Abstract: Disclosed herein are glass compositions that present several advantages over glasses and other materials currently used for redistribution layers for RF, interposers, and similar applications. The glasses disclosed herein are low cost, flat glasses that have high throughput for the laser damage and etching process used to create through glass vias (TGV). TGV generated using the silicate glasses and processes described herein have large waist diameters (Dw), which is a desirable feature with respect to producing glass articles such as interposers.

Abstract: A glass container is provided having a glass tube with a first end and a second end and a glass bottom closing the second end. The glass tube has a longitudinal axis and has, in a direction from the first to the second end, a top region, a junction region, a neck region, a shoulder region, and a body region. The top region is at the first end and has an outer diameter (dt), the neck region has an outer diameter (dn) with dn<dt, the body region extends to the second end and has an outer diameter (db) with db>dt, and the glass tube in the body region has a thickness (lb). The outer contour in a transition area between the top and neck regions is defined by a radius of curvature. The glass containers have a neck squeeze test load of at least 1100 N.

Abstract: A fiber connector, comprising a housing comprising a region extending in a lengthwise direction an optical fiber disposed in the region, a first portion of the optical fiber comprising an inner core, a cladding layer surrounding the core, and a first outer polymer layer surrounding the cladding layer and a second portion of the optical fiber comprising the inner core, the cladding layer surrounding the core and a second outer polymer layer that is different from the first polymer layer.

Abstract: A method of modifying a substrate comprising an etching step comprising contacting one or more primary surfaces of a glass, glass-ceramic, or ceramic substrate with a solution for a time period of 20 minutes to 8 hours to generate one or more etched primary surfaces, the solution comprising over 10 percent by weight of one or more alkali hydroxides, the solution having a temperature within the range of 100° C. to 150° C., the substrate having a thickness between the primary surfaces that decreases during the time period by 5 ?m to 100 ?m at a rate of 2 ?m per hour or greater. The solution of the etching step does not comprise hydrogen fluoride. The one or more alkali hydroxides of the solution of the etching step can be sodium hydroxide (NaOH), potassium hydroxide (KOH), or a combination of both sodium hydroxide and potassium hydroxide.

Abstract: Forming holes in a material includes focusing a pulsed laser beam into a laser beam focal line oriented along the beam propagation direction and directed into the material, the laser beam focal line generating an induced absorption within the material, the induced absorption producing a defect line along the laser beam focal line within the material, and translating the material and the laser beam relative to each other, thereby forming a plurality of defect lines in the material, and etching the material in an acid solution to produce holes greater than 1 micron in diameter by enlarging the defect lines in the material. A glass article includes a stack of glass substrates with formed holes of 1-100 micron diameter extending through the stack.

Abstract: An exemplary method for preparing a primary preform by etching and collapsing a deposited tube includes mounting a deposited tube on a lathe and introducing the deposited tube into a central aperture of a furnace mounted on the lathe, wherein the furnace and the deposited tube are movable in axial direction with respect to each other, and creating within the furnace a hot zone that moves in translation back and forth over the length of the deposited tube during one or more cycles, wherein (i) during at least one cycle at least part of the outside of the deposited tube is etched by supplying a fluorine-containing etching gas to an annular region between the outer surface of the deposited tube and the central aperture of the furnace, and (ii) during at least one cycle the deposited tube is collapsed.

Abstract: An embodiment of the invention relates to an optical device which is capable of realizing a secondary nonlinear optical phenomenon. The optical device is a fiber-type optical device which is comprised of glass containing SiO2, and includes a core region, a first cladding region, and a second cladding region. At least a part of a glass region configured by the core region and the first cladding region has such a repetition structure that a first section serving as a poled crystal region and a second section serving as an amorphous region are alternately disposed along a longitudinal direction of the optical device.

