Synthetic Polyamide Patents (Class 8/531)
  • Patent number: 8556995
    Abstract: A composition comprising (a) a betaine of formula wherein R1 is a monovalent radical of an aliphatic C4-C30-hydrocarbon, R2 and R3 independently of one another represent C1-C12alkyl and X and Y independently of one another denote a bivalent radical of an aliphatic C1-C12-hydrocarbon, (b) a quaternary ammonium salt of formula (2) wherein R4 is a monovalent radical of an aliphatic C4-C30-hydrocarbon, R5, R6 and R7 independently of one another represent C1-C12alkyl, C5-C24aryl or C6-C30aralkyl, A? is halogenide, nitrate, hydrogensulfate or sulfonate, and (c) an alkoxylated fatty alcohol, is suitable as shade enhancer for the EL portion in PA/EL blends in the dyeing process using dark shade dyes.
    Type: Grant
    Filed: September 6, 2010
    Date of Patent: October 15, 2013
    Assignee: Huntsman International LLC
    Inventors: Hans Peter Haerri, Franz Gruener, Edvard Ham, Huiya Yuan, Xiaolong Lu
  • Patent number: 8535654
    Abstract: Porous, permeable particles of meta-aramid can be chlorinated or brominated to produce antimicrobial and detoxifying particles for use in applications such as, but not limited to, nonwoven webs, paper, textiles, absorbent articles, healthcare products, paints, filter materials, powder coatings, clear coatings, molded plastic articles, binders for fibrous materials, and the like. The particles can be charged with halogen before or after incorporation into the application medium. The particles can contain blends of meta-aramid with other polymers such as, but not limited to, cellulose, cellulose acetate, polyurethane, and the like. The particles will be effective at inactivation of pathogenic and odor-causing microorganisms and toxic chemical agents. The particles, which contain N-halamine units, have unexpected resistance to ultraviolet light degradation.
    Type: Grant
    Filed: September 3, 2010
    Date of Patent: September 17, 2013
    Assignee: Auburn University
    Inventors: Roy M. Broughton, Hasan Basri Kocer, Shelby Davis Worley, Annelese Felmy Maddox, Wei Liu
  • Publication number: 20120304402
    Abstract: This application relates to laundry care compositions comprising thiophene azo carboxylate fabric shading dyes and methods of treating a textile comprising such laundry care compositions.
    Type: Application
    Filed: May 31, 2012
    Publication date: December 6, 2012
    Inventors: Gregory Scot MIRACLE, Eduardo Torres, John David Bruhnke
  • Patent number: 8026308
    Abstract: A process for producing a solid dispersion comprising a resin and a functional compound dispersed therein, which comprises: kneading a powdery functional compound together with deionized water while gradually introducing the deionized water; adding a resin and, according to need, an additive to the mixture; subsequently heating and kneading the resultant mixture in a vessel which has an atmosphere causing the resin to soften at a temperature not higher than the boiling point of the deionized water and which has been tightly closed according to need so as to function like a pressure cooker to thereby disperse the functional compound into the softened resin; and kneading the resultant dispersion with heating at ordinary pressure or a reduced pressure to remove the water by vaporization.
    Type: Grant
    Filed: March 8, 2005
    Date of Patent: September 27, 2011
    Assignee: Taisei Chemical Industries, Ltd.
    Inventors: Takashi Sunamori, Kiyoshi Shingae, Kazuo Yanauchi
  • Patent number: 7942937
    Abstract: The process of the present disclosure comprises applying to the hair at least one composition comprising at least one hydrophobic film-forming polymer, at least one pigment, and at least one volatile solvent, and heating the hair covered with the composition at a temperature above 40° C.
    Type: Grant
    Filed: December 15, 2008
    Date of Patent: May 17, 2011
    Assignee: L'Oreal S.A.
    Inventor: Gaëlle Brun
  • Patent number: 7931701
    Abstract: The present invention provides a composition that permits spray dyeing of a cellulosic, such as cotton, fabric or garment. The composition includes a wetter, an alkali, a reactive dye, and water, and preferably a thickener. The present compositions are made by first mixing together the wetter, reactive dye and water to form a first solution, then mixing the thickener into the first solution to form a second solution, and thereafter mixing or merging the alkali to the second solution within five minutes prior to spray application onto the cellulosic fabric or garment.
    Type: Grant
    Filed: January 24, 2006
    Date of Patent: April 26, 2011
    Assignee: HBI Branded Apparel Enterprises, LLC
    Inventors: Ruth E. May, Martin Bentham
  • Patent number: 7931699
    Abstract: Compositions are provided for spray dyeing of a cellulosic, such as cotton, fabric or garment. The compositions include a reactive dye, a wetter, an alkali, and water. The present compositions are made by first mixing the reactive dye, the wetter, and the water to form a solution, and thereafter adding the alkali to the solution.
