With Concurrent Production Of Iron(fe) And Other Desired Nonmetallic Product (e.g., Energy, Fertilizer, Etc.) Patents (Class 75/958)
  • Patent number: 11479830
    Abstract: A method for treating converter slag for the purpose of recirculating iron, wherein a converter slag is brought into contact with oxygen in such a way that by means of turbulence, the slag is mixed, the iron and iron oxide components that are present are oxidized, and the slag is then allowed to stand in the vessel or a vessel until a segregation into a solidifying, silicate and phosphorus-rich first fraction and an underlying liquid iron oxide-rich second fraction has taken place, with the converter slag that is used being mixed with a partial flow from the iron oxide-rich second fraction in such a way that the total FeO content of the slag that is to be treated with oxygen is over 35% by weight, thus enabling the segregation into two fractions.
    Type: Grant
    Filed: August 24, 2018
    Date of Patent: October 25, 2022
    Assignee: voestalpine Stahl GmbH
    Inventor: Herbert Schmid
  • Patent number: 8551213
    Abstract: A system of coal gasification and direct ironmaking attains both heat recovery in a coal-based direct ironmaking process and a reduction in equipment investment in a coal gasification process. A waste heat boiler in the system recovers heat of gas exhausted from a coal gasification furnace. A heater in exhaust gas lines of a heat reduction furnace in the coal-based direct ironmaking process superheats the steam generated by and exhausted from the waste heat boiler. A superheated steam line supplies the steam superheated by the heater as an oxidant to the coal gasification furnace.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: October 8, 2013
    Assignee: Kobe Steel, Ltd.
    Inventors: Masataka Tateishi, Masahiro Motoyuki
  • Patent number: 8545593
    Abstract: A method for producing liquid ferroalloy by direct processing of manganese and chromium bearing iron compounds, by the steps: of mixing carbonaceous reductant, fluxing agent, and a binder with materials such as iron sands, metallic oxides, manganese-iron ore concentrates and/or chromium-iron ore concentrates and silica sands, to form a mixture; forming agglomerates from the mixture; feeding the agglomerates to a melting furnace with other materials; melting the feed materials at a temperature of from 1500 to 1760° C. and forming a slag and hot metal; removing the slag; tapping the hot metal as liquid ferroalloy, and utilizing the off-gases from the melting furnace as combustion fuel to drive a turbine and to generate electricity.
    Type: Grant
    Filed: October 24, 2011
    Date of Patent: October 1, 2013
    Assignee: Cardero Resource Corporation
    Inventor: Glenn E. Hoffman
  • Patent number: 8506672
    Abstract: A system of coal gasification and direct ironmaking attains both heat recovery in a coal-based direct ironmaking process and a reduction in equipment investment in a coal gasification process. A waste heat boiler in the system recovers heat of gas exhausted from a coal gasification furnace. A heater in exhaust gas lines of a heat reduction furnace in the coal-based direct ironmaking process superheats the steam generated by and exhausted from the waste heat boiler. A superheated steam line supplies the steam superheated by the heater as an oxidant to the coal gasification furnace.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: August 13, 2013
    Assignee: Kobe Steel, Ltd.
    Inventors: Masataka Tateishi, Masahiro Motoyuki
  • Patent number: 7341658
    Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: March 11, 2008
    Assignee: Tatanium Corporation Inc.
    Inventor: Robert G. Reeves
  • Patent number: 6692549
    Abstract: The present invention generally relates to processes and apparatuses for the integration of a blast furnace and an air separation plant to increase blast furnace production. The present invention recovers energy from the air separation through the expansion of a product stream.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: February 17, 2004
    Assignee: Air Liquide Process and Construction, Inc.
    Inventors: Bao Ha, Jean-Renaud Brugerolle
  • Publication number: 20030192405
    Abstract: The invention relates to a steelmaking thermal energy recovery system. The steelmaking thermal energy recovery system comprises a steelmaking waste flue gas, a calcinable material, and a kiln. The steelmaking waste flue gas provides at least a portion of the thermal energy to the kiln for calcination of the calcinable material.
    Type: Application
    Filed: April 15, 2002
    Publication date: October 16, 2003
    Inventor: Willard K. McClintock
  • Patent number: 6592646
    Abstract: In a method of producing direct reduced iron with use of a coal-derived gas, coal is heated to lower the moisture thereof, and the moisture-lowered coal is gasified in a coal gasification furnace to produce a coal-derived gas containing a reducing gas. The reducing gas is then utilized to reduce iron ore in an iron ore reducing furnace. With use of an exhaust gas from the iron ore reducing furnace, the coal is heated in the step of heating coal.
