Patents Represented by Attorney Kevin M. Faulkner
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Patent number: 8049053Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.Type: GrantFiled: January 28, 2011Date of Patent: November 1, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
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Patent number: 8048402Abstract: The synthesis of a crystalline aluminophosphate or silicoaluminophosphate molecular sieve having a chabazite-type framework type is conducted in the presence of an organic directing agent having the formula (I) [R1R2R3N—R4]+X???(I) wherein R1, R2 and R3 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R4 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms; 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S; and aromatic groups optionally substituted by 1 to 3 alkyl groups, said alkyl groups having from 1 to 3 carbon atoms; and X? is an anion.Type: GrantFiled: August 18, 2005Date of Patent: November 1, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Guang Cao, Matu J. Shah
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Patent number: 8039526Abstract: A method for preparing a nanoclay-filled thermoplastic vulcanizate, the method comprising introducing an olefinic thermoplastic vulcanizate, a functionalized thermoplastic resin, and a surface-modified nanoclay, where the blending takes place at a temperature above the melt temperature of the thermoplastic vulcanizate but below the temperature at which the surface-modified nanoclay degrades.Type: GrantFiled: April 5, 2006Date of Patent: October 18, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Maria Dolores Ellul, Paul Edward McDaniel, Thomas Gregory Lengyel
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Patent number: 8013069Abstract: Blends of at least two polymers incorporating propylene-derived units and processes for producing such blends are provided. The first polymer of the blend is a low crystallinity polymer including propylene-derived units. The second polymer is a high crystallinity polymer including propylene-derived units. The polymer blends exhibit the beneficial performance characteristics of low crystallinity propylene polymers while minimizing certain processing and handling problems associated with low crystallinity propylene polymers. Low crystallinity propylene polymer pellets often exhibit a tendency to agglomerate because of the softness of such particles. Agglomeration of the pellets creates problems in handling and processing the particles. The polymer blends disclosed reduce the tendency of polymer pellets to agglomerate while maintaining the desirable physical properties, such as elastomeric properties, exhibited by low crystallinity propylene polymers.Type: GrantFiled: January 13, 2006Date of Patent: September 6, 2011Assignee: Exxonmobil Chemical Patents Inc.Inventors: Bruce Allan Harrington, Michael Glenn Williams, Sudhin Datta, Srivatsan Srinivas Iyer
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Patent number: 7994253Abstract: A composition is described in one aspect as comprising one or more propylene-?-olefin terpolymers; wherein the propylene-?-olefin terpolymer(s) possess a melting temperature (Tm) within the range of from less than 105° C., and a heat of fusion (Hf) within the range of from less than 75 J/g; one or more polyolefin(s); and oil; wherein fillers are present, if at all, at a level that maintains a Haze value of 65% or less for the composition. The terpolymer in one embodiment is a polymer comprising at least 65 wt %, by weight of the terpolymer, of propylene-derived units, within the range of from 5 to 35 wt % of ethylene or other ?-olefin and a diene such as ethylidiene norbornene, and in certain embodiments having a Mooney Viscosity (ML(1+4)@125° C.) within the range of from 10 to 50 (ASTM D1646). The compositions can be cured to form transparent or translucent articles such as sheets that are also flexible.Type: GrantFiled: April 15, 2008Date of Patent: August 9, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Sunny Jacob, Gary K. Lawrence, Edward John Blok, Ralph E. Raulie
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Patent number: 7989669Abstract: This invention is directed to a process for producing one or more olefins from an oxygenate feed. According to the invention, an oxygenate stream is provided and a recycle stream is added to the oxygenate stream to form a feed stream to an oxygenate-to-olefin conversion system. The recycle stream comprises (i.e., contains) propane and dimethyl ether.Type: GrantFiled: February 20, 2008Date of Patent: August 2, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Gerald G. McGlamery, Jr., James H. Beech, Jr., Michael P. Nicoletti, Cornelis F. Van Egmond
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Patent number: 7985801Abstract: The present invention relates to fibers and nonwovens made from plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.Type: GrantFiled: September 13, 2007Date of Patent: July 26, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Wen Li, Chon-Yie Lin, Bryan R. Chapman, Michael B. Kelly
