Abstract: A method of reacting carbon monoxide and hydrogen to form light hydrocarbons and alcohols in a slurry phase and in the presence of iron-containing active carbon catalyst is disclosed.
Type:
Grant
Filed:
August 22, 1984
Date of Patent:
April 23, 1985
Assignee:
Standard Oil Company (Indiana)
Inventors:
John F. Connolly, Arnold N. Wennerberg, Robert F. Waters
Abstract: A fluid bed system for retorting solid hydrocarbon-containing material, such as oil shale, coal and tar sands, in which solid hydrocarbon-containing material and heat carrier material are fed into a mixing chamber, mixed and rapidly transported upwardly by a lift gas through a lift pipe into a solids-containing vessel to retort the hydrocarbon-containing material with minimal thermal cracking of the liberated hydrocarbons to increase the recovery of condensable hydrocarbons. The retorted material can be conveyed to a dilute phase lift pipe and combustor vessel where carbon residue in the retorted material is combusted leaving hot spent material that can be fed into the mixing chamber as solid heat carrier material.
Abstract: This invention relates to carbamates of beta-hydroxyethylsulfoxides which are useful as cosurfactants in enhanced oil recovery, surfactants and biocides, and as hydraulic fluids when of sufficiently low molecular weight.
Abstract: A process for the manufacture of a phosphorus-vanadium oxide and a phosphorus-vanadium-co-metal catalyst suitable for the oxidation of butane to maleic anhydride is disclosed. The catalyst is prepared by reacting, in an aqueous medium, a vanadium compound, inorganic acid and, if used, a metal oxide. Ortho-phosphoric acid is then added to form a soluble vanadium-phosphorus or a vanadium-phosphorus-metal catalyst. The acidified water is removed and aliphatic alcohols and either aromatic acids or aromatic anhydrides, or a mixture of these, are added and the alcohols are removed. The solid phosphorus-vanadium, or phosphorus-vanadium-metal oxide is recovered under vacuum.
Abstract: Novel polyimides and molding compositions are prepared from novel tricyclo[4.2.1.0.sup.2,5 ] nonane-3,4-dimethyl-3,4,7,8-tetracarboxylic acid dianhydride. The dianhydride is useful for the manufacture of polyimides which are useful as engineering plastics.
Abstract: Novel polyimides, copolyimides and molding compositions are prepared from novel dianhydrides such as bicyclo[4.2.0]octane-2,5 diphenyl-7,8-dimethyl,3,4,7,8-tetracarboxylic dianhydride and bicyclo[4.2.0] octane-7,8-dimethyl-3,4,7,8-tetracarboxylic acid dianhydride. The novel polyimides are useful as engineering plastics. The novel dianhydrides are useful for the preparation of the polyimides.
Abstract: A catalyst composition comprising a cadmium component and a support comprising at least one of a crystalline borosilicate and a pillared smectite or vermiculite clay is disclosed.
Abstract: 3-Sulfoxy-1,2-propylene glycols-1-esters of tricyclo 4.2.2.0.sup.2,5) dec-9-ene-3,4,7,8-tetracarboxylic acid are prepared. These compounds are useful as surfactants, biocides and as cosurfactants in enhanced oil recovery.
Abstract: A sealing member capable of elastic deformations provides a seal from the atmosphere between the mouth of a fillpipe and a liquid dispensing nozzle having vapor recovery conduit means internal to the receptive fillpipe, typically for use with gasoline.
Abstract: A process to convert a substantially linear alkene, such as n-butene, to isomerized products comprises contacting such alkene under conversion conditions comprising a temperature of above 300.degree. C. to about 650.degree. C. and an alkene reactant partial pressure of less than about 0.4 atmospheres with an AMS-1B borosilicate catalyst composition containing at least 50 wt. % hydrogen from AMS-1B incorporated in an inert binder.
Abstract: Novel copolyoxadiazole-imides are disclosed. These copolyoxadiazole-imides are useful for the manufacture of fibers, films, felts, coatings and molded objects.
Abstract: Co-polyoxadiazoles prepared from 5-t-butylisophthalic acid and common organic diacids are disclosed. They are useful as fibers, films, coatings, felts, laminates and molded objects.