    Type: Grant
    Filed: December 8, 2008
    Date of Patent: April 26, 2011
    Assignee: HBI Branded Apparel Enterprises, LLC
    Inventor: Ruth E. May
  • Patent number: 7931700
    Abstract: The composition that permits spray dyeing of a cellulosic, such as cotton, fabric or garment. The composition includes a wetter, an alkali, a reactive dye, a thickener, and water. The present compositions are made by first mixing together the wetter, reactive dye and water to form a first solution, then mixing the thickener into the first solution to form a second solution, and thereafter mixing or merging the alkali to the second solution within thirty minutes prior to spray application onto the cellulosic fabric or garment.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: April 26, 2011
    Assignee: HBI Branded Apparel Enterprises, LLC
    Inventors: Ruth E May, Martin Bentham
  • Publication number: 20100125958
    Abstract: A method for yarn-dyeing split microfibers includes winding microfibers on a plurality of cones provided with outlet openings and inserting the microfiber-wound cones into a plurality of rods provided with discharge holes arranged in a lower part in a cheese dyeing machine, to load the microfibers in the cheese dyeing machine, adding an alkali agent to the microfibers in the cheese dyeing machine to induce a reduction of weight of the microfibers, spraying high-pressure water from the inside of the hollow rods through the discharge holes into the cheese dyeing machine, in a state wherein weight-reduced microfiber yarns wound on the cones are mounted on the rods, to allow the high-pressure water to pass through the microfibers through the discharge holes provided on the cone, and cause the water to remove foreign materials.
    Type: Application
    Filed: November 23, 2009
    Publication date: May 27, 2010
    Inventor: Sunghoon CHOI
  • Patent number: 7651540
    Abstract: A method of producing a multicolored textured carpet comprises blending a polyamide polymer and a color pigment to form a melt blend, extrusion spinning the melt blend to form pigmented polyamide yarns, tufting (1) the pigmented polyamide yarns and (2) white dyeable polyamide yarns into a carpet, and overdyeing the carpet with an amount of acid dye sufficient to produce the multicolored textured carpet. The color pigment and the acid dye are selected to provide desired multicolored effect in the carpet. The multicolored textured carpet having deeper color and dye light fastness is also disclosed.
    Type: Grant
    Filed: July 24, 2006
    Date of Patent: January 26, 2010
    Assignee: INVISTA Technologies S.A.R.l.
    Inventor: Sundar Mohan Rao
  • Patent number: 7597722
    Abstract: Process for manufacturing a fabric having distinctive and sharp differentially colored patterns or designs, which process comprises the steps of: (a) producing a first and a second polyamide, said polyamides having different concentrations of amine groups; (b) producing a first and a second polyamides having different concentrations of carboxyl end-groups and sulfonate groups; (c) producing a first yarn from said first polyamide and a second yarn from said second polyamide; (d) making a fabric having first surface areas defined by said first yarn and second surface areas defined by said second yarn; and (e) chemically dyeing said fabric in a dyeing bath comprising at least one anionic (acid) dyestuff and at least one cationic (basic) dyestuff, whereby said first yarn and therefore said first surface areas are dyed predominantly by said anionic dyestuff and said second yarn and therefore said second surface areas are dyed predominantly by said cationic dyestuff.
    Type: Grant
    Filed: February 19, 2004
    Date of Patent: October 6, 2009
    Assignee: Nilet Ltd.
    Inventors: Michael Eroshov, Alon Weiser, Thierry Mamodaly, Ran Rotem, Boris Streltses, Ariel Yedvab, Juliana Katz, Alexander Yermolaev, Samuel Gazit
  • Patent number: 7537621
    Abstract: A method is provided for dyeing a nonwoven fabric comprising a blend of fibers to a single color shade. The method includes selecting a nonwoven fabric formed of a blend of polyester and nylon fibers, where the polyester fibers comprise about X percent by weight of the fabric and the nylon fibers comprise about Y percent by weight of the fabric. A single bath is formulated having about X percent by weight disperse dye and about Y percent by weight acid dye, adjusted for the desired color shade/depth. The nonwoven fabric is then dyed to obtain a dyed fabric having a single color shade of at least Grade 4 when measured in accordance with AATCC Test Method 153 and a colorfastness of at least Grade 4 when measured in accordance with AATCC Test Method 61.
    Type: Grant
    Filed: July 27, 2005
    Date of Patent: May 26, 2009
    Assignee: HBI Branded Apparel Enterprises, LLC
    Inventor: Ruth E. May
  • Publication number: 20080295232
    Abstract: Systems and methods for dyeing inherently flame resistant fibers, and particularly aramid fibers, without the use of accelerants or carriers. Fabrics made from aramid fibers or blends thereof are immersed in an aqueous dye bath that includes at least one dye and at least one acid component. The temperature of the dye bath is increased from room temperature to a suitable temperature (e.g., between approximately 285° F. to 400° F.) capable of rendering the aramid fibers less crystalline so that the fibers can accept the dye. In this way, suitable color yields may be obtained without the use of accelerants or carriers as have been required in the past.
