Abstract: The present invention provides novel substituted pyrazines or pyrazine derivatives ("NPD") which are functional and have useful application as a monomer for a variety of high performance polymers such as polyester, polyarylate, polycarbonate, polyetherketones, epoxides, polyimides, polyamides, and polyamides-imides. These NPD have the general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are defined herein.
Type:
Grant
Filed:
February 4, 1994
Date of Patent:
October 17, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
George Kvakovszky, Richard Vicari, Ahamed M. Tafesh, Kathleen N. Juneau, Olan S. Fruchey, Joseph A. McDonough, Debasish Kuila
Abstract: A tent fabric constructed substantially of woven polyethylenenaphthalatebibenzoate (PENBB) yarns. The PENBB yarns of the fabric exhibit very low tenacity loss resulting from UV degradation, and exhibit very good dimensional stability, very low hot air shrinkage and very low creep. A flame retardant polymer may be added to the PENBB polymer before extrusion to provide flame resistance.
Type:
Grant
Filed:
October 12, 1993
Date of Patent:
October 17, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
Lie Shi, Dee A. Ling, Michelle C. Carter
Abstract: Arylketoamines are prepared by reacting arylisonitrosoalkanones with hydrogen in the presence of a transition metal catalyst and a liquid carboxylic acid at a temperature of less than about 60.degree. C.
Type:
Grant
Filed:
August 23, 1994
Date of Patent:
October 10, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
Ahmed M. Tafesh, George Kvakovszky, Charlet R. Lindley
Abstract: A purification process for cyclic formals, in which water is efficiently removed from a mixture of a cyclic formal and water which is difficult to be separated from the mixture, thereby obtaining a cyclic formal of high purity which contains only an extremely small amount of water.The purification process for cyclic formals is characterized by the steps of supplying a mixture of a cyclic formal and water into a distillation tower, effecting distillation while supplying n-pentane into the distillation tower and taking out a purified cyclic formal as a bottom liquid.
Abstract: The invention is a dye composition containing two or more dyes of the vinyl sulfone type which can be used in combination to dye polyamide substrates. Preferably the dye compositions of the invention contain at least three dyes of different primary colors.
Type:
Grant
Filed:
May 24, 1994
Date of Patent:
October 10, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
Walter Heimling, Mark Helle, Kerry Proulx, Leslie McIntosh, Philomen DeCroos
Abstract: A needlepunch fabric of staple polyester fibers is disclosed that is elastomeric and has foam-like compressibility and resilience. The polyester staple is formed of fibers having a differential birefringence. Mechanically crimped fibers are carded, crosslapped, and needlepunched to from about 150 to 1500 ppsi, and the resultant fabric is heated to from about 120.degree. to 240.degree. C. to induce a latent crimp in the fabric and to develop the elastomeric and foam-like properties of the fabric.
Abstract: Super-absorbent polymers having superior dryness properties when incorporated into absorbent articles are made from acrylic acid and crosslinking agent polymerized under controlled conditions.
Type:
Grant
Filed:
June 9, 1993
Date of Patent:
September 26, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
Douglas R. Chambers, Hubert H. Fowler, Jr., Yoji Fujiura, Fusayoshi Masuda
Abstract: The present invention provides a unique and novel way of producing polyhydroxystyrene which comprises the steps of (a) heating 4-hydroxyacetophenone under suitable hydrogenation conditions of temperature and pressure in the presence of a suitable palladium catalyst and for a sufficient period of time to form 4-hydroxyphenylmethylcarbinol; (b) heating 4-hydroxyphenylmethylcarbinol under suitable conditions of temperature and pressure and for a sufficient period of time to form said polyhydroxystyrene.
Type:
Grant
Filed:
March 1, 1995
Date of Patent:
September 26, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
James R. Sounik, Graham N. Mott, Charles B. Hilton
Abstract: The present invention provides a unique and novel way of producing vinyl phenols such as poly(4-hydroxystyrene) (PHS). In this new process, 4-hydroxyphenylmethylcarbinol (HPMC) is heated under suitable conditions of temperature and pressure and for a sufficient period of time to form the poly (4-hydroxystyrene) (PHS).
Type:
Grant
Filed:
March 17, 1995
Date of Patent:
September 26, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
James R. Sounik, Graham N. Mott, Charles B. Hilton
Abstract: Modules for use in fluid separations, especially contained liquid membrane separations, exhibit minimal effective membrane thickness. The modules have a module case and at least one pair of superposed fabric sheets disposed within the case, the fabric sheets being pleated and nested in the lengthwise direction of the case. Each fabric sheet contains warp-wise extending hollow fiber membranes. The hollow fiber membranes within the folds of one fabric sheet will therefore form alternating rows with the hollow fiber membranes within the folds of the other fabric sheet by virtue of the length-wise nested pleating. As a result, the effective membrane thickness value of the module is minimized thereby enhancing the efficacy of fluid separations.
