20130030116
Abstract: Provided is a film comprising a polymer that comprises a structural unit represented by the following formula (1), wherein at least part of the terminal structure of the polymer is at least one structure selected from the group consisting of structural units represented by the following formula (2) and structural units represented by the following formula (3).
Type: Application
Filed: April 20, 2011
Issued: January 31, 2013
Assignee: JSR Corporation
Inventors: Motoki Okaniwa, Takaaki Uno, Takashi Okada
Patent number: 8357769
Abstract: Disclosed is a method for producing a polyphenylene ether, which comprises a step of preparing a polymerization solution composed of 10-25 parts by mass of a phenolic compound (M) and 75-90 parts by mass of an aromatic solvent (A) with the total of the compound and the solvent being 100 parts by mass, and 0.1-10 parts by mass of a catalyst (C) containing a metal salt; a step of performing an oxidative polymerization of the phenolic compound (M) by passing an oxygen-containing gas through the polymerization solution; a step of stopping the polymerization by mixing an aqueous chelating agent solution into the polymerization solution; a step of subjecting a diphenoquinone compound produced as a by-product to a quinone binding process or removal by reduction; and a step of obtaining a polyphenylene ether by separating the aqueous phase through liquid-liquid separation. In the method for producing a polyphenylene ether, 0.001-0.
Type: Grant
Filed: April 16, 2009
Issued: January 22, 2013
Assignee: Asahi Kasei Chemicals Corporation
Inventors: Mutsumi Maeda, Hiroaki Furukawa
Patent number: 8349994
Abstract: Disclosed is an electrode electrolyte for solid polymer fuel cells, which uses a polymer electrolyte containing a polyarylene copolymer containing a nitrogen-containing aromatic ring having a substituent represented by —SO3H, —(O(CH2)hSO3H or —O(CF2)hSO3H (wherein h represents an integer of 1-12). By having such a constitution, the electrode electrolyte for solid polymer fuel cells can be produced at a low cost, while being excellent in proton conductivity, dimensional stability, hydrothermal resistance and mechanical strength. In addition, this electrode electrolyte for solid polymer fuel cells enables to recover a catalyst metal.
Type: Grant
Filed: May 16, 2008
Issued: January 8, 2013
Assignees: JSR Corporation, Honda Motor Co., Ltd.
Inventors: Toshiaki Kadota, Yoshitaka Yamakawa, Fusao Nakagawa, Nagayuki Kanaoka, Takaki Nakagawa
Patent number: 8349905
Abstract: Disclosed herein is a proton-conducting polymer and uses thereof and, more particularly, a hydrocarbon-based proton-conducting polymer derived from a monomer having a multi-naphthyl group and comprising a plurality of acid groups on the side chain of the repeating unit, an electrolyte membrane comprising the polymer, a membrane-electrode assembly comprising the electrolyte membrane, and a fuel cell comprising the membrane-electrode assembly.
Type: Grant
Filed: December 9, 2011
Issued: January 8, 2013
Assignee: Hyundai Motor Company
Inventors: Inchul Hwang, Nak Hyun Kwon, Young Taek Kim, Dong Il Kim, Ju Ho Lee, Jang-Bae Son
Patent number: 8344091
Abstract: A polymer represented by the following Formula 1, and a membrane-electrode assembly and a fuel cell system including the polymer: In the above Formula 1, definitions of the substituents are the same as in described in the detailed description.
Type: Grant
Filed: May 8, 2009
Issued: January 1, 2013
Assignee: Samsung SDI Co. Ltd.
Inventors: Sung-Guk An, Sung-Yong Cho, Sang-Il Han, Kie Hyun Nam
Patent number: 8344094
Abstract: An optical material is provided that has a high transmittance, a high refractive index, a low Abbe constant, a high secondary dispersion property, and a low water absorption rate. The optical material includes a polymer of a mixture which contains: a sulfur-containing compound represented by the following general formula (1): a sulfur-containing compound represented by the following general formula (2): and an energy polymerization initiator, in which a content of the sulfur-containing compound represented by the chemical formula (2) is 10% by weight or more to 60% by weight or less, an Abbe constant (?d) of the polymer of the mixture satisfies 18<?d<23, and a secondary dispersion property (?g,F) thereof satisfies 0.68<?g,F<0.69.
