Abstract: Approaches are described for coating various flexible media, such as sheets of paper, synthetic polymer (polyolefin, polyester, etc.) sheets or fabric sheets, with a silicone on high-speed rolls. For example, an efficient method is described for minimizing and/or reducing mist formation when coating flexible supports with a liquid silicone composition precursor of crosslinked coatings. The coating process can be performed using a coating device that includes a roll operating at a high speed.
Type:
Grant
Filed:
June 20, 2017
Date of Patent:
August 3, 2021
Assignee:
ELKEM SILICONES FRANCE SAS
Inventors:
Guillaume Pibre, Aymeric Genest, Stéphanie Benitou, Jean-Marc Frances, Etienne Fleury, François Ganachaud, Daniel Portinha De Almeida
Abstract: A method for producing a porous silicone material including the following steps: 1) implementing a direct emulsion E of silicone in water including: A) a silicone base A crosslinkable by polyaddition or polycondensation; B) at least one nonionic silicone surfactant B having a cloud point between 10 and 50° C.; C) optionally, at least one catalyst C; and D) water; 2) heating the emulsion E to a temperature greater than or equal to 60° C. to obtain a porous silicone material; and 3) optionally, drying the porous silicone material.
Type:
Application
Filed:
May 17, 2019
Publication date:
July 8, 2021
Applicants:
Elkem Silicones France SAS, Institut National des Sciences Appliquees de Lyon, Universite Claude Bernard Lyon I, Centre National de la Recherche Scientifique - CNRS, Universite Jean Monnet Saint Etienne
Inventors:
Francois GANACHAUD, Etienne FLEURY, Gabriel LARRIBE, David MARIOT, Frederic MARCHAL
Abstract: Silicone gels are described that are adhesive to the skin. The gels are able to be used in particular for articles that are adhesive to the skin for medical or paramedical use.
Abstract: The subject of the present invention is the use, as hydrosilylation and/or dehydrogenative silylation catalyst, of a cobalt compound of formula (1): [CO(N(SiR3)2)x]y in which: —the R symbols, which are identical or different, represent a hydrogen atom or a hydrocarbon-based radical having from 1 to 12 carbon atoms, and preferably the R symbols, which are identical or different, are chosen from the group consisting of: a hydrogen atom, alkyl groups having from 1 to 8 carbon atoms and aryl groups having from 6 to 12 carbon atoms, —x=1, 2 or 3 and—y=1 or 2.
Type:
Grant
Filed:
December 19, 2017
Date of Patent:
June 8, 2021
Assignee:
Elkem Silicones France SAS
Inventors:
Magali Bousquie, Vincent Monteil, Jean Raynaud, Magali Puillet
Abstract: A system and method for forming a silicone composition C that is crosslinkable by exposure to radiation with a wavelength between 200 nm and 450 nm, having: at least one radical photoinitiator A; and at least one co-initiator B chosen from compounds having at least one hydrogen atom bonded to a silicon atom.
Type:
Application
Filed:
January 27, 2021
Publication date:
May 20, 2021
Applicants:
ELKEM SILICONES FRANCE SAS, UNIVERSITE DE HAUTE ALSACE
Inventors:
Guillaume PIBRE, Jean-Marc FRANCES, Xavier ALLONAS, Ahmad IBRAHIM, Christian MALIVERNEY, Perrine THEIL
Abstract: The present invention relates to a silicone composition C that is crosslinkable by exposure to radiation with a wavelength between 200 nm and 450 nm, comprising: at least one radical photoinitiator A; and at least one co-initiator B chosen from compounds comprising at least one hydrogen atom bonded to a silicon atom.
Type:
Grant
Filed:
December 22, 2016
Date of Patent:
March 23, 2021
Assignees:
ELKEM SILICONES FRANCE SAS, UNIVERSITE DE HAUTE ALSACE
Inventors:
Guillaume Pibre, Jean-Marc Frances, Christian Maliverney, Perrine Theil, Xavier Allonas, Ahmad Ibrahim
Abstract: Nanoparticles that can be used as hydrosilylation and dehydrogenative silylation catalysts. The nanoparticles have at least one transition metal with an oxidation state of 0, chosen from the metals of columns 8, 9 and 10 of the periodic table, and at least one carbonyl ligand, preferably a silicide.
Type:
Application
Filed:
January 11, 2019
Publication date:
November 12, 2020
Applicants:
Elkem Silicones France SAS, Universite Claude Bernard Lyon I, CPE Lyon Formation Continue et Recherche - CPE Lyon FCR, Centre National de la Recherche Scientifique - CNRS
Abstract: The present invention relates to a non-implantable medical device (1, 1?) intended to cover wounds and skin lesions, comprising a biosensor (3E, 3E?), characterised in that said biosensor (3E, 3E?) comprises a piece made of absorbent, hydrophilic material fixing, on the surface and/or within the thickness thereof, a composition of agglomerated powders comprising particles of ethylene vinyl acetate (EVA) having a surface in part covered with at least one orthophosphoric acid salt and a visual indicator of microbiological growth. In particular, the medical device (1, 1?) may comprise several layers in order to enable the guiding of a liquid. The present invention relates to a method for preparing such a medical device (1, 1?).