Abstract: A manufacturing method of a glass substrate with a hole having a diameter ?f, and with a thickness ?f includes setting a thickness ?1 of a glass plate that is to be processed; preparing a glass plate with the thickness ?1, having first and second surfaces opposite to each other; forming one initial characteristic object or two or more initial characteristic objects in the glass plate by irradiating the glass plate with a laser from a side of the first surface of the glass plate, the initial characteristic object having a size of a diameter ?1 on the first surface; and performing wet etching for the glass plate having the initial characteristic object, so that from the initial characteristic object a hole having the diameter ?f on the first surface is formed, and a thickness of the glass plate is adjusted from ?1 to a target value of ?f.

Abstract: A nitrogen separation system includes a pressurizing apparatus, a temperature regulation apparatus, a nitrogen separation apparatus. The pressurizing apparatus is configured to pressurize a raw material gas to configure a pressurized raw material gas which is in a vapor-liquid equilibrium state with a liquefied gas and contains methane as a principal component and greater than or equal to 1 mol % nitrogen. The nitrogen separation apparatus is configured to separate nitrogen contained in the pressurized raw material gas by use of a nitrogen selective permeation membrane configured from an inorganic material. The pressurization apparatus pressurizes the raw material gas so that a partial pressure of nitrogen in the pressurized raw material gas is greater than or equal to 2 times and less than or equal to 5 times a pressure of the nitrogen-enriched gas.

Abstract: A method for producing a glass substrate with through glass vias according to the present invention includes: irradiating a glass substrate (10) with a laser beam to form a modified portion; forming a first conductive portion (20a) on a first principal surface of the glass substrate (10), the first conductive portion (20a) being positioned in correspondence with the modified portion (12); and forming a through hole (14) in the glass substrate (10) after formation of the first conductive portion by etching at least the modified portion (12) using an etchant. This method allows easy handling of a glass substrate during formation of a conductive portion such as a circuit on the glass substrate, and is also capable of forming a through hole in the glass substrate relatively quickly while preventing damage to the conductive portion such as a circuit formed on the glass substrate.

Abstract: Forming holes in a material includes focusing a pulsed laser beam into a laser beam focal line oriented along the beam propagation direction and directed into the material, the laser beam focal line generating an induced absorption within the material, the induced absorption producing a defect line along the laser beam focal line within the material, and translating the material and the laser beam relative to each other, thereby forming a plurality of defect lines in the material, and etching the material in an acid solution to produce holes greater than 1 micron in diameter by enlarging the defect lines in the material. A glass article includes a stack of glass substrates with formed holes of 1-100 micron diameter extending through the stack.

Abstract: A method for manufacturing an SiO2—TiO2 based glass upon a target by a direct method, includes a first process of preheating the target and a second process of growing an SiO2—TiO2 based glass ingot to a predetermined length upon the target which has been preheated, wherein the target is heated in the first process such that, in the second process, the temperature of growing surface of the glass ingot is maintained at or above a predetermined lower limit temperature.

Abstract: An optical sensor device includes a resin sealing portion for sealing an optical sensor element fixed to an element-mounting portion. The resin sealing portion is constituted of a resin having mixed and dispersed therein a glass filler obtained by pulverizing a phosphate-based glass which has spectral luminous efficacy properties by composition adjustment and high heat resistance and weatherability. The optical sensor device is highly reliable and capable of accommodating size and thickness reductions in packages and has stable and hardly changeable spectral luminous efficacy properties.

Abstract: Methods of forming a glass article are disclosed. In one embodiment, a method of forming a glass article includes translating a pulsed laser beam on a glass substrate sheet to form a laser damage region between a first surface and a second surface of the glass substrate sheet. The method further includes applying an etchant solution to the glass substrate sheet to remove a portion of the glass substrate sheet about the laser damage region. The method may further include strengthening the glass substrate sheet by an ion-exchange strengthening process, and coating the glass substrate sheet with an acid-resistant coating. Also disclosed are methods where the laser damage region has an initial geometry that changes to a desired geometry following the reforming of the glass substrate sheet such that the initial geometry of the laser damage region compensates for the bending of the glass substrate sheet.

