Abstract: A composition suitable as an additive in down-hole fluid for inhibiting clay swelling in a down-hole formation is comprised of an aqueous solution of a quaternary amine-based cationic polyelectrolyte and salt(s). The cation of the salt(s) may be a divalent salt cation, a choline cation, are certain N-substituted quaternary ammonium salt cations. The salt(s) anion may be a monovalent inorganic anion or an anion derived from an organic acid having from 2 to 6 carbons.
Abstract: A flocculating agent which comprises: a particulate polyethylene oxide; an inert liquid vehicle comprising a mixture of a glycol and glycerine, wherein the specific gravity of the polyethylene oxide is approximately the same as the specific gravity of the inert liquid vehicle; a suspension agent, and, optionally, an acidic compound.
Abstract: A hydrophobic polyelectrolyte copolymer which is useful in the removal of color in paper mill waste water. The copolymer preferably comprises diallyldimethylammonium chloride and a hydrophobic monomer selected from the group consisting of quaternized dimethylaminoethylacrylates and quaternized dimethylaminoethylmethacrylates.
Type:
Grant
Filed:
October 7, 1993
Date of Patent:
August 16, 1994
Assignee:
Nalco Chemical Company
Inventors:
Manian Ramesh, John W. Sparapany, Martha R. Finck, Kristine S. Siefert, Chandrashekar S. Shetty
Abstract: An acrylamide co-polymer which contains from between 1-60 mole percent of (2-acrylamido-2-hydroxy ethyl) trialkyl ammonium salt groups. These co-polymers are made by reacting (formylmethyl) trialykl ammonium salts at a pH of at least 9 and a temperature of between 15-80 degrees centigrade.
Abstract: Alkylation catalyst of the type used in the refining of petroleum can be improved by using a promoter composition which contains an alkyl phosphate ester amine salt and pinene.
Abstract: The invention provides a method of recycling waste oil fluids including dispersed solids and emulsified water. According to the method, the waste oil is treated with an effective amount of a dispersion of a water-soluble cationic polymer.
Type:
Grant
Filed:
March 1, 1993
Date of Patent:
July 26, 1994
Assignee:
Nalco Chemical Company
Inventors:
Michael L. Braden, Wayne M. Carlson, Manian Ramesh, Ananthasubramanian Sivakumar
Abstract: The invention provides a method of recovering water from an acid workover, the water including dispersed solids and emulsified oil. According to the method, the water is treated with an effective amount of a dispersion of a water-soluble cationic polymer.
Abstract: A method for concentrating coal tailings which comprises steps of: feeding the coal tailings to a thickener; treating the coal tailings with a hydrophobic polyelectrolyte copolymer coagulant which comprises diallyldimethylammonium chloride and a more hydrophobic monomer, the coagulant is added to the coal tailings in an amount between about 0.05 to about 0.25 lb/ton; treating the coal tailings with a flocculant in an amount between about 0.05 to about 0.25 lb/ton; discharging substantially concentrated tailing; and withdrawing substantially clarified liquid from the thickener.
Type:
Grant
Filed:
August 18, 1992
Date of Patent:
July 19, 1994
Assignee:
Nalco Chemical Company
Inventors:
Manian Ramesh, Ram A. Venkatadri, Lawerence J. Connelly, Jeffrey R. Cramm
Abstract: An environmentally acceptable and economically appealing method of inhibiting corrosion in brine solution systems wherein an aqueous brine solution is treated with gluconate or sorbitol.
Abstract: One aspect of the invention provides a method of removing emulsified oil from oil field produced water. According to the method, the oil-containing water is treated with an effective amount of a dispersion of a water-soluble cationic polymer.
Type:
Grant
Filed:
October 30, 1992
Date of Patent:
July 19, 1994
Assignee:
Nalco Chemical Company
Inventors:
Norman E. Byrne, Robert A. Marble, Manian Ramesh
Abstract: A wastewater treatment system and method for chemical precipitation and removal of metals from wastewater in a continuous or batch treatment process includes an ion-selective sulfide electrode and a reference electrode disposed in a precipitation tank for measuring an electrochemical potential therebetween in a predetermined range. A controller unit is provided which is responsive to the electrochemical potential in the predetermined range and is connected to a precipitant feed unit for automatically controlling the chemical precipitant fed into the precipitation tank.
Type:
Grant
Filed:
March 8, 1993
Date of Patent:
July 12, 1994
Assignee:
Nalco Chemical Company
Inventors:
Kristine S. Siefert, Pek L. Choo, Wayne M. Carlson
Abstract: Alkylation processes of the type used in the refining of petroleum can be improved by using a promoter composition which contains an alkyl phosphate ester amine salt and pinene.