    Type: Application
    Filed: May 8, 2008
    Publication date: December 4, 2008
    Applicant: Southern Mills, Inc.
    Inventors: Rembert Joseph Truesdale, III, Phillip Howell Riggins
  • Patent number: 7396370
    Abstract: A method of dyeing or printing synthetic polyamide fiber materials, wherein (a) the fiber material is dyed or printed with at least one reactive dye, and (b) the dyed or printed fiber material is subjected to after-treatment with a reducing agent, the fiber material not being treated with polycondensable or polymerizable compounds for fixing the dye on the fiber, results in dyeings and printings that are distinguished by good fastness properties.
    Type: Grant
    Filed: June 3, 2003
    Date of Patent: July 8, 2008
    Assignee: Huntsman International LLC
    Inventors: Franz Grüner, Jürgen Schmiedl, Ulrich Fembacher, Ulrich Strahm
  • Publication number: 20080152888
    Abstract: Flame resistant stretch fabrics made from aramid fibers and elastomeric fibers and methods and systems for dyeing such fabrics while significantly retaining the stretch properties of the fabrics. Such methods and systems include the use of certain dye carriers not conventionally used in the aramid dyeing process that enable the fabric to be dyed under normal aramid dyeing conditions without eliminating or significantly impacting the stretch properties of the fabric. Such suitable dye carriers for use in the process include, but are not limited to, benzyl alcohol, butyl benzoate, n-butyl phthalimide, isopropyl phthalimide, dimethyl phthalate, biphenyl, monochlorotoluene, and combinations thereof. Phthalimides, and more particularly blends of n-butyl phthalimide and isopropyl phthalimide, have proven particularly effective at dyeing the aramid fibers at high temperatures while retaining the elastomeric properties of the fabric.
    Type: Application
    Filed: September 10, 2007
    Publication date: June 26, 2008
    Applicant: Southern Mills, Inc.
    Inventors: D. Craig Tutterow, Rembert Joseph Truesdale
  • Patent number: 7179303
    Abstract: A preparation for coloring keratin fibers containing dyes and/or dye precursors, at least one silicone oil and/or silicone gum and at least one polymer which contains at least one monomer unit corresponding to formula (I): in which n is a number of 1 to 3 and Y is a physiologically compatible anion. Also disclosed is a method of applying this preparation to keratin fibers.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: February 20, 2007
    Assignee: Henkel Kommanditgesellschaft Auf Aktien (Henkel KGaA)
    Inventors: Wolfgang Wolff, Mustafa Akram, Shigeri Tanaka, legal representative, Hiroshi Tanaka, deceased
  • Patent number: 7033669
    Abstract: Dyed sheath/core polyamide-containing fibers are disclosed. Further, methods of making dyed sheath/core polyamide-containing fibers are disclosed. Articles containing dyed sheath/core polyamide-containing fibers are also disclosed.
    Type: Grant
    Filed: February 7, 2003
    Date of Patent: April 25, 2006
    Inventor: Ronald O. Skidds
  • Patent number: 6867154
    Abstract: The present disclosure relates to patterned, flame resistant fabrics and methods of making them. Generally speaking, the fabrics comprise a plurality of high tenacity, flame resistant fibers, and a plurality of cellulosic fibers containing a flame retardant compound, and at least one color which is printed on the fabric to form the pattern. In a preferred embodiment, the flame resistant fibers are para-aramid fibers and the cellulosic fibers are rayon fibers to yield a strong, flame resistant fabric.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: March 15, 2005
    Assignee: Southern Mills, Inc.
    Inventors: Clyde C. Lunsford, Phillip H. Riggins, Michael T. Stanhope
  • Patent number: 6858044
    Abstract: Use of (PA) water-dispersible or colloidally soluble polyamides which contain hydrophilic polyalkylene glycol ether chains in the skeletal structure as wet-acting lubricants in the treatment of textile piece goods in rope or tubular form with a textile treatment agent (T) by exhaust methods from aqueous liquor under conditions which would otherwise in the textile substrate favor the formation of transport folds and/or the occurrence of friction in or on the substrate, particularly as wet-acting lubricants in the dyeing of polyamides in the jet, the corresponding wet-acting lubricants, certain polyamide preparations and certain polyamides, and their production.
