Abstract: Liquid hydroxyurethane products having cyclocarbonate end groups are prepared by reacting a molar excess of a bis-carbonate of a bis-glycidyl ether of neopentyl glycol or 1,4-cyclohexanedimethanol with a polyoxyalkylenediamine such as a polyoxypropylenediamine. These products are useful for the preparation of polyurethanes, polyurethane polyols, polyester polyurethane polyols, and polycarbonate polyurethane polyols.
Type:
Grant
Filed:
July 19, 1993
Date of Patent:
August 23, 1994
Assignee:
Texaco Chemical Company
Inventors:
Wheeler C. Crawford, Edward T. Marquis, Howard P. Klein
Abstract: A process for the dissolution of cured polyester resins is disclosed. A cured polyester resin may be dissolved, or removed from a substrate, by contacting the polyester resin with an alkylene carbonate, alone or as a co-solvent with one or more other solvents in which the cured polyester resin is at least partially soluble.
Abstract: A method for the manufacture of alkylene carbonates is disclosed. Alkylene carbonates are prepared by reacting alkylene oxides and carbon dioxide in the presence of a metal phthalocyanine catalyst.
Abstract: A process is disclosed for preparing synthetic lubricant base stocks having a high dimer to trimer ratio from long-chain olefins. These synthetic lubricant base stocks are prepared in good yield by dimerizing linear olefins using a catalyst comprising a silica gel alkylsulfonic acid.
Type:
Grant
Filed:
July 27, 1992
Date of Patent:
January 4, 1994
Assignee:
Texaco Chemical Company
Inventors:
Sanderson John R., John F. Knifton, Edward T. Marquis
Abstract: An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using sulfate-activated molecular sieves as catalyst.
Type:
Grant
Filed:
December 9, 1991
Date of Patent:
September 7, 1993
Assignee:
Texaco Chemical Company
Inventors:
John R. Sanderson, John F. Knifton, Edward T. Marquis
Abstract: Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefin monomers using certain acidic calcium montmorillonite clay catalysts. When the oligomers are prepared at a temperature greater than about 200.degree. C., and any unreacted linear olefin monomer is removed, oligomers having an iodine value less than about 3 mg/g are obtained. An even lower iodine value is obtained when a hydrocarbon possessing a tertiary hydrogen is mixed with the linear olefin feed, and the mixture is contacted with the clay at a temperature greater than about 200.degree. C. Little or no hydrogenation may be required of oligomers prepared in this manner to obtain base stocks suitable for use as synthetic lubricants.
Type:
Grant
Filed:
May 24, 1991
Date of Patent:
August 3, 1993
Assignee:
Texaco Chemical Company
Inventors:
John R. Sanderson, John F. Knifton, Edward T. Marquis
Abstract: Synthetic lubricant base stocks having an increased viscosity are disclosed. These synthetic lubricant base stocks comprises a mixture of (1) oligomers prepared from a linear olefin having from 10 to 24 carbon atoms; and (2) alkylated anisole having an alkyl group containing from 10 to 24 carbon atoms. These synthetic lubricant base stocks may be prepared by co-reacting a linear olefin having from 10 to 24 carbon atoms and anisole. Optionally, the mixture of oligomers and alkylated anisoles may be hydrogenated, to prepare a mixture of reduced oligomers and alkylated methoxycyclohexanes.
Abstract: An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using a sulfate-activated Group IV oxide particularly zirconium dioxide, as the catalyst.
Type:
Grant
Filed:
November 4, 1991
Date of Patent:
March 2, 1993
Assignee:
Texaco Chemical Company
Inventors:
John R. Sanderson, John F. Knifton, John M. Larkin
Abstract: An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using montmorillonite clays which have a halogenated phosphorous- containing acid deposited thereon.
Abstract: An epoxy resin curative composition that provides cured epoxy resins exhibiting improved properties is disclosed. The curative composition comprises a mixture of 1-isopropyl-2-aryl imidazole and 1-isopropyl-2-aryl imidazoline.
