Patents Assigned to Basell Poliolefine Italia S.p.A.
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Patent number: 6723865Abstract: Aromatic silane compounds containing at least an aromatic ring bound directly to the silicon atom, wherein the aromatic ring has at least one substituent located in the ortho position selected from C1-10 hydrocarbon groups, are useful as electron donors in olefin polymerization catalysts for the production of polyolefins having a stereoblock content of from about 7 to about 25%.Type: GrantFiled: April 4, 2002Date of Patent: April 20, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Eric J. Evain, Constantine A. Stewart
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Patent number: 6723792Abstract: A dispersion of one or more additives to be used in the processing of olefin polymers or copolymers, said dispersion comprising nonextruded particles of olefin polymers containing at least two immiscible polyolefinic phases and having internal voids partially or totally filled by the said additive or additives.Type: GrantFiled: May 9, 2002Date of Patent: April 20, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventor: Ugo Zucchelli
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Patent number: 6716939Abstract: The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from substituted succinates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.Type: GrantFiled: October 1, 2001Date of Patent: April 6, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Giampiero Morini, Giulio Balbontin, Peter A. A. Klusener
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Patent number: 6699814Abstract: The present invention relates to catalysts particularly suitable for the sterospecific polymermerization of olefins, comprising Ti, Mg, halogen and an electron donor compound selected from heteroatoms containing esters of malonic acids. Polymers produced by the catalysts have high isotactic index expressed in terms of high xylene insolubility.Type: GrantFiled: June 6, 2003Date of Patent: March 2, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Giampiero Morini, Giulio Balbontin, Yuri V. Gulevich
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Patent number: 6696520Abstract: An elastomeric thermoplastic polyolefin composition comprising (i) an heterophasic olefin polymer composition comprising a crystalline propylene homopolymer of copolymer fraction and an elastomeric ethylene copolymer fraction and (ii) an elastomeric polymer having a hardness equal to or less than 90 points selected from the group consisting of copolymers of ethylene, ethylene-methyl acrylate copolyers, saturated or unsaturated styrene block copolymers and unsaturated norbornene polymers.Type: GrantFiled: October 14, 1998Date of Patent: February 24, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Giampaolo Pellegatti, Vittorio Braga, Roberto Bonari
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Patent number: 6689850Abstract: The present invention relates to a process for the polymerization of olefins using catalyst components and catalysts obtained therefrom comprising Ti, Mg, halogen and an electron donor compound selected from heteroatoms containing esters of malonic acids. The catalysts are particularly suitable for the sterospecific polymermerization of olefins having high isotactic index expressed in terms of high xylene insolubility.Type: GrantFiled: June 6, 2003Date of Patent: February 10, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Giampiero Morini, Giulio Balbontin, Yuri V. Gulevich
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Patent number: 6689845Abstract: A process for the gas-phase catalytic polymerisation carried out in two interconnected polymerisation zones, to which one or more monomers are fed in the presence of a catalyst under polymerisation conditions and from which the produced polymer is discharged. The growing polymer particles flow through a first poly-merisation zone under fast fluidisation conditions, leave said first zone and enter a second polymerisation zone through which they flow in a densified form under the action of gravity, leave said second zone and are reintroduced into the first polymerisation zone, thus establishing a circulation of polymer between the two polymerisation zones. The present invention is characterised in that a gas of composition different from that present in the first polymerisation zone is introduced into the second polymerisation zone and it is avoided that the gases present in the first polymerisation zone are introduced into the second polymerisation zone.Type: GrantFiled: March 2, 2000Date of Patent: February 10, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Gabriele Govoni, Massimo Covezzi
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Patent number: 6677395Abstract: Irradiated, oxidized olefin polymer dispersing aids for use in the manufacture of additive concentrates and additive-containing olefin polymer compositions.Type: GrantFiled: November 27, 2002Date of Patent: January 13, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Vu A. Dang, Richard J. Fezza, Daniel E. Schneckenburger, Cheng Q. Song