    Type: Grant
    Filed: September 21, 2000
    Date of Patent: February 22, 2005
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bernard Danner, Francis Palacin
  • Patent number: 6852134
    Abstract: A method of treating articles having a textile surface (such as broadloom carpets or carpet tiles) with a stainblocker composition is disclosed. A pile surface structure having pile elements containing nylon yarns having both acid dyeability and cationic dyeability is dyed with both acid dye and cationic dye and then passed through a hot stainblocker treatment bath and a cooling zone. Substantially the entire height of each pile element is coated with a stainblocker composition whereby the pile surface structure has a stain resistance of 9 or higher on the AATCC Red 40 Stain Scale. The resulting pile surface has good color separation and stability, and no color loss from the catatonically dyeable yarns.
    Type: Grant
    Filed: January 2, 2002
    Date of Patent: February 8, 2005
    Assignee: Invista North America S.A.R.L.
    Inventors: Markus Baumann, Rainer Heinz, Klaus Stark
  • Patent number: 6818024
    Abstract: Fabric blends of inherently flame resistant fibers and flame resistant cellulosic fibers that contain a flame retardant. According to the method of production of these blends, the inherently flame resistant fibers can be dyed a full shade of color without depleting the flame retardant contained in the cellulosic fibers. In addition, the potential for laundering shrinkage of the inherently flame resistant fibers of the blends is reduced regardless of whether both, one of, or neither of the inherently flame resistant fibers and the flame resistant cellulosic fibers are dyed. Dyeing and/or shrinkage prevention of these blends is conducted at temperatures below 100° C., typically approximately between 70° C. and 100° C.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: November 16, 2004
    Assignee: Southern Mills, Inc.
    Inventors: Clyde C. Lunsford, Phillip H. Riggins, Michael T. Stanhope
  • Patent number: 6812172
    Abstract: In a preferred embodiment, the present process involves subjecting a fabric comprised of conjugate yarns to an acidic treatment, which degrades a portion of one component of the conjugate yarns and to dyeing. The acid treatment, given certain reaction kinetics, removes a portion of the polyamide element of the conjugate filament. The at least partial removal of the polyamide component results in a fabric has enhanced dyed appearance, especially when dyed a dark shade. In an alternate embodiment, the fabric may also be treated with a basic solution to improve its moisture transport properties.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: November 2, 2004
    Assignee: Milliken & Company
    Inventors: Heather J. Hayes, Crystal A. Garner, Kirkland W. Vogt, Kaushal Gandhi
  • Patent number: 6811574
    Abstract: A method of treating articles having a textile surface (such as broadloom carpets or carpet tiles) with a stainblocker composition is disclosed. After coloring, a stainblocker composition having a temperature from twenty to ninety-five degrees Celsius (20 to 95° C.) is applied. If the articles are carpet tiles, the stainblocker is applied using a flood process. The article is dried in a drying zone having a temperature in the range from seventy-five degrees Celsius to ninety-five degrees Celsius (75-95° C.) for a time sufficient to allow the stainblocker composition to react with the nylon yarn in the textile surface. Preferably, an infra-red oven is used to define the drying zone.
    Type: Grant
    Filed: January 2, 2002
    Date of Patent: November 2, 2004
    Assignee: DuPont Textiles & Interiors, Inc.
    Inventors: Markus Baumann, Helen Frances Latham
  • Patent number: 6802873
    Abstract: The invention relates to a method for producing dyed textile materials consisting of polyester and polyamide. The textile material is dyed by means of pigments or a disperse dye that stains polyester. Surplus dye is removed. The polyamide portion is dyed using vat dyes, leuco vat dyes, sulphide dyes or soluble sulphide dyes. Said dyes are vatted if this is required for obtaining a solubility and are oxidatively converted into the real dyes after attaching.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: October 12, 2004
    Assignee: Carl Freudenberg KG
    Inventors: Heike Bartl, Kurt Jörder
  • Publication number: 20040194236
    Abstract: The present invention relates to a method of mass-colouring synthetic materials, which comprises using at least one pigment dye of formula (1) wherein R and R1 together form a phenyl or heteroaryl radical and R2 is hydrogen, or R1 and R2 together form a phenyl or heteroaryl radical and R is hydrogen, and the rings A and B may each independently of the other be substituted by C1-C4?alkyl, C1-C4alkoxy, halogen, —COOR3, —CONHR4 and/or by —SR5, wherein R3, R4 and R5 are each independently of the others hydrogen, C1-C4alkyl, C6-C12aryl or heteroaryl, to synthetic materials coloured with such pigment dyes, and to novel pigment dyes of formula (3), wherein R6 is hydrogen or bromine.
