Patents Represented by Attorney, Agent or Law Firm David M. Shold
  • Patent number: 7045488
    Abstract: Cyclic oligomers derivable from the copolymerization of isobutylene and isoprene can be hydrogenated to form 1-(2,2,4-trimethylpentyl)-2-isopropyl-3,3,5,5-tetramethylcyclohexane and related compounds, which are useful in lubricants such as a traction fluids.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: May 16, 2006
    Assignee: The Lubrizol Corporation
    Inventors: Stuart L. Bartley, Douglas M. Barr, Richard M. Lange, Craig D. Tipton
  • Patent number: 7034079
    Abstract: A process for preparing a radial polymer comprising at least 3 polymeric arms and a central core comprising a polymerized di- or polyfunctional monomer, said process comprising the steps, (a) polymerizing at an elevated temperature, a charge comprising at least one free radical-polymerizable monomer to prepare a stabilized active polymer block (A) using a free radical polymerization process, wherein a stable free radical agent is employed during the polymerization, thereby preserving the stabilized active polymerization site at the terminus of the polymer; optionally (b) adding at least one additional free radical-polymerizable monomer, at least one of which is different from the monomers making up the first charge of monomers, to the stabilized active polymer block (A); and further reacting the mixture using a free radical process to effect copolymerization of said monomers, thereby preparing an A-B block copolymer having a stabilized active polymerization site at the terminus of the polymer; then (c) add
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: April 25, 2006
    Assignee: The Lubrizol Corporation
    Inventors: Daniel C. Visger, Richard M. Lange
  • Patent number: 6949236
    Abstract: Addition of an aminosulfonate product to an inorganic nitrogen-containing salt provides a composition of matter with improved properties. In particular, 2-acrylamido-2-methylpropanesulfonic acid and its derivatives can be added to ammonium nitrate to provide improved prills.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: September 27, 2005
    Assignee: The Lubrizol Corporation
    Inventors: Kastrui Lal, Alvin E. Haas, Ricardo M. Collins, Jeffrey M. Carey
  • Patent number: 6846782
    Abstract: This invention relates to a method of reducing intake valve deposits in a direct injection engine, the method comprising lubricating the engine with a lubricating oil composition comprising a base oil mixture, the base oil mixture comprising (i) a Group III, a Group IV oil, or a mixture thereof, in combination with (ii) a synthetic ester oil, the weight ratio of (i) to (ii) being from about 0.2:1 to about 6:1.
    Type: Grant
    Filed: April 4, 2003
    Date of Patent: January 25, 2005
    Assignee: The Lubrizol Corporation
    Inventor: Raymond M. Calder
  • Patent number: 6825258
    Abstract: A powder coating additive composition containing (a) a non-crosslinked product made by the reaction of an organic alcohol and a carboxylic acid or a reactive equivalent of the carboxylic acid; the product containing at least one ester functionality and at least one hydrocarbyl group of about 10 to about 100 carbon atoms; and (b) a fluoropolymer. The cured coatings exhibit lower coefficient of friction and substantial gloss retention.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: November 30, 2004
    Assignee: The Lubrizol Corporation
    Inventor: Thomas F. Steckel
  • Patent number: 6818601
    Abstract: A composition of matter suitable for use as a dispersant-viscosity improver for lubricating oil compositions comprises the reaction product of reactants comprising (a) hydrocarbon polymer grafted with an &agr;,&bgr;-ethylenically unsaturated carboxylic acid or functional derivative thereof; and (b) an amine selected from the group consisting of (b-1) a product made by contacting at least one hydroxy-containing material with at least one amine having at least one N—H group, and (b-2) an acylated derivative of (b-1) containing at least one condensable N—H group.
    Type: Grant
    Filed: June 22, 2000
    Date of Patent: November 16, 2004
    Assignee: The Lubrizol Corporation
    Inventor: Richard M. Lange
  • Patent number: 6793695
    Abstract: A fuel composition exhibiting improved anti-static properties, comprises a liquid fuel which contains less than 500 parts per million by weight sulfur; 0.001 to 1 ppm of a hydrecarbyl monoamine or hydrocarbyl-substituted poly(alkylenieamine); and 10 to 500 ppm of at least one fatty acid containing 8 to 24 carbon atoms, or an ester thereof.
