Abstract: Hydrogen storage materials are provided by a quaternary alloy of the formula:Zr.sub.1-x Ti.sub.x CrFe.sub.ywherein x has a value in a range from 0.1 to 0.3, and y has a value in a range from 1.2 to 1.4, and their hydrides.

Abstract: A method of protecting organic materials from fungi and/or bacteria is provided which comprises applying to said organic material a minor but effective biocidal amount of a compound of the formula: ##STR1## wherein M is selected from H,P and an alkali metal or alkali earth metal and n is an integer selected from 1 to 3.

Abstract: 1,4-dihydroxy, 5,8-dihydronaphthalene and related compounds are provided from benzoquinone, and 1,3-butadiene which may be substituted with halogen, acyl, and alkyl, in a one step reaction in the presence of a ferric salt catalyst.

Abstract: 2,6-dialkyl substituted phenols such as 2,6-ditertiary butylphenol are reacted with formaldehyde in methyl alcohol in the presence of an inert gas and a tertiary amine catalyst to produce a bis(3,5-di-t-butyl-4-hydroxybenzyl)ether; and the bis ether subjected to hydrogenolysis in the presence of a catalyst, a solvent and an amine to prepare a trisubstituted phenol such as 2,6-di-t-butyl-4-methyl-phenol.

Abstract: An improved method for screening and fractionation. By using a housing interiorly divided by a screen plate into a primary and a secondary chamber with the secondary chamber further divided by a fluid impermeable wall, a process fluid stream containing particulate material has a second and a third process fluid stream diverted from it. The second stream is outputed from the housing while the third stream is recirculated to the first chamber. It is demonstrated that high screening or fractionation efficiency is obtained by this method.

Abstract: A phenol-resorcinol-formaldehyde resin and a method for making the same. In this method phenol and formaldehyde at an initial pH of 8.5 to 9.2 are reacted in the presence of a sodium sulfite catalyst. The reaction mixture is heated and refluxed until it has a viscosity of u-v on the Gardner bubble test. Additional resorcinol is added to the mixture and refluxing is continued until it has a viscosity of 30 to 100 Garner sections. The reaction mixture is diluted with a water miscible solvent to obtain a resin solution having a solids content of about 40 to 60 percent by weight and a viscosity of 2.0 to 3.5 poise. An alkali metal carbonate material in the amount of 4 to 8 percent by weight of the resin is added to make adhesives including this resin fast curing. Fumed silica is also added to the resin solution by means of high shear apparatus to make the solution thixotropic.

Abstract: A process is disclosed for one-step preparation of substituted tetrathiafulvalenes by reaction of carbon disulfide with acetylenic compounds under pressures of at least about 1,000 atmospheres. Substituted tetrathiafulvalenes made by this process are particularly useful as precursors to very pure tetrathiafulvalene, a compound which can complex with tetracyano-p-quinodimethane to form a charge-transfer salt having very high electrical conductivity.

Abstract: Novel compositions useful as antioxidants are formed by the reaction of resorcinol with an alkenylbenzene.

Abstract: A method and apparatus for manufacturing the screw flight section of a screw conveyor is disclosed. The apparatus includes two horizontal arms which extend from a vertical support and at the terminal end of these arms there are dies for engaging the inner and outer peripheral edges of a flat, sheet metal, annulus-shaped blank with a radial slit. One die is turned on its longitudinal axis while the other remains stationary so that the blank is twisted. After the blank is circumferentially displaced relative to the dies, it is again twisted in the above described manner. This procedure is repeated around the entire circumference of the blank with the result that a helical form is applied to the blank.

Abstract: Rust preventives are provided comprising divalent metal salts of the formula: ##STR1## wherein the R groups are independently selected from methyl, hydrogen, and decyl of the formula: ##STR2## wherein n=0 to 3; and wherein from two to three R groups are decyl, zero to two R groups are methyl, and zero to two R groups are hydrogen; and M is a divalent metal selected from Mg, Ca, Ba, and Zn. Useful intermediates for preparing the said rust preventives are also provided.

Abstract: Hydrogen storage materials are provided of a ternary alloy of the formula:ZrMnFe.sub.xwherein x has a value from 1.2 to 1.3, and their hydrides.

Abstract: A rotary vane valve having a cylindrical housing with a pair of opposed end bells and an interior axial shaft. Opposed inlet and outlet openings on the side of the cylindrical housing allow transverse fluid flow through the housing and radial vanes project from the axial shaft to facilitate the transfer of fluid from the inlet at one pressure to the outlet at a different pressure. A pair of spaced shroud structures are fixed to the shaft at the ends of the vanes to generally separate the interior of the cylindrical housing from the end bells.