    Type: Application
    Filed: January 20, 2004
    Publication date: October 7, 2004
    Inventors: Jean-Marie Adam, Jean-Pierre Bacher
  • Patent number: 6752840
    Abstract: The present invention relates to a denim-like clothing mainly including a woven or knitted fabric and having a whitening index of less than or equal to Class 4, which woven or knitted fabric includes ultrafine fibers or fibers capable of forming ultrafine fibers on its surface, and the whitening index is expressed in grey scale for assessing change in color specified in Japanese Industrial Standards (JIS). In preferred embodiments, the denim-like clothing has, for example, the following characteristics: (a) The denim-like clothing has a roughness index of equal to or more than 3 micrometers as determined using a measuring machine, KES-FB4; (b) the ultrafine fibers or the fibers capable of forming ultrafine fibers are ultrafine fibers having a fineness of less than or equal to 0.6 dtex or fibers capable of forming ultrafine fibers having a fineness of less than or equal to 0.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: June 22, 2004
    Assignee: Toray Industries, Inc.
    Inventors: Takashi Onishi, Keiji Okamoto, Yoshinobu Hirano
  • Publication number: 20040045103
    Abstract: The present disclosure relates to flame resistant fabrics that comprise a plurality of inherently flame resistant fibers and a plurality of cellulosic fibers containing a flame retardant compound. In one arrangement, the inherently flame resistant fibers have been dyed and/or shrinkage controlled with a dye-assistant such that the fabric contains a residual amount of a dye-assistant selected from the group consisting of N-cyclohexylpyrrolidone, benzyl alcohol, N,N-dibutylformamide, N,N-diethylbenzamide, hexadecyltrimethyl ammonium salt, N,N-dimethylbenzamide, N,N-diethyl-m-toluamide, N-octylpyrrolidone, aryl ether, an approximately 50/50 blend of N,N-dimethylcaprylamide and N,N-dimethylcapramide, and mixtures thereof.
    Type: Application
    Filed: September 9, 2003
    Publication date: March 11, 2004
    Inventors: Clyde C. Lunsford, Phillip H. Riggins, Michael T. Stanhope
  • Patent number: 6692541
    Abstract: The present invention relates generally to a method of making nonwoven fabrics, wherein the fabrics are formed from splittable filaments or staple length fibers having a plurality of sub-components which are at least partially separable. The filaments or fibers are at least partially separated into their sub-components attendant to hydroentanglement, which can be effected on a three-dimensional image transfer device. Improved physical properties, including improved tensile strength, elongation, and Taber Abrasion resistance are achieved.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: February 17, 2004
    Assignee: Polymer Group, Inc.
    Inventors: Cheryl Carlson, John Elves, Kyra Dorsey, Ralph A. Moody, III, Valeria Erdos
  • Patent number: 6689175
    Abstract: In a preferred embodiment, the present process involves subjecting a fabric comprised of conjugate yarns to an acidic treatment, which degrades a portion of one component of the conjugate yarns and to dyeing. The acid treatment, given certain reaction kinetics, removes a portion of the polyamide element of the conjugate filament. The at least partial removal of the polyamide component results in a fabric has enhanced dyed appearance, especially when dyed a dark shade. In an alternate embodiment, the fabric may also be treated with a basic solution to improve its moisture transport properties.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: February 10, 2004
    Assignee: Milliken & Company
    Inventors: Heather J. Hayes, Crystal A. Garner, Kirkland W. Vogt, Kaushal Gandhi
  • Patent number: 6626964
    Abstract: The present disclosure relates to flame resistant fabrics that comprise a plurality of inherently flame resistant fibers and a plurality of cellulosic fibers containing a flame retardant compound. In one arrangement, the inherently flame resistant fibers have been dyed and/or shrinkage controlled with a dye-assistant such that the fabric contains a residual amount of a dye-assistant selected from the group consisting of N-cyclohexylpyrrolidone, benzyl alcohol, N,N-dibutylformamide, N,N-diethylbenzamide, hexadecyltrimethyl ammonium salt, N,N-dimethylbenzamide, N,N-diethyl-m-toluamide, N-octylpyrrolidone, aryl ether, an approximately 50/50 blend of N,N-dimethylcaprylamide and N,N-dimethylcapramide, and mixtures thereof.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: September 30, 2003
    Inventors: Clyde C. Lunsford, Phillip H. Riggins, Michael T. Stanhope
  • Publication number: 20030167580
    Abstract: Fabric blends of inherently flame resistant fibers and flame resistant cellulosic fibers that contain a flame retardant. According to the method of production of these blends, the inherently flame resistant fibers can be dyed a full shade of color without depleting the flame retardant contained in the cellulosic fibers. In addition, the potential for laundering shrinkage of the inherently flame resistant fibers of the blends is reduced regardless of whether both, one of, or neither of the inherently flame resistant fibers and the flame resistant cellulosic fibers are dyed. Dyeing and/or shrinkage prevention of these blends is conducted at temperatures below 100° C., typically approximately between 70° C. and 100° C.