    Type: Grant
    Filed: October 3, 2001
    Date of Patent: July 15, 2003
    Assignees: Kabushiki Kaisha Kobe Seiko Sho, Babcock-Hitachi Kabushiki Kaisha
    Inventors: Takuo Shigehisa, Jinichi Tomuro, Eiichiro Makino
  • Patent number: 6572674
    Abstract: Steel work gases (blast-furnace gases, coke-oven gases, converter gases, etc.) are burnt with an exhaust gas from a gas turbine, optionally with a supply of natural gas and of air, in a postcombustion section between the outlet of the gas turbine and the inlet of a recovery boiler, the steam from which is utilized especially for producing electrical energy.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: June 3, 2003
    Assignee: L'Air Liquide - Société Anonyme á Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Pascal Avart, Jérôme Girard, Geneviève Mure, Emmanuel Pousset
  • Patent number: 6475264
    Abstract: A process for direct smelting a metalliferous feed material is disclosed. The process includes the steps of partially reducing metalliferous feed material and substantially devolatilising coal in a pre-reduction vessel and producing a partially reduced metalliferous feed material and char. The process also includes direct smelting the partially reduced metalliferous feed material to molten metal in a direct smelting vessel using the char as a source of energy and as a reductant and post-combusting reaction gas produced in the direct smelting process with pre-heated air or oxygen-enriched air to a post-combustion level of greater than 70% to generate heat required for the direct smelting reactions and to maintain the metal in a molten state.
    Type: Grant
    Filed: March 21, 2000
    Date of Patent: November 5, 2002
    Assignee: Technological Resources Pty Ltd
    Inventor: Rodney James Dry
  • Patent number: 6379422
    Abstract: A process for direct smelting metalliferous feed material is disclosed. Iron oxides are partially reduced in a solid state in a pre-reduction vessel. The partially reduced iron oxides are smelted to molten iron in a direct smelting vessel which contains a molten bath of iron and slag and is supplied with a solid carbonaceous material as a source of reductant and energy and with an oxygen-containing gas for post-combusting carbon monoxide and hydrogen generated in the vessel. The direct smelting step generates an off-gas that contains sulphur and the off-gas is released from the direct smelting vessel. Part only of the off-gas released from the direct smelting vessel is used in the pre-reduction step to pre-reduce iron oxides in the pre-reduction vessel. Part only of the off-gas is used in the pre-reduction step in order to control the amount of sulphur that is returned with the partially reduced iron oxides to the direct smelting vessel.
    Type: Grant
    Filed: August 4, 2000
    Date of Patent: April 30, 2002
    Assignee: Technological Resources Pty. Ltd.
    Inventor: Rodney James Dry
  • Patent number: 6361757
    Abstract: This invention provides a catalyst for producing hydrogen gas from a mixed gas comprising dimethyl ether and water vapor or carbon dioxide gas, which comprises copper, iron, cobalt, palladium, iridium, platinum, rhodium, or nickel as an active component, and a method of producing synthesis gas or hydrogen gas in a high yield at a low temperature. By using the catalyst, a fuel cell, electricity generation, reduction of iron ore and the like can be carried out.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: March 26, 2002
    Assignee: NKK Corporation
    Inventors: Tsutomu Shikada, Yotaro Ohno, Norio Inoue, Masatsugu Mizuguchi, Keiji Tomura, Takeshi Furukawa, Takuya Kadowaki, Sadayoshi Iwabuchi, Takashi Ogawa, Masami Ono, Kaoru Fujimoto
  • Patent number: 6306195
    Abstract: The present invention relates to an improved process for the preparation of high grade synthetic rutile from ilmenite with pig iron as a by-product. The process comprises subjecting ilmenite to reduction with coal, cooling and removing unreacted coal to obtain a product having 80-95% metallization, smelting the metallized ilmenite mixed with less than 10% carbon (w/w) in a transferred arc plasma using arc current, under flow of inert gas for a fixed time. The metal is then separated as pig iron and TiO2 as slag, the slag ground followed by oxidation at high temperature in the presence of an oxidizing gas, the oxidized product being leached with dilute HCl followed by filtration, washing and drying to obtain synthetic rutile.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: October 23, 2001
    Assignee: Council of Scientific and Industiral Research
    Inventors: Pawvathu Narayanan Nair Mohan Das, Karval Harikrishna Bhat, Melay Eriyat Kochu Janaki, Sreedharan Sasibhushanan, Parthasarathi Mukherjee, Bishnu Charan Rabindha Mohanty, Hem Shanker Ray
  • Patent number: 6251160
    Abstract: In a process for dechroming, and/or depleting the MgO content of, steel slags, oxygen is introduced into the liquid steel slag to an extent sufficient for converting iron quantitatively to iron oxide and at least 5% by weight of the iron oxide contained in the slag to iron-III-oxide. The oxidized slag obtained solidifies and is disintegrated, whereupon the paramagnetic portions formed are magnetically isolated and separated from the dechromed slag.
