Abstract: Disclosed is a method of making a continuous mixed oxide thin film. A composition is prepared of an alkoxide source of one of the metals in the mixed oxide, a chelate source of a second metal in the mixed oxide, sufficient alcohol to solubilize sources of all metals in said mixed oxide and about 1 to about 2 moles of water per mole of mixed oxide. The composition is applied to a substrate and the coating on the substrate is heated to at least about 500.degree. C. to evaporate the solvent and produce the mixed oxide film on the substrate.

Abstract: Disclosed is a water based thermosetting epoxy composition of a water compatible epoxy resin, about 5 to about 35% based on total solids of a water polymerized impact modifier in a water based latex, about 1.5 to about 7% based on the weight of the epoxy resin of a water compatible epoxy hardener, up to about 0.3% based on the weight of the epoxy resin of a catalyst, and sufficient water to provide a viscosity of about 100 to about 400 centipoises. The compositions are used to prepare high impact strength, high damping laminates.

Abstract: Disclosed is a UV-curable coating composition and method of preparing it, a method of coating a conductor with it, and the resulting coated conductor. The composition comprises about 20 to about 40% by weight of an acrylated epoxy which is the reaction product of an epoxy resin and an acrylate adduct. The acrylate adduct is the reaction product of an acrylate which may be either 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxyethyl methacrylate or mixture thereof, and either an anhydride or a diisocyanate. The anhydride may be phthalic anhydride, maleic anhydride, trimellitic anhydride, or mixtures thereof. The diisocyanate can be toluene diisocyanate, 4,4'-diisocyanato diphenyl methane, or mixtures thereof. The composition also includes about 4 to about 15% by weight of an acrylated blocked isocyanate which is the reaction product of caprolactam and an acrylated isocyanate.

Abstract: Apparatus is disclosed for collecting and concentrating trace ions from a pressurized aqueous sample in a sample line. A three-way valve is connected to the sample line which in one position can divert the sample into a syringe and in another position can close off the sample line and permit the sample to flow from the syringe through the three-way valve into a concentrator column. In an alternative apparatus, the sample line is connected to a tee which permits the diversion of the sample into a concentrator column connected to the tee. The other end of the concentrator column is joined to a syringe for drawing the sample through the concentrator column. Methods of operating the apparatus are also disclosed.

Abstract: Uranium is recovered from a carbonate leach solution containing a dissolved uranium salt and a monovalent ion. The pH of the leach solution is adjusted to about 5 to about 7.5, and preferably to about 6 to about 7. Phosphate ion is then added to typical in-situ leach solutions in an amount from about 10 to about 30 mole % in excess of the amount needed to stoichiometrically react with the uranium in said solution. This results in the precipitation of a compound made up of the monovalent ion, uranium, and the phosphate ion, which is insoluble in the solution. The precipitate is then separated from the solution preferably by means of a centrifuge or a vortex clarifier. It can then be dissolved in acid, and the uranium extracted into an organic solvent such as DEHPA-TOPA in kerosene.

Abstract: A method is disclosed of immobilizing actinide metal oxide ions. A liquid composition is prepared of the actinide metal oxide ions and a monomer which is capable during electropolymerization of complexing with the actinide metal ions. An optional polar solvent may be included in the composition if it is necessary to dissolve a solid monomer. The monomer is then electropolymerized to form a polymeric complex with the actinide metal oxide ion. The polymeric complex can be separated from the remainder of the liquid composition by the addition of a non-solvent for the polymeric complex which results in its precipitation. Vinylimidazoles have been found to be suitable monomers for use in this process.

