Patents Represented by Attorney Richard A. Anderson
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Patent number: 4260735Abstract: Using an alkanolamine titanium chelate catalyst, such as triethanolamine titanium chelate, in small catalytic amounts to esterify and polycondense aromatic polycarboxylic acids or anhydrides, such as terephthalic acid, with a glycol, such as ethylene glycol at low glycol to acid reactant ratios surprisingly yields a polyester of low diethylene glycol content without adding an additional diethylene glycol suppressant.Type: GrantFiled: February 12, 1980Date of Patent: April 7, 1981Assignee: Allied Chemical CorporationInventors: John A. Bander, Stanley D. Lazarus, Ian C. Twilley
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Patent number: 4251481Abstract: A low shrinkage, dimensionally stable, polyester industrial fiber is produced by a process which involves conditions of continuously spinning and drawing filaments wherein the filaments are passed through a steam impinging draw point localizing jet (25) at a temperature of about 460.degree. C. to 580.degree. C. to thereby heat the filaments substantially immediately above their second order transition temperature. The low shrinkage polyester fibers are particularly useful in the preparation of industrial products, including industrial belts, conveyor belts, and reinforced elastomeric structures.Type: GrantFiled: May 24, 1979Date of Patent: February 17, 1981Assignee: Allied Chemical CorporationInventor: Maxwell C. Hamlyn
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Patent number: 4237187Abstract: A process for producing a highly oriented, partially drawn, untwisted, compact poly(.epsilon.-caproamide) yarn at windup speeds of from 3500 to 6000 meters per minute is disclosed. The process features the steps of overfeeding the yarn, by from 0.5 to 2.0 percent, to entangling means, and overfeeding the shrinking yarn to the winder. The yarn is "drawn" in the quench stack. Draw-twisting is omitted by this process; yarn so produced performs as well as conventional, draw-twisted yarn in end use applications, e.g., knitting and weaving.Type: GrantFiled: February 26, 1979Date of Patent: December 2, 1980Assignee: Allied Chemical CorporationInventors: James C. Raybon, Jr., Malcolm O. Darby, Thomas V. Derrick, Jr.
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Patent number: 4233279Abstract: Ammonium nitrite is commercially produced by contacting a gaseous stream containing nitric oxide, nitrogen dioxide, nitrogen and oxygen with an aqueous solution containing a basically reacting ammonium compound in an absorption system. However, at normal production rates, serious problems have been encountered because of relatively low yield of ammonium nitrite and the emission of unreacted nitric oxide which causes pollution of the atmosphere. It has now been found that in situ generation of nitrogen dioxide in the absorption system by operating the absorption system under slight pressure greatly improves ammonium nitrite yield, reduces nitrogen oxide emission, reduces loss of ammonia as nitrogen and minimizes mist formation in the vent gas.Type: GrantFiled: June 4, 1979Date of Patent: November 11, 1980Assignee: Allied Chemical CorporationInventors: Laszlo J. Balint, Lamberto Crescentini, William B. Fisher, Muhammad S. Sahli
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Patent number: 4212606Abstract: Apparatus is disclosed for bringing into proximity and connecting a quench stack and monomer ring for the melt spinning of synthetic polymer fibers. These members are brought into proximity through use of a reel assembly and are connected by means of a clamping device. The clamp, which is mounted on the quench stack, features a drawpiece comprising a rod. The rod is curved into a "U" shape, the base of which engages with a keeper element and the legs of which describe a circle bend prior to terminating in a threaded shank for mounting to the clamp.Type: GrantFiled: May 25, 1978Date of Patent: July 15, 1980Assignee: Allied Chemical CorporationInventor: Harold G. Sachleben, Sr.