    Type: Grant
    Filed: April 23, 1999
    Date of Patent: June 26, 2001
    Assignee: “Holderbank” Financiere Glarus AG
    Inventor: Alfred Edlinger
  • Patent number: 6152984
    Abstract: A system for producing directly reduced iron integrated with a turbine power generator and preferably a cryogenic air separation plant wherein off-gas from the direct reduction drives the turbine and preferably oxygen from the air separation plant is used to generate synthesis gas for the direct reduction and nitrogen from the air separation plant dampens NOx generation and augments power generation in the turbine.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: November 28, 2000
    Assignee: Praxair Technology, Inc.
    Inventor: Raymond Francis Drnevich
  • Patent number: 6068677
    Abstract: The method for processing waste or waste fractions, such as, for example, household refuse, car shredder light fractions or the like, provides for pyrolysis, gasification and/or combustion, whereupon the residues are melted under reducing conditions. The reduced portions are then are subjected to a stepwise oxidation, with chromium being quantitatively separated in a first oxidation stage. After this, a calcium ferrite slag is formed by further oxidation, whereupon the remaining metal bath is further processed in order to recover nonferrous heavy metals.
    Type: Grant
    Filed: August 5, 1997
    Date of Patent: May 30, 2000
    Assignee: "Holderbank" Financiere Glarus AG
    Inventor: Alfred Edlinger
  • Patent number: 6053961
    Abstract: Method and apparatus for smelting iron ore in which iron ore is preheated and partly reduced within a first reaction zone and then further reduced in a second reaction zone. The first reaction zone can be a shaft reduction furnace and the second reaction zone can be a melter gasifier. An auxiliary third reaction zone partially oxidizes a carbonaceous material to produce char for the third reaction zone. A reducing gas produced by partial oxidation of the char is used to effect the partial reduction conducted within the first reaction zone. Volatile substances contained within a heating gas produced by the partial oxidation within the auxiliary third reaction zone is further oxidized and used to preheat the iron ore within the first reaction zone.
    Type: Grant
    Filed: March 17, 1998
    Date of Patent: April 25, 2000
    Assignee: The BOC Group, Inc.
    Inventor: Donald Prentice Satchell, Jr.
  • Patent number: 6051048
    Abstract: A first, solid, carbon-containing fuel is gasified and iron is melted in a gasifier-melter. A first flow of resulting fuel gas is employed to form the iron in a vertical shaft furnace by direct reduction of iron ore. A second flow of resulting fuel gas is mixed with fuel gas produced by separately gasifying a second carbon-containing fuel in a second gasifier, in which no iron is melted and which supplies essentially no carbonaceous solid fuel to the first gasification stage. This mixing helps to dampen fluctuations in the flow rate of the second flow of the resulting fuel gas.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: April 18, 2000
    Assignee: The BOC Group plc
    Inventor: Brian Anthony Keenan
  • Patent number: 6033456
    Abstract: The present invention relates to an integrated process and apparatus for supplying at least a portion of, or substantially all, or all of the reducing gas feedstock to a reduction reactor, such as a reactor for the direct reduction of iron, wherein the reducing gas contacts a feed material at a mean operating gas pressure and effects reduction of the feed material to provide a reduced product. The integrated process includes the production of a hydrogen-rich gas by the partial oxidation of a hydrocarbonaceous feedstock to produce a hydrogen-rich gas, which can also be referred to as a synthesis gas or syngas. The synthesis gas is at a pressure substantially greater than the mean operating gas pressure in the reduction reactor. The synthesis gas is expanded to lower its pressure to substantially the mean operating gas pressure in the DRI reduction reactor to thereby form the reducing gas feedstock at the pressure conditions used for the DRI reaction.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: March 7, 2000
    Assignee: Texaco Inc.
    Inventor: Frederick C. Jahnke
  • Patent number: 6030430
    Abstract: Described herein is an Improved Converter System designed to help reduce air, land and water pollution by completely converting materials that presently cause pollution into clean burning fuels and a host of other products beneficial to mankind. The primary conversion unit in the system is a zone controlled multipurpose slagging-ash oxygen jet blast converter. All incoming materials are passed through this process computer aided talented offspring of its two ancient prototypes the blast furnace and slagging-ash gas producers and the zone controlled blast furnaces described in U.S. Pat. Nos. 4,381,938, 4,495,054, 3,928,023 and 3,814,404. It employs two sets of tuyeres located in the bosh to input endothermic reacting gases, vapors and dusts through tuyere sets T1 and T2. A 100% oxygen jet blast is also input through tuyere set T2.
