Patents Represented by Attorney, Agent or Law Firm Harold E. Cole
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Patent number: 6846526Abstract: An ink jet recording element comprising a support having thereon a porous image-receiving layer comprising particles, a poly(vinyl alcohol) binder and a crosslinking agent, the particles having a primary particle size of from about 7 to about 40 nm in diameter which may be aggregated up to about 300 nm, and the crosslinking agent being present in an amount of at least about 20 weight % of the poly(vinyl alcohol) binder.Type: GrantFiled: January 26, 2001Date of Patent: January 25, 2005Assignee: Eastman Kodak CompanyInventors: Alexandra D. Bermel, Lori J. Shaw-Klein
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Patent number: 6843560Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon, in order, a hydrophilic absorbing layer and a polymeric overcoat layer of a derivitized poly(vinyl alcohol) having at least one hydroxyl group replaced by ether or ester groups, the polymeric overcoat layer also containing a sulfurous acid salt and an ammonium salt; C) loading the printer with an ink jet ink; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.Type: GrantFiled: August 7, 2002Date of Patent: January 18, 2005Assignee: Eastman Kodak CompanyInventors: Charles E. Romano, Jr., Amanda R. Broska, Eric L. Boyle, Kevin Dockery
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Patent number: 6827768Abstract: An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A)m—Q—(Z)n wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n+m is at least 1; and with the further proviso that at least about 50 wt.Type: GrantFiled: August 30, 2002Date of Patent: December 7, 2004Assignee: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Steven Evans, Dale E. Decann
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Patent number: 6821586Abstract: An inkjet recording element comprising a support having thereon an image-receiving layer comprising non-silicon-containing inorganic oxide particles, the particles having their surfaces treated with a silane coupling agent having a hydrophilic, organic moiety.Type: GrantFiled: December 12, 2001Date of Patent: November 23, 2004Assignee: Eastman Kodak CompanyInventors: David M. Teegarden, Sridhar Sadasivan
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Patent number: 6815020Abstract: An ink jet recording element having a support having thereon a porous image-receiving layer having: (a) particles having a mean particle size of from greater than 0.04 &mgr;m to about 5 &mgr;m; and (b) water insoluble, cationic, polymeric particles having at least about 20 mole percent of a cationic mordant moiety.Type: GrantFiled: August 31, 2001Date of Patent: November 9, 2004Assignee: Eastman Kodak CompanyInventors: Sridhar Sadasivan, Elizabeth A. Gallo, John M. Baier
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Patent number: 6815018Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink-retaining layer; and b) a fusible, porous ink-transporting layer of a film-forming, hydrophobic binder and fusible, polymeric particles of a cellulose ester.Type: GrantFiled: September 30, 2002Date of Patent: November 9, 2004Assignee: Eastman Kodak CompanyInventors: Allan Wexler, Kevin M. O'Connor, Kurt M. Schroeder
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Patent number: 6814437Abstract: An ink jet printing process, having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon in order: i) at least one porous, ink carrier liquid receptive layer; ii) a fusible, porous dye-trapping layer of fusible polymeric particles, a binder, and a dye mordant; and iii) a fusible, porous ink-transporting layer of fusible, polymeric particles and a film-forming, hydrophobic binder; C) loading the printer with an ink jet ink compositions; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.Type: GrantFiled: September 30, 2002Date of Patent: November 9, 2004Assignee: Eastman Kodak CompanyInventor: Allan Wexler
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Patent number: 6796649Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon an image-receiving layer of a polymeric network formed by a chemical reaction between a wet strength polymer, amino-functionalized inorganic particles and a hydrophilic polymer other than a wet-strength polymer; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the ink jet ink in response to the digital data signals.Type: GrantFiled: December 16, 2002Date of Patent: September 28, 2004Assignee: Eastman Kodak CompanyInventors: Lixin Chu, Lori J. Shaw-Klein, Kenneth J. Ruschak, Elizabeth A. Gallo, Christine M. Vargas, Charles B. Salerno
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Patent number: 6789891Abstract: An ink jet printing method, having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon a fusible, porous, image-receiving layer of non-porous polymeric particles having a core/shell structure of a polymeric, hydrophobic core covered with a polymeric, hydrophobic shell, the Tg of the polymeric, hydrophobic core being at least about 25° C. higher than the Tg of the polymeric, hydrophobic shell; C) loading the printer with an ink jet ink composition of water, a humectant, and a water-soluble dye; and D) printing on the overcoat layer using the inkjet ink in response to the digital data signals.Type: GrantFiled: December 4, 2001Date of Patent: September 14, 2004Assignee: Eastman Kodak CompanyInventors: Xiaoru Wang, Hwei-Ling Yau, Wendy S. Krzemien
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Patent number: 6779885Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon an image-receiving layer of porous polymeric particles in a polymeric binder, the porous polymeric particles being prepared in the presence of an anionic or ationic dispersant, and the image-receiving layer containing a surfactant having a charge opposite to that of the dispersant used to make the porous polymeric particles, the surfactant being present in an amount from about 0.04 parts to about 0.30 parts by weight of the dispersant; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the ink jet ink composition in response to the digital data signals.Type: GrantFiled: December 4, 2001Date of Patent: August 24, 2004Assignee: Eastman Kodak CompanyInventors: Gregory E. Missell, Jeanne E. Kaeding, Dennis E. Smith, Paul B. Merkel
