Patents Assigned to Cree Research, Inc.
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Patent number: 5631190Abstract: A method of producing light emitting diodes from silicon carbide with increased external efficiency is disclosed which includes directing a beam of laser light at one surface of a portion of silicon carbide, and in which the laser light is sufficient to vaporize the silicon carbide that it strikes to thereby define a cut in the silicon carbide portion; and then dry etching the silicon carbide portion to remove by-products generated when the laser light cuts the silicon carbide portion. The resulting wafer and diode structure are also disclosed.Type: GrantFiled: October 7, 1994Date of Patent: May 20, 1997Assignee: Cree Research, Inc.Inventor: Gerald H. Negley
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Patent number: 5629531Abstract: A method of obtaining high quality passivation layers on silicon carbide surfaces by oxidizing a sacrificial layer of a silicon-containing material on a silicon carbide portion of a device structure to substantially consume the sacrificial layer to produce an oxide passivation layer on the silicon carbide portion that is substantially free of dopants that would otherwise degrade the electrical integrity of the oxide layer.Type: GrantFiled: December 9, 1994Date of Patent: May 13, 1997Assignee: Cree Research, Inc.Inventor: John W. Palmour
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Patent number: 5612260Abstract: A method of obtaining high quality passivation layers on silicon carbide surfaces by oxidizing a sacrificial layer of a silicon-containing material on a silicon carbide portion of a device structure to substantially consume the sacrificial layer to produce an oxide passivation layer on the silicon carbide portion that is substantially free of dopants that would otherwise degrade the electrical integrity of the oxide layer.Type: GrantFiled: December 9, 1994Date of Patent: March 18, 1997Assignee: Cree Research, Inc.Inventor: John W. Palmour
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Patent number: 5604135Abstract: A light emitting diode is disclosed that emits in the green portion of the visible spectrum, along with a method of producing the diode. The light emitting diode comprises a 6H silicon carbide substrate having a planar surface inclined more than one degree off axis toward one of the <11 20> directions; an ohmic contact to the substrate; a first epitaxial layer of 6H silicon carbide on the inclined surface of the substrate and having a first conductivity type; a second epitaxial layer of 6H silicon carbide on the first layer and having the opposite conductivity type for forming a p-n junction between the first and second layers; and an ohmic contact to the second epitaxial layer. The diode produces a peak wavelength of between about 525 and 535 nanometers with a spectral half width of no more than about 90 nanometers.Type: GrantFiled: August 12, 1994Date of Patent: February 18, 1997Assignee: Cree Research, Inc.Inventors: John A. Edmond, Alexander V. Suvorov
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Patent number: 5592501Abstract: A Group III nitride laser structure is disclosed with an active layer that includes at least one layer of a Group III nitride or an alloy of silicon carbide with a Group III nitride, a silicon carbide substrate, and a buffer layer between the active layer and the silicon carbide substrate. The buffer layer is selected from the group consisting of gallium nitride, aluminum nitride, indium nitride, ternary Group III nitrides having the formula A.sub.x B.sub.1-x N, where A and B are Group III elements and where x is zero, one, or a fraction between zero and one, and alloys of silicon carbide with such ternary Group III nitrides. In preferred embodiments, the laser structure includes a strain-minimizing contact layer above the active layer that has a lattice constant substantially the same as the buffer layer.Type: GrantFiled: September 20, 1994Date of Patent: January 7, 1997Assignee: Cree Research, Inc.Inventors: John A. Edmond, Gary E. Bulman, Hua-Shuang Kong
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Patent number: 5539217Abstract: The SiC thyristor has a substrate, an anode, a drift region, a gate, and a cathode. The substrate, the anode, the drift region, the gate, and the cathode are each preferably formed of silicon carbide. The substrate is formed of silicon carbide having one conductivity type and the anode or the cathode, depending on the embodiment, is formed adjacent the substrate and has the same conductivity type as the substrate. A drift region of silicon carbide is formed adjacent the anode or cathode and has an opposite conductivity type as the anode or cathode. A gate is formed adjacent the drift region or the cathode, also depending on the embodiment, and has an opposite conductivity type as the drift region or the cathode. An anode or cathode, again depending on the embodiment, is formed adjacent the gate or drift region and has an opposite conductivity type than the gate.Type: GrantFiled: August 9, 1993Date of Patent: July 23, 1996Assignee: Cree Research, Inc.Inventors: John A. Edmond, John W. Palmour
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Patent number: 5523589Abstract: A light emitting diode emits in the blue portion of the visible spectrum and is characterized by an extended lifetime. The light emitting diode comprises a conductive silicon carbide substrate; an ohmic contact to the silicon carbide substrate; a conductive buffer layer on the substrate and selected from the group consisting of gallium nitride, aluminum nitride, indium nitride, ternary Group III nitrides having the formula A.sub.x B.sub.1-x N, where A and B are Group III elements and where x is zero, one, or a fraction between zero and one, and alloys of silicon carbide with such ternary Group III nitrides; and a double heterostructure including a p-n junction on the buffer layer in which the active and heterostructure layers are selected from the group consisting of binary Group III nitrides and ternary Group III nitrides.Type: GrantFiled: September 20, 1994Date of Patent: June 4, 1996Assignee: Cree Research, Inc.Inventors: John A. Edmond, Gary E. Bulman, Hua-Shuang Kong, Vladimir Dmitriev