    Type: Grant
    Filed: August 28, 2002
    Date of Patent: September 21, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Mark F. Wilkes, David A. Duncan, Shaun P. Carney
  • Patent number: 6787663
    Abstract: A composition of an antioxidant of the formula where R3 is an alkyl group of 2 to 6 carbon atoms, and a dispersant or a detergent, is a useful additive package for lubricant compositions.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: September 7, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Paul E. Adams, Thomas J. Wolak
  • Patent number: 6777378
    Abstract: This invention relates to a lubricating oil composition, comprising: (A) a base oil; (B) a molybdenum and sulfur containing composition derived from a basic nitrogen containing compound, a molybdenum compound and carbon disulfide; (C) a boron-containing compound; and (D) optionally a phosphorus containing compound, provided the phosphorus content of the lubricating oil composition does not exceed about 0.10% by weight.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: August 17, 2004
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, Jack C. Kelley, Jonathan S. Vilardo
  • Patent number: 6770605
    Abstract: A composition suitable for reducing sludge and degradation of elastomer seals in engines comprises an oil of lubrication viscosity and a minor amount of a sludge preventing/seal protecting nitrogen containing dispersant, which is a reaction product of a hydrocarbyl-substituted succinic acylating agent having a limited amount of low molecular weight substituent; and a polyamine or condensed polyamine containing less than 20 mole percent of polyamine components of 6 or fewer nitrogen atoms.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: August 3, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Carl F. Stachew, Gordon D. Lamb, William D. Abraham, Mary Galic Raguz
  • Patent number: 6764982
    Abstract: This invention relates to a lubricating oil composition, comprising: (A) a base oil; and a phosphorus-containing compound represented by the formulae wherein in Formulae (B-I) and (B-II), R1, R2 and R3 are independently hydrogen or hydrocarbyl groups, and a, b and c are independently zero or 1; the lubricating oil composition being characterized by a sulfur content of about 0.01 to about 0.25% by weight.
    Type: Grant
    Filed: January 31, 2002
    Date of Patent: July 20, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Ewa A. Bardasz, Virginia A. Carrick, William D. Abraham, Gordon D. Lamb
  • Patent number: 6759375
    Abstract: A sump-lubricated internal combustion engine equipped with exhaust gas recycle, lubricated with (a) an oil of lubricating viscosity, (b) 0.05 to 1 percent by weight of an amide of an aliphatic carboxylic acid, and (c) at least one additional dispersant, detergent, or anti-wear agent, exhibits reduced temperature of the lubricant in the sump.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: July 6, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Thomas T. Curtis, Ewa A. Bardasz, Daniel H. Heath, Peter B. Thomson
  • Patent number: 6730640
    Abstract: Continuously variable transmissions are lubricated by supplying to the transmission a composition of an oil of lubricating viscosity and an oil-soluble zinc salt containing at least one hydrocarbyl group of at least 4 carbon atoms. The amount of the zinc salt is sufficient to provide an increased steel-on-steel dynamic coefficient of friction for the composition, being at least 0.125. The composition is substantially free from thiophosphate salts and exhibits a copper corrosion rating of 1B or better (ASTM-130).