Abstract: Methods for forming vias in glass substrates by laser drilling and acid etching are disclosed. In one embodiment, a method forming a via in a glass substrate includes laser drilling the via through at least a portion of a thickness of the glass substrate from an incident surface of the glass substrate. The method further includes etching the glass substrate for an etching duration to increase a diameter of an incident opening of the via and applying ultrasonic energy to the glass substrate during at least a portion of the etching duration. The applied ultrasonic energy has a frequency between 40 kHz and 192 kHz.

Abstract: A method for manufacturing an enclosure for an electronic device using laser texturing to create a first surface having different surface characteristics than a second surface adjacent to the first surface.

Abstract: Disclosed herein are methods for strengthening glass articles having strength-limiting surface flaws, together with strengthened glass articles produced by such methods, and electronic devices incorporating the strengthened glass articles. The methods generally involve contacting the glass articles with a substantially fluoride-free aqueous acidic treating medium for a time at least sufficient to increase the rupture failure points of the glass articles.

Abstract: The present invention provides an optical member including a porous glass film on a base member, wherein a ripple is suppressed. The optical member includes the base member and the porous glass film disposed on the base member, wherein the porosity increases in the direction from the base member toward the porous glass film in an interfacial region between the base member and the porous glass film and the porosity is continuous in the film thickness direction from the base member to the surface of the porous glass film in the optical member.

Abstract: The invention relates to new glass formulations with alumina contents greater than 35 mol % and methods for making these glasses. The glass may be a porous glass or a dense glass.

Abstract: A method for fabricating a high-density array of holes in glass comprises providing a glass sheet having a front surface and irradiating the glass sheet with a laser beam so as to produce open holes extending into the glass sheet from the front surface of the glass sheet. The beam creates thermally induced residual stress within the glass around the holes, and after irradiating, the glass sheet is annealed to eliminate or reduce thermal stress caused by the step of irradiating. The glass sheet is then etched to produce the final hole size. Preferably, the glass sheet is also annealed before the step of irradiating, at sufficiently high temperature for a sufficient time to render the glass sheet dimensionally stable during the step of annealing after irradiating.

Abstract: Disclosed herein is a CMP slurry composition. The CMP slurry composition includes cerium oxide particles, an adsorbent for adsorbing the cerium oxide particles to a polishing pad, an adsorption adjusting agent for adjusting adsorption performance of the adsorbent, and a pH adjusting agent. The CMP slurry composition may improve polishing efficiency of a patterned oxide layer and lifespan of a diamond disc conditioner.

Abstract: A process for making soda-lime glass includes calcining calcium carbonate in solid phase and at elevated temperature to form calcium oxide in solid phase and carbon dioxide gas. Sodium silicate glass is formed and refined separately in liquid phase. The solid phase calcium oxide is dissolved in the refined liquid phase sodium silicate glass to form a soda-lime glass melt. Formation of sodium silicate glass as an intermediate product before mixing with calcium oxide has the advantage of promoting release of gaseous reaction products from the sodium silicate glass during the refining step due at least in part to the relatively low viscosity of the sodium silicate glass. One or more steps in the process can be carried out under reduced pressure to promote release of gases and to reduce bubble formation.

Abstract: An optical member including a porous glass layer on a base member is provided, wherein the reflectance is reduced and a ripple is suppressed. The optical member is provided with a base member and a glass layer holding a transparent material in the inside of a porous structure disposed on the base member, wherein in the thickness direction of the glass layer, the porosity in the base member side with respect to the center line of the glass layer in the thickness direction is smaller than the porosity in the side opposite to the base member with respect to the center line of the glass layer in the thickness direction.

Abstract: To provide an optical member in which crystallization is suppressed and which has a porous glass layer on a base material. An optical member has a base material 1 and a porous glass layer 2 which is formed on the base material 1 and has a three-dimensional through pore, in which the existence ratio of crystals of 0.2 micrometer or more in the porous glass layer 2 is 1.0% or lower.