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Patent number: 5506421Abstract: The power metal oxide semiconductor field effect transistor (MOSFET) has a drain region, a channel region, and a source region formed of silicon carbide. The drain region has a substrate of silicon carbide of a first conductivity type and a drain-drift region of silicon carbide adjacent the substrate having the same conductivity type. The channel region is adjacent the drain-drift region and has the opposite conductivity type from the drain-drift region. The source region is adjacent the channel region and has the same conductivity type as the drain-drift region. The MOSFET also has a gate region having a gate electrode formed on a first portion of the source region, a first portion of the channel region, and a first portion of the drain region. A source electrode is formed on a second portion of the source region and a second portion of the channel region. Also, a drain electrode is formed on a second portion of the drain region.Type: GrantFiled: November 24, 1992Date of Patent: April 9, 1996Assignee: Cree Research, Inc.Inventor: John W. Palmour
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Patent number: 5465249Abstract: A random access memory (RAM) cell in 6H-SiC having storage times when all bias is removed long enough to be considered nonvolatile. The nonvolatile random access memory (NVRAM) cell comprises a bit line, a charge storage device in silicon carbide, and a transistor in silicon carbide connecting the charge storage device to the bit line. The bipolar NVRAM cell has a bipolar transistor with a base region, an emitter region, and a floating collector region, wherein the charge storage device in the bipolar NVRAM is a p-n junction adjacent the floating collector region of the cell. The metal-oxide-semiconductor (MOS) NVRAM has a MOS field effect transistor (MOSFET) with a channel region, a source region, and a drain region, wherein the charge storage device in the MOS NVRAM is a MOS capacitor adjacent the drain region of the MOSFET.Type: GrantFiled: November 26, 1991Date of Patent: November 7, 1995Assignees: Cree Research, Inc., Purdue Research FoundationInventors: James A. Cooper, Jr., John W. Palmour, Calvin H. Carter, Jr.
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Patent number: 5459107Abstract: A method of obtaining high quality passivation layers on silicon carbide surfaces by oxidizing a sacrificial layer of a silicon-containing material on a silicon carbide portion of a device structure to substantially consume the sacrificial layer to produce an oxide passivation layer on the silicon carbide portion that is substantially free of dopants that would otherwise degrade the electrical integrity of the oxide layer.Type: GrantFiled: June 5, 1992Date of Patent: October 17, 1995Assignee: Cree Research, Inc.Inventor: John W. Palmour
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Patent number: 5416342Abstract: A light emitting diode is disclosed that emits light in the blue portion of the visible spectrum with high external quantum efficiency. The diode comprises a single crystal silicon carbide substrate having a first conductivity type, a first epitaxial layer of silicon carbide on the substrate and having the same conductivity type as the substrate, and a second epitaxial layer of silicon carbide on the first epitaxial layer and having the opposite conductivity type from the first layer. The first and second epitaxial layers forming a p-n junction, and the diode includes ohmic contacts for applying a potential difference across the p-n junction.Type: GrantFiled: June 23, 1993Date of Patent: May 16, 1995Assignee: Cree Research, Inc.Inventors: John A. Edmond, Hua-Shuang Kong
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Patent number: 5409859Abstract: A method and resulting ohmic contact structure between a high work function metal and a wide bandgap semiconductor for which the work function of the metal would ordinarily be insufficient to form an ohmic contact between the metal and the semiconductor. The structure can withstand annealing while retaining ohmic characteristics. The ohmic contact structure comprises a portion of single crystal wide bandgap semiconductor material; a contact formed of a high work function metal on the semiconductor portion; and a layer of doped p-type semiconductor material between the single crystal portion and the metal contact. The doped layer has a sufficient concentration of p-type dopant to provide ohmic behavior between the metal and the semiconductor material.Type: GrantFiled: April 22, 1994Date of Patent: April 25, 1995Assignees: Cree Research, Inc., North Carolina State UniversityInventors: Robert C. Glass, John W. Palmour, Robert F. Davis, Lisa S. Porter
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Patent number: 5393993Abstract: A transition crystal structure is disclosed for providing a good lattice and thermal match between a layer of single crystal silicon carbide and a layer of single crystal gallium nitride. The transition structure comprises a buffer formed of a first layer of gallium nitride and aluminum nitride, and a second layer of gallium nitride and aluminum nitride adjacent to the first layer. The mole percentage of aluminum nitride in the second layer is substantially different from the mole percentage of aluminum nitride in the first layer. A layer of single crystal gallium nitride is formed upon the second layer of gallium nitride. In preferred embodiments, the buffer further comprises an epitaxial layer of aluminum nitride upon a silicon carbide substrate.Type: GrantFiled: December 13, 1993Date of Patent: February 28, 1995Assignee: Cree Research, Inc.Inventors: John A. Edmond, Vladimir Dmitriev, Kenneth Irvine