    Type: Application
    Filed: January 17, 2003
    Publication date: September 11, 2003
    Inventors: Clyde C. Lunsford, Phillip H. Riggins, Michael T. Stanhope
  • Patent number: 6607563
    Abstract: Provided is a hair dye composition containing a direct dye A—D═D—B. This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye even after storage. A represents any one of the following groups (2) to (8): (in which R1, R4, R5 and R6 each represents H, (substituted) C1-6 alkyl group, etc., R2 and R3 each represents (substituted) C1-6 alkyl group, etc., or form, when taken together with the adjacent C, a cycloalkane ring, Q represents N or group CR′, R7 represents (substituted) aralkyl group or a group CH2—CH(OH)—CH2—OR″, R8 and R9 each represents H, (substituted) C1-6 alkyl, etc., or form, when taken together with the adjacent N, a heterocycle, X− represents an anion, and rings C-I may each have a further substituent or a condensed ring), D represents N or group CR′″, and B represents the residue of a coupling component.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: August 19, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga, Shintaro Totoki, Yoshinori Saito
  • Patent number: 6576025
    Abstract: The instant invention is directed to dyed fabric blends of aramid fibers and flame resistant (FR) cellulosic fibers, which retains a substantial amount of its strength and durability after dyeing. The dyeing process comprises the steps of: providing a fabric comprising a blend of aramid fibers and cellulosic fibers, dyeing the cellulosic fibers of the fabric, and dyeing the aramid fibers of the fabric. Dyeing of the aramid fibers being preformed with low agitation, an aryl ester carrier, and, preferably, at a temperature between 100-110° C.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: June 10, 2003
    Assignee: Difco Performance Fabrics, Inc.
    Inventor: Francois Lapierre
  • Patent number: 6547835
    Abstract: Fabric blends of inherently flame resistant fibers and flame resistant cellulosic fibers that contain a flame retardant. According to the method of production of these blends, the inherently flame resistant fibers can be dyed a full shade of color without depleting the flame retardant contained in the cellulosic fibers. In addition, the potential for laundering shrinkage of the inherently flame resistant fibers of the blends is reduced regardless of whether both, one of, or neither of the inherently flame resistant fibers and the flame resistant cellulosic fibers are dyed. Dyeing and/or shrinkage prevention of these blends is conducted at temperatures below 100° C., typically approximately between 70° C. and 100° C.
    Type: Grant
    Filed: July 6, 2000
    Date of Patent: April 15, 2003
    Assignee: Southern Mills, Inc.
    Inventors: Clyde C. Lunsford, Phillip H. Riggins, Michael T. Stanhope
  • Patent number: 6527815
    Abstract: Textiles made of synthetic fibers and synthetic fiber blended fabrics are constructed in the form of a garment then dyed while avoiding setting permanent creases and permanent wrinkles in the garment. The process includes selecting a synthetic or synthetic blended fabric for the dyeing process by determining the fabric's shrinkage in the warp and fill directions, for instance no greater than 6%, constructing a garment from the fabric selected, then dyeing the constructed garment in an aqueous dyebath at a temperature in the range of 220 to 260° F. for a time sufficient to achieve a desired shade and levelness of color followed by drying and optionally pressing the dyed garment.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: March 4, 2003
    Assignee: Burlington Industries, Inc.
    Inventors: Katherine T. Bryant, John E. Newbern, Earl E. Bradsher, III, Terry L. Currans, G. Lewis Best, III, Ashutosh Karnik, John W. McAnulty
  • Patent number: 6524503
    Abstract: A process for the manufacturing of a differentially dyeable yarn includes the steps of: a) producing two polymers having a different concentration of amine end-groups; b) spinning yarns from said two polymers; and c) producing a yarn by intermingling said spun yarns made from said two polymers, in texturing, or draw twisting, or draw winding processes.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: February 25, 2003
    Assignee: Nilit Ltd.