Abstract: This invention provides an optical member in which ripple is suppressed and a porous glass layer is formed on a base member and also provides a method for easily manufacturing the optical member. An optical member has a base member (1) and a porous glass layer (2) formed on the base member (1), in which a textured structure is formed on the interface contacting the porous glass layer (2) of the base member (1) and the height of the textured structure is 100 nm or more and equal to or lower than the thickness of the porous glass layer (2).

Abstract: This invention provides a porous glass with a varied porous structure that shows an excellent optical performance. A method of manufacturing a porous glass comprising: a first step of forming a surface layer containing a boron compound and an alkali metal compound as main ingredients on a matrix glass containing a silicon oxide, a boron oxide and an alkali metal oxide; a second step of heat treatment the matrix glass and the surface layer for phase separation to form a phase-separated glass; and a third step of acid treatment the phase-separated glass to form the porous glass having pores.

Abstract: Disclosed herein are methods for strengthening glass articles having strength-limiting surface flaws, together with strengthened glass articles produced by such methods, and electronic devices incorporating the strengthened glass articles. The methods generally involve contacting the glass articles with a substantially fluoride-free aqueous acidic treating medium for a time at least sufficient to increase the rupture failure points of the glass articles.

Abstract: A cover glass element can extend to the edges of an electronic device while maintaining the optical flatness and thickness needed for the cover glass. A first glass sheet with the desired thickness and flatness can be thermally bonded to a second glass sheet machined to include an opening to be received by the edges of the electronic device. The resulting three-dimensional cover element forms a uni-body frame that is significantly stiffer than a single sheet of glass, and the larger surface area of the edge provides for enhances pressure distribution, particularly after chemical strengthening, thus enhancing the durability of the electronic device. Further, the thermal bonding process uses lower temperatures than processes such as slumping or pressing, which could potentially affect the flatness and optical clarity of the original sheet glass.

Abstract: Impact-damage-resistant glass sheet comprising at least one chemically etched surface in combination with a tempering surface compression layer, the glass sheet exhibiting a high standardized ball drop failure height and a high flexural modulus of rupture strength, useful to provide damage-resistant glass cover sheets for consumer electronic video display devices, is provided by subjecting thin glass sheet to a combination of a surface tempering treatment and a surface etching treatment that improves strength while maintaining the optical glass sheet properties required for video display applications.

Abstract: A method for cutting a tempered glass including the steps of strengthening a glass substrate to form, from a surface to the inside of the glass substrate, at least one compression stress layer and a tensile stress layer corresponding to the compression stress layer; removing a part of the glass substrate, wherein the compression stress layer is formed in the part of the glass substrate and a predetermined cutting path passes through the part of the glass substrate; and cutting the glass substrate along the predetermined cutting path.

Abstract: To impart antiglare properties without reducing the amount of transmitted light, a method for processing a surface of light-transmitting-glass according to the present invention comprises a blasting step of ejecting abrasive grains with particle sizes of #800 to #3000 (average particle diameter 14 ?m to 4 ?m) such as WA (white alundum: high-purity alumina) having higher hardness than that of the glass onto a light-receiving surface of the glass having light-transmitting property to be processed for forming indentations and protrusions in the light-receiving surface of the glass, and after the blasting step, a hydrofluoric acid treatment step of immersing the light-receiving surface of the glass into a hydrofluoric acid solution in 10% to 20% concentration for 30 to 600 seconds thereby increase a height (amplitude) of indentations and protrusions of the surface of light-transmitting-glass.

Abstract: The invention relates to new glass formulations with alumina contents greater than 35 mol % and methods for making these glasses. The glass may be a porous glass or a dense glass.

Abstract: Systems and methods for processing lead-containing glass are generally described. In certain embodiments, at least a portion of the lead within the bulk of the lead-containing glass is removed from the lead-containing glass and transferred to a liquid leaching medium. Removal of lead from the bulk of the lead-containing glass, as opposed to the surface and areas closely adjacent to the surface of the lead-containing glass, can allow for the production of recycled glass that includes substantially no lead within its boundaries.