Abstract: A blend of cellulose acetate and starch acetate used to make fibers, filaments, yarns, fabrics, plastic materials and other uses is disclosed. Additionally, the invention relates to the process of making said blend; cigarette filters made from tow composed of said blend; cigarettes made with filters made from tow of said blend as well as acetate flake and other compositions containing said blend.
Type:
Grant
Filed:
January 5, 1995
Date of Patent:
August 29, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
Joanne C. Maheras, John B. Hopkins, Jr., Heribert Tatzlaff
Abstract: A heterofilament of a PBT sheath, a multifilament composite yarn composed of a plurality of heterofilaments having PBT sheath, and a conductive bundle containing a wire wrapped with a plurality of the multifilament composite yarn.
Abstract: This invention provides novel ethylenically unsaturated urethane monomers and photoreactive compositions comprising such monomers as essential constituents. The monomers can be photopolymerized or photocrosslinked and are useful in coating systems and multilayer color proofing systems. Additionally, they offer superior advantages such as significantly reduced migration between layers in multilayer color proofing systems.
Abstract: Provided herein is a brushgraining process to improve the quality of lithographic printing plate substrate surfaces. In the process, the surface is brushed in an aqueous slurry comprising a mixture of particulates of alumina and quartz in a weight ratio range 95:5 to 5:95, with the particulates being in the size range of 1-20 microns. Such a process surprisingly lessens the number of scratches produced on the substrate surface than when compared to using alumina alone or quartz alone or a mixture of alumina and quartz with particle sizes higher than the range disclosed.
Type:
Grant
Filed:
September 29, 1993
Date of Patent:
July 11, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
Stanley F. Wanat, Major S. Dhillon, Gerhard Sprintschnik, Allen W. Loveland, Dennis A. King
Abstract: A cut-resistant tarpaulin has a waterproof coating bonded to a cut-resistant woven fabric. The fabric has a leno or gauze weave. The fabric has warp yarns and weft yarns of braided fibers. The fibers have an initial modulus greater than 400 grams per denier.
Abstract: An arylisonitrosoalkanone is hydrogenated in the presence of a noble metal catalyst and a weak carboxylic acid to form an arylalkanolamine which is then hydrogenated in the presence of a strong mineral acid and the transition metal catalyst to form an arylalkylamine. When the arylisonitrosoalkanone is an isonitrosoacetophenone, the isonitrosoacetophenone is prepared by one of two methods.In the first method, a substituted or an unsubstituted isonitrosoacetophenone is prepared from a corresponding substituted or unsubstituted acetophenone by oxidizing the acetophenone to form a substituted or an unsubstituted phenylglyoxalacetal in a reactor, hydrolyzing the phenylglyoxal acetal in the same reactor to form a corresponding substituted or unsubstituted phenylglyoxal, and condensing the phenylglyoxal with hydroxylamine or a salt thereof in the same reactor to form the substituted or unsubstituted isonitrosoacetophenone.
Type:
Grant
Filed:
January 19, 1994
Date of Patent:
July 4, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
Joseph A. McDonough, Ahmed M. Tafesh, Olan S. Fruchey
Abstract: The present invention provides new polymer compositions which contain novel substituted pyrazines or pyrazine derivatives ("NPD") which are functional and have useful application as a monomer (co-monomer) for a variety of high performance polymers such as polyester, polyarylate, polycarbonate, polyetherketones, epoxides, polyimides, polyamides, and polyamides-imides. These NPD have the general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are defined herein.
Type:
Grant
Filed:
November 1, 1994
Date of Patent:
July 4, 1995
Assignee:
Hoechst Celanese Corporation
Inventors:
George Kvakovszky, Richard Vicari, Olan S. Fruchey, Ahmed M. Tafesh, Charles B. Hilton
Abstract: This invention relates to water developable, negative working photosensitized sheet constructions which, upon exposure to an actinic radiation source through a screened image, can accurately reproduce said image. The construction is useful as a color proofing film which can be employed to predict the image quality from a lithographic printing process. The invention provides both overlay and transfer type proofing sheets which have good fingerprint resistance.
Abstract: A method of preparing substituted and unsubstituted 1,4-dihydro-4-oxo-2 and -3 quinolinic carboxylic acids which comprises heating an ester selected from the group consisting of substituted and unsubstituted anilinomethylenemalonates, anilinofumurates, anilinomaleates and mixutres thereof in the presence of chlorosulfonic acid, oleum and mixtures thereof.
Abstract: Ternary mixtures of C.sub.4 to C.sub.8 alkyl acetate, C.sub.4 to C.sub.8 alkyl alcohol, and water, formulated to have a flash point of above 100.degree. F., are disclosed, particularly for use in edge residue removal processes in the fabrication of integrated circuits and like products.