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: May 4, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Roger L. Sowerby, Craig D. Tipton, James L. Sumiejski
  • Patent number: 6727208
    Abstract: A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and an additive system comprising (A) from about 0.1 to about 5% by weight of a detergent composition comprising at least two metal overbased compositions wherein said detergent composition consists essentially of (A-1) at least one alkali metal overbased detergent and (A-2) at least one calcium overbased detergent, wherein the ratio of total base number on a per 100 TBN and diluent-free basis contributed by the alkali metal detergent to the total base number contributed by the calcium detergent ranges from about 99.5-20 to about 0.5-80; (B) from about 1 to about 10% by weight of a succinimide dispersant; and (C) from about 0.1 to about 5 % by weight of a metal dihydrocarbyl dithiophosphate of the formula (I) wherein R1 and R2 are each, independently, hydrocarbyl groups containing from 3 to 13 carbon atoms, M is a metal and n is an integer equal to the valence of M.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: April 27, 2004
    Assignee: The Lubrizol Corporation
    Inventor: Melody A. Wilk
  • Patent number: 6706672
    Abstract: A composition comprising: a high-sulfur API Group I mineral oil base stock; a molybdenum dithiocarbamate in an amount suitable to provide 50 to about 600 ppm molybdenum to the composition; a succinimide dispersant based on a polyolefin-substituted succinic structure, where the polyolefin has a number average molecular weight of at least 1500; a zinc dialkyldithiophosphate derived from at least one secondary alcohol; and a hindered phenol, alkylated aromatic amine, or sulfurized olefin oxidation inhibitor, is capable of passing a Sequence III test.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: March 16, 2004
    Assignee: The Lubrizol Corporation
    Inventor: Jack C. Kelley
  • Patent number: 6677282
    Abstract: Hydrocarbyl substituted carboxylic compositions and derivatives thereof useful as dispersant/viscosity improvers for lubricating oil and fuel compositions. Carboxylic compositions are derived from (A) a hydrocarbon polymer having Mn ranging from about 20,000 to about 500,000, and (B) an &agr;,&bgr;-unsaturated carboxylic compound prepared by reacting (1) an active methylene compound of the formula (I), and (2) a carbonyl compound of the general formula (II), wherein Ra is H or hydrocarbyl and Rb is a member of the group consisting of H, hydrocarbyl and (III), wherein each R′ is independently R or OR and each R is, independently, H or a hydrocarbyl group; and lower alkyl acetals, ketals, hemiacetals and hemiketals of the carbonyl compound (2).
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: January 13, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Richard M. Lange, Stuart L. Bartley, Daniel M. Vargo
  • Patent number: 6610637
    Abstract: A lubricant containing (a) a synthetic base oil composition having an overall kinematic viscosity of at least about 4.8×10−6m2/s (4.8 cSt) at 100° C. and a viscosity index of at least about 110; (b) a dispersant-viscosity modifier; and (c) a sulfur-free functionalized hydrocarbyl-substituted phenol detergent provides improved valve train wear, with longer drain intervals, to heavy duty diesel engines.
    Type: Grant
    Filed: October 16, 2001
    Date of Patent: August 26, 2003
    Assignee: The Lubrizol Corporation
    Inventors: Thomas T. Curtis, Gordon D. Lamb, William D. Abraham
  • Patent number: 6605572
    Abstract: This invention relates to a lubricating oil composition, comprising: (A) a base oil and (B) a boron-containing compound represented by the formulae wherein in Formulae (B-I), (B-II) and (B-III), each R is independently an organic group and any two adjacent R groups may together form a cyclic group; the lubricating oil composition containing sulfur, boron and optionally phosphorus with the ratio of sulfur to boron to phosphorus being represented by the formula S1+5B1+3P1>0.35 wherein S1 is the concentration in percent by weight of sulfur in the composition, B1 is the concentration in percent by weight of boron in the composition, and P1 is the concentration in percent by weight of phosphorus in the composition; the concentration of sulfur in the lubricating oil composition being from about 0.01% to about 0.25% by weight; the concentration of phosphorus in the lubricating oil composition being up to about 0.08% by weight.
    Type: Grant
    Filed: January 31, 2002
    Date of Patent: August 12, 2003
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, Ewa A. Bardasz, William D. Abraham, Gordon D. Lamb
  • Patent number: 6596672
    Abstract: A low sulfate ash lubricating oil composition comprising an oil of lubricating viscosity, 0.1 to 3.0% of a calcium overbased acidic material, 0.1 to 2.0% of a magnesium overbased acidic material, and at least 0.5% of a combination of an alkylene-coupled hindered phenol antioxidant and an antioxidant other than an alkylene-coupled hindered phenol antioxidant, is particularly useful for lubricating stationary gas engines.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: July 22, 2003
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, Ewa A. Bardasz, David E. Ripple
  • Patent number: 6588393
    Abstract: This invention relates to a low-sulfur consumable lubricating oil composition, comprising: a base oil; an acylated nitrogen-containing compound having a substituent of at least about 10 aliphatic carbon atoms; and a sulfur content of about 5 to about 250 ppm; said composition being characterized by the absence of an extreme-pressure additive comprised of metal and phosphorus.
    Type: Grant
    Filed: December 4, 2000
    Date of Patent: July 8, 2003
    Assignee: The Lubrizol Corporation
    Inventors: William Bricker Chamberlin, III, John Kent Pudelski