Abstract: An object of the present invention is to provide a surface-treated glass plate having a concave portion on the order of nanometers, in which the depth of the concave portion is sufficiently large for the size thereof and which is free from an abnormal bump portion and excellent in the transparency to visible light. The present invention relates to a surface-treated glass plate having a plurality of the concave portions provided in a glass surface, in which a plane of the glass surface, excluding a region in which the concave portions are formed, is a flat plane, and the concave portions have an average open pore diameter of 10 nm to less than 1 ?m in a cross-sectional view thereof.

Abstract: To provide an optical member having a porous glass layer on a substrate and rarely causing ripples. The optical member has a porous glass layer on a substrate. The porous glass layer includes a first porous glass layer and a second porous glass layer in this order on the substrate. The first porous glass layer has a uniform porosity. The second porous glass layer has a higher uniform porosity than the first porous glass layer.

Abstract: The present invention provides an optical member including a porous glass layer on the base member, wherein a ripple is suppressed. The optical member includes the porous glass layer which is disposed on the base member and which has a thickness of 400 nm or more, wherein the porous glass layer includes at least a gradient region having a porosity increasing from the interface between the base member and the porous glass layer toward the surface of the porous glass layer, the porosity is continuous in the thickness direction from the base member to the surface of the porous glass layer, and a specific relational expression is satisfied.

Abstract: The present invention provides an optical member having a high transmittance, wherein a composition change of a phase-separable base material glass film is suppressed. A method for manufacturing an optical member provided with a porous glass film on the base member includes the steps of forming a glass powder film containing a glass powder on the base member, forming a phase-separable base material glass film on the base member by heating and fusing the glass powder film in an atmosphere having an oxygen concentration of more than 20%, forming a phase-separated glass film on the base member by heating the base material glass film, and forming a porous glass film on the base member by subjecting the phase-separated glass film to an etching treatment.

Abstract: There is provided a method of manufacturing a plate member including preparing a base plate member having main faces, and performing etching by immersing at least part of the base plate member in an etching liquid while controlling a lowering speed of a liquid surface of the etching liquid on the main faces of the base plate member to a desired lowering speed.

Abstract: Methods for machining glass structures may be performed on fusion-drawn glass laminates having a core layer interposed between a first cladding layer and a second cladding layer. The core layer may be formed from a core glass composition having a core photosensitivity, the first cladding layer may be formed from a glass composition having a photosensitivity different from the core photosensitivity, and the second cladding layer may be formed from a glass composition having a photosensitivity different from the core photosensitivity. At least one of the core layer, the first cladding layer, and the second cladding layer is a photomachinable layer. The methods may include exposing a selected region of a photomachinable layer in the fusion-drawn laminate to ultraviolet radiation; heating the glass structure until the selected region crystallizes; and removing the crystallized material selectively from the photomachinable layer.

Abstract: Laminated glass articles and methods for making the same are disclosed. In one embodiment, a laminated glass article may include a glass core layer and at least one glass cladding layer fused to the glass core layer. The at least one glass cladding layer may be phase separated into a first phase and at least one second phase having different compositions. The first phase of the at least one glass cladding layer may have an interconnected matrix. The at least one second phase of the at least one glass cladding layer may be dispersed throughout the interconnected matrix of the first phase of the at least one glass cladding layer. In some embodiments, the at least one second phase may be selectively removed from the interconnected matrix leaving a porous, interconnected matrix of the first phase.

Abstract: A glass substrate chemically strengthened, includes a primary surface that has a compressive stress layer formed in an uppermost surface layer thereof. The compressive stress layer is configured to enhance strength of the glass substrate due to a compressive stress generated in the compressive stress layer. The compressive layer consists of a layer of a potassium ion concentration equal to or less than 5000 parts per million (ppm).