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Patent number: 4204828Abstract: A quench system for spinning multifilament synthetic fiber using a fog in the quench stack is disclosed. The system and method comprisea. spinning synthetic multifilament fiber from the molten synthetic polymer through a spinnerette into a quench stack,b. quenching the freshly spun fiber in the quench stack with a combination of flowing air and airless atomized water in the form of a fog, andc. taking up the fiber onto a wound package,d. while controlling the air flow, controlling the formation of the fog, and removing any excess water droplets formed in the quench stack.Type: GrantFiled: August 1, 1978Date of Patent: May 27, 1980Assignee: Allied Chemical CorporationInventors: Frank L. Peckinpaugh, Raymond J. Biron
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Patent number: 4200553Abstract: In a process for producing cyclohexanone comprising hydrogenating phenol in the liquid phase in the presence of a catalyst composed of a carrier having deposited thereon a layer of palladium and an alkali metal compound as a promoter, the improvement wherein the carrier consists of carbon particles having diameters of 5 to 300 microns and the catalyst is admixed with 0.1 to 10 parts by weight, per part of catalyst, of carbon particles having diameters less than 5 microns. This improvement effectively reduces long-term accumulation of catalyst poisons on the catalyst, including catalyst poisons that are by-products of the hydrogenation reaction.Type: GrantFiled: October 16, 1978Date of Patent: April 29, 1980Assignee: Allied Chemical CorporationInventors: Jan F. Van Peppen, William B. Fisher
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Patent number: 4197606Abstract: The method of this invention comprises the improvement of using an open frame skein carrier with arms to loosely hang the yarn skeins. This allows a shorter total heat-setting time; eliminates kinks, and improves bulk and bulk uniformity of the yarn.Type: GrantFiled: October 10, 1978Date of Patent: April 15, 1980Assignee: Allied Chemical CorporationInventors: Harry F. Hale, Lewis R. Hackler, Raymond J. Biron
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Patent number: 4193880Abstract: A yarn finish composition is disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. The composition comprises (a) a nonhomogeneous mixture of a salt of dinonyl sulfosuccinate, a salt of dimethyl naphthalene sulfonate, and ammonium perfluoroalkyl carboxylate, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: March 30, 1979Date of Patent: March 18, 1980Assignee: Allied Chemical CorporationInventor: Robert M. Marshall
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Patent number: 4192754Abstract: A yarn finish composition is disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. The composition comprises (a) a solution of a salt of dioctyl sulfosuccinate, propylene glycol and water, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: December 28, 1978Date of Patent: March 11, 1980Assignee: Allied Chemical CorporationInventors: Robert M. Marshall, Kimon C. Dardoufas
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Patent number: 4191656Abstract: A finish composition for polyamide yarn which comprises an oil in water emulsion and an effective amount of 2[(hydroxymethyl)amino]ethanol biocide resists bacteria growth and causes the treated yarn to resist yellowing under steam heat treatment. The oil in water emulsion and biocide most preferably form, respectively, 99.9 percent and 0.1 percent by weight of the finish composition. The preferred oil in water emulsion is about 10 to 20 percent by weight of the oil portion, the oil portion consisting essentially of from about 55 to 65 percent by weight of coconut oil, about 20 to 35 percent by weight of polyoxyethylene hydrogenated castor oil, and about 7 to 15 percent by weight of potassium salt of polyoxyethylene tridecyl phosphate. The finish composition is especially useful for application to polyamide yarn to be processed into either staple carpet yarn or bulked continuous filament carpet yarn.Type: GrantFiled: October 5, 1978Date of Patent: March 4, 1980Assignee: Allied Chemical CorporationInventor: Robert M. Marshall
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Patent number: 4190545Abstract: Several spin finishes are disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. All of the spin finishes include a yarn finish composition which comprises (a) a nonhomogeneous mixture of a salt of dinonyl sulfosuccinate, a salt of dimethyl naphthalene sulfonate, and ammonium perfluoroalkyl carboxylate, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxy-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: March 30, 1979Date of Patent: February 26, 1980Assignee: Allied Chemical CorporationInventors: Robert M. Marshall, Kimon C. Dardoufas
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Patent number: 4188430Abstract: A cut/loop or cut pile carpet having a beneath-the-surface patterning effect is fabricated from at least two yarn groups:(A) a multiple ply heat-set yarn having a relatively light dye affinity combined with a nonheat-set yarn having a first relatively darker dye affinity, and(B) a heat-set yarn having a relatively light dye affinity combined with a nonheat-set yarn having a second relatively darker dye affinity,so that the nonheat-set yarns shrink to a lower pile height than the heat-set yarn(s) due to heat and moisture during dyeing and drying the carpet, whereby at least two colorways are established in the carpet.Type: GrantFiled: June 12, 1978Date of Patent: February 12, 1980Assignee: Allied Chemical CorporationInventors: Lewis M. DeBernard, Jr., Donald G. Mercer