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Patent number: 7977521Abstract: This invention, in one embodiment, is drawn to a process for forming olefin product by contacting an oxygenate with an olefin-forming catalyst under supercritical conditions to form an olefin product. This invention also relates to methods for activating molecular sieve catalyst, regenerating molecular sieve catalyst, and forming and/or disposing a co-catalyst within a molecular sieve catalyst, each under supercritical conditions.Type: GrantFiled: June 11, 2008Date of Patent: July 12, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Luc R. M. Martens, Stephen N. Vaughn, John R. Shutt
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Patent number: 7964672Abstract: A high strength thermoplastic vulcanizate (TPV) composition is provided. The TPV includes a dispersed rubber component, a polyolefinic thermoplastic resin component, a propylene copolymer and mineral filler present in the amount of 20 wt % to 70 wt % based on total of the thermoplastic vulcanizate composition. Preferably, the propylene copolymer has 60 wt % or more units derived from propylene; includes isotactically arranged propylene derived sequences; and has a heat of fusion less than 45 J/g. Preferably, the mineral filler is halogen free and flame retardant. The high strength TPV can be useful for making a variety of articles for electrical, construction, automotive, and consumer applications, including fuel cell.Type: GrantFiled: November 5, 2004Date of Patent: June 21, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventor: Trazollah Ouhadi
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Patent number: 7955540Abstract: A method of forming a thermoplastic vulcanizate by first providing a melt-blender having a die through which melt-blended thermoplastic vulcanizate passes to form a shaped article; wherein the die comprises a flow design having at least one flow branch having a taper angle and a flow reservoir at the end of each flow branch; and wherein the taper angle of the flow design ranges from 5 to 20 degrees; followed by melt-blending a thermoplastic and an elastomer with an organic peroxide curative in the melt-blender to form a thermoplastic vulcanizate; and finally, passing the melt-blended thermoplastic vulcanizate through the flow design to form the shaped article.Type: GrantFiled: January 19, 2007Date of Patent: June 7, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Felix M. Zacarias, Rachna Mohan, John Bowers
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Patent number: 7951316Abstract: Process for forming an annular member by extruding a thermoplastic profiled strip at an elevated temperature. Prior to cooling the strip, the still-molten ends undergo in-line compression molding to form an annular member having a joint section. The cross-section of the annular member is continuous in the joint section and the remainder of the body. Preferably, the extrudate may contain a thermoplastic elastomer, more preferably a thermoplastic vulcanizate formed by a dynamic vulcanization process. During the extrusion and compression molding processes, the extrudate may be supported on a rotatable turntable, or alternately on a rotatable molding cylinder.Type: GrantFiled: April 5, 2005Date of Patent: May 31, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jeffrey M. Smith, Duane E. Peterson, Harold H. Seymour
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Patent number: 7951871Abstract: A method for preparing a thermoplastic vulcanizate, the method comprising dynamically vulcanizing a rubber within a blend that includes the rubber and a thermoplastic polymer, where said dynamically vulcanizing is effected with a cure system that includes a hydrosilating agent and a catalyst, where the hydrosilating agent includes a compound including at least 3 silicon hydride groups defined by the formula where each R is independently a monovalent organic group or hydrogen, and where the silicon atoms of the respective silicon hydride groups are spatially separated by at least 6 atoms.Type: GrantFiled: November 10, 2006Date of Patent: May 31, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Edward J. Blok, Maria D. Ellul, Alfred V. Pickett, Carl Voellmecke
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Patent number: 7951732Abstract: Elastic laminates and articles for manufacture are provided. The elastic laminate can include one or more facing layers comprising one or more thermoplastic resins and one or more propylene-based polymers, and one or more inner layers comprising one or more propylene-based polymers. Each facing layer can include at least 50% by weight of the one or more propylene-based polymers where the propylene-based polymer has (i) 60 wt % or more units derived from propylene, (ii) isotactically arranged propylene derived sequences, and (iii) a heat of fusion less than 45 J/g.Type: GrantFiled: January 26, 2007Date of Patent: May 31, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Narayanaswami Raja Dharmarajan, Monica Gonzalez Correa, Vincent Bernard Benoît Ghislain Gallez
