Patents Represented by Attorney James Paul O'Sullivan
  • Patent number: 4265990
    Abstract: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises a polycarbonate resin containing from about 25 to about 75 percent by weight of one or more of a compound having the general formula: ##STR1## wherein X is selected from the group consisting of an alkyl group having from 1 to about 4 carbon atoms (e.g. methyl, ethyl, propyl, butyl, etc.) and chlorine in the ortho, meta or para position. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
    Type: Grant
    Filed: December 4, 1978
    Date of Patent: May 5, 1981
    Assignee: Xerox Corporation
    Inventors: Milan Stolka, Damodar M. Pai, John F. Yanus
  • Patent number: 4252433
    Abstract: A method and apparatus for recovering the residual image from an electrostatic recording surface in an electrostatic copying system which is accomplished by presenting a wiping element in pressure contact with the residual image on the recording surface whereby the residual image is substantially removed therefrom, moving a conductive member in close proximity to the toner particles being removed from the recording surface, applying a DC voltage opposite in polarity to that of the toner particles and of sufficient magnitude to the conductive member whereby the toner particles are attracted onto the surface of the conductive member, and continuously removing the toner particles from the conductive member into a collection zone for reuse in the copying system.
    Type: Grant
    Filed: May 22, 1973
    Date of Patent: February 24, 1981
    Assignee: Xerox Corporation
    Inventor: William A. Sullivan
  • Patent number: 4233384
    Abstract: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting photogenerated holes into a contiguous charge transport layer. The charge transport layer comprises a polycarbonate resin containing from about 25 to about 75 percent by weight of one or more of a compound having the general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are selected from the group consisting of hydrogen, an ortho, meta or para alkyl group having from 1 to about 4 carbon atoms, an ortho, meta or para halogen atom, a para phenyl group and combinations thereof.
    Type: Grant
    Filed: April 30, 1979
    Date of Patent: November 11, 1980
    Assignee: Xerox Corporation
    Inventors: S. Richard Turner, John F. Yanus, Damodar M. Pai
  • Patent number: 4232102
    Abstract: An imaging member comprising a layer of particulate photoconductive material dispersed in an organic resinous binder, said photoconductive material comprising trigonal selenium containing a mixture of an alkali metal selenite and an alkali metal carbonate. This layer can be the charge generation layer of an imaging member also having a charge transport layer in contact therewith.
    Type: Grant
    Filed: May 18, 1979
    Date of Patent: November 4, 1980
    Assignee: Xerox Corporation
    Inventors: Anthony M. Horgan, Richard W. Radler, Jr.
  • Patent number: 4175959
    Abstract: Disclosed is a method of forming finely divided photosensitive trigonal selenium particles which are submicron in size and generally spherical in shape. The method comprises forming an alkaline solution containing selenide and/or polyselenide ions, followed by the precipitation of finely divided trigonal selenium particles from said solution by the addition of an oxidizing agent to said alkaline solution. The trigonal selenium particles are formed into a binder layer photosensitive device by dispersing them with an organic resin in solution with an organic solvent which when applied to a substrate in a uniform layer, is heated to remove the solvent and form the device. Continued heat treatment of the device can result in enhancement of its ability to accept an electrostatic charge.
    Type: Grant
    Filed: December 23, 1976
    Date of Patent: November 27, 1979
    Assignee: Xerox Corporation
    Inventors: Ronald E. Karam, David J. Swarthout
  • Patent number: 4172933
    Abstract: Disclosed are monomers of the formula: ##STR1## wherein R is ##STR2## R' is hydrogen or methyl; R" is alkyl of 1-10 carbon atoms;X and Y are independently selected from the group consisting of NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene;A and a' can range from 0-3; andN is 1-10.These monomers can be readily polymerized to polymers suitable for use in electophotographic imaging members and methods.
    Type: Grant
    Filed: May 23, 1977
    Date of Patent: October 30, 1979
    Assignee: Xerox Corporation
    Inventor: Sam R. Turner
  • Patent number: 4161490
    Abstract: Disclosed are electron acceptor monomers of the formula: ##STR1## wherein R is ##STR2## R' is hydrogen or methyl; X and Y are independently selected from the group consisting of --NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene; and a and b can range from 0 to 3;With the proviso that at least one of R is ##STR3## AND POLYMERS PREPARED THEREFROM. These monomers and polymers are suitable for use in electrophotographic devices and methods.
    Type: Grant
    Filed: September 13, 1978
    Date of Patent: July 17, 1979
    Assignee: Xerox Corporation
    Inventor: Sam R. Turner
  • Patent number: 4153802
    Abstract: Disclosed are electron acceptor monomers of the formula: ##STR1## wherein R is ##STR2## or --H; R' is hydrogen or methyl;X and Y are independently selected from the group consisting of --NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene; andA and b can range from 0 to 3; with the proviso that at least one of R is ##STR3## and polymers prepared therefrom. These monomers and polymers are suitable for use in electrophotographic devices and methods.