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Patent number: 4175147Abstract: Physically blending small amounts of polycarbonate resin into polyethylene terephthalate resin which is to be extruded and cooled to form an unoriented amorphous sheet reduces deposits of terephthalic acid on the cooling rolls during sheet extrusion.Type: GrantFiled: October 5, 1976Date of Patent: November 20, 1979Assignee: Allied Chemical CorporationInventors: Philip S. Bollen, Alfieri Degrassi
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Patent number: 4171828Abstract: A dolly is provided for transporting and storing textile tubes. The dolly comprises a split shallow-walled platform mounted on a plurality of casters. The two halves of the platform are hinged so that they can be pivoted to an open or closed position. One half of the platform is mounted on at least two stationary casters to inhibit lateral movement of the dolly when in the open position.Type: GrantFiled: December 16, 1977Date of Patent: October 23, 1979Assignee: Allied Chemical CorporationInventors: Gerald F. Goodwin, John R. Letchworth, Richard A. Botset
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Patent number: 4171422Abstract: High molecular weight linear condensation polyesters are stabilized against deterioration by heat by reacting the polyester in molten form with certain polycarbonates in the presence of a catalytic amount of a phosphonium compound selected from the group consisting of tetra-n-alkylphosphonium acetates and tetra-n-alkylphosphonium halides. For the purpose of this disclosure, polycarbonates are defined as linear polyesters of carbonic acid in which the carbonate groups recur in the polymer chain. In continuous production of the improved polyesters, it is preferred that the polycarbonate and catalyst be added to the process stream with mixing at a point to give 2 to 15 minutes reaction time under superatmospheric pressure before the polyester enters the last polycondensation reactor.Type: GrantFiled: September 11, 1978Date of Patent: October 16, 1979Assignee: Allied Chemical CorporationInventors: Stanley D. Lazarus, Kalidas Chakravarti, Hugh H. Rowan, James G. Neal
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Patent number: 4164515Abstract: A computer controlled process for preparation of cyclohexanone by liquid phase, catalytic hydrogenation of phenol in three or more hydrogenation stages by using a computer control system interrelated with a phenol hydrogenation system in such a manner that it is capable of correlating a predetermined mole ratio of phenol to cyclohexanone with a predetermined maximum temperature in each of the hydrogenation stages, whereby intrinsic safety of operation is achieved by operating at temperatures at or below the atmospheric boiling point in each reactor.Type: GrantFiled: November 21, 1977Date of Patent: August 14, 1979Assignee: Allied Chemical CorporationInventors: Jan F. Van Peppen, William B. Fisher
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Patent number: 4162267Abstract: A controlled process for preparation of cyclohexanone by liquid phase, catalytic hydrogenation of phenol in two or more hydrogenation stages by correlating a predetermined mole ratio of phenol to cyclohexanone with a predetermined maximum temperature in each of the hydrogenation stages, whereby intrinsic safety of operation is achieved by operating at temperatures at or below the atmospheric boiling point in each reactor. The process provided improved control by use of a hydrogenation gas comprising hydrogen and nitrogen and recycling unreacted gas to the reaction zone to promote flashing overhead of product cyclohexanone. At least part of the recycling gas is treated by a cryogenic hydrogen recovery process to remove inerts from the system.Type: GrantFiled: June 22, 1978Date of Patent: July 24, 1979Assignee: Allied Chemical CorporationInventors: William B. Fisher, Jan F. Van Peppen
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Patent number: 4161391Abstract: Apparatus for melting solid particles of synthetic polymer is provided which features an enclosure in which at least one annular member and a heating unit are disposed. The heating unit zigzags in cross-section across the enclosure between the annular member and enclosure inlet. Jacket means substantially surrounds the enclosure at and downstream of a point corresponding to the heating unit. The annular member, heating unit, and jacket means are heated, preferably in series, to above the melt temperature of the solid synthetic polymer particles to provide melting surfaces for the polymer. The molten polymer is withdrawn through an outlet in the base of the enclosure.Type: GrantFiled: March 14, 1978Date of Patent: July 17, 1979Assignee: Allied Chemical CorporationInventor: Herbert W. Parker
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Patent number: 4152318Abstract: High molecular weight linear condensation polyesters are stabilized against deterioration by heat by reacting the polyester in molten form with an epoxy compound having 5 to 25 carbon atoms in the molecule and selected from the group consisting of ##STR1## where R represents the radical remaining after removal of the carboxyl group from a monocarboxylic acid, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen or hydrocarbon radicals, and n is an integer that can be 0 to 3.Type: GrantFiled: March 20, 1978Date of Patent: May 1, 1979Assignee: Allied Chemical CorporationInventors: Stanley D. Lazarus, Kalidas Chakravarti