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Patent number: 6677403Abstract: A propylene resin composition which is improved in performance of properties, which has a uniform structure, which is high in mechanical strengths and which is excellent in heat resistance, rigidity, impact resistance, moldability and the like, containing a propylene resin and an elastic material, which composition is provided by a specific morphology that the separated micro phase structure of a specific elastic material present in a propylene resin composition as measured by an acoustic microscope has a percolation structure.Type: GrantFiled: August 13, 2001Date of Patent: January 13, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventor: Kazuto Abe
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Patent number: 6673855Abstract: The invention concerns polyolefin compositions with high flame resistance. The compositions comprise (percent by weight): A) from 20 to 60% by weight of a heterophasic olefin polymer composition comprising a crystalline olefin polymer (a) and an elastomeric olefin polymer (b), said composition (A) being optionally modified with at least one functional monomer in an amount from 0.005% to 0.6% by weight with respect to the total weight of the total composition; B) from 15 to 40% by weight of one or more than one inorganic hydrated fillers; C) from 12 to 40% by weight of one or more than one organic flame retardants containing nitrogen in the molecule; D) from 0 to 40% by weight of one or more than one inorganic anhydrous fillers. Possible applications include the use as insulating material in electric wires and cables and the use as waterproofing sheets for roofs and tunnels.Type: GrantFiled: August 14, 2001Date of Patent: January 6, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Vittorio Braga, Paolo Goberti, Ugo Zucchelli, Roberta Marchini
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Patent number: 6673869Abstract: An elastomeric thermoplastic polyolefin composition comprising (I) a crystalline propylene polymer containing at least 80% by weight of a fraction insoluble in xylene at room temperature, the intrinsic viscosity being higher than 0.5 dL/g; (II) an atactic or amorphous propylene polymer having an intrinsic viscosity higher than 0.5 dL/g; and (III) an elastomeric olefin polymer comprising copolymers of ethylene with a comonomer selected from C3-C8 &agr;-olefins, the intrinsic viscosity ranging from 1 to 4 dL/g. In said polyolefin composition the density of the elastomeric olefin polymer (deOP) satisfies the following relationship: deOP±0.005={dcPP×[wcPP/(wcPP+waPP)]}+{daPP×[waPP/(wcPP+waPP)]} (1) wherein wcPP and waPP are the weight percentage content of components (I) and (II) respectively and dcPP and daPP are the density at room temperature of components (I) and (II) respectively.Type: GrantFiled: July 25, 2001Date of Patent: January 6, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Rosanna Silvestri, Jean News
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Patent number: 6667367Abstract: A directly paintable polyolefin composition contains (1) a graft copolymer, composition containing (a) a graft copolymer having a backbone of propylene polymer material having graft polymerized thereto at least one vinyl monomer capable of being polymerized by free radicals, (b) a rubber component, and, optionally, (c) a broad molecular weight distribution propylene polymer material, (2) an oxidized polyethylene wax, (3) a propylene-homopolymer or copolymer grafted with an anhydride of an aliphatic &agr;,&bgr;-unsaturated dicarboxylic acid, (4) a functionalized polymer that is reactive with the anhydride groups of the grafted polymers, (5) optionally, a polyolefin rubber grafted with an anhydride of an aliphatic &agr;,&bgr;-unsaturated dicarboxylic acid, and (6) optionally, an ethylene polymer grafted with an anhydride of an aliphatic &agr;,&bgr;-unsaturated dicarboxylic acid.Type: GrantFiled: October 10, 2000Date of Patent: December 23, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventor: Dominic A. Berta
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Patent number: 6657033Abstract: The present invention relates to thermal bondable fibers comprising a random polymer of propylene with one or more olefins comonomers different from ethylene, to the process for preparing said fibers, and to the thermally bonded articles obtained from said fibers. Fibers of certain thermoplastic materials are used widely in the manufacturing of thermally bonded products.Type: GrantFiled: February 20, 2001Date of Patent: December 2, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventors: Franco Sartori, Giancarlo Braca
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Patent number: 6624099Abstract: A multi-layer sheet made from olefin polymer materials includes (1) at least one outer layer of (a) a propylene polymer, (b) graft copolymer comprising a backbone of a propylene polymer material, to which is graft polymerized a vinyl monomer, either (a) or (b) optionally containing a nucleating agent, or (c) an olefin polymer composition, and (2) at least one layer made from alternating layers of a propylene polymer material and glass fiber mat.Type: GrantFiled: December 17, 1999Date of Patent: September 23, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventor: Bakhtiar Alam Shah