    Type: Grant
    Filed: May 4, 1977
    Date of Patent: May 8, 1979
    Assignee: Xerox Corporation
    Inventor: Sam R. Turner
  • Patent number: 4129581
    Abstract: Disclosed are monomers of the formula: ##STR1## WHEREIN R is ##STR2## R' is hydrogen or methyl;R" is alkyl of 1-10 carbon atoms;X and Y are independently selected from the group consisting of NO.sub.2, halogen, cyano and --CF.sub.3 ;Z is oxygen or dicyanomethylene;A and a' can range from 0-3; andN is 1-10.These monomers can be readily polymerized to polymers suitable for use in electrophotographic imaging members and methods.
    Type: Grant
    Filed: May 23, 1977
    Date of Patent: December 12, 1978
    Assignee: Xerox Corporation
    Inventor: Sam R. Turner
  • Patent number: 4098984
    Abstract: Process for preparation of monomers of the formula ##STR1## wherein R is hydrogen or methyl;X and Y are independently selected from the group consisting of NO.sub.2, halogen, --CN and --CF.sub.3 ; andm and n can range from 0 to 3.Typical monomers embraced by the above formula can be prepared by Lewis Acid catalyzed esterification of methacrylic acid with a diazo derivative of an electron acceptor such as 9-diazo-2,4,7-trinitrofluorenone. These monomers can be used with other binders or polymerized by standard, free-radical techniques to polymers capable of forming self-supporting films which are useful in electrophotographic imaging members and methods.
    Type: Grant
    Filed: April 20, 1977
    Date of Patent: July 4, 1978
    Assignee: Xerox Corporation
    Inventor: Sam R. Turner
  • Patent number: 4078925
    Abstract: An imaging member comprising a first layer of electrically active charge transport material contained on a supporting substrate, a photoconductive layer overlying said active layer, and a second layer of electrically active charge transport material overlying said photoconductive layer, said photoconductive layer exhibiting the capability of photogeneration of charge carriers and injection of said charge carriers, one of said electrically active layers which comprises an electrically inactive resinous material made electrically active by the addition of certain activating compounds thereto exhibits the capability of facile hole injection and transport and the other electrically active layer exhibits the capability of facile electron injection and transport.
    Type: Grant
    Filed: November 1, 1976
    Date of Patent: March 14, 1978
    Assignee: Xerox Corporation
    Inventor: Anthony M. Horgan
  • Patent number: 4075012
    Abstract: Method for achieving free radical initiated copolymerization of an addition monomer having pendant therefrom a strong donor group with an addition monomer having pendant therefrom a strong acceptor group. Copolymers prepared according to this method can be represented by the following formula: ##STR1## WHEREIN R is hydrogen or methyl;R' is hydrogen or methyl;R" is hydrogen or methyl;R'" is alkyl of 1-10 carbon atoms;R'.sup.v is selected from the group consisting of --NO.sub.2, halogen, --CN and --CF.sub.3 ;X and Y are independently selected from the group consisting of hydrogen, chlorine, bromine, alkyl of 1-4 carbon atoms and phenyl;Z is oxygen or dicyanomethylene;a and b can range from 0-4; andn and m can range from about 5 to about 95 percent.The polymeric compositions prepared according to this method are suitable for use in electrophotography either alone as the primary photoresponsive entity or in combination with other photoconductive materials.
    Type: Grant
    Filed: August 20, 1976
    Date of Patent: February 21, 1978
    Assignee: Xerox Corporation
    Inventors: Sam R. Turner, Milan Stolka
  • Patent number: 4074000
    Abstract: Disclosed is a novel pressure sensitive adhesive drafting film which is specially formulated to permit it to be imaged in electrostatographic copiers. The film is a multilayered structure comprising layers from the top down of:(a) a matte coating capable of receiving and holding graphic information;(b) a layer of organic resinous material in film form;(c) a layer of pressure sensitive adhesive;(d) a release coating;(e) a layer of an organic resinous material in film form as release liner; and(f) a back coating which is a layer of an organic resinous binder material having dispersed therein:I. a particulate solid material of particle size ranging from 3 to 20 microns in the longest dimension, andIi. a water insoluble antistatic agent of a type to cause the film to have a surface resistivity in the range of from 10.sup.9 to 10.sup.14 ohms/sq.
    Type: Grant
    Filed: October 27, 1976
    Date of Patent: February 14, 1978
    Assignee: Xerox Corporation
    Inventors: Roy H. Hankee, Alp T. Akman
  • Patent number: 4072519
    Abstract: Photoconductive composition comprising an insulating polymeric matrix and a compound of the formula ##STR1## WHEREIN Ar is anthryl; naphthyl; pyrenyl; indolyl; N-alkyl 2-CARBAZYL; JULOLIDINYL; AND THE SUBSTITUTED ANALOGUES THEREOF, WHEREIN SAID SUBSTITUENTS ARE CAPABLE OF RELEASING ELECTRONS TO THE RELATIVELY ELECTRON DEFICIENT CENTERS WITHIN THE COMPOUND;X is --NO.sub.2 or halogen; andN can range from 1 to 5.These compositions have good spectral response in the visible region of the electromagnetic spectrum and are suitable for use in electrostatographic imaging members and methods.