    Type: Grant
    Filed: July 24, 1998
    Date of Patent: February 29, 2000
    Assignees: Material Conversions, Inc., Improved Converters Inc.
    Inventors: H. Bruce Claflin, John Jasbinsek
  • Patent number: 5653182
    Abstract: Method for neutralizing waste, such as powder from luminescent tubes and similarly, residue from incineration of household waste, optionally comprising environmentally hazardous components, such as Hg, Cd, Zn, Co or Ba. The waste is fed into a melting furnace in conjunction with an SiO.sub.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: August 5, 1997
    Assignee: HAS Holding AS
    Inventor: Arvid Inge Sorvik
  • Patent number: 5643354
    Abstract: A direct ironmaking process in which coal and oxygen are used directly for reducing ore and smelting the resulting sponge iron wherein a high-temperature ion transport membrane process recovers oxygen for use in the ironmaking process. Heat for oxygen recovery is provided by combustion of medium-BTU fuel gas generated by the ironmaking process and/or by heat exchange with hot gas provided by the ironmaking process. The ironmaking and oxygen recovery processes can be integrated with a combined cycle power generation system to provide an efficient method for the production of iron, oxygen, and electric power.
    Type: Grant
    Filed: April 6, 1995
    Date of Patent: July 1, 1997
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Rakesh Agrawal, Michael Shi-Kuan Chen, Arthur Ramsden Smith, Robert Michael Thorogood, Thomas Joseph Ward
  • Patent number: 5630862
    Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising petroleum coke and the sulfur and heavy metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier having an upper fuel charging end, a reduction gas discharging end, a lower molten metal and slag collection end, and means providing an entry for charging ferrous material into the melter gasifier; introducing a carbonaceous fuel including petroleum coke into the melter gasifier at the upper fuel charging end; blowing oxygen-containing gas into the petroleum coke to form at least a first fluidized bed of coke particles from the petroleum coke; introducing ferrous material into the melter gasifier through the entry means, reacting petroleum coke, oxygen and particulate ferrous material to combust the major portion of the petroleum coke to produce reduction gas and molten iron or steel preproducts containing heavy metals freed
    Type: Grant
    Filed: June 15, 1995
    Date of Patent: May 20, 1997
    Assignee: Bechtel Group, Inc.
    Inventor: Richard B. Greenwalt
  • Patent number: 5613997
    Abstract: Method and apparatus for performing a metallurgical process in which a carbonaceous material is converted to a reducing gas and a metal is melted in a main reactor, particulate coal is partially oxidized in a secondary reactor to form a particulate char and a calorific gas under conditions which minimize the formation of carbon monoxide, and at least part of the char and some of the calorific gas are introduced into the main reactor.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: March 25, 1997
    Assignee: The BOC Group plc
    Inventor: Donald P. Satchell, Jr.
  • Patent number: 5529599
    Abstract: A method for the co-production of fuel and iron from coal and from iron ore respectively, which is comprised of heating the coal in the absence of oxygen to make a raw coal gas and a residual coke, and of increasing the content of free hydrogen in the coal gas through the cracking against a desulfurizing hot reagent, of the hydrocarbons contained in the gas in order to yield a hydrogen rich, desulfurized, hot reducing synthetic gas. This synthetic gas which is highly reactive, is fed through a bed of iron ore in order to directly reduce the ore to metallized iron. The off-gas exiting from the bed of ore is divided into three parts:-a first part is mixed with the raw coal gas, and is recycled for further use; a second part is used to provide the thermal energy required for the heating of the coal to make the raw gas and the coke; and a third part which is purged to maintain the process in balance, is utilized for other thermal needs.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: June 25, 1996
    Inventor: Albert Calderon
  • Patent number: 5496392
    Abstract: The present invention relates to a process for the production of metal alloys, metal oxides and slag-based products, such as mineral wool, from industrial waste materials. More specifically, the present invention relates to a process for recycling industrial waste materials into valuable commercial products, including, pure metals, metal alloys, metal oxides, and a molten slag comprising non-reducible metal oxides which thereafter can be converted to vitreous fiber and shot. Industrial waste materials suitable for use in the present invention include metal-containing waste products, particularly inorganic hazardous waste materials. The present process accomplishes total recycling in such a manner that the entire industrial waste material is consumed and converted to useful products.
