Patents Represented by Attorney William K. Wissing
  • Patent number: 5494602
    Abstract: The present invention is directed to methods of preparing hydrophobically-terminated polysaccharide polymers. The methods utilized to prepare the hydrophobically-terminated polysaccharide polymers utilize water as the reaction solvent and do not any cosolvent. The invention is also directed to hydrophobically-terminated polysaccharide polymers which are useful as deflocculants in liquid detergent compositions and to the liquid detergent compositions which contain the hydrophobically-terminated polysaccharide polymers.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: February 27, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: John S. Thomaides, James Burkert
  • Patent number: 5491182
    Abstract: The present invention is directed to sizing compositions for use on glass fibers which are used to reinforce lamination resins used in the formation of glass laminates. The sizing compositions contain a low molecular weight, polymer latex prepared by polymerizing at least one monomer(s) selected from the group consisting of acrylic acid, methacrylic acid, C.sub.1 -C.sub.18 alkyl esters of acrylic acid, C.sub.1 -C.sub.18 alkyl esters of methacrylic acid, glycidyl acrylate, glycidyl methacrylate, C.sub.1 -C.sub.4 hydroxyalkyl esters of acrylic acid, C.sub.1 -C.sub.4 hydroxyalkyl esters of methacrylic acid, vinyl esters of saturated aliphatic monocarboxylic acids containing up to 10 carbon atoms, (meth)acrylamide and their N-substituted derivatives, vinyl ethers, N-vinyl lactams, halogenated vinyl compounds, alkyl vinyl ketones, (meth)allyl ester of saturated aliphatic monocarboxylic acids, vinyl compounds such as vinyl pyrrole, olefins, diesters of itaconic, maleic and/or fumaric acid, and styrene.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: February 13, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Charles R. Key, Yen-Jer Shih
  • Patent number: 5489397
    Abstract: Liquid detergent compositions comprise hydrophobically-terminated, hydrophilic polymers as deflocculating agents, phase stabilizers, builders or co-builders and viscosity modifiers, in addition to detergent active material and electrolytes contained in an aqueous continuous phase.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: February 6, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Peter Bainbridge
  • Patent number: 5478881
    Abstract: Novel mono- and multi-functional non-ionic urethane monomers are prepared from surfactants comprising poly(ethylene oxide)(butylene oxide) copolymers, preferably C.sub.1 -C.sub.4 alkoxy-terminated, monohydric, ethylene oxide/butylene oxide block polymers and monoethylenically unsaturated aliphatic isocyanates. When polymerized with, e.g. acrylic acid or alkyl acrylates, these monomers provide copolymers exhibiting greatly enhanced thickening efficiency.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: December 26, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: John M. Wilkerson, III, Daniel W. Verstrat, Milagros C. Barron
  • Patent number: 5478553
    Abstract: The present invention relates to hair fixative compositions which utilize as the hair fixative resin a polymer which is prepared from N-vinyl formamide (NVF). The polymer may be a homopolymer of NVF or an interpolymer of NVF and at least one vinyl monomer(s). The polymer is present in amounts effective to provide the inventive hair fixative compositions with hair fixative properties. In preferred embodiments, the hair fixative composition is a stable, aqueous gel which forms a clear, non-tacky film upon drying. In certain embodiments, the gel has a rheology effective to allow the gel to be applied to the hair via a spray pump.
    Type: Grant
    Filed: August 5, 1994
    Date of Patent: December 26, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Rama S. Chandran, Jean-Pierre Leblanc, John C. Leighton, Gary T. Martino
  • Patent number: 5455298
    Abstract: The invention relates to an acrylic polymer latex comprising the polymerization product of an acetoacetate moiety of the structure ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and are selected from the group consisting of C.sub.1 -C.sub.22 alkyl groups and X is a halogen, in amounts effective to improve the water resistance of the acrylic latex; and at least one monomer(s) selected from the group consisting of C.sub.3 -C.sub.6 monocarboxylic acids, C.sub.4 -C.sub.6 dicarboxylic acids and their C.sub.1 -C.sub.4 half esters, C.sub.1 -C.sub.10 alkyl esters of acrylic acid, C.sub.1 C.sub.10 alkyl esters of methacrylic acid, styrene, halogenated styrene and substituted styrene and latex compositions containing the novel latexes.