Type: Grant
Filed: September 8, 2009
Issued: January 1, 2013
Assignee: Canon Kabushiki Kaisha
Inventors: Hidefumi Iwasa, Shigeo Kiso, Terunobu Saitoh, Toshiji Nishiguchi
Application number: 20120322010
Abstract: A novel novolac prepared by acid catalyzed condensation between biphenols or bisphenofluorenes and fluorenone is presented. The polymers exhibit excellent oxidative thermal stability and high carbon content, suitable for dielectric, etch stop applications as spin-on material.
Type: Application
Filed: June 6, 2012
Issued: December 20, 2012
Assignee: SILECS OY
Inventor: Jyri Paulasaari
Patent number: 8334358
Abstract: The present invention relates to a sulfonated poly(arylene ether) copolymer, a manufacturing method thereof and a polymer electrolyte membrane for fuel cell using the same.
Type: Grant
Filed: October 29, 2010
Issued: December 18, 2012
Assignee: Hyundai Motor Company
Inventors: Inchul Hwang, Ki Yun Cho, Dong Il Kim, Ju Ho Lee
Patent number: 8324285
Abstract: Provided are methods of treating an open cell polyimide foam product to produce a treated polyimide foam product having a property of repelling water or oil. The method includes the steps of: selecting a polyimide foam product having an external surface area and an open cell structure that has an interior surface area, wetting the exterior surface area and the interior surface area with a chemical treatment fluid comprising a treatment chemical that has a property of repelling water or oil, and distributing the treatment chemical onto at least a portion of the interior surface area sufficient to modify a surface property of the interior surface. Also provided are treated polyimide foam products that have an open cell polyimide foam substrate with an interior surface area and a treatment chemical on at least a portion of the interior surface area. The treatment chemical renders the interior surface hydrophobic or oleophobic.
Type: Grant
Filed: November 6, 2007
Issued: December 4, 2012
Assignee: The Boeing Company
Inventor: George F. Nicholas
Application number: 20120298193
Abstract: A polymer including moiety A represented by Chemical Formula 1, and a solar cell including the polymer are provided.
Type: Application
Filed: May 22, 2012
Issued: November 29, 2012
Assignee: SAMSUNG ELECTRONICS CO., LTD.
Inventors: Soo-Ghang Ihn, Yeong Suk Choi, Sungyoung Yun, Younhee Lim, Bulliard Xavier
Patent number: 8314202
Abstract: The invention provides novel flame-retardant polymers and materials, their synthesis and use. More particularly, the flame-retardant polymers are deoxybenzoin-derived polymers.
Type: Grant
Filed: March 30, 2009
Issued: November 20, 2012
Assignee: University of Massachusetts
Inventors: Todd Emrick, E. Bryan Coughlin, Thangamani Ranganathan, Michael Beaulieu, Richard Farris, Bon-Cheol Ku
Patent number: 8309678
Abstract: Provided is a solid polymer electrolyte having increased heat resistance and high proton conductivity and a proton conductive membrane composed of the electrolyte. Also provided is a copolymer having a sulfonic acid group.
Type: Grant
Filed: May 16, 2008
Issued: November 13, 2012
Assignee: JSR Corporation
Inventors: Toshiaki Kadota, Yoshitaka Yamakawa
Patent number: 8298402
Abstract: The present invention relates to alkylphenol-aldehyde resins containing oligo- or polymers having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula -(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radicals or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or -alkenyl, n is from 1 to 100 and k is 1 or 2.
