Abstract: Continuously variable headlamps offer greater flexibility for roadway illumination but offer challenges in automatic control design. Each continuously variable headlamp has an effective illumination range varied by changing at least one parameter from a set including horizontal direction aimed, vertical direction aimed, and intensity emitted. A system for automatically controlling continuously variable headlamps on a controlled vehicle includes an imaging system capable of determining lateral and elevational locations of headlamps from oncoming vehicles and tail lamps from leading vehicles. The system also includes a control unit that can acquire an image from in front of the controlled vehicle. The image covers a glare area including points at which drivers of oncoming and leading vehicles would perceive the headlamps to cause excessive glare. The image is processed to determine if at least one oncoming or leading is within the glare area.

Abstract: An improved electrochromic rearview mirror for motor vehicles, the mirror incorporating thin front and rear spaced glass elements having a thickness ranging from about 0.5 to about 1.5. A layer of transparent conductive material is placed onto the mirror's second surface, and either another layer of transparent conductive material or a combined reflector/electrode is placed onto the mirror's third surface. A chamber, defined by the layers on the interior surfaces of the front and rear glass elements and a peripheral sealing member, contains a free-standing gel comprising a solvent and a crosslinked polymer matrix. The chamber further contains at least one electrochromic material in solution with the solvent and interspersed in the crosslinked polymer matrix.

Abstract: Anodic electrochromic materials for use in an electrochromic device comprising a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene, and a second moiety, wherein the second moiety comprises at least one constituent which serves to increase the solubility of the first moiety in an associated solvent relative to solubility of the first moiety without the second moiety.

Abstract: A control system for automatically detecting moisture on the windshield of a vehicle. The automatic moisture detecting system includes an optical system for imaging a portion of the windshield on to an image array sensor, such as a CMOS active pixel sensor. The voltages of each of the pixels which represents the illumination level is converted to a corresponding gray scale value by an analog digital converter. The gray scale values corresponding to the image are stored in memory. The spatial frequency composition of the gray scale values are analyzed to determine the amount of rain present. In order to provide a control signal to control the operation of the windshield wipers of the vehicle as a function of the amount of moisture present. The system is also adapted to detect the level of fog both on the interior of the windshield as well as the exterior of the windshield.

Abstract: Coupling of anodic electrochromic compounds by a covalent bond or a bridge link which provides for electronic communication between the coupled electrochromic compounds results in coupled electrochromic compounds which exhibit greater stability as well as electrochromic activity that differs from the monomeric electrochromic compounds. Extension of the absorption spectrum into the near-infrared region of the spectrum is frequently observed. The coupled electrochromic compounds are highly suitable for use in electrochromic media used to produce electrochromic devices.

Abstract: The present invention provides improved electrochromic layers, which comprise polymeric matrices with electrochromic solutions interspersed therein. Varying an electrical potential difference across a layer of the invention results in reversible variation in the transmittance of light across the layer because of electrochemical processes in the electrochromic solution of the layer. The invention further provides electrochromic devices, in which the electrochromic layers of the invention provide reversibly variable transmittance to light, and various apparatus in which the devices of the invention provide light-filtering or light-color modulation. Such apparatus include windows, including those for use inside and on the outside walls of buildings and in sunroofs for automobiles, and variable reflectance mirrors, especially rearview mirrors for automobiles.

Abstract: A control system for a plurality of electrochromic elements, for example, used in automobiles, to control the glare of the IEC elements used as a rearview mirror (20) as well as the OEC elements (24, 26) used as sideview mirrors (24, 26). The IEC element and each of the OEC elements is provided with an individual drive circuit (21, 22). The drive circuits for the OEC's elements may be customized to account for various factors such as the type of curvature as well as the size and shape. Since individual drive circuitry is provided for the IEC elements and each of the OEC elements, the reflectance of each of the electrochromic elements (20, 24, 26) can be relatively accurately controlled by way of glare signal from inside the automobile.

Abstract: A simplified mirror sub-assembly for exterior automotive mirrors includes an electrochromic mirror element, a circuit board disposed on a rear surface of the mirror element, and a carrier plate attached to the circuit board via double-sided adhesive tape. The sub-assembly may include a conductive trace disposed on the surface of the circuit board that mates with the mirror element to dissipate heat generated by electronic components on the circuit board and act as a heater for the mirror element at the same time. The electronic components on the circuit board are arranged to lie in a void created by a peripheral edge in the carrier plate so that the inventive structure can incorporate a known carrier plate structure, if desired, to allow easy installation into a known mirror housing.

Abstract: Dihydrophenazines and bis(dihydrophenazines) are prepared in high yield under commercially viable reaction conditions by reacting a catechol with a 1,2-diaminoaryl compound, wherein either the catechol or the 1,2-diaminoaryl compound is provided in at least 50% molar stoichiometric excess. The product may be oxidized to the corresponding phenazine, but is preferably derivatized at one or both of the 5,10-positions to form a monosubstituted or disubstituted dihydrophenazine or bis(dihydrophenazine). Most preferably, 5,10-dialkyl-5,10-dihydrophenazines are prepared starting from catechol and 1,2-diaminoaryl compound in a one pot synthesis. The products are useful as dyes, and in particular as chromophores in electrochromic systems.

Abstract: Electrochromic windows and panels are provided which have first and second spaced elements that are optically transparent to visible light. The first and second elements each have first and second sides, and the windows and panels define a sealed chamber disposed between the second side of the first element and the first side of the second element. The sealed chamber is filled with an electrochromic medium, and the transmission of visible light through the electrochromic medium is variable when an electrical potential is applied to electrically conductive coatings that are provided on the second side of the first element and the first side of the second element.