    Type: Grant
    Filed: March 29, 1994
    Date of Patent: March 5, 1996
    Assignee: Enviroscience
    Inventors: Bobby H. Sims, Carl T. Philipp
  • Patent number: 5464464
    Abstract: A method for reducing particulate iron oxide and/or other iron units to molten iron utilizing gaseous hydrogen as reductant in a reducing furnace, in which the ore freely falls during the melting and reduction process. Reacted top gas is purified and recirculated through the reduction furnace, establishing a counter-flow relationship to the particulate iron oxide, thereby heating and reducing the oxide. The heat for reduction is generated by combusting a fraction of the hydrogen reductant with oxygen. Heat may also be supplied via the use of electric arc heating. Oxygen may be partially or wholly replaced with water in order to maintain reaction oxidizer ratios while reducing heat supplied to the reaction.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: November 7, 1995
    Assignee: Borealis Technical Incorporated Limited
    Inventor: Jonathan Edelson
  • Patent number: 5431710
    Abstract: A fine particle mixture of iron concentrate and pulverized flux is introduced into the upper portion of the vertical prereduction section of a sealed unitary vessel. Heated gas partially reduces the iron concentrate particles to form wustite which falls to the lower portion where it is melted to form fluid slag. The slag passes into the horizontal section of the vessel which is divided by a barrier into a reduction portion and an oxidation portion. In the reduction portion, pulverized coal and oxygen are introduced and iron oxide in the slag is reduced to iron. The entrained iron droplets in the slag are permitted to sediment in a quiescent zone where the slag is removed. The molten iron may be recovered or converted into steel by flowing through passages in the lower portion of the barrier into the oxidation portion where oxygen is introduced to remove C, Si, P and other impurities and to convert iron into steel or semi-steel. The final product and slag are separately removed from the oxidation portion.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: July 11, 1995
    Inventor: Li W. Ebenfelt
  • Patent number: 5397376
    Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising petroleum coke and the sulfur and heavy metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier having an upper fuel charging end, a reduction gas discharging end, a lower molten metal and slag collection end, and means providing an entry for charging ferrous material into the melter gasifier; introducing petroleum coke into the melter gasifier at the upper fuel charging end; blowing oxygen-containing gas into the petroleum coke to form at least a first fluidized bed of coke particles from the petroleum coke; introducing ferrous material into the melter gasifier through the entry means, reacting petroleum coke, oxygen and particulate ferrous material to combust the major portion of the petroleum coke to produce reduction gas and molten iron or steel preproducts containing heavy metals freed from combustion of the petrole
    Type: Grant
    Filed: June 30, 1993
    Date of Patent: March 14, 1995
    Assignee: Bechtel Group, Inc.
    Inventor: Richard B. Greenwalt
  • Patent number: 5380352
    Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising rubber tires and the sulfur and metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier. The metals freed from combustion of the rubber tires is contained in the molten iron and sulfur freed from combustion of the rubber tires is contained in the slag.
    Type: Grant
    Filed: May 18, 1993
    Date of Patent: January 10, 1995
    Assignee: Bechtel Group, Inc.
    Inventor: Richard B. Greenwalt
  • Patent number: 5364447
    Abstract: A smelting process for blending hazardous and non-hazardous inorganic industrial wastes with carbon or aluminum reducing agents to simultaneously recover metal alloys (reducible metals), metal oxides (volatile reducible metals), carbon dioxide and man-made vitreous fiber (non reducible metals). Wastes including hazardous wastes of U.S. EPA Series D, F, P, K, and U are pulverized and blended with liquids such as water or waste water to produce a homogeneous mass. The mass is formed into briquettes and melted in a cupola or plasma arc furnace in the presence of carbon or aluminum to reduce metals. Other types of furnaces such as an electric arc furnace may be used to avoid the steps of forming and curing briquettes. Reduction is carried out at temperatures between 1660 and 3100 degrees Fahrenheit. Calcium flux from calcium-stabilized wastes enhances mineral wool quality, lowers the sulfur content of metals and raises pH to facilitate metal reduction. Reducible metals are reduced and drawn off into molds.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: November 15, 1994
    Assignee: Enviroscience, Inc.
    Inventors: Carl T. Philipp, Bobby H. Sims
  • Patent number: 5354356
    Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising petroleum coke and the sulfur and heavy metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier having an upper fuel charging end, a reduction gas discharging end, a lower molten metal and slag collection end, and means providing an entry for charging ferrous material into the melter gasifier; introducing petroleum coke into the melter gasifier at the upper fuel charging end; blowing oxygen-containing gas into the petroleum coke to form at least a first fluidized bed of coke particles from the petroleum coke; introducing ferrous material into the melter gasifier through the entry means, reacting petroleum coke, oxygen and particulate ferrous material to combust the major portion of the petroleum coke to produce reduction gas and molten iron or steel preproducts containing heavy metals freed from combustion of the petrole
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: October 11, 1994
    Assignee: Bechtel Group Inc.
