Patents Assigned to Cassella AG.
  • Patent number: 5230711
    Abstract: Water-soluble sulphur dyes can be applied to cellulose without reducing agents, without added salt and without oxidising agents if the cellulose has been grafted with a polymer obtained by polymerisation of at least one N-containing basic monomer.
    Type: Grant
    Filed: April 1, 1992
    Date of Patent: July 27, 1993
    Assignee: Cassella AG
    Inventors: Karl-Heinz Keil, Thomas Martini
  • Patent number: 5169404
    Abstract: Use of water-insoluble monoazo dyestuffs of the formula I ##STR1## wherein R.sup.1 denotes alkyl having 1 to 6 C atoms, cyclopentyl, cyclohexyl, fluorine, chlorine, bromine, alkoxy having 1 to 4 C atoms or trifluoromethyl,R.sup.2 denotes alkyl having 1 to 7 C atoms andR.sup.3 and R.sup.4 independently of one another denote alkyl having 1 to 4 C atoms,for the sublimation transfer process.
    Type: Grant
    Filed: February 21, 1991
    Date of Patent: December 8, 1992
    Assignee: Cassella AG
    Inventors: Ulrich Buhler, Erika Kunz, Josef Ritter
  • Patent number: 5041496
    Abstract: The present invention relates to hydrophilic, swellable graft copolymers composed, in random distribution, of 0.5 to 20% by weight of radicals of the general formula I ##STR1## of 79 to 99% by weight of radicals containing an acidic group, of the general formula II ##STR2## and of 0.1 to 2% by weight of radicals of a crosslinking agent which are derived from monomers having at least two olefinically unsaturated double bonds, and the radicals X, Z, m, n, z and also R.sup.1 to R.sup.4 are defined as given in the description, a process for the preparation of these graft copolymers and also their use as absorbents for water and aqueous solutions.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: August 20, 1991
    Assignee: Cassella AG
    Inventors: Friedrich Engelhardt, Ulrich Riegel, Jurgen Kuhlwein
  • Patent number: 5037962
    Abstract: The .beta.-modification, which is stable under dyeing conditions, of the dyestuff of the formula ##STR1## is prepared by heating the .alpha.-modification, which is unstable under dyeing conditions, at temperatures of 60.degree. to 180.degree. C. and the .beta.-modification is useful in printing and dyeing fiber materials of cellulose esters, synthetic linear polyesters or mixed fabrics of the polyester fiber material with wool or viscose staple.
    Type: Grant
    Filed: August 21, 1989
    Date of Patent: August 6, 1991
    Assignee: Cassella AG
    Inventors: Hubert Kruse, Ulrich Buhler, Konrad Opitz, Willi Steckelberg
  • Patent number: 5011892
    Abstract: The present invention relates to hydrophilic, swellable graft copolymers composed, in random distribution, of 0.5 to 20% by weight of radicals of the general formula I ##STR1## 79 to 99% by weight of radicals containing an acidic group, of the general formula II ##STR2## and 0.1 to 2% by weight of crosslinking structures which are derived from monomers having at least two olefinically unsaturated double bonds, where the radicals X, Y, R.sup.1 to R.sup.4 and n have the meanings given in claim 1, and which are used as absorbents for water and aqueous solutions.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: April 30, 1991
    Assignee: Cassella AG
    Inventors: Friedrich Engelhardt, Ulrich Riegel
  • Patent number: 4918221
    Abstract: A valuable starting material for the manufacture of tetrachlorothioindigo pigments is 2,5-dichlorophenylthioglycollic acid which is prepared by:(a) diazotizing 2,5-dichloroaniline with aqueous alkali metal nitrite at acidic pH to produce 2,5-dichlorophenyl-diazonium salt,(b) reacting the 2,5-dichlorophenyl-diazonium salt from (a) with thiourea in an aqueous medium at acidic pH in the presence of a catalyst to produce 2,5-dichlorophenyl-isothiuronium salt of the formula ##STR1## wherein X.sup..crclbar. is an anion of a mineral acid, (c) hydroloyzing the 2,5-dichlorophenylisothiuronium salt from (b), without intermediate isolation, at alkaline pH to produce 2,5-dichlorothiophenol and(d) condensing the 2,5-dichlorothiophenol with monochloroacetic acid to produce 2,5-dichlorophenylthioglycollic acid.
    Type: Grant
    Filed: April 27, 1988
    Date of Patent: April 17, 1990
    Assignee: Cassella AG
    Inventors: Wolfgang Bauer, Willi Steckelberg
  • Patent number: 4305939
    Abstract: Physiologically-acceptable 3-aminosydnonimines of the formula ##STR1## and their pharmacologically-acceptable acid-addition salts, when formulated into medicament dosage forms, are useful for reducing systemic blood pressure, pulmonary artery pressure and left ventricular end diastolic pressure when orally administered to patients in need of such pressure reduction. These compounds are prepared by cyclizing a compound which, in its free-base state, is of the formula ##STR2## to a corresponding product which, in its free-base state, is of the formula ##STR3## and, when R.sup.2 is other than --H, acylating that product.
    Type: Grant
    Filed: July 8, 1980
    Date of Patent: December 15, 1981
    Assignee: Cassella AG
    Inventors: Karl Schonafinger, Rudi Beyerle, Rolf-Eberhard Nitz, Piero A. Martorana, Volker Fiedler
  • Patent number: 4304569
    Abstract: The formulation for brightening synthetic fibers or mixtures of synthetic fibers and natural fibers, which is an aqueous dispersion comprising at least one finely divided optical brightener and a dispersing agent, wherein the improvement comprises the dispersing agent being a water-soluble or water-dispersible polyester containing at least one phosphonic acid ester moiety.
    Type: Grant
    Filed: November 26, 1980
    Date of Patent: December 8, 1981
    Assignee: Cassella AG.
    Inventors: Friedrich Engelhardt, Karl Hintermeier, Herbert Friedrich, Thomas Martini