Abstract: Adhesive compositions containing a base compound or resin and an epoxy compound or resin with allyl or vinyl functionality show enhanced adhesive strength. The compositions can be used in microelectronic applications.
Type:
Grant
Filed:
July 7, 2000
Date of Patent:
June 15, 2004
Assignee:
National Starch and Chemical Investment Holding
Corporation
Inventors:
Mark R. Bonneau, Yun K. Shin, Gina Hoang, Martin Sobczak
Abstract: A curable composition comprises a compound having at least one epoxy group and at least one maleimide, styrenic or cinnamyl group per molecule. A representative compound has the structure
in which Z′ and Z are any monomeric, oligomeric or polymeric organic moiety; X is a direct bond or a functional group; and R and R′ are hydrogen, an alkyl group having 1 to 12 carbon atoms, or an aromatic or heteroaromatic ring or fused ring having 3 to 10 carbon atoms within the ring structure.
Type:
Grant
Filed:
July 22, 2002
Date of Patent:
April 6, 2004
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: Adhesion promoting compounds or resins containing a thiazole functionality (including benzothiazole) and a polymerizable functionality (Z) give improved adhesive strength to metal substrates. A representative structure is the following, in which R1 and R2 together can form a cyclic or aromatic structure, or are linear or branched organic moieties.
Type:
Grant
Filed:
July 19, 2002
Date of Patent:
March 16, 2004
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: Compounds with both vinyl ether and carbamate, thiocarbamate or urea functionality are suitable for use in microelectronics applications and show enhanced adhesive strength compared to compounds that do not contain carbamate, thiocarbamate or urea functionality.
Type:
Grant
Filed:
August 10, 2001
Date of Patent:
March 2, 2004
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: A process for the manufacture of copolymers of formaldehyde and diphenyl oxide and a carboxylic acid uses and acid with a pKa in the range of 1.2 to 3 as the catalyst.
Type:
Grant
Filed:
January 16, 2002
Date of Patent:
November 11, 2003
Assignee:
National Starch and Chemical Investment Holding
Corporation
Inventors:
Kelly J. Seheult, Shane M. Carter, Lawrence J. Scotchie
Abstract: Fabrication of a CSP or a stacked chip CSP can be accomplished with an unsupported film adhesive or an adhesive supported on a rigid carrier, using standard die attach equipment constructed for use with a paste adhesive.
Type:
Grant
Filed:
October 23, 2001
Date of Patent:
September 16, 2003
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: Curable compositions comprise a benzoxazine compound or resin in combination with at least one additional curable compound or resin. Optionally, the composition will further comprise a curing agent and/or a filler. These compositions have utility as adhesives, coatings and encapsulants, especially for use within the semiconductor fabrication industry, with particular utility as die attach adhesives, films, and underfill materials, such as no-flow underfills, capillary flow underfills, wafer level underfills, and as lead free solders.
Type:
Grant
Filed:
February 23, 2002
Date of Patent:
September 16, 2003
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: Compounds containing vinyl silane and electron donor or electron acceptor functionality can be used as adhesion promoters or as the main resin in curable compositions.
Type:
Grant
Filed:
September 28, 2001
Date of Patent:
May 27, 2003
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: An adhesion promoter containing silane, and carbamate, thiocarbamate or urea functionality, and electron donor or electron acceptor functionality, displays low volatility.
Type:
Grant
Filed:
May 18, 2000
Date of Patent:
August 27, 2002
Assignee:
National Starch and Chemical Investment Holding
Corporation
Inventors:
Osama M. Musa, Colin McLean, Mark Bonneau, Nikola A. Nikolic
Abstract: Allylated amide compounds are formulated into curable compositions with a free radical curing agent, and optionally, one or more fillers, for use as adhesives in the manufacture of microelectronic devices.
Type:
Grant
Filed:
June 29, 2001
Date of Patent:
May 14, 2002
Assignee:
National Starch and Chemical Investment Holding
Corporation
Inventors:
Rose Ann Schultz, Donald E. Herr, Chaodong Xiao
Abstract: A polymer composition, a process for its preparation and a molded article formed from the polymer composition are claimed. The polymer composition comprises (a) a base polymer that is a poly(alkyl(meth)acrylate; and (b) a rubber toughening agent selected from the group consisting of (i) copolymers of (alkyl)acrylate rubbers, (ii) copolymers of vinyl aromatic monomers with (alkyl)acrylates, (iii) copolymers of vinyl aromatic monomers with conjugated diolefins; (iv) copolymers of vinyl aromatic monomers with monoethylenically unsaturated monomers, in which the rubber toughening agent is present in the polymer composition as discrete islands substantially surrounded by the base polymer and in which islands are sub-islands of the base polymer.
Type:
Grant
Filed:
November 2, 2000
Date of Patent:
April 16, 2002
Assignee:
National Starch and Chemical Investment Holding
Corporation
Inventors:
Patrick Terence McGrail, Stephen Derek Jenkins, Christopher Ian Lindsay, Gordon Thomas Emmerson
Abstract: A thermoplastic or thermosetting adhesive for bonding an electronic component to a substrate in which the adhesive is cured in situ from a curable composition comprises one or more poly- or mono-functional maleimide compounds, or one or more poly- or mono-functional vinyl compounds other than maleimide compounds, or a combination of maleimide and vinyl compounds, a curing initiator and optionally, one or more fillers.
Type:
Grant
Filed:
April 14, 2000
Date of Patent:
March 12, 2002
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: This invention relates to underfill encapsulant compositions prepared from allylated amide compounds to protect and reinforce the interconnections between an electronic component and a substrate in a microelectronic device.
Type:
Grant
Filed:
June 7, 2001
Date of Patent:
February 26, 2002
Assignee:
National Starch and Chemical Investment Holding
Corporation
Inventors:
Rose Ann Schultz, Donald Herr, Chaodong Xiao
Abstract: A curable composition for encapsulating an electronic component comprises one or more mono- or polyfunctional maleimide compounds, or one or more mono- or polyfunctional vinyl compounds other than maleimide compounds, or a combination of maleimide and vinyl compounds, with a free radical curing agent, and optionally, one or more fillers.
Type:
Grant
Filed:
June 28, 2001
Date of Patent:
February 26, 2002
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: A curable composition for encapsulating an electronic component comprises one or more mono- or polyfunctional maleimide compounds, or one or more mono- or polyfunctional vinyl compounds other than maleimide compounds, or a combination of maleimide and vinyl compounds, with a free radical curing agent, and optionally, one or more fillers.
Type:
Grant
Filed:
June 18, 1999
Date of Patent:
November 13, 2001
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: Hybrid electron donor compounds, suitable for use as adhesives or as components in adhesives, contain a carbon to carbon double bond attached to an aromatic ring and conjugated with the unsaturation in the aromatic ring and a vinyl ether moiety.
Type:
Grant
Filed:
May 18, 2000
Date of Patent:
October 23, 2001
Assignee:
National Starch and Chemical Investment Holding
Corporation
Abstract: Compounds containing both electron donor and electron acceptor functionality are suitable for use in adhesives. The electron donor group is a carbon to carbon double bond attached to an aromatic ring and conjugated with the unsaturation in the ring. The electron acceptor group is a maleimide, acrylate, fumarate or maleate.
Type:
Grant
Filed:
May 18, 2000
Date of Patent:
October 9, 2001
Assignee:
National Starch and Chemical Investment Holding
Corporation