Abstract: A process for fabricating a nanochannel system using a combination of microelectromechanical system (MEMS) microfabrication techniques, atomic force microscopy (AFM) nanolithography, and focused ion beam (FIB). The nanochannel system, fabricated on either a glass or silicon substrate, has channel heights and widths on the order of single to tens of nanometers. The channel length is in the micrometer range. The nanochannel system is equipped with embedded micro and nanoscale electrodes, positioned along the length of the nanochannel for electron tunneling based characterization of nanoscale particles in the channel. Anodic bonding is used to cap off the nanochannel with a cover chip.

Abstract: An layout for a glass manufacturing system may include a hot process part having a batch plant for storing a glass raw material, a tank for melting the raw material and storing a molten glass, a float bath for forming the molten glass into a glass of a ribbon shape, an annealing lehr for cooling the glass ribbon, and a cold end connected to the annealing lehr, and an etching process part having a final cutting sector for cutting the glass provided from the cold end into sheet glasses of a preset final size, a beveling and etching sector for bevel the edges of the cut sheet glasses and etching the beveled sheet glasses, and a first inspection sector for inspecting the etched sheet glasses, and the hot process part and the etching process part may be connected by a single conveyor to form a continuous line.

Abstract: A chemically-strengthened glass sheet including: a smooth first side; and a rough second side, wherein the compressive stress values of the smooth first-side and the rough second-side are substantially in equipoise. Methods of making and using the glass sheet, as defined herein, are disclosed. A display system that incorporates the glass sheet, as defined herein, is also disclosed.

Abstract: [Object] In manufacturing a GRIN lens by a sol-gel method, an operation for preparing a wet gel is facilitated and cracking in a base material during sintering and foaming during drawing are prevented. [Solution] The object is achieved by obtaining a GRIN lens by producing a wet gel from an alcohol solution containing a silicon alkoxide, a dopant alkoxide, and a boron alkoxide as the main ingredients, leaching the same, drying the same to form a dry gel, and sintering and drawing the same.

Abstract: A tempered glass includes a glass substrate and a glue. The glass substrate includes a first surface and a second surface opposite to the first surface, and defines a plurality of strip recesses regularly arrayed on the first surface. The glue is infilled into the strip recesses to be coplanar with the first surface. The refractive index of the glue is substantially equal to the refractive index of the glass substrate.

Abstract: The present invention provides a method of easily chamfering and polishing an inner peripheral face and an outer peripheral face of a glass disk at low cost. By continuously supplying fresh etchants to an inner peripheral face and an outer peripheral face of a glass disk stacked body in which a plurality of glass disks are stacked, the inner and outer peripheral faces are polished.

Abstract: In one embodiment, a method of forming a glass container may include forming a glass container comprising a sidewall at least partially enclosing an interior volume. At least a portion of the interior surface of the sidewall may have an interior surface layer with a persistent layer heterogeneity relative to a midpoint of the sidewall. The interior surface layer of the glass container may be removed from the interior surface of the sidewall such that a modified interior surface of the sidewall has an interior region extending from about 10 nm below the modified interior surface into a thickness of the sidewall. The interior region may have a persistent layer homogeneity relative to the midpoint of the sidewall such that the modified interior surface is resistant to delamination.

Abstract: Methods include providing a glass, wherein the glass is capable of being phase separated; phase separating the glass; leaching at least one surface of the glass to form a leached glass surface layer; and replenishing the leached glass surface layer with constituents to form a replenished glass surface layer, wherein the constituents cause swelling of the replenished glass surface layer.

Abstract: Methods of forming a glass article are disclosed. In one embodiment, a method of forming a glass article includes translating a pulsed laser beam on a glass substrate sheet to form a laser damage region between a first surface and a second surface of the glass substrate sheet. The method further includes applying an etchant solution to the glass substrate sheet to remove a portion of the glass substrate sheet about the laser damage region. The method may further include strengthening the glass substrate sheet by an ion-exchange strengthening process, and coating the glass substrate sheet with an acid-resistant coating. Also disclosed are methods where the laser damage region has an initial geometry that changes to a desired geometry following the reforming of the glass substrate sheet such that the initial geometry of the laser damage region compensates for the bending of the glass substrate sheet.