Abstract: Molybdenum compositions suitable for improving the properties of lubricants and fuels comprise the reaction product of molybdenum and a polyamine Mannich reaction product, a polyamine hydrocarbyl-substituted dicarboxylic acid compound reaction product, and the oxidized and/or sulfurized reaction products thereof.
Abstract: A process for the removal of para-toluic acid from purified terephthalic acid is disclosed. This process comprises extracting the para-toluic acid with paraxylene from the aqueous terephthalic acid-water phase and recycling the para-toluic acid and paraxylene to the paraxylene oxidation reactor. The process improves the overall yield of purified terephthalic acid recovered. Purified terephthalic acid is used as a basic raw material in the manufacture of polyester fibers and films.
Type:
Grant
Filed:
September 15, 1983
Date of Patent:
February 19, 1985
Assignee:
Standard Oil Company (Indiana)
Inventors:
Bruce C. Petty-Weeks, Martin A. Zeitlin
Abstract: A process to convert a normal butene to isomerized products comprises contacting such alkene under conversion conditions with a hydrogen form AMS-1B borosilicate catalyst composition at a conversion temperature below 250.degree. C.
Abstract: A process to convert an alkene to oligomerized, aromatized and isomerized products comprises contacting such alkene under conversion conditions with an AMS-1B borosilicate catalyst composition.
Abstract: An absorbent for sulfur oxides comprising an inorganic oxide composition in association with at least one free or combined rare earth metal selected from the group consisting of lanthanum, cerium, praseodymium, samarium and dysprosium, wherein said inorganic oxide composition is selected from the group consisting of MgAl.sub.2 O.sub.4, mixtures of alumina with magnesium oxide and mixtures of magnesium oxide with MgAl.sub.2 O.sub.4. The absorbent can be circulated through a fluidized catalytic cracking process together with hydrocarbon cracking catalyst to reduce sulfur oxide emissions from the regeneration zone.
Type:
Grant
Filed:
September 27, 1983
Date of Patent:
February 5, 1985
Assignee:
Standard Oil Company (Indiana)
Inventors:
Ralph J. Bertolacini, Eugene H. Hirschberg, Frank S. Modica
Abstract: A method for producing branched aliphatic hydrocarbons by reacting H.sub.2 with a C.sub.1 -C.sub.6 alcohol and/or a C.sub.2 -C.sub.6 olefin in the presence of a cadmium component and a support which comprises an amorphous refractory inorganic oxide, a pillared smectite or vermiculite clay, a molecular sieve consisting essentially of unexchanged or cation-exchanged chabazite, clinoptilite, zeolite A, zeolite L, zeolite X, zeolite Y, ultrastable zeolite Y, or crystalline borosilicate molecular sieve, or a combination thereof.
Abstract: Diesters of phosphorodithioic acid are stabilized against thermal decomposition by the addition of small amounts of a stabilizer which is selected from the group consisting of ammonia, ammonium carbonate, ammonium salts of carboxylic acids, the oxides, hydroxides and carbonates of lithium, sodium, potassium, rubidium, cesium, berylium, magnesium, calcium, strontium and barium, and mixtures thereof.
Abstract: An oil shale process is provided to retort oil shale and purify oil shale retort water. In the process, raw oil shale is retorted in an in situ underground retort or in an above ground retort to liberate shale oil, light hydrocarbon gases and oil shale retort water. The retort water is separated from the shale oil and gases in a sump or in a fractionator or quench tower followed by an API oil/water separator. After the retort water is separated from the shale oil, the retort water is steam stripped, carbon adsorbed and biologically treated, preferably by granular carbon adsorbers followed by activated sludge treatment or by activated sludge containing powdered activated carbon. The retort water can be granularly filtered before being steam stripped. The purified retort water can be used in various other oil shale processes, such as dedusting, scrubbing, spent shale moisturing, backfilling, in situ feed gas injection and pulsed combustion.
Type:
Grant
Filed:
April 16, 1982
Date of Patent:
January 22, 1985
Assignees:
Standard Oil Company (Indiana), Gulf Oil Corporation