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Patent number: 6605562Abstract: The present invention relates to catalyst components for the polymerization of olefins, and to the catalyst obtained therefrom, particularly suitable for the stereospecific polymerization of olefins, comprising Ti, Mg, halogen and an electron donor compound selected from heteroatom containing esters of malonic acids (heteroatom containing malonates). Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.Type: GrantFiled: June 28, 2000Date of Patent: August 12, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventors: Giampiero Morini, Giulio Balbontin, Yuri V. Gulevich
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Patent number: 6599986Abstract: Propylene polymer compositions comprising (percent by weight): A) from 70 to 90% of a random copolymer of propylene with ethylene, containing from 1 to 6% of ethylene, having a content of fraction insoluble in xylene at room temperature (about 23° C.) of not less than 93%; B) from 10% to 30% of a copolymer of propylene with ethylene, containing from 8 to 18% of ethylene; wherein the ratio (B)/C2B of the percent by weight of (B), with respect to the total weight of (A) and (B), to the percent by weight of ethylene in (B), with respect to the total weight of (B), represented in the above formula by C2B, is 2.5 or lower.Type: GrantFiled: January 18, 2002Date of Patent: July 29, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventors: Anteo Pelliconi, Päivi Helena Huovinen, Maria Di Diego
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Patent number: 6586531Abstract: A masterbatch composition, a polyolefin composition prepared from the masterbatch and articles prepared from the polyolefin composition. The masterbatch contains (percent by weight) from 20% to 90% of A) a crystalline polypropylene containing from 25% to 75% of a fraction AI having a melt flow rate MFRI of from 0.5 to 10 g/10 min., and from 75% to 25% of a fraction AII having a melt flow rate MFRII such that MFRII/MFRI is from 30 to 2000; and from 10% to 80% of B) a copolymer of ethylene and at least one C3-C10 &agr;-olefin, the copolymer containing from 10 to 70% of ethylene, the copolymer being soluble in xylene at room temperature, and having an intrinsic viscosity [&eegr;] of from 4 to 9 dl/g. Articles prepared from the polyolefin composition exhibit a good balance of physical properties and reduced surface defects such as tiger striping.Type: GrantFiled: September 27, 2001Date of Patent: July 1, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventors: Junichiro Washiyama, Kazuhiko Minowa, Hiroshi Takenouchi, Takeshi Nakajima, Masamitsu Yamauchi, Yutaka Yokoyama, Anteo Pelliconi
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Patent number: 6569945Abstract: A polyolefin composition which contains 45 to 5 weight percent of a low viscosity propylene homopolymer having an as polymerized melt flow rate of 250 to 550 g/10 minutes and 55 to 95 weight percent of an olefin polymer composition, preferably a random copolymer of propylene and ethylene and/or a C4-10 alpha-olefin or mixtures thereof, containing from 90 to 99 weight percent propylene. The composition may be formed into fibers having a diameter of from 15 to 23 microns. The fibers may be used to produce nonwoven fabrics.Type: GrantFiled: August 23, 2002Date of Patent: May 27, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventors: Daniele C. Bugada, Michael E. Starsinic
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Patent number: 6548705Abstract: Disclosed is a compound comprising a saturated oligomer of isoprene bonded to a polar group, said compound having formula (I): in which R is H or a C1-C4 alkyl, n is 2-17, and R′ is a radical selected from the group consisting of X, COOR″, CN, NR2, and NR2.HX, wherein R″ is selected from the group consisting of R, NR2, and NR2.HX or a monovalent metal cation, X being I, Cl, Br or F, and each R in NR2 and NR2.HX being the same or different. In a preferred embodiment the polar group is a quaternary ammonium radical. The compound is useful as a compatibilizer of solid inorganic material, and propylene and ethylene polymer material.Type: GrantFiled: June 16, 2000Date of Patent: April 15, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventors: C. Edward Bishop, Suhas G. Niyogi
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Patent number: 6544920Abstract: Solid catalyst component for the polymerization of olefins, includes the product of the direct reaction, with no subsequent reactions with reducing organometallic compounds, between a titanium compound and a support obtained by contacting a metal oxide containing hydroxyl groups with a solution containing A) a magnesium chloride; B) from 1 to 6 moles of an alcohol per mole of magnesium chloride, in a halogenated hydrocarbon or aromatic hydrocarbon organic solvent C) capable of bringing the magnesium chloride in solution in quantities greater than or equal to 5 grams per liter in the presence of the above-mentioned quantities of alcohol B), the solvent not being able to form adducts with the magnesium chloride.Type: GrantFiled: November 3, 1997Date of Patent: April 8, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventors: Gianni Pennini, Arrigo Arletti, Giampiero Morini