Patents Represented by Attorney, Agent or Law Firm Howard J. Troffkin
  • Patent number: 5824405
    Abstract: A polyimide gas separation membrane can be used to make protective cloth having good water vapor breathability as well as good resistance to permeation by noxious gases and penetration by liquid water.
    Type: Grant
    Filed: June 7, 1996
    Date of Patent: October 20, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Lloyd Steven White
  • Patent number: 5798055
    Abstract: An oxygen scavenging composition composed of a carrier material and a metal-loaded cationic exchange material having the metal in a zero valence state. The composition is contained within the interior cavity of a container to scavenge oxygen therein. The composition may form at least a part of the interior surface of the container or be present therein in the form of a film, mat, sachet or ceramic.
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: August 25, 1998
    Inventors: Thomas Andrew Blinka, Drew Ve Speer, William Alfred Feehley, Jr.
  • Patent number: 5779788
    Abstract: A cement admixture composed of a mixture of lower alkyl ether oxyalkylene adducts with a sulfonated organocyclic material to provide cement compositions of mortar and concrete which inhibit drying shrinkage while attaining very high slump and/or increased compressive strength.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: July 14, 1998
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Neal Steven Berke, Michael Paul Dallaire, Awdhoot Vasant Kerkar
  • Patent number: 5772934
    Abstract: A polymer bonded sheet product suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: June 30, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Kenneth Orville MacFadden
  • Patent number: 5753032
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of phosphoric acid, and from about 0.1 to about 4% by weight of a source of fluoride ions. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Jacob Block
  • Patent number: 5753033
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of a boron tetrafluoride salt, free of or having only small amounts of an inorganic acid, an inorganic acid salt or a mixture thereof. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Jacob Block
  • Patent number: 5753031
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of an inorganic acid, and from about 0.1 to about 4% by weight of a hexafluorosilicate of ammonia, an alkali metal or an alkaline earth metal. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Jacob Block
  • Patent number: 5753034
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of a hexafluorosilicate salt, and free of or having only small amounts of an inorganic acid, an inorganic acid salt or a mixture thereof. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co. -Conn.
    Inventor: Jacob Block
  • Patent number: 5753035
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of an inorganic acid, and from about 0.1 to about 4% by weight of a tetrafluoroborate of ammonia, an alkali metal or an alkaline earth metal. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: May 19, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Jacob Block
  • Patent number: 5749927
    Abstract: Solid polymer electrolytes are extruded with active electrode material in a continuous, one-step process to form composite electrolyte-electrodes ready for assembly into battery cells. The composite electrolyte-electrode sheets are extruded onto current collectors to form electrodes. The composite electrodes, as extruded, are electronically and ionically conductive. The composite electrodes can be overcoated with a solid polymer electrolyte, which acts as a separator upon battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte separator has low resistance.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: May 12, 1998
    Assignee: W. R. Grace & Co. -Conn.
    Inventors: Terry Song-Hsing Chern, David Gerard Keller, Kenneth Orville MacFadden
  • Patent number: 5743841
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of an acid component, at least about 0.1% by weight of a source of fluoride ions, and a stable foam forming amount of a foaming agent system having both cationic and non-ionic functionality. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition in the form of a foam also disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: April 28, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Jacob Block, Natalia Vera Krupkin, Daniel Reid Kuespert, Gary Masaru Nishioka, John Wing-Keung Lau, Nigel Innes Palmer
  • Patent number: 5741358
    Abstract: A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed, wherein the composition comprises water, at least about 30% by weight of an acid component, optionally a source of fluoride ions, and a corrosion inhibiting amount of thiourea, a lower alkylthiourea, a C.sub.8 -C.sub.15 alkylpyridinium halide or mixtures thereof. A method of transforming an asbestos-containing building material, while part of a building structure, into a non-asbestos material by using the present composition also is disclosed.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: April 21, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Judithann Ruth Hartman
  • Patent number: 5725657
    Abstract: The present invention is directed to a polyoxyalkylene ammonium salt of an imidized polycarboxylic acid polymer cement admixture, storage stable aqueous solutions of said polymer, and to improved cement compositions containing said polymer.
    Type: Grant
    Filed: March 24, 1996
    Date of Patent: March 10, 1998
    Inventors: David Charles Darwin, Ellis Martin Gartner
  • Patent number: 5725822
    Abstract: An electrode sheet product is formed using an extruder having a feed throat and a downstream section by separately mixing an active electrode material and a solid polymer electrolyte composition that contains lithium salt. The active electrode material is fed into the feed throat of the extruder, while a portion of at least one fluid component of the solid polymer electrolyte composition is introduced to the downstream section. The active electrode material and the solid polymer electrolyte composition are compounded in a downstream end of the extruder. The extruded sheets, adhered to current collectors, can be formed into battery cells.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: March 10, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: David Gerard Keller, Richard Thomas Giovannoni, Kenneth Orville MacFadden
  • Patent number: 5700554
    Abstract: An article useful for packaging oxygen-sensitive products is disclosed. The article is a single or multi-layer article capable of enveloping the oxygen sensitive product. The article has at least one layer which contains a composition composed of an ethylenically unsaturated hydrocarbon polymer and a transition metal salt. The layer is capable of scavenging oxygen at a rate of at least 1 cc oxygen per square meter per day and has a capacity of at least 250 cc oxygen per square meter per mil thickness of the layer.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: December 23, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Drew V. Speer, William P. Roberts, Charles R. Morgan, Cynthia L. Ebner
  • Patent number: 5698147
    Abstract: A process for fabricating an electrolyte-electrode composite suitable for high energy alkali metal battery that includes mixing composite electrode materials with excess liquid, such as ethylene carbonate or propylene carbonate, to produce an initial formulation, and forming a shaped electrode therefrom. The excess liquid is then removed from the electrode to compact the electrode composite which can be further compacted by compression. The resulting electrode exhibits at least a 75% lower resistance.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: December 16, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Terry Song-Hsing Chern, Kenneth Orville MacFadden, Steven Lloyd Johnson
  • Patent number: 5679150
    Abstract: A cement admixture composition composed of an oxyalkylene compound and betaine. The betaine permits air entrainment in the presence of the oxyalkylene compound, which is used as a shrinkage reduction aid.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: October 21, 1997
    Inventors: Awdhoot Vasant Kerkar, Michael Paul Dallaire
  • Patent number: 5665158
    Abstract: The present invention is directed to a polyoxyalkylene ammonium salt of an imidized polycarboxylic acid polymer cement admixture, storage stable aqueous solutions of said polymer, and to improved cement compositions containing said polymer.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: September 9, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: David Charles Darwin, Ellis Martin Gartner
  • Patent number: 5656075
    Abstract: A cement composition including spodumene which has been heated to at least 1000.degree. C. which is capable of inhibiting expansion of the concrete due to the alkali-silica reaction. The present invention also provides a method of reducing expansion in cement compositions.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: August 12, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: James Michael Gaidis, Ellis Martin Gartner
  • Patent number: 5656393
    Abstract: A polymer bonded electrode composite composed of a polymer matrix having electrochemically active particulate therein and having a porous conductive sheet encapsulated within the matrix is disclosed. Further, a continuous process of forming the electrode composite by extrusion using a cross-head die is also disclosed.
    Type: Grant
    Filed: October 21, 1994
    Date of Patent: August 12, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Frank Peter Boer, James Daniel Idol, Jr., Ketan Vasantlal Shah, Cung Vu