Type:
Grant
Filed:
February 28, 1991
Date of Patent:
February 23, 1993
Assignee:
Texaco Chemical Company
Inventors:
Harold G. Waddill, Wei-Yang Su, George P. Speranza
Abstract: Vinyl monomers are polymerized in high yield to water-soluble polymers or copolymers by free radical polymerization of an aqueous reaction mixture containing the vinyl monomer(s), an UV-activated photoinitiator and a heat-activated chemical initiator. The polymerization is initially carried out by exposing the monomer mixture to UV radiation to activate the photoinitiator and then is carried out under the influence of free radicals produced by the chemical initiator.
Abstract: A process for the dissolution of polyurethane foams is disclosed. A polyurethane foam may be dissolved, or removed from a substrate, by contacting the polyurethane foam with 1,2-dialkyl imidazole, alone or as a co-solvent.
Type:
Grant
Filed:
April 1, 1991
Date of Patent:
February 2, 1993
Assignee:
Texaco Chemical Company
Inventors:
Edward T. Marquis, George P. Speranza, Wei-Yang Su
Abstract: A process for preparing synthetic lubricant base stocks having improved properties is disclosed. The process comprises co-reacting vinylcyclohexene and long-chain linear olefin in the presence of a Friedel-Crafts type catalyst, preferably anhydrous aluminum chloride.
Type:
Grant
Filed:
March 28, 1991
Date of Patent:
January 19, 1993
Assignee:
Texaco Chemical Company
Inventors:
John R. Sanderson, Wheeler C. Crawford, David R. McCoy
Abstract: A process is disclosed for preparing synthetic lubricant base stocks having improved properties. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefins using certain acidic montmorillonite clay catalysts. When a mixture of poly(isobutylene) and long-chain linear olefin, in which up to about 10 wt. % of the mixture is poly(isobutylene), is co-reacted in the presence of these catalysts, a synthetic lubricant base stock having a high viscosity and a high viscosity index is prepared.
Abstract: An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using certain acidic calcium montmorillonite clay catalysts which have aluminum nitrate deposited thereon.
Abstract: A co-solvent system for the dissolution of cured flexible polyurethane foams, cured rigid polyurethane foams, and cured polyester resins is disclosed. The co-solvent system comprises a mixture of an alkylene carbonate and tetramethyl urea.
Abstract: A method for the manufacture of alkylene carbonates is disclosed. Alkylene carbonates that are free of halogen contaminants are prepared by reacting alkylene oxides and carbon dioxide in the presence of a catalyst selected from the group consisting of cerous acetate, ceric ammonium nitrate, cerous nitrate hexahydrate, and ceric potassium nitrate.
Abstract: Synthetic lubricant base stocks having a low pour point are disclosed. These synthetic lubricant base stocks comprise a mixture of (1) oligomers prepared from a linear olefin having from 10 to 24 carbon atoms; and (2) alkylated decalin having an alkyl group containing from 10 to 24 carbon atoms. These synthetic lubricant base stocks may be prepared by hydrogenating the co-reaction products of a linear olefin having from 10 to 24 carbon atoms and naphthalene.
Abstract: A process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing long-chain olefins using certain acidic calcium montmorillonite clay catalysts. When long-chain vinylidene olefin and long-chain alpha- and/or internal-olefin are co-oligomerized, a synthetic lubricant base stock having a lower pour point is obtained.
Abstract: Synthetic lubricant base stocks having an increased viscosity are disclosed. These synthetic lubricant base stocks comprise a mixture of (1) oligomers prepared from a linear olefin having from 10 to 24 carbon atoms; and (2) alkylated cyclohexanol having an alkyl group containing from 10 to 24 carbon atoms. These synthetic lubricant base stocks may be prepared by hydrogenating the co-reaction products of a linear olefin having from 10 to 24 carbon atoms and phenol.