Abstract: A selective catalytic material is used in a method for selective oxidation of carbon monoxide in the presence of hydrocarbons and contains rhodium and a bismuth component either as a supported catalytic material dispersed on a refractory inorganic oxide support or as an unsupported catalytic material prepared, for example, by co-precipitation from a solution containing dissolved bismuth and rhodium salts. The bismuth and rhodium components are present in amounts that provide an atomic ratio of bismuth to rhodium in the range of from about 0.1:1 to 10:1, e.g., from about 1:1 to 2.5:1. The selective catalytic material is contacted under oxidizing conditions with a gas stream containing carbon monoxide and hydrocarbons.

Abstract: A color effect material is composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a first layer which acts as a reflector to light directed thereon, a visibly transparent second organic layer encapsulating the first layer in which the second layer provides an optically variable reflection of light impinging thereon and a third layer encapsulating the second layer and being selectively transparent to light directed thereon.

Abstract: The invention provides a process for carrying out the water gas shift reaction comprising employing a methane production suppressing water gas shift reaction catalyst, wherein the methane production suppressing water gas shift reaction catalyst comprises a methane production suppressing effective amount of a basic metal oxide.

Abstract: A sulfur sorber for the reduction of gaseous sulfur compounds, e.g., H2S, in a gas stream The sulfur sorber, e.g., zinc oxide, is present in the form of one or more layers on the surface of a monolith carrier, e.g., cordierite. The layers have a total thickness of at least 3 g/in3 of the carrier. Preferably, the sorber is present in the form of at least three layers on the surface of the monolith carrier.

Abstract: Method for aging catalyst materials which involves subjecting a catalyst or adsorbent material to a continuous or substantially continuous flow of a gaseous composition containing catalyst or adsorbent deactivating substances.

Abstract: A shrinkable iridescent film constitutes an oriented multilayer coextruded iridescent film having at least 10 generally parallel, very thin layers of substantially uniform thickness in which the contiguous adjacent layers are of heat shrinkable thermoplastic resinous material, each of which is heat shrinkable in at least one dimension in the plane of the film, the continuous adjacent layers being substantially uniformly shrinkable so as to have refractive indexes which differ by at least 0.03. The shrinkable film is made by selecting appropriate thermoplastic resinous materials, coextruding them into a thick film and then subjecting the film to orientation below the heat set temperature of the resinous materials.

Abstract: Non-bleeding, non-agglomerated, lustrous colored combination pigments constitute a platy substrate and absorption colorant bound thereto with metal hydroxides and one or more hydrolyzed silane coupling agents.

Abstract: The present invention provides a carbon-containing catalyst support that includes at least a carbonaceous material nd a thermosetting or sinterable polymer. The components are mixed and the polymer sintered or thermoset to provide a non-crushable, non-friable, and non-breakable composite. A catalytically active metal can be supported on the carbonaceous material prior to mixing, or on the composite after mixing and heating the mixture to sinter or thermoset the polymer.

Abstract: The present invention is directed to an iron-promoted zeolite beta catalyst useful in the selective catalytic reduction of nitrogen oxides with ammonia in which the iron-promoted zeolite beta is treated so as to provide increased amounts of the iron promoter in the form of Fe(OH).

Abstract: A catalytic trap disposed in an exhaust passage of an internal combustion engine which is operated with periodic alternations between lean and stoichiometric or rich conditions, for abatement of NOx in an exhaust gas stream which is generated by the engine. The trap comprises a catalytic trap material and a refractory carrier member on which the catalytic trap material is disposed. The catalytic trap material comprises: (i) a refractory metal oxide support; (ii) a catalytic component effective for promoting the reduction of NOx under stoichiometric or rich conditions; and (iii) a NOx sorbent effective for adsorbing the NOx under lean conditions and desorbing and reducing the NOx to nitrogen under stoichiometric or rich conditions. The NOx sorbent comprises a metal oxide selected from the group consisting of one or alkali metal oxides, alkaline earth metal oxides and mixtures of one or more alkali metal oxides and alkaline earth metal oxides.

Abstract: Composite of at least two metal oxides in the form of Primary Particles and a support having a particle size greater than the Primary Particles used in the formation of a catalyst composition for the treatment of a pollutant containing gas.