Type: Grant
Filed: September 22, 2006
Issued: October 30, 2012
Assignee: Clariant Produkte (Deutschland) GmbH
Inventors: Matthias Krull, Carsten Cohrs, Heidi Rausch
Patent number: 8299208
Abstract: By a temper treatment a polyaryletherketone powder is processed such that it is particularly suited for the use in a method for a layer-wise manufacturing of a three-dimensional object. To this effect the powder is tempered at a temperature that is at least 20° C. above the glass transition temperature for at least 30 minutes before it is used as building material.
Type: Grant
Filed: November 4, 2010
Issued: October 30, 2012
Assignee: EOS GmbH Electro Optical Systems
Inventors: Frank Müller, Andreas Pfister, Martin Leuterer
Patent number: 8288500
Abstract: The present invention relates to a sulfonated poly(arylene ether) copolymer, a manufacturing method thereof and a polymer electrolyte membrane for fuel cell using the same.
Type: Grant
Filed: November 2, 2010
Issued: October 16, 2012
Assignee: Hyundai Motor Company
Inventors: Ju Ho Lee, Dong Ii Kim, Nak Hyun Kwon, Inchul Hwang
Application number: 20120259086
Abstract: A cyclic poly (phenylene ether ether ketone) composition includes not less than 60% by weight of a cyclic poly (phenylene ether ether ketone) represented by the following Formula (I), which is characterized in that the cyclic poly (phenylene ether ether ketone) is a mixture of cyclic poly (phenylene ether ether ketone)s having different repeating numbers (m) and the composition has a melting point of not higher than 270° C.; and a method of producing a poly (phenylene ether ether ketone) characterized by heat-polymerizing the cyclic poly (phenylene ether ether ketone) composition: where m represents an integer of 2 to 40.
Type: Application
Filed: December 24, 2010
Issued: October 11, 2012
Assignee: Toray Industries, Inc.
Inventors: Kohei Yamashita, Shunsuke Horiuchi, Koji Yamauchi
Application number: 20120252217
Abstract: A resist underlayer film-forming composition includes (A) a polymer that includes a repeating unit shown by a formula (1), and has a polystyrene-reduced weight average molecular weight of 3000 to 10,000, and (B) a solvent, wherein R3 to R8 individually represent a group shown by the following formula (2) or the like, —O—R1?R2 ??(2) wherein R1 represents a single bond or the like, and R2 represents a hydrogen atom or the like.
Type: Application
Filed: August 30, 2011
Issued: October 4, 2012
Assignee: JSR Corporation
Inventors: Shin-ya MINEGISHI, Yushi MATSUMURA, Shinya NAKAFUJI, Kazuhiko KOMURA, Takanori NAKANO, Satoru MURAKAMI, Kyoyu YASUDA, Makoto SUGIURA
Patent number: 8236919
Abstract: A process for preparing a polyether ether ketone. Sodium carbonate is used alone as the condensation agent, and 4,4?-difluorodibenzophenone, p-benzenediol and biphenyldiol are subjected to polymerizing. After the corresponding prepolymer is obtained, the reaction temperature is elevated and p-benzenediol is further added as a chain extender to react for a period of time to produce high-viscosity polyether ether ketone.
Type: Grant
Filed: November 30, 2010
Issued: August 7, 2012
Assignee: Jilin Jinzheng Macromolecule Materials R & D Co., Ltd.
Inventors: Guirong Wu, Yuning Xie
Application number: 20120189713
Abstract: The invention relates to novel monomers of Formula (I) useful for preparation of phase-separated biocompatible polymers or polymer compositions. These polymers or polymer compositions may be bioresorbable and/or biodegradable and have desirable mechanical properties, such as fracture and/or fatigue toughness, which have not been a primary design criteria for such polymers previously. The polymers or polymer compositions are useful in a variety of medical applications, such as in the fabrication of medical devices. Therefore, methods for preparing these polymers or polymer compositions and medical devices are also encompassed by this disclosure.