    Type: Grant
    Filed: August 11, 1976
    Date of Patent: February 7, 1978
    Assignee: Xerox Corporation
    Inventors: James M. Pearson, David J. Williams, William W. Limburg
  • Patent number: 4067782
    Abstract: A process for nickel plating a cylindrically shaped hollow core mandrel suitable for chromium plating for use in an electroforming process for the production of endless seamless nickel xerographic belts, is disclosed. The process comprises providing a hollow core aluminum or aluminum alloy cylindrically shaped member and (1) anodizing this core member by using this core member as an anode in an anodizing bath where the cathode comprises lead or lead alloys and (2) nickel plating this anodized core member in a nickel electroforming bath where the core member becomes the cathode and the anode is nickel or nickel alloy. Additionally and optionally, this core member may then be (3) subjected to an acid dip bath where the core member remains for a particular length of time and, additionally, then the core member is (4) plated with chromium by placing the core member in a chromium electroplating bath with a metal anode of lead or lead alloys.
    Type: Grant
    Filed: May 9, 1977
    Date of Patent: January 10, 1978
    Assignee: Xerox Corporation
    Inventors: Raymond E. Bailey, William G. Herbert
  • Patent number: 4053311
    Abstract: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting the photo-generated holes into a contiguous charge transport layer. The charge transport layer comprises poly(N-vinylcarbazole) which contains an electrically active plasticizer comprising from about 1 to about 25 percent by weight of bis(4-diethylamino-2-methylphenyl)phenylmethane. The charge transport layer while substantially non-absorbing in the spectral region of intended use, is "active" in that it allows injection of photo-generated holes from the photoconductive layer, and allows these holes to be transported through the charge transport layer. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
    Type: Grant
    Filed: April 2, 1976
    Date of Patent: October 11, 1977
    Inventors: William W. Limburg, John F. Yanus, Damodar M. Pai
  • Patent number: 4052205
    Abstract: Novel photoconductive imaging members are provided comprising a layer of inorganic photoconductive material contained on a supporting substrate with a contacting layer of an electrically active organic material contiguous with the photoconductive layer comprising a plasticizer of an alkyl substituted anthracene.
    Type: Grant
    Filed: September 24, 1975
    Date of Patent: October 4, 1977
    Assignee: Xerox Corporation
    Inventors: Milan Stolka, John F. Yanus
  • Patent number: 4050935
    Abstract: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises trigonal selenium which is capable of photogenerating holes and injecting the photo-generated holes into a contiguous charge transport layer. The charge transport layer comprises a transparent electrically inactive organic resinous material containing from about 15 to about 75 percent by weight (throughout) of bis(4-diethylamino-2-methylphenyl)phenylmethane. The charge transport layer while substantially non-absorbing in the spectral region of intended use, is "active" in that it allows injection of photo-generated holes from the trigonal selenium carrier generating layer, and allows these photo-generated holes to be transported through the charge transport layer. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.
    Type: Grant
    Filed: April 2, 1976
    Date of Patent: September 27, 1977
    Assignee: Xerox Corporation
    Inventors: William W. Limburg, John F. Yanus, Damodar M. Pai
  • Patent number: 4043812
    Abstract: Process for preparation of 2-anthryl and substituted 2-anthryl functional monomers and polymers. In the process for preparation of these monomers, an anthracenic reactant of the formula: ##STR1## wherein X and Y are independently selected from hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms or phenylIs acylated in nitrobenzene under conditions which favor reaction at the two position. The resulting acylated product can then be (a) reacted with an alkylidenephosphorane (Wittig synthesis) or (b) reduced to the corresponding alcohol. Subsequent to such reduction, this alcohol can undergo further modification at the hydroxyl function to form a polymerizable addition monomer.
    Type: Grant
    Filed: March 7, 1975
    Date of Patent: August 23, 1977
    Assignee: Xerox Corporation
    Inventors: Milan Stolka, James M. Pearson, John F. Yanus
  • Patent number: 4037952
    Abstract: An improved electrophoretic development method comprising providing a liquid developer system having a backing electrode and a developer electrode, wherein the development electrode comprises a plurality of individually biased electrodes. According to this improved method, as an electrostatically imaged insulating member is contacted with the liquid developer and directed through a development zone defined by said electrodes, the leading edge of said insulating member selectively activates the individually biased development electrodes in synchronization with the travel of the insulation member through said zone, and the trailing edge of said insulating member selectively inactivates the individually biased development electrodes upon the withdrawal of the insulating member from said zone. This method is especially suitable for preparation of reversal images by electrophoretic development.
    Type: Grant
    Filed: October 20, 1975
    Date of Patent: July 26, 1977
    Assignee: Rank Xerox Ltd.
    Inventor: Seiji Matsumoto