    Inventor: Richard B. Greenwalt
  • Patent number: 5338336
    Abstract: The present invention provides a method for processing environmentally undesirable materials including petroleum coke and the sulfur and heavy metals contained therein and agglomerated waste dust from an electric arc furnace and the zinc, cadmium, lead and iron oxides contained therein and of providing fuel and a charging material for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier. Metallized arc furnace waste dust material from a reduction furnace is introduced into the melter gasifier. The petroleum coke, oxygen and metallized waste dust material are reacted to produce reduction gas and molten iron from the iron oxides in the waste dust material. The molten iron contains the metals freed from combustion of the petroleum coke. The reduction gas is removed from the melter gasifier for use in the reduction furnace to produce an top off gas containing vapors of zinc, cadmium and lead.
    Type: Grant
    Filed: June 30, 1993
    Date of Patent: August 16, 1994
    Assignee: Bechtel Group, Inc.
    Inventor: Richard B. Greenwalt
  • Patent number: 5322544
    Abstract: This invention relates to the melting of scrap metal containing steel in an electric arc furnace using whole scrap rubber tires as an additional source of heat. Also, scrap rubber may be pylarized to form combustibles which are fed into the electric arc furnace for combustion.
    Type: Grant
    Filed: February 8, 1993
    Date of Patent: June 21, 1994
    Assignee: Nucor Corporation
    Inventor: Franklin L. Stebbing
  • Patent number: 5320676
    Abstract: The invention relates to a method of making iron or steel preproducts and reduction gas with a low slag forming process utilizing petroleum coke as a fuel in a melter gasifier.
    Type: Grant
    Filed: July 29, 1993
    Date of Patent: June 14, 1994
    Assignee: Bechtel Group, Inc.
    Inventor: Richard B. Greenwalt
  • Patent number: 5317862
    Abstract: In a process integration, particularly with a blast furnace, nitrogen under pressure is moisturized by the addition to it of hot, pressurized water. The moisturized nitrogen is expanded and power thereby generated. The nitrogen is not mixed with combustion gases. Improved heat balance and work recovery are achieved.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: June 7, 1994
    Assignee: The BOC Group, plc
    Inventor: Thomas Rathbone
  • Patent number: 5295351
    Abstract: In a process integration, particularly with a blast furnace, low grade fuel gas produced by the furnace is compressed and moisturized. The moisturized fuel is burnt using a major part of a compressed air stream to support its combustion. The resulting combustion gases are then expanded with the generation of power. The minor part of the air is separated into oxygen and nitrogen. Oxygen is used in the blast furnace.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: March 22, 1994
    Assignee: The BOC Group, plc
    Inventor: Thomas Rathbone
  • Patent number: 5268019
    Abstract: Air is taken from the air compressor of a gas turbine including in addition to the compressor a combustion chamber and an expansion turbine. The gas turbine drives an alternator. The air taken from the compressor is cooled in heat exchanger to remove heat of compression therefrom. The air is separated in an air separation plant into oxygen and nitrogen. A stream of oxygen is withdrawn from the plant and used in a blast furnace in which iron is made. The off-gas from the blast furnace is a low grade gaseous fuel. It is compressed in compressor which has interstage cooling to remove at least some of the heat of compression. The compressed fuel gas is passed through the heat exchanger countercurrently to the air stream. The resulting pre-heated fuel gas flows into the combustion chamber of the gas turbine and is burned therein to generate gaseous combustion products that are expanded in the turbine. A nitrogen stream is withdrawn in the air separation plant.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: December 7, 1993
    Assignee: The BOC Group plc
    Inventor: Thomas Rathbone
  • Patent number: 5259864
    Abstract: The invention provides a method for both disposing of an environmentally undesirable material comprising petroleum coke and the sulfur and heavy metals contained therein and of providing fuel for a process of making molten iron or steel preproducts and reduction gas in a melter gasifier having an upper fuel charging end, a reduction gas discharging end, a lower molten metal and slag collection end, and means providing an entry for charging ferrous material into the melter gasifier; introducing petroleum coke into the melter gasifier at the upper fuel charging end; blowing oxygen-containing gas into the petroleum coke to form at least a first fluidized bed of coke particles from the petroleum coke; introducing ferrous material into the melter gasifier through the entry means, reacting petroleum coke, oxygen and particulate ferrous material to combust the major portion of the petroleum coke to produce reduction gas and molten iron or steel preproducts containing heavy metals freed from combustion of the petrole
    Type: Grant
    Filed: October 6, 1992
    Date of Patent: November 9, 1993
    Assignee: Bechtel Group, Inc.