Abstract: Disclosed is a method of making a non-aqueous emulsion from which a polymer can be electrodeposited. A mixture is prepared of about 50 to about 150 parts by weight of a non-aqueous organic, non-electrolizable, non-solvent for the polymer with about 0.8 to about 1.2 parts by weight of a nitrogen-containing base which can be a tertiary amine, an imidazole, or mixture of a tertiary amine and an imidazole. To the mixture is added a solution of 1 part by weight of the polymer which can be a polyamic acid, a polyamide imide, a polyimide, a polyparabanic acid, a polysulfone, or a mixture of these polymers. The polymer is in a non-aqueous, organic, non-electrolizable aprotic solvent such as N-methyl-2-pyrrolidone.

Abstract: Disclosed is a device and a method for measuring the partial pressure of oxidizing species in a liquid. A metal or incompletely oxidized metal oxide which is susceptible to anodic oxidation and which forms an oxide having a Pilling-Bedworth ratio greater than one is placed in the liquid. The oxide formed on the metal is confined and the pressure of the confined oxide is measured. That pressure is a known function of the concentration of oxidizing species in the liquid. The device is calibrated in liquids of known oxygen content to establish the relationship between oxide content and pressure.

Abstract: Disclosed is a method of preparing a clear partially hydrolyzed aluminum alkoxide solution by mixing an aluminum alkoxide with about 0.4 to about 1 moles of water per mole of aluminum alkoxide in the presence of sufficient alcohol to give a maximum weight percent of equivalent alumina of 10%. The mixture is then heated until clear, which typically requires a temperature of about 40.degree. to about 60.degree. C. Then sufficient additional water is added to bring the number of moles of water per mole of alkoxide up to at least about 2. The water is added in the presence of sufficient alcohol to give a maximum weight percent of equivalent alumina of about 3%. A polymerized alumina glass can be prepared from the composition by heating it to a temperature of at least 500.degree. C.

Abstract: Disclosed is a conductor coated with a fused and cured powder applied insulating coating over which is a coating of an ultraviolet B-stageable, thermally C-stageable liquid resin. The coating is cured to the B-stage and strands of the conductor are placed side-by-side. The coating is then cured to the C-stage which fuses the strands of the conductor into a solid mass. The adhesive coated conductors may be used to form transformer coils, transposed cables, or other articles.

Abstract: Disclosed is an apparatus which is resistant to electrical breakdown consisting of a chamber containing electrodes separated by dielectric gas supersaturated with the vapor from a dielectric liquid.

Abstract: Disclosed is a method of making a pellet from a powder by placing the powder in a heat-shrinkable container, sealing the container and isostatically pressing the container at a temperature which causes it to shrink, followed by decomposition of the container and sintering of the powder. In preparing nuclear fuel pellets, a free-flowing fissile powder is mixed with a free-flowing fertile powder and the mixture is placed in the heat-shrinkable container. The container is sealed, heated and isostatically pressed, then decomposed and the powder is sintered.

Abstract: Disclosed is a method of containing nuclear waste. A composition is first prepared of about 25 to about 80%, calculated as SiO.sub.2, of a partially hydrolyzed silicon compound, up to about 30%, calculated as metal oxide, of a partially hydrolyzed aluminum or calcium compound, about 5 to about 20%, calculated as metal oxide, of a partially hydrolyzed boron or calcium compound, about 3 to about 25%, calculated as metal oxide, of a partially hydrolyzed sodium, potassium or lithium compound, an alcohol in a weight ratio to hydrolyzed alkoxide of about 1.5 to about 3% and sufficient water to remove at least 99% of the alcohol as an azeotrope. The azeotrope is boiled off and up to about 40%, based on solids in the product, of the nuclear waste, is mixed into the composition. The mixture is evaporated to about 25 to about 45% solids and is melted and cooled.