    Inventors: Samuel Gazit, Ran Rotem, Uri Afek, Martin Blutstein, Alon Weiser
  • Patent number: 6495660
    Abstract: A process for making a polyamide substrate characterized by enhanced breaking strength and fade resistance is disclosed. The process features the steps of treating a polyamide substrate, preferably a nylon 6 substrate having a hindered amine light stabilizer chemically bound thereto, with an effective amount of an ultraviolet inhibitor, an antioxidant and optionally, a dye, in the presence of a swelling agent for the polyamide that is also a solvent for the ultraviolet inhibitor and the antioxidant to impart high breaking strength to the substrate. A life preserver or other type of buoyancy device may be made from the process. A polyamide fabric comprising a dye, an ultraviolet inhibitor and an antioxidant also is disclosed. When a polyamide fiber of the present invention is exposed to sunlight, the useful life of the fiber is greatly increased compared to untreated polyamide fiber.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: December 17, 2002
    Assignee: Honeywell International Inc
    Inventor: Donald Ray Long
  • Patent number: 6258928
    Abstract: A process for improving characteristics such as, whiteness retention, degradation, and dyeability of a polyamide by contacting the polyamide with thiocyanate. A polyamide produced by the process has improved dyed color depth, dyed color uniformity, hue, elimination of light dyeing ends, protection of dye sites from degradation, protection from UV degradation, reduced yellowing or oxidation, and/or resistance to loss of dyeability.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: July 10, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Bennett Ray Baird, David Malcolm Lewis, Kamleshkumar Chunilal Patel
  • Patent number: 6132476
    Abstract: Fabric blends of inherently flame resistant fibers and flame resistant cellulosic fibers that contain a flame retardant. According to the method of production of these blends, the inherently flame resistant fibers can be dyed a full shade of color without depleting the flame retardant contained in the cellulosic fibers. In addition, the potential for laundering shrinkage of the inherently flame resistant fibers of the blends is reduced regardless of whether both, one of, or neither of the inherently flame resistant fibers and the flame resistant cellulosic fibers are dyed. Dyeing and/or shrinkage prevention of these blends is conducted at temperatures below 100.degree. C., typically approximately between 70.degree. C. and 100.degree. C.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: October 17, 2000
    Assignee: Southern Mills, Inc.
    Inventors: Clyde C. Lunsford, Phillip H. Riggins, Michael T. Stanhope
  • Patent number: 6129879
    Abstract: Process for treating a textile product comprising propylene polymer fibers comprises heating the textile product with the fibers in a substantially relaxed state at at least one temperature that is below the melting point of the propylene polymer but no more than about 20.degree. C. below such melting point. In one embodiment, the propylene polymer fibers subjected to such heating are characterized by a particular crystalline microstructure as determined by small angle X-ray diffraction. In another embodiment, the propylene polymer fibers subjected to such heating are melt spun, oriented fibers heated at at least one lower temperature.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: October 10, 2000
    Assignee: BP Amoco Corporation
    Inventors: Bruce Howard Bersted, Richard Tutt Norris, Jr., Leonid Slutsker, Ty Jackson Stokes
  • Patent number: 6086638
    Abstract: The method for dyeing a polyamide fabric of the present invention comprises the step of dyeing a polyamide fabric having structural variations in the longitudinal direction of the fibers, by a dye liquor containing an anionic reactive dye and regulated at pH 3.about.8. The dyed product of the present invention is a dyed polyamide fabric obtained by said dyeing method. Furthermore, the dyed product of the present invention is obtained as a grandrelle tone dyed product by dyeing a polyamide fabric having structural variations in the longitudinal direction of the fibers by a reactive dye, and being 4th or higher grade in the wash fastness specified in JIS L-0844.The present invention can provide a method for dyeing a polyamide fabric in a clear high grade grandrelle tone and to have excellent wash fastness, and also a grandrelle tone dyed product.
    Type: Grant
    Filed: April 6, 1999
    Date of Patent: July 11, 2000
    Assignee: Toray Industries, Inc.
    Inventors: Tomoyuki Horiguchi, Yutaka Masuda, Katsuhiko Mochizuki
  • Patent number: 6042616
    Abstract: A method for finishing a cellulose fiber-containing textile fabric comprises treating a cellulose fiber-containing textile fabric with liquid ammonia, applying a resin finishing agent to said fabric, subjecting subsequently to either or both of a hot calendering treatment and a heat treatment, and finally treating the resultant fabric with hot water. The resultant fabric keeps its shape stability including a crease or shrink resistance when washed, without involving any problem on residual formaldehyde.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: March 28, 2000
    Assignee: Nisshinbo Industries, Inc.
    Inventors: Yuichi Yanai, Masayoshi Oba, Kazuhiko Ichimura, Yasushi Takagi, Kazuhiko Harada
  • Patent number: 5998592
    Abstract: A monoazo dye of the formula: ##STR1## wherein: R.sup.1 represents --C.sub.3 H.sub.6 CN, --C.sub.2 H.sub.4 Cl, --C.sub.3 H.sub.6 Cl, --C.sub.2 H.sub.4 OCOCH.sub.3 or --C.sub.2 H.sub.4 OCOCH.sub.2 Cl;R.sup.2 and R.sup.3 each independently represent a C.sub.1-4 -alkyl group; andR.sup.4, R.sup.5 and R.sup.6 each independently represent H, F, Cl, Br, I, --SO.sub.2 F, or an organic moiety selected from the group consisting of C.sub.1-6 alkyl, C.sub.1-6 alkoxy, C.sub.1-4 alkanoylamino, --NHSO.sub.2 alkyl, --NHCOC.sub.1-4 alkyl and -Ophenyl moieties, each organic moiety being unsubstituted or substituted by at least one nonionic substituent.