Abstract: A rotary vane valve having a cylindrical housing with a pair of opposed end bells and an interior axial shaft. A pair of spaced shroud structures are fixed to the shaft at the ends of the vanes to generally separate the interior of the cylindrical housing from the end bells. These shroud structures are spaced from the cylindrical housing at their outer peripheral edges, but an annular throttle plate is spaced axially outwardly at a close distance from these shrouds and adjacent at its outer edge to the cylindrical housing to increase the velocity of purge gas flowing inwardly between the cylindrical housing and the outer peripheral edge of the shroud so that the escape of gas from the interior of the cylindrical housing is effectively prevented. The inner lateral surface of the annular throttle plate is divided into a low pressure zone adjacent the inlet opening and a high pressure zone adjacent the outlet opening in situations where the inlet opening is at a lower pressure than the outlet opening.

Abstract: An alloy consisting of zirconium, chromium, iron and optionally titanium is characterized in having C14 hexagonal crystal structure and ZrCr.sub.2 stoichiometry. Members of a preferred class of compounds, represented by the empirical formula Zr.sub.1-x Ti.sub.x Cr.sub.2-y Fe.sub.y wherein "x" has a value between 0.0 and 0.9 and "y" has a value of 0.1 to 1.5, are particularly suitable for use as hydrogen storage materials.

Abstract: A hog granulator for plastic material in which a plurality of longitudinal knives are arranged on a rotor inside a cutting chamber to engage in a cooperative cutting action with bed knives on the cutting chamber walls. A plurality of spaced, longitudinal pockets in the peripheral surface of the rotor bring cooling air to the cutting surfaces, and ribs are arranged across these pockets to reduce power requirements by preventing excessively large pieces of plastic material to be reduced from being received into and taking up residence in these pockets.

Abstract: The present invention is directed to aqueous phenol formaldehyde resoles that have particular application in manufacturing phenolic foam insulation. The resoles are essentially phenol formaldehyde condensation polymers having molar ratios of formaldehyde to phenol of from about 1.7:1 to 2.3:1, preferably from 1.75:1 to 2.25:1 and most preferably about 2:1. The resoles have a weight average molecular weight greater than 800 and preferably from 950-1500. The resoles also have a number average molecular weight greater than 350 and preferably from about 400 to about 600 and a dispersivity greater than about 1.7, preferably from 1.8 to 2.6. Phenol formaldehyde resoles having these characteristics are processable into phenolic foams having a low k value and having other physical characteristics which make the phenolic foam especially useful as an insulation material.

Abstract: Quaternary hyperstoichiometric alloys of the formula: ZrCrFeT.sub.x and their hydrides are provided, characterized as having MgZn.sub.2 hexagonal crystal structure wherein T is selected from Mn, Fe, Co, Ni and Cu, and X is a number from 0.1 to 1.0. These alloys readily form hydrides at low hydrogen pressure and are suitable for use as hydrogen storage materials.

Abstract: A process is disclosed for separating 3,5-xylenol or 3,4-xylenol from other closely boiling polymethylated phenolics by treating a mixture of the phenolics with a metal halide salt. The metal halide salt preferentially forms a complex with the xylenol over other related phenolics in the mixture. The preferentially-formed complex of the xylenol may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of the xylenol.

Abstract: A process is disclosed for separating nitrated phenolic compounds from other nitrated and unnitrated phenolics by treating a mixture of the phenolics with a metal halide salt. The metal halide salt preferentially forms a complex with one of the phenolics over other related phenolics in the mixture. The preferentially-formed complex of one of the phenolics may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of, one phenolic. The process is particularly suitable for resolving a mixture comprising phenol or cresol from their ortho-nitrated derivatives, or a mixture of two isomeric nitrated phenols or cresols or a mixture of mono- and dinitrated phenols or cresols.

Abstract: A method and apparatus for mixing granular, particulate or pulverant material is disclosed. An unhomogenous mixture of two or more such materials is introduced into and moved through a preferably inclined trough structure having rigid side walls and a flexible floor member. At one or more isolated positions on this floor member it is subjected to relatively intense vibrational motion. It is found that such restricted use of vibrational motion results in a thorough yet gentle mixing of granular, particulate or pulverant materials.