Type: Application
Filed: July 31, 2010
Issued: July 26, 2012
Assignee: RUTGERS, THE STATE UNIVERSITY OF NEW JERSEY
Inventors: Joachim B. Kohn, Durgadas Bolikal, Ramiro Rojas
Patent number: 8222367
Abstract: A proton conducting hydrocarbon-based polymer has acid groups on side chains attached to the main chain, where the acid groups are between 7 and 12 atoms away from the main chain. Another polymer includes a semi-fluorinated aromatic hydrocarbon main chain and side chains that include at least one —CF2— group and an acid group. Another polymer includes an aromatic hydrocarbon main chain and side chains that include at least one —CH2-CF2— group and an acid group. Another aromatic polymer includes acid groups attached to both the main chain and the side chains where less than about 65 weight percent of the acid groups are attached to the side chains. Another aromatic polymer includes side chains attached to the main chain that include at least one aryl ring, and acid groups attached to both the main chain and to the aryl groups. Another polymer includes an aliphatic hydrocarbon main chain, side chains that include at least one deactivating aryl ring, and acid groups attached to the deactivating aryl rings.
Type: Grant
Filed: September 29, 2006
Issued: July 17, 2012
Assignee: Battelle Memorial Institute
Inventors: Ramanathan S. Lalgudi, Bhima R. Vijayendran, Jeffrey Cafmeyer, Jay R. Sayre
Application number: 20120130041
Abstract: The present disclosure relates to a transparent polyarylene ether polymer with high heat resistance and a method for preparing the same. More particularly, the present disclosure relates to a polyarylene ether polymer and a method for preparing the same, wherein the polyarylene ether polymer has a repeating structure in which cardo-type aromatic diols having a large molecular volume, polyether sulfones which are amorphous polymers having a high glass transition temperature and superior film formability, and polyether ketones which are crystalline polymers having superior heat resistance and mechanical properties are sequentially arranged. The polyarylene ether polymer is both transparent and heat resistant and, thus, can be used, for example, for a flexible plastic substrate.
Type: Application
Filed: December 10, 2010
Issued: May 24, 2012
Assignee: IUCF-HYU (Industry-University Coperation Foundatio Hanyang University
Inventors: Yang Kyoo Han, Gyoung Pyo Kong, Moon Ki Kim, Bo Ra Hong, Hyun Aee Chun
Patent number: 8168732
Abstract: The present description discloses a polymeric composition which is a melt-processed alloy comprised of (a) a polyarylene sulfide resin, (b) a polyaryl-ether-ketone resin, and a reactive compound which results in (c) a graft copolymer of the polyarylene sulfide resin and/or the polyaryl-ether-ketone resin in addition to the starting resins. Exemplary melt-processed polymeric compositions can be made by reacting an alkoxy silane with the polyarylene sulfide resin and/or the polyaryl-ether-ketone resin to produce a graft copolymer of a portion of one or both of the resins, sufficient to render the composition uniform and homogeneous. It is normally preferred for the exemplary organosilane compound, to be an amino silane. The subject invention further reveals an insulated wire comprising (1) an electrical conductor and (2) a layer of the melt-processed alloy composition; and fiber reinforced composites comprising fibers substantially fully impregnated with the alloy polymeric composition.
Type: Grant
Filed: April 18, 2008
Issued: May 1, 2012
Assignee: Ticona LLC
Inventors: Manoj Ajbani, Andrew Auerbach, Ke Feng
Patent number: 8163864
Abstract: The invention relates to the field of polymer chemistry and relates to sulfonated polyarylene compounds such as can be used for example in ion exchange membranes in fuel cells, as well as a method for the production thereof and the use thereof. The object of the present invention is to disclose hydrolytically and thermally resistant sulfonated polyarylene compounds with a defined degree and position of sulfonation, from which membrane materials with an improved resistance to hydrolysis can be produced. The object is attained through sulfonated polyarylene compounds according to at least one of the general formulas (I)-(IV).
Type: Grant
Filed: July 13, 2007
Issued: April 24, 2012
Assignee: Leibniz-Institut fuer Polymerforschung Dresden E.V.