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Patent number: 6777041Abstract: An ink jet recording element having a support having thereon a fusible, porous, image-receiving layer having non-porous polymeric particles having a core/shell structure having a polymeric, hydrophobic core covered with a polymeric, hydrophobic shell, the Tg of the polymeric, hydrophobic core being at least about 25° C. higher than the Tg of the polymeric, hydrophobic shell.Type: GrantFiled: December 4, 2001Date of Patent: August 17, 2004Assignee: Eastman Kodak CompanyInventors: Hwei-Ling Yau, Xiaoru Wang, Wendy S. Krzemien
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Patent number: 6770336Abstract: An inkjet recording element having a support having thereon in order: (I) a base layer of at least about 50% by weight of inorganic particles; and (II) an image-receiving layer of: (a) colloidal, inorganic oxide particles having a mean particle size of from about 10 to about 500 nm; and (b) water-insoluble, cationic, polymeric particles having a benzyldimethyl benzylammonium moiety.Type: GrantFiled: December 12, 2001Date of Patent: August 3, 2004Assignee: Eastman Kodak CompanyInventors: Yongcai Wang, Lori J. Shaw-Klein, Thomas P. Nicholas, Sridhar Sadasivan, Lixin Chu
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Patent number: 6759106Abstract: An ink jet recording element having a support having thereon a porous image-receiving layer with at least 30% by weight of particles and at least 30% by weight of a binder, the particles being a mixture of a) silica gel particles having an average particle size of greater than about 9 &mgr;m in diameter; and b) silica gel particles having an average particle size of between 1 and about 8 &mgr;m in diameter; wherein the ratio of the a) silica gel particles to the b) silica gel particles is from about 0.5 to about 5.Type: GrantFiled: December 4, 2002Date of Patent: July 6, 2004Assignee: Eastman Kodak CompanyInventors: Lixin Chu, Lori J. Shaw-Klein, Kenneth J. Ruschak, Elizabeth A. Gallo, Christine M. Vargas, Charles R. Salerno
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Patent number: 6726991Abstract: Core/shell particles having a core of a porous polymer and a shell of an inorganic colloid, the inorganic colloid having a median diameter of less than about 0.07 &mgr;m, and the core/shell particles having a median diameter of less than about 50 &mgr;m.Type: GrantFiled: September 9, 2002Date of Patent: April 27, 2004Assignee: Eastman Kodak CompanyInventors: Jeanne E. Kaeding, Dennis E. Smith
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Patent number: 6723397Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink-retaining layer, and b) a fusible, porous ink-transporting layer of fusible, polymeric particles and a film-forming, hydrophobic binder.Type: GrantFiled: September 18, 2001Date of Patent: April 20, 2004Assignee: Eastman Kodak CompanyInventor: Allan Wexler
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Patent number: 6712892Abstract: An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition including water, humectant and a metallized, phthalocyanine colorant, the metallized, phthalocyanine colorant having the formula: MPc(SO3X)a(SO2NRR′)b wherein: M represents a metal; Pc represents a phthalocyanine nucleus; each X independently represents hyrdrogen, alkali metal or an organic cation; a is from 0 to 3; b is from 1 to 4; each R independently represents a substituted or unsubstituted alkyl group having from 1 to about 15 carbon atoms, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; and each R′ independently represents R or hydrogen; with the proviso that a+b is an average of from 2 to 4; and with the further proviso that at least about 50 wt.Type: GrantFiled: August 30, 2002Date of Patent: March 30, 2004Assignee: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Samuel Chen, Dale E. Decann
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Patent number: 6712891Abstract: An ink jet ink composition including water, humectant and a metallized, phthalocyanine colorant, the metallized, phthalocyanine colorant having the formula: MPc(SO3X)a(SO2NRR′)b wherein: M represents a metal; Pc represents a phthalocyanine nucleus; each X independently represents hydrogen, alkali metal or an organic cation; a is from 0 to 3; b is from 1 to 4; each R independently represents a substituted or unsubstituted alkyl group having from 1 to about 15 carbon atoms, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; and each R′ independently represents R or hydrogen; with the proviso that a+b is an average of from 2 to 4; and with the further proviso that at least about 50 wt. % of the metallized, phthalocyanine colorant is present in the composition as particles.Type: GrantFiled: August 30, 2002Date of Patent: March 30, 2004Assignee: Eastman Kodak CompanyInventors: Andrei Andrievsky, David T. Southby, Samuel Chen, Dale E. Decann
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Patent number: 6706102Abstract: An ink jet ink composition comprising water, a humectant and a mixture of a water-soluble, magenta anthrapyridone dye and Reactive Red 23, Reactive Red 24, Reactive Red 31, Reactive Red 120, Reactive Red 180, Reactive Red 241, Acid Red 35, Acid Red 52, Acid Red 249, Acid Red 289, Acid Red 388, Direct Red 227 or CAS No. 153204-88-7.Type: GrantFiled: August 1, 2001Date of Patent: March 16, 2004Assignee: Eastman Kodak CompanyInventors: James W. Blease, Elizabeth A. Gallo
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Patent number: 6695447Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink carrier liquid receptive layer; b) a fusible, porous dye-trapping layer of fusible polymeric particles, a binder, and a dye mordant; and c) a fusible, porous ink-transporting layer of fusible, polymeric particles and a film-forming, hydrophobic binder.Type: GrantFiled: September 30, 2002Date of Patent: February 24, 2004Assignee: Eastman Kodak CompanyInventor: Allan Wexler
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Patent number: 6689431Abstract: An ink jet recording element comprising a substrate having thereon a porous image-receiving layer having a) organic particles encapsulated with an organic polymer having a Tg of less than about 100° C.; and b) water-insoluble, cationic, polymeric particles.Type: GrantFiled: December 12, 2001Date of Patent: February 10, 2004Assignee: Eastman Kodak CompanyInventors: Sridhar Sadasivan, Elizabeth A. Gallo, Xiaoru Wang