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Patent number: 5381103Abstract: A method of testing a semiconductor device, having the steps of pulsing the semiconductor device with a predetermined level of current for a duration of time so as to cause inadequate parts to degrade and to cause adequate parts to stabilize, and measuring predetermined electrical or optical performance characteristics for the semiconductor device after the current pulse. A system for testing a semiconductor device on a wafer is also provided having a contact probe for applying current pulses to the semiconductor device on the wafer, measuring means electrically connected to the probe for measuring predetermined electrical or optical performance characteristics of the semiconductor device on the wafer, and optical detection means electrically connected to the measuring means for detecting radiation emitted from the semiconductor device on the wafer.Type: GrantFiled: October 13, 1992Date of Patent: January 10, 1995Assignee: Cree Research, Inc.Inventors: John A. Edmond, Douglas A. Asbury, Calvin H. Carter, Jr., Douglas G. Waltz
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Patent number: 5359345Abstract: A high resolution, full color display is provided having a liquid crystal pixel selectably addressable during a predetermined time period, a set of at least one red, one green and one blue color light source adjacent the liquid crystal pixel for emitting light through the liquid crystal pixel, and means for addressing the liquid crystal pixel a plurality of times during the predetermined time period for each color so as to provide persistence when changes in color are perceived by the human eye. A method of producing a high resolution, full color display is also provided by lighting a set of one red, one green, and one blue light sources by lighting the respective colored light sources for a predetermined time period for each color and shuttering the set of light sources with a liquid crystal pixel for at least a portion of the predetermined time period to thereby emit light from the shuttered pixel for a selected time period so as to provide persistence when changes in color are perceived by the human eye.Type: GrantFiled: August 5, 1992Date of Patent: October 25, 1994Assignee: Cree Research, Inc.Inventor: C. Eric Hunter
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Patent number: 5338944Abstract: A light emitting diode is disclosed that emits light in the blue region of the visible spectrum with increased brightness and efficiency. The light emitting diode comprises an n-type silicon carbide substrate; an n-type silicon carbide top layer; and a light emitting p-n junction structure between the n-type substrate and the n-type top layer. The p-n junction structure is formed of respective portions of n-type silicon carbide and p-type silicon carbide. The diode further includes means between the n-type top layer and the n-type substrate for coupling the n-type top layer to the light-emitting p-n junction structure while preventing n-p-n behavior between the n-type top layer, the p-type layer in the junction structure, and the n-type substrate.Type: GrantFiled: September 22, 1993Date of Patent: August 16, 1994Assignee: Cree Research, Inc.Inventors: John A. Edmond, Hua-Shuang Kong, Vladimir Dmitriev, Gary E. Bulman
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Patent number: 5270554Abstract: A high power, high frequency, metal-semiconductor field-effect transistor comprises a bulk single crystal silicon carbide substrate, an optional first epitaxial layer of p-type conductivity silicon carbide formed upon the substrate, and a second epitaxial layer of n-type conductivity silicon carbide formed upon the first epitaxial layer. The second epitaxial layer has two separate well regions therein that are respectively defined by higher carrier concentrations of n-type dopant ions than are present in the remainder of the second epitaxial layer. Ohmic contacts are positioned upon the wells for respectively defining one of the well regions as the source and the other as the drain. A Schottky metal contact is positioned upon a portion of the second epitaxial layer that is between the ohmic contacts and thereby between the source and drain for forming an active channel in the second epitaxial layer when a bias is applied to the Schottky contact.Type: GrantFiled: June 14, 1991Date of Patent: December 14, 1993Assignee: Cree Research, Inc.Inventor: John W. Palmour
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Patent number: 5264713Abstract: A junction field-effect transistor is disclosed that comprises a bulk single crystal silicon carbide substrate having respective first and second surfaces opposite one another, the substrate having a single polytype and having a concentration of suitable dopant atoms so as to make the substrate a first conductivity type. A first epitaxial layer of silicon carbide is formed on the first surface of the substrate, and having a concentration of suitable dopant atoms that give the first epitaxial layer the first conductivity type. A second epitaxial layer of silicon carbide is formed on the first epitaxial layer, the second epitaxial layer having a concentration of suitable dopant atoms to give the second epitaxial layer a second conductivity type opposite from the first conductivity type.Type: GrantFiled: June 14, 1991Date of Patent: November 23, 1993Assignee: Cree Research, Inc.Inventor: John W. Palmour
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Patent number: 5210051Abstract: The invention is a method of growing intrinsic, substantially undoped single crystal gallium nitride with a donor concentration of 7.times.10.sup.17 cm.sup.-3 or less. The method comprises introducing a source of nitrogen into a reaction chamber containing a growth surface while introducing a source of gallium into the same reaction chamber and while directing nitrogen atoms and gallium atoms to a growth surface upon which gallium nitride will grow.Type: GrantFiled: June 5, 1991Date of Patent: May 11, 1993Assignee: Cree Research, Inc.Inventor: Calvin H. Carter, Jr.
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Patent number: 5200022Type: GrantFiled: October 3, 1990Date of Patent: April 6, 1993Assignee: Cree Research, Inc.Inventors: Hua-Shuang Kong, Calvin H. Carter, Jr.