Inventors: Dieter Lehmann, Jochen Meier-Haack, Claus Vogel, Wladimir Butwilowski
Patent number: 8158742
Abstract: Deoxybenzoin-phosphonate and other copolymer compounds, compositions and related methods.
Type: Grant
Filed: January 3, 2011
Issued: April 17, 2012
Assignee: University of Massachusetts
Inventors: Todd Emrick, Thangamani Ranganathan, E. Bryan Coughlin, Richard J. Farris, Joseph Zilberman
Patent number: 8153753
Abstract: A polyamide having at least an alicyclic or aromatic group exhibiting a light transmittance of 80% or more in the wavelength region of 450 to 700 nm is produced by using an aramide polymer comprising specific structural units at an amount of 50 mol % or more. Colorless transparent alicyclic or aromatic polyamide films having high rigidity and high thermal resistance are provided by using the polyamide. Further, the invention provides various optical members made by using the polyamide or the polyamide films, and polyamide copolymers.
Type: Grant
Filed: April 7, 2004
Issued: April 10, 2012
Assignee: Toray Industries, Inc.
Inventors: Hideki Moriyama, Akimitsu Tsukuda
Patent number: 8129496
Abstract: An approach is presented for designing a polymeric layer for nanometer scale thermo-mechanical storage devices. Cross-linked polyimide oligomers are used as the recording layers in atomic force data storage device, giving significantly improved performance when compared to previously reported cross-linked and linear polymers. The cross-linking of the polyimide oligomers may be tuned to match thermal and force parameters required in read-write-erase cycles. Additionally, the cross-linked polyimide oligomers are suitable for use in nano-scale imaging.
Type: Grant
Filed: March 27, 2008
Issued: March 6, 2012
Assignee: International Business Machines Corporation
Inventors: Urs T. Duerig, Jane Elizabeth Frommer, Bernd Walter Gotsmann, Erik Christopher Hagberg, James Lupton Hedrick, Armin W. Knoll, Victor Yee-Way Lee, Teddie Peregrino Magbitang, Robert Dennis Miller, Russell Clayton Pratt, Charles Gordon Wade, Johannes Windeln
Patent number: 8125882
Abstract: A composition of matter for the recording medium of nanometer scale thermo-mechanical information storage devices and a nanometer scale thermo-mechanical information storage device. The composition includes: one or more polyaryletherketone polymers, each of the one or more polyaryletherketone polymers having two terminal ends, each terminal end having two or more phenylethynyl moieties. The one or more polyaryletherketone polymers are thermally cured and the resulting cross-linked polyaryletherketone resin used as the recording layers in atomic force data storage devices.
Type: Grant
Filed: January 28, 2011
Issued: February 28, 2012
Assignee: International Business Machines Corporation
Inventors: Richard Anthony DiPietro, Urs T. Duerig, Jane Elizabeth Frommer, Bernd Walter Gotsmann, Erik Christopher Hagberg, James Lupton Hedrick, Armin W. Knoll, Teddie Peregrino Magbitang, Robert Dennis Miller, Russell Clayton Pratt, Charles Gordon Wade
Patent number: 8110636
Abstract: Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.
Type: Grant
Filed: April 17, 2009
Issued: February 7, 2012
Assignee: Sandia Corporation
Inventors: Cy H. Fujimoto, Michael Hibbs, Andrea Ambrosini
Patent number: 8088882
Abstract: A main object of the present invention is to provide a polymer precursor which exhibits high transmittance to a shorter wavelength range with respect to an electromagnetic wave though the polymer precursor has a part which sequences an unsaturated bond having a ? electron orbit and a single bond alternately.
Type: Grant
Filed: March 28, 2006
Issued: January 3, 2012
Assignee: Dai Nippon Printing Co., Ltd.
Inventor: Katsuya Sakayori
Patent number: 8084568
Abstract: The present invention relates to a poly(arylene ether) copolymer having an ion exchange group, particularly a positive ion exchange group, a method for manufacturing the same, and use thereof. In the poly(arylene ether) copolymer having the ion exchange group according to the present invention, physical characteristics, ion exchanging ability, metal ion adsorption ability and a processability are excellent, and thus the copolymer can be molded in various shapes and can be extensively applied to various fields such as recovering of organic metal, air purification, catalysts, water treatment, medical fields and separating of proteins.