Abstract: A process for removing color from a pulp and paper wastewater which comprises the following steps: (a) treating the wastewater with a reducing agent which is capable of inactivating color producing functional groups of the wastewater; and (b) treating the wastewater subsequent to step (a) with a polymer which is capable of removing color from the wastewater.
Type:
Grant
Filed:
September 1, 1993
Date of Patent:
July 5, 1994
Assignee:
Nalco Chemical Company
Inventors:
Jawed M. Sarkar, Amy M. Tseng, John H. Collins
Abstract: A method and apparatus for automatically measuring the acidity of overhead water in an oil refinery, and dispensing a neutralizing agent into the refinery system at a rate responsive to that measurement. A sample of overhead water is collected and passed through a filter and cation exchange resin. The acid concentration of the sample is then automatically measured and a signal generated based on the concentration. The signal goes to a controller which controls the dispensation rate of neutralizing agent into the refinery system, thus reducing the acidity of the overhead water and limiting the corrosive effects of such acidity.
Abstract: A method for preventing fouling of ethylene dichloride distillation units which comprises treating the feed to such unit with a fouling preventing amount of a composition comprising (a) 2-15 weight % of an oil soluble polyacrylate ester or methacrylate ester with alcohol radical of the ester group containing from C.sub.4 -C.sub.22 carbon atoms which contains between 0.1-25 mole % of amino alcohol ester groups; (b) 20-40 weight % a phenylene diamine compound having the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.1 -C.sub.20 aryl, C.sub.1 -C.sub.20 alkaryl or C.sub.1 -C.sub.20 aralkyl, with the proviso that at least one of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 is hydrogen; and (c) the balance is a heavy aromatic solvent.
Abstract: This invention is a method for inhibiting corrosion in metallic flow lines containing hydrocarbon and/or aqueous fluids comprising adding to the fluid contained in the flow line a corrosion inhibiting amount of a water-soluble ampholytic substituted imidazoline having the formula: ##STR1## wherein R1 comprises a radical selected from the group consisting of hydrogen, alkyl, and aryl groups having 6 to 30 carbons; R2 comprises a radical selected from the group consisting of polyalkylene polyamines having from 2 to 16 carbon atoms, NH.sub.2, N(R.sub.4).sub.2, OH and SH; R.sub.3 is a radical selected from the group consisting of carboxylate, carbonate, sulfite, sulfate, phosphite, and phosphate; n is a number from 1 to 10; and, R4 comprises a branched or linear alkyl chain having a length of 1 to 8.
Abstract: A corrosion inhibitor treatment composition for cooling water systems is disclosed in which no chromate is used and no free orthophosphate is present comprising a combination of a localized corrosion inhibitor in the form of a salt of molybdenum, vanadium, or tungsten, a general corrosion and scale inhibitor comprising zinc or nickel, a pair of organic phosphonates, and a stabilizing agent.
Abstract: Leakage of water from a boiler water system wherein steam is generated in a boiler from feedwater fed to the boiler, and the concentration of impurities in the boiler water within the boiler is reduced by withdrawing fractions thereof as blowdown while admitting additional feedwater as boiler-water makeup, is determined. The boiler has a concentration cycle value, the concentration cycle value being the average value of the concentration of an inert component in the blowdown at steady state (C.sub.F) divided by the concentration of the inert component in the feedwater (C.sub.I). The concentration of the inert component in the boiler at steady state varies from a high concentration C.sub.H, having a value that is higher than C.sub.F, to a low concentration C.sub.L, having a value between the (C.sub.I) and the (C.sub.F), within a time period.
Type:
Grant
Filed:
April 20, 1993
Date of Patent:
June 14, 1994
Assignee:
Nalco Chemical Company
Inventors:
Stanley C. Avallone, Roger W. Fowee, James R. MacDonald, Nicholas J. Furibondo
Abstract: Siliceous materials produced by thermally treating Bayer process liquors are obtained in modified form when produced in the presence of ammonium, aromatic amine, and amine compounds, or compounds bearing ammonium, aromatic amine or amine moieties, such as N-propylamine, pyridine and tetramethylammonium hydroxide. These modified siliceous materials possess morphologies which confer upon them a reduced tendency to deposit on surfaces throughout the process.
Abstract: Magnesium hydroxide is added to aqueous sprays used in the cooling of steel produced by continuous casting to reduce the corrosion of ferrous metals in contact with these sprays. The magnesium hydroxide when added to aqueous sprays used in the cooling of steel produced by continuous casting further reduces the potential for calcium fluoride scale formation by reducing the fluoride content of the system water.