    Inventor: Richard B. Greenwalt
  • Patent number: 5259865
    Abstract: The invention relates to a method of making iron or steel preproducts and reduction in gas a substantially slag free process utilizing petroleum coke as a fuel in a melter gasifier.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: November 9, 1993
    Assignee: Bechtel Group, Inc.
    Inventor: Richard B. Greenwalt
  • Patent number: 5258054
    Abstract: A fine particle mixture of iron concentrate and pulverized flux is introduced into the upper portion of the vertical prereduction section of a sealed unitary vessel. Heated gas partially reduces the iron concentrate particles to form wustite which falls to the lower portion where it is melted to form fluid slag. The slag passes into the horizontal section of the vessel which is divided by a barrier into a reduction portion and an oxidation portion. In the reduction portion, pulverized coal and oxygen are introduced and the FeO in the slag is reduced to iron. The entrained iron droplets in the slag are permitted to sediment in a quiescent zone where the slag is removed. The molten iron flows through passages in the lower portion of the barrier into the oxidation portion where oxygen is introduced to remove C, Si, P and other impurities. The final product and waste are separately removed from the oxidation portion. Exhaust gases exit a vertical stack where heat is recaptured and dust particles removed.
    Type: Grant
    Filed: November 6, 1991
    Date of Patent: November 2, 1993
    Inventor: Li W. Ebenfelt
  • Patent number: 5198190
    Abstract: A method of recycling hazardous and non-hazardous industrial wastes to reclaim valuable metals, metal alloys, and metal oxides, and to produce mineral wool. Wastes including hazardous wastes of USEPA Series D, F, P, K, and U are pulverized and blended with liquids such as water or wastewater to produce a homogeneous mass. Calcium from calcium-stabilized wastes is used to enhance the quality of the mineral wool, lower the sulfur content, remove phosphorous, and raise pH to facilitate metal reduction. The mass is formed into briquettes and melted in a cupola or shaft furnace in the presence of carbon or aluminum to reduce metals. Other types of furnaces such as an electric arc furnace may be used to avoid the steps of forming and curing briquettes. Reduction is carried out at temperatures between 1660 and 3100 degrees Fahrenheit. Reducible metals are reduced and drawn off into molds. Substantial purity is obtained in the recovered reducible metals.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: March 30, 1993
    Assignee: Enviroscience, Inc.
    Inventors: Carl T. Philipp, Bobby H. Sims
  • Patent number: 5186740
    Abstract: This method of preheating scrap iron mixed with plastic, rubber and resinous, ie organic, materials and intended for electric furnaces, in particular electric arc furnaces, is characterized by transforming the plastic, rubbery or resinous and like materials of organic nature present in the scrap iron, to advantageously eliminate them by a path able to produce thermal energy usable for preheating the scrap to be melted, said path consisting of pyrolysis in an environment fed both with the scrap to be melted and with said organic materials, the whole being previously shredded.
    Type: Grant
    Filed: September 13, 1990
    Date of Patent: February 16, 1993
    Assignee: Blufin S.r.l.
    Inventor: Roberto Sancinelli
  • Patent number: 5124008
    Abstract: A method for the extraction of valuable minerals and precious metals from oil sands ore bodies or other related ore bodies that is synergistically unique in the arrangement of processes for production of valuable minerals and precious metals in an economically and environmentally acceptable manner. The oil sands ores from oil sands ore bodies and other related ores from other related ore bodies including overburden and interburden mineral ores are crushed, the hydrocarbons, if any exists in worthwhile quantities, are recovered and the resulting coarse sands, other related ores and fines streams are processed in a definite sequence using known processes to recover the valuable minerals and precious metals values. All reactants and reagents, including water, are recycled in the method and tailings ponds are not required. Heat recovery is used extensively to cogenerate almost all of the process steam and process electrical requirements for the method.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: June 23, 1992
    Assignee: Solv-Ex Corporation
    Inventors: John S. Rendall, Valentine W. Vaughn, Jr.
  • Patent number: 5076837
    Abstract: A method and apparatus for recovering work from a nitrogen stream, wherein the nitrogen is preheated via heat exchange with hot fluid from a chemical process, which process utilizes the oxygen product of the air separation. Preferably at least a part of the expanded nitrogen is utilized to preheat at least one fluid reactant of the chemical process. The chemical process may be gasification or direct reduction of iron oxide, as well as the conversion of natural gas into synthesis gas.