Type:
Application
Filed:
November 29, 2018
Publication date:
September 17, 2020
Applicants:
Biomerieux, Elkem Silicones France SAS, F.D.S., Fibroline, Hospices Civils De Lyon, Universite Claude Bernard Lyon 1, Institut National de la Sante et de la Recherche Medicale (INSERM), Ecole Normale Superieure De Lyon, Centre National de la Recherche Scientifique (CNRS)
Abstract: Silicone gels are described that are adhesive to the skin. The gels can be used in particular for articles that are adhesive to the skin for medical or paramedical use.
Abstract: There is provided a process for producing an organopolysiloxane A comprising at least one (meth)acrylate group, said process comprising the following steps: a) the following are reacted at a temperature of between 50 and 140° C., optionally between 70 and 130° C.: at least one organopolysiloxane B comprising at least one epoxy group, with acrylic acid or methacrylic acid or a mixture of the two, in the presence of a catalyst C which is a complex of iron in the oxidation state (III), of formula (1) below: [Fe(L1)3]??(1) in which the symbols L1, which may be identical or different, represent a ligand chosen from the group made up of: a ?-dicarbonylato anion or the enolate anion of a ?-dicarbonyl compound, a carboxylate anion and an alkoxide anion, and of at least one solvent, and b) the product obtained, which is said organopolysiloxane A or a mixture containing predominantly said organopolysiloxane A, is isolated.
Abstract: The general field of the invention is that of silicone coating compositions, in particular those of two-component or multi-component type, that can be crosslinked by polyaddition or hydrosilylation reactions to produce a support coated by a silicone elastomer as a thin layer. These silicone compositions, when they are crosslinked, are suitable, inter alia, as coatings, for example for the protection or mechanical reinforcement of various textile substrates such as for example fibrous, woven, knitted or nonwoven supports. The targeted objective is to provide a silicone elastomer coating composition that can be crosslinked by polyaddition reactions and that is useful in particular for applications in the field of inflatable safety bags for vehicles, or airbags, having, after crosslinking, optimum properties in terms of adhesion, thinness, lightness and crease and abrasion resistance, but also good mechanical properties. This silicone coating composition should also be easy to use and to apply.
Type:
Grant
Filed:
September 22, 2016
Date of Patent:
June 9, 2020
Assignee:
Elkem Silicones France SAS
Inventors:
Karine Borecki, Anne Seggio, Damien Djian, Bertrand Bordes
Abstract: The invention relates to a method for hydrosilylating an unsaturated compound comprising at least one ketone function, one aldehyde function, one alkene function and/or one alkyne function, with a compound comprising at least one hydrogenosilyl function, using an organic germanium catalyst.
Type:
Grant
Filed:
May 5, 2017
Date of Patent:
May 26, 2020
Assignees:
Elkem Silicones France SAS, Centre National de la Recherche Scientifique (CNRS
Abstract: A process is described for preparing a storage-stable mixture including an MDT silicone resin containing hydroxyl groups and an organic compound that contains at least one epoxy group.
Abstract: The present invention concerns a method for the hydrosilylation of an unsaturated compound comprising at least one ketone function, one aldehyde function, one alkene function and/or one alkyne function, with a compound comprising at least one hydrogen-silyl function implementing an organic catalyst of tri-coordinated germanium.
Type:
Grant
Filed:
November 12, 2015
Date of Patent:
October 15, 2019
Assignees:
Elkem Silicones France SAS, Centre National de la Recherche Scientifique
Abstract: The present invention concerns an organopolysiloxane (A) able to be obtained by the reaction, at a temperature of between 10° C. and 75° C., between—at least one compound (C) chosen from the organic compounds comprising at least one alkene or alkyne functional group, at least one of the substituents of which is an acid functional group and the organic compounds comprising at least one acid functional group and at least one alkene or alkyne functional group, at least one of the substituents of which is an electron-withdrawing group; and—at least one organopolysiloxane (B) chosen from the organopolysiloxanes comprising siloxyl units (I.1) and (I.2) of the following formulae: (I) The present invention also concerns compositions comprising said organopolysiloxanes (A) and the uses thereof. ( I ) Y a ? Z b 1 ? SiO 4 - ( a + b ) 2 ; ( I ? .1 ) Z c 2 ? SiO 4 - c 2 ( I ? .
Type:
Grant
Filed:
December 21, 2015
Date of Patent:
July 23, 2019
Assignees:
ELKEM SILICONES FRANCE SAS, INSTITUT NATIONAL DES SCIENCES APPLIQUÉES LYON, UNIVERSITÉ CLAUDE BERNARD LYON 1, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE JEAN MONNET SAINT ETIENNE
Inventors:
François Ganachaud, Etienne Fleury, Daniel Portinha De Almeida, Aymeric Genest, Emmanuel Pouget
Abstract: A method of lubricating an expandable rubber bladder is described for use during a vulcanization of a green tire within a metal press. The method can include applying compositions in the form of emulsions of silicone oils to the inner surface of the green tires and/or to the outer surface of the vulcanization bladders to facilitate the molding-demolding thereof during the manufacture of the tires.
Type:
Grant
Filed:
December 12, 2014
Date of Patent:
May 28, 2019
Assignee:
ELKEM SILICONES FRANCE SAS
Inventors:
Stefan Breunig, Gérald Guichard, Jérôme Bordas