Abstract: A method is disclosed for producing a dimensionally stable UO.sub.2 fuel pellet of large grain mole %, and relatively large pore size. A dopant containing an element selected from the group consisting of aluminum, calcium, magnesium, titanium, zirconium, vanadium, niobium, and mixtures thereof is added to a highly sinterable UO.sub.2 powder, which is a UO.sub.2 powder that is sinterable to at least 97% theoretical density at 1600.degree. C. in one hour, and the UO.sub.2 powder can then be formed into fuel pellets. Alternatively, the dopant can be added at a step in the process of producing ammonium diuranate. The ammonium diuranate is collected with about 0.05 to about 1.7 mole%, based on UO.sub.2, of a compound containing said element. That mixture is then calcined to produce UO.sub.2 and the UO.sub.2 is formed into a fuel pellet. The addition of the dopant can also be made at the hydrolysis stage in the manufacture of UO.sub.2 by a dry conversion process.

Abstract: Disclosed is an improved water reducible modified polyester resin. The improvement is including in the resin about 20 to about 50% by weight, based on total solids weight, of a mixture of hexamethoxymethyl melamine and methylated melamine formaldehyde in a weight ratio of about 2 to 1 to about 1 to 2. The mixture is preferably about 25 to about 35% of the resin based on total solids weight and the weight ratio of hexamethoxymethyl melamine to methylated melamine formaldelhyde is preferably about 1 to 1. The mixture should be at least about 75% by weight of any melamine resin present.

Abstract: Disclosed is a method of making a non-aqueous emulsion from which a polymer can be electrodeposited. A mixture is prepared of about 50 to about 150 parts by weight of a non-aqueous organic, non-electrolizable, non-solvent for the polymer with about 0.8 to about 1.2 parts by weight of a nitrogen-containing base which can be a tertiary amine, an imidazole, or mixture of a tertiary amine and an imidazole. To the mixture is added a solution of 1 part by weight of the polymer which can be a polyamic acid, a polyamide imide, a polyimide, a polyparabanic acid, a polysulfone, or a mixture of these polymers. The polymer is in a non-aqueous, organic, non-electrolizable aprotic solvent such as N-methyl-2-pyrrolidone.

Abstract: Disclosed is a method of inhibiting the attack by perchloroethylene on copper and organic polymers subject to said attack, such as parylene, by adding to perchloroethylene about 20 to about 1000 ppm of a stabilizer having the general formula ##STR1## The preferred concentration of the stabilizer is about 40 to about 500 ppm. Also disclosed is an electrical apparatus containing copper or organic polymer subject to attack by perchloroethylene and perchloroethylene containing the stabilizer.

Abstract: Disclosed is a process for containing a solution of nuclear waste, where the nuclear waste is at least 10% sodium or nitrate. A composition is prepared in an alcohol of about 1 to about 99% of a silicon alkoxide and about 1 to about 99% of a boron alkoxide. The pH of the nuclear waste solution is adjusted to about 4 to about 6 and the pH of the composition is adjusted to match. The composition is dried to about 50 to about 75% of its original volume and is mixed with up to about 30% of the solution of nuclear waste, thereby forming a gel. The mixture is dried and heated at up to about 500.degree. C. Finally, it is consolidated either by warm pressing at about 400.degree. to about 800.degree. C. at about 40,000 to about 100,000 psi, or by melting at about 700.degree. to about 1150.degree. C.

Abstract: Disclosed is a method of making an insulated conductor by coating a conductor with a triazole and applying the insulation over the triazole coating. The triazole is preferably benzyltriazole or tolyltriazole. It can be applied dissolving the triazole in water, immersing the conductor in the solution and evaporating the water. The invention is particularly useful with epoxy powder coatings on copper conductors which are used in perchloroethylene containing insulating fluid.

Abstract: Disclosed is an improvement on a method of making an electrode wherein a suspension in a liquid is prepared of a powdered catalyst containing a noble metal, carbon powder and a binder, and the suspension is poured over a carbon substrate dried, compressed and sintered to form a solid catalyst layer bonded to the carbon substrate. The improvement is placing a carbon paper on the catalyst layer prior to compressing. The improved electrode can be used as either a cathode or an anode in a sulfur dioxide depolarized electrolyzer in a process for producing hydrogen from water.