Abstract: A mirror assembly for a vehicle includes a housing defining a cavity and a front opening, and an electrochromic mirror subassembly supported in the front opening. A support plate is supported by the housing in the cavity, and a printed circuit board is supported behind the support plate. The support plate includes a front surface located proximate but spaced rearward of a rear surface of the mirror subassembly to form a thin gap of about 0.3 mm to 1.0 mm, and preferably of about 0.5 mm, therebetween. The support plate covers at least about 50%, and preferably about 80%, of glass elements in the mirror subassembly. The support plate includes forwardly-oriented biasing fingers shaped to press on a back perimeter of the mirror subassembly to maintain the gap without distorting the mirror subassembly. The support plate permits flexure of the mirror subassembly into the thin gap, but prevents excessive deformation of the mirror subassembly, thus reducing a tendency of the mirror subassembly to fracture.

Abstract: An electrochromic element driver has a feedback loop that imparts a negative output resistance wherein the drive voltage across the electrochromic element varies in response to changes in current draw by the electrochromic element. The amount of current drawn by the electrochromic element varies as a function of temperature. At high temperatures, the drive voltage increases, enabling the electrochromic element to darken uniformly at high temperatures. At lower temperatures, the drive voltage decreases, improving the useful life of the electrochromic element. Transitions between the opaque and non-opaque states are achieved quickly, and steady state currents are lower than in many conventional implementations, decreasing power consumption.

Abstract: A time-independent, event-based system for receiving and discriminating unique codes from multiple transmitters has an event-based detection cycle instead of a time-based detection cycle. The system detects received ID codes from multiple transmitters and compares the received ID codes with registers for ID codes in an array in memory. Counters corresponding to the stored ID codes increment each time there is a match between the received ID code and the stored ID code. After a predetermined total number of increments, the system evaluates the received signals to discriminate between ID codes received from desired transmitters and those from undesired transmitters before resetting the counter. Because the system is event based and not a function of time, it will operate over a wide range of time cycles.

Abstract: Single-compartment, self-erasing, solution-phase electrochromic devices, solutions of electrochromic compounds for use as media of variable transmittance in such devices, and electrochromic compounds for such solutions are provided. The devices of the invention are surprisingly stable to cycling between light and dark states, have continuously variable transmittance to light as a function of electrical potential applied across the solution in a device, and have transmittance that can be varied over more than a factor of 10, from clear to dark or from dark to clear, in several seconds. Thus, the devices are especially suitable as variable transmittance components of variable transmission light filters, including windows, and variable reflectance mirrors, including anti-glare rearview mirrors in automobiles.

Abstract: An improved seal member is provided as a part of an electrochromic device to bond two glass elements together in a spaced-apart relationship. In one embodiment the seal member provides improved adhesion to a reflector/electrode on the third surface of an electrochromic mirror, or to a layer of metal on the second or third surface for an electrochromic light filter. This seal member comprises a mixture of an organic resin scaling system and an adhesion promoter, where the adhesion promotor comprises a first and a second region, where the first region interacts with the reflector/electrode or the metal layer, and a second region that interacts with the organic resin sealing system, and may even chemically react with the organic resin sealing system. In another embodiment the seal member is provided with a coefficient of thermal expansion that is closer to glass than a standard epoxy sealing system.

Abstract: An electrochromic assembly includes a transparent front element and a rear element each having front and rear surfaces. At least one of the front and rear elements is made from a plastic that maintains its integrity when exposed to organic solvents. A layer of transparent conductive material is disposed on the rear surface of the front element. A layer of conductive material is also disposed on the front surface of the rear element. The front element and the rear element when joined form a chamber therebetween. The chamber contains at least one electrochromic material in solution with the organic solvent, which is effective to attenuate light passing therethrough.

Abstract: Electrochromic devices and materials having enhanced daylight stability are described. The materials have a redox center linked to an energy receptor site that may serve to dissipate excited state energy from the redox center, alternatively the receptor site may absorb harmful radiation prior to the absorption by the redox center.

Abstract: Electrochromic compounds capable of reversibly attenuating the transmittance of the near infrared portion of the electromagnetic spectrum are provided. These compounds exhibit an energy difference between the singly occupied molecular orbital (SOMO) energy and the highest doubly occupied molecular orbital (HDOMO) energy (ESOMO−EHDOMO) of less than about 3.6 eV. In addition, these compounds have a transition moment of the configuration made up of the HDOMO and SOMO that is “long axis polarized”.

Abstract: A mirror and housing assembly includes a multi-layer electrochromic (EC) mirror subassembly supported by a carrier. The EC mirror subassembly includes a front transparent element and a rear element, each having front and rear surfaces, a reflector on one of the surfaces of the rear element, and further includes a seal spacing the front and rear elements apart to define a chamber therebetween. An EC material, such as solution phase, gel phase, solid phase, or a hybrid EC material, fills the chamber and is electrically connected to a control for controlled dimming of reflections from the reflector. The front and rear elements each are characteristically very thin, such as about 1.6 mm to 0.8 mm, or more preferably 1.2 mm to 1.0 mm, and most preferably 1.1 mm, such that the EC mirror subassembly is characteristically surprisingly and unexpectedly low in weight.

Abstract: An electrochromic device is disclosed having a self-cleaning, hydrophilic optical coating. The electrochromic device preferably forms an external rearview mirror for a vehicle. The coating preferably includes alternating layers of a photocatalytic material having a high index of refraction and a hydrophilic material having a low refractive index. More specifically, the coating includes a first layer having a high refractive index, a second layer having a low refractive index, a third layer of titanium dioxide, and a fourth layer of silicon dioxide provided as an outermost layer. The disclosed optical coating exhibits a reflectance at the front surface of the reflective element that is less than about 20 percent, and has sufficient hydrophilic properties such that water droplets on a front surface of the optical coating exhibit a contact angle of less than about 20°.