Type: Grant
Filed: December 6, 2010
Issued: December 27, 2011
Assignee: Hyundai Motor Company
Inventors: Inchul Hwang, Nak Hyun Kwon, Young Taek Kim, Dong Il Kim, Ju Ho Lee
Patent number: 8071710
Abstract: The manufacture of polyetherquinoxalines may be accomplished by polymerization of quinoxaline and related monomers with a bisphenol under aromatic nucleophilic substitution reaction conditions. A method of manufacture includes contacting a substituted or unsubstituted quinoxaline having replaceable groups at the 2,3 positions with a bisphenol or a bisphenol derivative under aromatic nucleophilic substitution reaction conditions. The resulting polyetherquinoxalines contain quinoxaline groups joined by ether linkages at the 2 and 3 positions of the quinoxaline groups. In one example, the polyetherquinoxaline has a formula represented as wherein “n” is an integer from 1 to 10000, and R1, R2, R3, R4 are independently hydrogen, methyl, CF3, tert-butyl, benzoyl, benzenesulfonyl, a sulfonic acid salt, an aliphatic group, an alicyclic group, or an aryl group, and Ar is an aromatic radical.
Type: Grant
Filed: August 19, 2009
Issued: December 6, 2011
Assignee: The University of Akron
Inventors: Haci Bayram Erdem, Frank Wayne Harris
Patent number: 8067523
Abstract: It is an object of the present invention to provide a thermosetting resin composition having satisfactory adhesiveness, good processability, high heat resistance, and excellent dielectric characteristics in the GHz band; and a laminate and a circuit board including the thermosetting resin composition. The present invention provides a thermosetting resin composition including an imide oligomer component (A) containing at least one imide oligomer having a specific structure and an epoxy resin component (B) containing at least one epoxy resin. Furthermore, the present invention provides the thermosetting resin composition further including a polyimide resin component (C).
Type: Grant
Filed: October 4, 2006
Issued: November 29, 2011
Assignee: Kaneka Corporation
Inventors: Shigeru Tanaka, Kanji Shimoohsako, Takashi Ito, Mutsuaki Murakami
Patent number: 8044151
Abstract: The present invention provides a wholly aromatic liquid-crystalline polyester consisting of the repeating units represented by formulae (I), (II), (III) and (IV): wherein: the molar proportion of the repeating unit represented by formula (I) based on the total repeating units constituting the wholly aromatic liquid-crystalline polyester is 40-80 mol %; the molar ratio of the total amount of the repeating units represented by formulae (II) and (III) to the repeating unit represented by formula (IV) is from 90/100 to 100/90; the molar proportion of the repeating unit represented by formula (II) based on the total amount of the repeating units represented by formulae (II) and (III) is 80-99.9 mol%; and the two “—O—” attached to the benzene ring in formula (III) are positioned meta or para to each other and “Ar” in formula (IV) represents a bivalent aromatic group.
Type: Grant
Filed: October 29, 2008
Issued: October 25, 2011
Assignee: Ueno Fine Chemicals Industry, Ltd.
Inventors: Motoki Asahara, Hiroaki Terada, Hiroyuki Kato
Application number: 20110257332
Abstract: A polyaryletherketone polymeric material, for example polyetheretherketone and composite materials comprising said polymeric material are described. The polymeric material has a melt viscosity (MV) in the range 0.05 to 0.12 kNsm?2, preferably in the range 0.085 to 0.095 kNsm?2.