    Type: Grant
    Filed: July 27, 1994
    Date of Patent: October 3, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Rajeev Farwaha, Lien Phan, William Currie
  • Patent number: 5442091
    Abstract: Novel mono- and multi-functional non-ionic urethane monomers are prepared from surfactants comprising poly(ethylene oxide)(butylene oxide) copolymers, preferably C.sub.1 -C.sub.4 alkoxy-terminated, monohydric, ethylene oxide/butylene oxide block polymers and monoethylenically unsaturated aliphatic isocyanates. When polymerized with, e.g. acrylic acid or alkyl acrylates, these monomers provide copolymers exhibiting greatly enhanced thickening efficiency.
    Type: Grant
    Filed: November 15, 1994
    Date of Patent: August 15, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: John M. Wilkerson, III, Daniel W. Verstrat, Milagros C. Barron
  • Patent number: 5442001
    Abstract: The use of C.sub.1 -C.sub.5 alkyl butyrates, d-limonene, ethylene glycol monobutyl ether and C.sub.5 -C.sub.20 petroleum distillates and normal paraffins in place of methyl chloroform (1,1,1-trichloroethane) in conventional waterborne packaging and converting adhesives provides comparable or better adhesive products with reduced environmental and health related problems.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: August 15, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: M. Erin Jones, Paul P. Puletti
  • Patent number: 5436307
    Abstract: An aqueous coating composition with excellent adhesion and waterproof properties is prepared by copolymerizing an alkoxysilane compound, a hydrophilic monomer, and a hydrophobic ethylenically unsaturated monomer at a specific ratio in an organic solvent, and then substituting the organic solvent with aqueous medium. The copolymerization reaction is stable, and the aqueous composition, which is a solution or dispersion, does not contain any substances to deteriorate the water resistance of the resulting film.
    Type: Grant
    Filed: June 21, 1993
    Date of Patent: July 25, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Akifumi Katsushima
  • Patent number: 5412142
    Abstract: Novel mono- and multi-functional non-ionic urethane monomers are prepared from surfactants comprising poly(ethylene oxide)(butylene oxide) copolymers, preferably C.sub.1 -C.sub.4 alkoxy-terminated, monohydric, ethylene oxide/butylene oxide block polymers and monoethylenically unsaturated aliphatic isocyanates. When polymerized with, e.g. acrylic acid or alkyl acrylates, these monomers provide copolymers exhibiting greatly enhanced thickening efficiency.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: May 2, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: John M. Wilkerson, III, Daniel W. Verstrat, Milagros C. Barron
  • Patent number: 5403884
    Abstract: A process for flocking cured or uncured elastomeric substrates comprising the steps of applying to the substrate an aqueous adhesive comprising 10 to 100% (dry weight) of an alkaline dispersion of an ethylene carboxylic acid copolymer and 0 to 90% of an aqueous elastomeric dispersion; electrostatically applying flocking fibers thereto; and drying the thus flocked substrate.
    Type: Grant
    Filed: January 13, 1993
    Date of Patent: April 4, 1995
    Assignee: National Starch And Chemical Investment Holding Corporation
    Inventor: Witold Perlinski
  • Patent number: 5399617
    Abstract: Copolymerizable amphoteric surfactants of the structural formula ##STR1## in which R.sub.1 =C.sub.1 -C.sub.2 alkyl, R.sub.2 =C.sub.1 -C.sub.2 alkyl, X.sup.- =SO.sub.3.sup.- or COO.sup.-, a=2-3, and b=1-6, are polymerized into copolymer latexes for use in paint formulations, in an amount of 1-3 parts per hundred parts by weight of monomers used to form the copolymer, to impart superior wet adhesion and freeze-thaw stability to the latex paints. The copolymer latexes contain no more than one part by weight carboxylic acid functionality per hundred part monomers. The monomers with which the amphoteric surfactants are copolymerized are selected from alkyl esters of acrylic and methacrylic acid, acrylic and methacrylic acid, styrene and mixtures thereof.
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: March 21, 1995
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Rajeev Farwaha, William Currie
  • Patent number: 5360847
    Abstract: A coating composition for concrete that is an effective water barrier and that is relatively easily removed comprises an acrylic copolymer or a styrene copolymer latex and a polysaccharide. The polysaccharide makes the coating composition susceptible to enzyme action and thus easily removable by flooding the surface of the coated concrete with a dilute solution of enzyme reactive with the polysaccharide.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: November 1, 1994
    Assignee: National Starch and Chemical Investment Holding Corp.
    Inventors: Dennis R. Dewacker, Leon Rosenberg, Nicholas J. Lacamera, Jr.
