Abstract: A chemical sensor (11) including a light source (12) for producing a light flux bundle (16), an optical detector (14) for receiving a transmitted light flux bundle (24), and an absorber/expander sensor element (18) supported by a holder or support (20). Absorber/expander sensor element (18) is positioned in the space between light source (12) and optical detector (14). The absorber/expander material of sensor element (18) changes its size by either expanding or contracting in the presence of a particular chemical component. An edge (22) of sensor element (18) acts like a shutter and moves in and out of the path of travel of light flux (16), as the sensor element changes in size, which affects the intensity of light reaching and detected by optical detector (14).

Abstract: A method and apparatus for detecting the presence of hydrocarbon analyte in at least one of a liquid and vapor state. The apparatus (21) includes an optical fiber (22), an absorber-expander (31) mechanically coupled (32) to the optical fiber (22) to produce a change in transmission of light along the fiber (22) upon absorption of the hydrocarbon (33). The absorber-expander (31) is selected to absorb hydrocarbons, but not water, and to be capable of multiple reversible expansion and contraction cycles without significant structural degradation. Methyl terminated, silica and iron oxide filled, dimethyl polysiloxane provides a material which will experience substantial swelling in the presence of a hydrocarbon and yet is substantially reversible on desorption of the hydrocarbon from the absorber-expander (31).