Type: Application
Filed: February 14, 2011
Issued: October 20, 2011
Assignee: Victrex Manufacturing Limited
Inventors: Craig Meakin, Dianne Flath, Brian Wilson
Patent number: 8030437
Abstract: A method for forming a polyimide composite article utilizes a polyimide resin system including at least a first prepolymer component and a second prepolymer component. A preform structure is tackified with the first prepolymer component. Using resin infusion or resin transfer molding techniques, the tackified preform structure is contacted with the second prepolymer component. The polyimide resin system is cured under suitable cure conditions so that the first and second prepolymer components mix and react to produce the polyimide composite structure.
Type: Grant
Filed: December 27, 2007
Issued: October 4, 2011
Assignee: General Electric Company
Inventors: Stephen Mark Whiteker, Lisa Vinciguerra Shafer, Warren Rosal Ronk
Patent number: 8026339
Abstract: A polysulfone is provided with a nitrogen-containing functional group having an affinity to an acid, an electrolyte membrane using the polysulfone, and a fuel cell including the electrolyte membrane. In particular, the polysulfone includes a nitrogen-containing functional group that has an affinity to an acid, such as a phosphoric acid, thereby having an excellent acid retaining ability. In an electrolyte membrane including the polysulfone and an acid, the amount of the retained acid can be controlled. Therefore, the electrolyte membrane has a high ionic conductivity and a high mechanical strength. A polysulfone blend of polysulfone and a thermoplastic resin prevents the dissolution of polysulfone by phosphoric acid, so that an electrolyte membrane using the polysulfone blend has an improved durability. A cross-linked reaction product of polysulfone, a cross-linking agent and a polymerization product of polysulfone, a thermoplastic resin, and a cross-linking agent strongly resist a phosphoric acid.
Type: Grant
Filed: June 1, 2007
Issued: September 27, 2011
Assignee: Samsung SDI Co., Ltd.
Inventors: Chung-kun Cho, Myung-jin Lee, Myeong-soon Kang
Application number: 20110230590
Abstract: Granules or pellets comprising polymeric materials such as polyaryletherketones and ceramic materials may be prepared and used to make a variety of different parts of components for use in medical applications, by melt-processing. The ceramic material may be a bioactive glass and/or a controlled-release glass, and may include less than 20 mole % sodium oxide and/or be water soluble.
Type: Application
Filed: October 14, 2009
Issued: September 22, 2011
Assignee: INVIBIO LIMITED
Inventors: Marcus Jarman-Smith, Andrew Holden, Andrew Elleray
Application number: 20110224399
Abstract: Improved poly(aryletherketone)s with superior melt stability, lower gel content and lower color and a new process for their manufacture.
Type: Application
Filed: August 8, 2008
Issued: September 15, 2011
Assignee: SOLVAY ADVANCED POLYMERS, L.L.C.
Inventors: Chantal Louis, Satchit Srinivasan, William Gandy
Application number: 20110224398
Abstract: The present invention provides a novel polymer composed of polyarylene in the main chain and having oxocarbon groups which is particularly useful in battery and fuel cell applications.
Type: Application
Filed: May 24, 2011
Issued: September 15, 2011
Assignee: Sumitomo Chemical Company, Limited
Inventors: Ken YOSHIMURA, Lanny S. LIEBESKIND
Patent number: RE43880
Abstract: This invention relates to the composition and a solvent-free process for preparing novel imide oligomers and polymers specifically formulated with effective amounts of a dianhydride such as 2,3,3?,4-biphenyltetra carboxylic dianydride (a-BPDA), at least one aromatic diamine and an endcapped of 4-phenylethynylphthalic anhydride (PEPA) or nadic anhydride to produce imide oligomers that possess a low-melt viscosity of 1-60 poise at 260-280° C. When the imide oligomer melt is cured at about 371° C. in a press or autoclave under 100-500 psi, the melt resulted in a thermoset polyimide having a glass transition temperature (Tg) equal to and above 310° C. A novel feature of this process is that the monomers; namely the dianhydrides, diamines and the endcaps, are melt processable to form imide oligomers at temperatures ranging between 232-280° C. (450-535° F.) without any solvent.
Type: Grant
Filed: May 8, 2006
Issued: December 25, 2012
Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space Administration
Inventor: Chun-Hua Chuang