    Type: Grant
    Filed: October 16, 1989
    Date of Patent: December 31, 1991
    Assignee: The BOC Group plc
    Inventors: Thomas Rathbone, John T. Lavin
  • Patent number: 5066325
    Abstract: A process and arrangement are provided for the efficient generation of energy from coal, while at the same time providing for a relatively inexpensive step in processing of iron or steel, and the extraction of valuable materials such as oils from coal. An advantage to the process is that relatively low quality coals can be utilized, since the coal is pretreated before any burning operation. Generally, the process involves three interacting stages. In the First Stage, a coal liquefaction/pyrolysis procedure is utilized to drive off volatiles, and form a very low volatile char. The volatiles can be collected and utilized as a valuable oil product, such as for diesel fuel or the like. The char material is preferably pelletized and utilized as a reductant, in a Second Stage of iron reduction and melting.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: November 19, 1991
    Assignee: Northern States Power Company
    Inventor: John M. Lehto
  • Patent number: 5066326
    Abstract: Process and apparatus for the rapid efficient melting of solid ferrous metal scrap without direct exposure to water vapor, carbon dioxide, oxygen or oxygen-containing gases, using natural gas and/or other caloric gaseous fuels. The apparatus includes a furnace having a refractory base, means for introducing ferrous metal such as solid steel scrap to the well area, means for providing a slag layer over the solid steel scrap, and gas burner means for emitting one or more forced gas flames for superheating the slag layer to a liquid which covers the scrap and for agitating and circulating the molten slag to form a highly-efficient heat-transfer medium for melting and refining the steel scrap while it is insulated against contact with gases, particularly water vapor, carbon dioxide, oxygen or oxygen-containing gases. The process may operate continuously and can recover heat for scrap preheating, turbine power and other efficient uses.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: November 19, 1991
    Assignee: Gas Research Institute
    Inventors: Jagdish A. Agarwal, Richard Gannon, Victor Goldfarb, David Stickler, Jaime Woodroffe
  • Patent number: 5055131
    Abstract: A process and arrangement are provided for the efficient generation of energy from coal, while at the same time providing for a relatively inexpensive step in processing of iron or steel, and the extraction of valuable materials such as oils from coal. An advantage to the process is that relatively low quality coals can be utilized, since the coal is pretreated before any burning operation. Generally, the process involves three interacting stages. In the First Stage, a coal liquefaction/pyrolysis procedure is utilized to drive off volatiles, and form a very low volatile char. The volatiles can be collected and utilized as a valuable oil product, such as for diesel fuel or the like. The char material is preferably pelletized and utilized as a reductant, in a Second Stage of iron reduction and melting.
    Type: Grant
    Filed: October 16, 1989
    Date of Patent: October 8, 1991
    Assignee: Northern States Power Company
    Inventor: John M. Lehto
  • Patent number: 5045112
    Abstract: A process and arrangement are provided for the efficient generation of energy from coal, while at the same time providing for a relatively inexpensive step in processing of iron or steel, and the extraction of valuable materials such as oils from coal. An advantage to the process is that relatively low quality coals can be utilized, since the coal is pretreated before any burning operation. Generally, the process involves three interacting stages. In the First Stage, a coal liquefaction/pyrolysis procedure is utilized to drive off volatiles, and form a very low volatile char. The volatiles can be collected and utilized as a valuable oil product, such as for diesel fuel or the like. The char material is preferably pelletized and utilized as a reductant, in a Second Stage of iron reduction and melting.
    Type: Grant
    Filed: August 22, 1988
    Date of Patent: September 3, 1991
    Assignee: Northern States Power Company
    Inventor: John M. Lehto
  • Patent number: 4957546
    Abstract: The present invention relates to a new steelmaking process and apparatus which operates on an intermittent basis where several cycles composed of reducing and oxidizing periods are performed to create sufficient energy for melting of solid metallic charge, i.e., sponge iron, scrap, iron ore. During the reducing period, oxygen and carbonaceous material are injected through the vessel bottom thus attaining both carburization of a steam of the melt and generation of CO+H.sub.2 rich gas, and when the dissolved carbon of the melt is in the range of 3%-4%, conditions are then changed to the oxidizing period where solid metallic charge is added initially while oxygen injection is maintained, and until the solid charge has been melted, thus generating a stream of CO+CO.sub.2 gas rich in CO. In addition, other fluids and solids participate in the process, i.e., nitrogen, hydrocarbons, fluxes, and are used according to the appropriate period of the process.
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: September 18, 1990
    Assignee: Instituto Mexicano de Investigaciones Siderurgicas
    Inventor: Arturo Lazcano-Navarro