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Patent number: 7947621Abstract: This invention provides a process for manufacturing a catalyst with a desired attrition index, comprising the steps of selecting at least one molecular sieve having a morphology and size index (MSI) of from 1 to about 1000 to secure said desired attrition index of said catalyst.Type: GrantFiled: January 12, 2007Date of Patent: May 24, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Yun-feng Chang, Machteld Maria Mertens, Stephen N. Vaughn
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Patent number: 7943711Abstract: In a process for producing an elastomer composition, ethylene, at least one alpha-olefin, and at least one diene is contacted with a catalyst system comprising at least two metallocene catalyst compounds and a non-coordinating anion activator wherein one of the metallocene catalyst compounds is an indenyl complex having the general formula: (In1R1m)R3(In2R2p)MXq, and at least one metallocene catalyst compound comprises a compound having the general formula: wherein M is a transition metal from Group 3, 4, or 5 of the Periodic Table of the Elements and other deatures defined herein.Type: GrantFiled: May 14, 2007Date of Patent: May 17, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventor: Periagaram Srinivasan Ravishankar
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Patent number: 7943701Abstract: A nonwoven fabric made from a composition comprising (a) a propylene-based elastomer characterized by including from about 5% to about 35% by weight units deriving from alpha-olefin and a heat of fusion, as determined by DSC, of less than 80 J/g, (b) a propylene-based thermoplastic polymer characterized by an MFR (ASTM D-1238 2.16 kg @ 230° C.) of from about 3 to about 300 dg/min, and a heat of fusion, as determined by DSC, of greater than 80 J/g, and (c) a feel modifier selected from the group consisting of (i) a high-MFR thermoplastic resin having an MFR (ASTM D-1238 2.16 kg @ 230° C.) in excess of 400 dg/min, (ii) a hydrocarbon resin, (iii) a polyolefin wax, (iv) a functionalized hydrocarbon resin, (v) a functionalized polyolefin, and (vi) a combination of two or more of the foregoing feel modifiers, and (d) optionally a slip aid.Type: GrantFiled: January 26, 2007Date of Patent: May 17, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Narayanaswami Raja Dharmarajan, Smita Kacker
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Patent number: 7935857Abstract: A gas-solids reaction system is provided for improving product recovery in a multiple reactor reaction system. The solids of the product gas-solids flows from the multiple reactors are separated out in a separation vessel having a baffled transition zone. Additional product vapor is stripped from the solids as the solids pass through the baffled transition zone. The solids are then returned to the multiple reactors.Type: GrantFiled: February 14, 2007Date of Patent: May 3, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: James H. Beech, Richard E. Walter, Arun K. Sharma, Jeffrey S. Smith
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Patent number: 7927695Abstract: Roofing composites and methods of producing the roofing composites are disclosed. The roofing composites are multi-layer structures in which two layers of the composite structures are bonded to each other by a thermoplastic elastomer composition. The layers are bonded to each other by heat fusing the elastomer composition in one embodiment. The composite structures have a variety of uses, including uses in construction materials such a roofing membranes, interior and exterior siding, and wall coverings.Type: GrantFiled: May 31, 2006Date of Patent: April 19, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventor: Ralph E. Raulie
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Patent number: 7923261Abstract: This invention is directed to a method for determining a source of carbon feed used in manufacturing product produced from the carbon feed. The invention further provides a method for tracking products, particularly MTO products, derived from a particular carbon feed. In general, the method involves a variety of steps that include one or more of determining, comparing, inventorying, and tracking the 13C:12C ratio (or HD:H2 ratio) of the product that is being tracked to the measured or predetermined 13C:12C ratio (or HD:H2 ratio) of the feed used to make the product.Type: GrantFiled: June 6, 2008Date of Patent: April 12, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventor: Thomas H. Colle
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Patent number: 7914760Abstract: A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.Type: GrantFiled: October 8, 2009Date of Patent: March 29, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld M. Mertens, An Verberckmoes, Marcel J. Janssen, Yun Feng Chang, Luc R. M. Martens, Stephen Neil Vaughn, Kenneth Ray Clem, Wilfried J. Mortier