    Type: Grant
    Filed: August 17, 1998
    Date of Patent: December 7, 1999
    Assignee: BASF Aktiengesellschaft
    Inventor: Nigel Hall
  • Patent number: 5922088
    Abstract: A process for fixing dyes impregnated in fine-dimensional synthetic textile substrates in an environmentally safe manner. The process comprises contacting the dyed synthetic substrates with a phenol- and formaldehyde-free dye-fixative composition comprising:(a) polymethacrylic acid,(b) copolymers of methacrylic acid consisting essentially of methacrylic acid and an ethylenically unsaturated comonomer selected from the group consisting of 2-acrylamido-2-methyl-propanesulfonic acid, sodium vinyl sulfonate, sodium styrene sulfonate, alkyl acrylate,(c) sulfamic acid, and(d) combinations of (a), (b) and (c).
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: July 13, 1999
    Assignee: Henkel Corporation
    Inventors: Howard Cole, Brian Francois, David I. Devore
  • Patent number: 5876466
    Abstract: Suede-like artificial leather is described that is treated with at least one dye selected from the group consisting of sulfur dyes, vat dyes and sulfur vat dyes, and 2,2',4,4'-tetrahydroxy benzophenone. The suede-like artificial leather has excellent color resistance to light and color fastness to both washing and dry-cleaning.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: March 2, 1999
    Assignee: Kuraray Co., Ltd.
    Inventors: Hitoshi Nakashima, Hisao Yoneda
  • Patent number: 5810890
    Abstract: A process for dyeing synthetic polyamide fibers, in particular in form of micro fibers, is described comprising the use of polyamide fibers having an amino end group content of at least 60 gram equivalents per 1000 kilograms of polyamide polymer and using a dye composition of water-soluble dyes containing at least one dye having 1 or 2 vinylsulfonyl groups and at least 1 dye having 1 or 2 groups of the general formula (A)--SO.sub.2 --CH.sub.2 --CH.sub.2 --N(R)--V--X (A)(in which R is hydrogen or alkyl of 1 to 4 carbon atoms which may be interrupted by 1 or 2 hetero groups and substituted by sulfo, carboxy, hydroxy, sulfato, phosphato and/or lower alkanoylamino, V is a covalent bond or alkylene of 2 to 4 carbon atoms or a group of the formula --CO--NH--CH.sub.2 --CH.sub.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: September 22, 1998
    Assignee: Dystar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Werner Hubert Russ, Mike Elliott, Robert Dewhurst, Charles Richard Langrick, David John Marfell
  • Patent number: 5811040
    Abstract: The specification describes a process of making a fiber for a carpet face yarn, the yarn being made of polyolefin/polymer filaments which contain a plurality of longitudinally dispersed relatively small, short polymer fibrils inside the filaments generally concentrated toward the center thereof within the polyolefm matrix. The yarn has the stain resistant properties of polyolefm based yarns and the resiliency of polyamide based yarns at a substantially lower cost than nylon carpet yarns.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: September 22, 1998
    Inventor: William C. Mallonee
  • Patent number: 5587118
    Abstract: The specification describes a conjugate carpet face yarn including trilobal or delta cross-section polyolefin filaments and a plurality of generally co-linear smaller polyamide fibrils embedded within the polyolefin filaments. This yarn has the stain resistant properties of polyolefin based yarns and the resiliency of polyamide based yarns.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: December 24, 1996
    Inventor: William C. Mallonee
  • Patent number: 5560973
    Abstract: A process for preparing melt spun polymeric fiber made from polymerized amide monomers includes the steps of pigmenting the polymer, incorporating within the polymer sufficient SO.sub.3 H groups or salts thereof to give the polymer a sulphur content of between about 10 and about 160 equivalents per 10.sup.6 grams polymer and thereafter chemically blocking with a chemical blocking agent a portion of amino end groups present in the sulphonated polymer.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: October 1, 1996
    Assignee: BASF Corporation
    Inventors: Matthew B. Hoyt, Andrew M. Coons, III, David N. Dickson
  • Patent number: 5527887
    Abstract: Disazo acid dyestuff with the following general formula: ##STR1## wherein R represents H, C.sub.n H.sub.2n+1 wherein n is a natural number between 1 and 4, or (CH.sub.2).sub.m OR' wherein m is a natural number between 1 and 4 and R' represents C.sub.p H.sub.2p+1 wherein p is an integral number between 0 and 4; wherein R" represents H, CN or COOR wherein R has the same definition as above. The sulfo group may be at any position of the benzene ring.
    Type: Grant
    Filed: January 12, 1995
    Date of Patent: June 18, 1996
    Assignee: Allied Industrial Corp., Ltd.
    Inventors: Hsien-Chyang Tsien, Chen-Kung Chi, Hung Chang