  • Patent number: 5286845
    Abstract: The present invention relates to the conversion of tall oil soap to produce crude tall oil. An aqueous tall oil soap solution generated in a kraft wood-pulping process is placed in contact with carbon dioxide, under pressure, to form crude tall oil and sodium bicarbonate brine. The crude tall oil and sodium bicarbonate brine are then allowed to separate, under pressure, into a crude tall oil layer and a sodium bicarbonate brine layer. The crude tall oil layer is then separated from the sodium bicarbonate brine layer, again under pressure. The separated crude tall oil may then be further refined to yield fatty acids, resin acids, and other constituents, which are useful in numerous industrial applications, such as in soaps, lubricants, inks, adhesives, and coatings.
    Type: Grant
    Filed: May 20, 1992
    Date of Patent: February 15, 1994
    Assignee: Union Camp Corporation
    Inventors: Derk T. A. Huibers, James W. Gillis, Andrew Robbins
  • Patent number: 5242545
    Abstract: Paper suitable for use in corrugated shipping containers is provided. Medium paper of this invention has a basis weight of at least about 15 pounds and a relatively high cross-direction crush resistance typically exceeding 2.4 pounds force per six inches width per unit base weight of the oven-dried product in lbs/1000 ft.sup.2. Linerboard of this invention has a correspondingly greater cross-direction crush resistance. The paper is preferably produced by applying starch solutions at high percent solids at elevated temperatures using a size press technique to provide at least about 30% of the starch in a defined inner zone of the paper sheet. The strength of the paper is improved through a carefully controlled distribution of the starch throughout the thickness of the paper.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: September 7, 1993
    Assignee: Union Camp Corporation
    Inventors: Keith E. Bradway, Richard F. Rudolph
  • Patent number: 5241122
    Abstract: Catalysts, catalyst precursors, and catalytic systems are provided. The catalysts generally comprise a substrate that includes a group IB metal and a porous, microcrystalline layer that includes the metal and that is disposed on at least a portion of the substrate. The catalysts are prepared by providing a substrate that includes group IB metal, oxidizing said substrate in the presence of stainless steel to produce an oxide coating of said group IB metal, and reducing substantially all of said oxidized substrate.
    Type: Grant
    Filed: March 3, 1992
    Date of Patent: August 31, 1993
    Assignee: Union Camp Corporation
    Inventors: James B. Woell, John W. Catino
  • Patent number: 5236996
    Abstract: Stable aqueous dispersions of finely divided piperazine-containing polyamide resin particles and methods for the manufacture thereof are provided. Dispersions according to this invention find use in hot melt adhesives, coatings, inks, and the like.
    Type: Grant
    Filed: July 24, 1991
    Date of Patent: August 17, 1993
    Assignee: Union Camp Corporation
    Inventor: George A. Smith
  • Patent number: 5217208
    Abstract: Methods and apparatus for maintaining a restraining device placed over a load in constant tension as the load shifts during transit are disclosed. The present invention provides a winch having two ratchets, the first of which provides the initial tension in the restraining device. The second ratchet is connected to a spring, which is connected to the shaft upon which the restraining device is wound. By operating the second ratchet, the spring is displaced and an urging force is created. Upon a reduction of the initial tension in the restraining device, the urging force acts upon the shaft, advancing the shaft and the first ratchet, thereby maintaining the tension in the restraining device. Since the first ratchet is advanced, any slack in the restraining device is accumulated and the strap is locked into a tighter position. Methods and apparatus providing a locking bar to prevent unauthorized use of the winch and theft of the restraining device are also disclosed.
    Type: Grant
    Filed: February 15, 1991
    Date of Patent: June 8, 1993
    Assignee: Union Camp Corporation
    Inventor: Everett H. Stephenson
  • Patent number: 5206217
    Abstract: The present invention relates to novel indane compounds, such as, for example, 5-formyl-1,1,2,3,3,4,6-heptamethylindane, a compound of the formula ##STR1## and to compositions including the same, as well as to methods for their preparation. Compounds and compositions of the invention possess a fragrant musk-like aroma and have utility in the perfumery and/or other industries.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: April 27, 1993
    Assignee: Union Camp Corporation
    Inventor: Walter C. Frank
  • Patent number: 5204322
    Abstract: The present invention relates to novel nitrile and aldoxime indane compounds, such as 1,1,2,3,3,4,6-heptamethylindane-5-nitrile and 1,1,2,3,3,4,6-heptamethylindane-5-aldoxime, and to compositions containing the same. Compounds and compositions of the invention possess a fragrant musk-like aroma, and thus are useful in the perfumery and/or other industries.
    Type: Grant
    Filed: December 31, 1991
    Date of Patent: April 20, 1993
    Assignee: Union Camp Corporation
    Inventor: Walter C. Frank