Abstract: Low molecular weight mercaptans are extracted from petroleum (e.g., crude oil) or gas condensate by contacting the mercaptans with oxygen in an aqueous solution of a metal hydroxide in the presence of a cobalt dihalodihydroxydisulfophthalocyanine catalyst. The catalyst is introduced into the crude oil or gas condensate continuously in the form of a catalytic complex in an aqueous solution of a metal hydroxide.
Type:
Grant
Filed:
July 31, 1995
Date of Patent:
November 4, 1997
Assignee:
Chevron U.S.A. Inc.
Inventors:
Akhmet Mazgarovich Mazgarov, Azat Faridovich Vildanov, Nailya Gilmutdinovna Bazhirova, Gulnara Burkhanova Niamutdinova, Sergei Nikolaevich Sukhov
Abstract: The present invention relates to new crystalline zeolite SSZ-44 prepared by processes for preparing crystalline molecular sieves, particularly large pore zeolites, using a N,N-diethyl-cis-2,6-dimethyl piperidinium cation templating agent.
Abstract: The present invention relates to new crystalline zeolite SSZ-41 which comprises oxides of (1) silicon or a mixture of silicon and germanium, and (2) zinc, said zinc being present in an amount from about 2 wt % to about 5 wt % of zinc metal based on the total weight of metals in said zeolite. Zeolite SSZ-41 may also optionally contain oxides of aluminum, iron, gallium or mixtures thereof. Zeolite SSZ-41 has the X-ray diffraction lines of Table I and has an argon adsorption capacity of at least about 0.06 cc/gm at 87.degree. K. Also disclosed are methods of making and using zeolite SSZ-41.
Abstract: The present invention relates to new crystalline zeolite SSZ-42 prepared by processes for preparing crystalline molecular sieves, particularly large pore zeolites, using an organic templating agent selected from the group consisting of N-benzyl-1,4-diazabicyclo[2.2.2]octane cations and N-benzyl-1-azabicyclo[2.2.2]octane cations.
Abstract: The present invention relates to a process for preparing the zeolite ZSM-11 using 3,5-dimethylpiperidinium compounds as an organic templating agent, and to the zeolite ZSM-11 in the pure phase form.
Abstract: A crystalline zeolite high-silica SSZ-37 is prepared using a N,N-dimethyl-4-azoniatricyclo [5.2.2.0.sup.(2,6) ] undec-8-ene cation as a template wherein said zeolite is used in hydrocarbon conversion processes.
Abstract: A process is provided for the removal of hydrogen sulfide from a hydrogen sulfide-containing gas by contacting said gas with an aqueous solution comprising chelated iron, an organic amine, an alkali metal hydroxide, carbonate or bicarbonate, and an alkali metal or ammonium phosphate or polyphosphate.
Type:
Grant
Filed:
June 2, 1995
Date of Patent:
April 1, 1997
Assignee:
Chevron U.S.A. Inc.
Inventors:
Akhmet M. Mazgarov, Akhmatfail M. Fakhriev, Rais N. Khafizov, Leonid A. Kashevarov, Mikhail P. Alimov
Abstract: The present invention relates to new crystalline zeolite SSZ-41 which comprises oxides of (1) silicon or a mixture of silicon and germanium, and (2) zinc, said zinc being present in an amount from about 2 wt % to about 5 wt % of zinc metal based on the total weight of metals in said zeolite. Zeolite SSZ-41 may also optionally contain oxides of aluminum, iron, gallium or mixtures thereof. Zeolite SSZ-41 has the X-ray diffraction lines of Table I and has an argon adsorption capacity of at least about 0.06 g/g argon at 87.degree. K. Also disclosed are methods of making and using zeolite SSZ-41.
Abstract: The present invention relates to new crystalline zeolite SSZ-44 prepared by processes for preparing crystalline molecular sieves, particularly large pore zeolites, using a N,N-diethyl-cis-2,6-dimethyl piperidinium cation templating agent.
Abstract: A method is disclosed for preparing a crystalline aluminosilicate zeolite from a reaction mixture containing only sufficient water so that the reaction mixture may be shaped if desired. In the method, the reaction mixture is heated at crystallization conditions and in the absence of an external liquid phase, so that excess liquid need not be removed from the crystallized material prior to drying the crystals.
Abstract: An aluminophosphate-type molecular sieve is prepared using a templating agent derived for an organosulfonium cation of the form S.sup.+ (R).sub.3, wherein each R is independently selected from alkyl, aryl and alkylaryl.
Abstract: A process is provided for catalyst dehydrogenation of light paraffinic hydrocarbons using a catalyst comprising a noble metal and an intermediate pore size zeolite having a specified alkali content. The catalyst is sulfur tolerant, so that the dehydrogenation process can be carried out in the presence of sulfur or with periodic exposure to sulfur.
Abstract: A process is disclosed for preparing a non-zeolitic molecular sieve from a dense gel containing sufficient liquid that the dense gel may be formed into self-supporting particles if desired prior to crystallization. In the process, the dense gel, which is optionally in the form of particles, is heated at crystallization conditions and in the absence of an external liquid phase, so that excess liquid need not be removed at the conclusion of the crystallization step.
Abstract: Molecular sieves, particularly metalloaluminophosphates are prepared using templates derived from a 4-azonia-tricyclo 5.2.n.0.sup.2,6 !alkene family of compounds. The templates may be prepared in a series of reaction steps which include a Diels-Alder reaction between a diene and a dienophile.
Abstract: Molecular sieves, particularly zeolites, are prepared using heterobridged aza-polycyclic templates. The templates may be prepared in a series of reaction steps which include a Diels-Alder reaction between a diene and a dienophile.
Type:
Grant
Filed:
February 8, 1994
Date of Patent:
June 20, 1995
Assignee:
Chevron Research and Technology Company, A Division of Chevron U.S.A. Inc.
Abstract: Disclosed is a catalyst system for the homopolymerization and copolymerization of alpha-olefins having 2-8 carbon atoms, said catalyst system comprising a cyclopentadienyl Group 6b metal compound having at least one oxo, thio, imido or phosphido group bonded directly to the Group 6b metal, and at least one organic radical bonded to the Group 6b metal through a carbon atom, said Group 6b metal compound being supported on an inorganic support. The catalyst system may also contain a Group 2 or Group 3 metal alkyl compound cocatalyst.
Abstract: A crystalline zeolite SSZ-32 of novel composition is prepared using an N-lower alkyl-N'-isopropyl-imidazolium cation as a template. Also disclosed is a process for converting hydrocarbons with crystalline zeolite SSZ-32.
Type:
Grant
Filed:
February 28, 1994
Date of Patent:
March 14, 1995
Assignee:
Chevron U.S.A. Inc.
Inventors:
Stacey I. Zones, James N. Ziemer, Donald S. Santilli, Robert A. Innes, Dennis L. Holtermann