Abstract: The present invention relates to an article comprising a catalyst composition and a method useful for the removal of NOx and SOx contaminants from a gaseous stream, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with catalysts of the type generally referred to as “close coupled catalysts” which are designed to reduce pollutants in engine exhaust emissions during engine cold start conditions. The article comprises a lean burn gasoline engine having an exhaust outlet, an upstream section having a close coupled catalyst composite in communication with the exhaust outlet, and a downstream section. The upstream close coupled catalyst composite comprises a first support; a first platinum group component; and a SOx sorbent component selected from the group consisting of oxides and mixed oxides of barium, lanthanum, magnesium, manganese, neodymium, praseodymium, and strontium.

Abstract: A nickel catalyst comprising 0.1 to 12.5 wt. % of at least one structural promoter, selected from the group of oxides of metals and metalloids and combinations thereof, and 87.5 to 99.9 wt. % nickel, calculated on the weight of nickel and the structural promoter together, the catalyst having an nickel surface area, as defined herein, of at least 10 m2/g catalyst and an average pore diameter, as defined herein, of 10 to 60 nm. It has been found that already very small amounts of promoter improves the structure of the catalyst. High amounts still provide a stable, sinter resistant material, but result in a decrease in the pore size to lower levels. Furthermore, properties and sulfur uptake capacity.

Abstract: A laminar pigment which has an aluminum- or an aluminum-cerium oxide coating combined with a hydrolyzed silane coupling agent treated surface is used as a pigment for a powder coating composition. By combining the pigment with a powdery film-forming polymer, a film-forming composition which can be applied by electrostatic coating is produced.

Abstract: A process for adsorbing hydrocarbons from an acid gas stream includes passing the acid gas stream through an adsorbent which selectively removes hydrocarbons, desorbing the hydrocarbons from the adsorbent and contacting the desorbed hydrocarbons with an acid gas removal solution to remove acid gases which have been coadsorbed with the hydrocarbons. The process is particularly useful in removing hydrocarbons from a hydrogen sulfide-containing stream which is being directed to Claus processing for conversion into elemental sulfur. Useful adsorbents include crystalline titanium silicate molecular sieves containing titania octahedral sites such as ETS-10 and similar materials, as well as high silica aluminosilicate zeolite.

Abstract: A silver/gold coated laminar substrate pearlescent product is improved by incorporating rhodium in an amount of up to about 2% into the coating and/or by overcoating with a silane in an amount of up to about 5%.

Abstract: Separation of ethylene from ethane is achieved by feeding a mixture of the C2 hydrocarbons in contact with a CTS-1 crystalline titanium silicate molecular sieve which has a controlled pore size to selectively adsorb ethylene and size exclude ethane. The feed stream can also contain acetylene which can be selectively adsorbed from both ethane and ethylene by further controlling the pore size of the CTS-1 molecular sieve. Propane/propylene separation is also disclosed.

Abstract: A composition and method for improving the adhesion properties of catalytic and adsorptive compositions to a substrate through the addition of clay and/or silicone binder is disclosed. Preferably, the composition includes manganese dioxide and attapulgite clay and/or a silicone polymer which is adhered to a metal substrate, such as a motor vehicle radiator.

Abstract: In one embodiment, the present invention relates to a pesticide delivery system, containing a continuous film having a thickness from about 1 &mgr;m to about 1,000 &mgr;m and noncontinuous areas having sizes less than about 100 &mgr;m, the continuous film containing a particulate material wherein at least 90% by weight of the particulate material has a particle size of about 10 microns or less, and a pest control agent at least partially coating the particulate material.

Abstract: One aspect of the present invention relates to a catalyst system for use in olefinic polymerization, containing a solid titanium catalyst component prepared by contacting a titanium compound and a magnesium compound; an organoaluminum compound having at least one aluminum-carbon bond; and an organosilicon compound comprising at least one of cyclobutyl group. Another aspect of the present invention relates to a method of making a catalyst for use in olefinic polymerization, involving the steps of reacting a Grignard reagent having a cyclobutyl group with an orthosilicate to provide an organosilicon compound having a cyclobutyl moiety; and combining the organosilicon compound with an organoaluminum compound having at least one aluminum-carbon bond and a solid titanium catalyst component prepared by contacting a titanium compound and a magnesium compound.