Abstract: The invention provides a process for hydroformylation of diisobutene and a C4 to C7 olefin in a common reaction zone. The hydroformylation is carried out with synthesis gas in the presence of a homogeneous catalyst system that comprises at least Co or Rh and optionally a phosphorus-containing ligand.
Type:
Application
Filed:
July 18, 2024
Publication date:
January 23, 2025
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter KUCMIERCZYK, Maren TERMÜHLEN, Annika REINHARDT, Armin Matthias RIX, Robert FRANKE, Dirk FRIDAG, Anna Chiara SALE, Ana MARKOVIC
Abstract: The invention provides a process for alkoxycarbonylation of diisobutene and a C4 to C7 olefin in a common reaction zone. The alkoxycarbonylation is carried out with an alcohol and carbon monoxide in the presence of a homogeneous catalyst system that comprises at least one metal from group 8 to 10 of the periodic table of the elements or a compound thereof, a phosphorus-containing ligand and an acid.
Type:
Application
Filed:
July 18, 2024
Publication date:
January 23, 2025
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter KUCMIERCZYK, Maren TERMÜHLEN, Annika REINHARDT, Armin Matthias RIX, Robert FRANKE, Dirk FRIDAG, Anna Chiara SALE, Ana MARKOVIC
Abstract: The invention provides a process for alkoxycarbonylation of diisobutene and a C4 to C7 olefin in a common reaction zone. The alkoxycarbonylation is carried out with an alcohol and carbon monoxide in the presence of a homogeneous catalyst system that comprises at least one metal from group 8 to 10 of the periodic table of the elements or a compound thereof, a phosphorus-containing ligand and an acid.
Type:
Application
Filed:
July 19, 2024
Publication date:
January 23, 2025
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter Kucmierczyk, Maren Termühlen, Annika Reinhardt, Armin Matthias Rix, Robert FRANKE, Dirk Fridag, Anna Chiara Sale, Ana Markovic
Abstract: The invention provides a process for alkoxycarbonylation of disobutone and a C4 to C7 olefin in a common reaction zone. The alkoxycarbonylation is carried out with an alcohol and carbon monoxide in the presence of a homogeneous catalyst system that comprises at least one metal from group 8 to 10 of the periodic table of the elements or a compound thereof, a phosphorus-containing ligand and an acid.
Type:
Application
Filed:
July 18, 2024
Publication date:
January 23, 2025
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter KUCMIERCZYK, Maren TERMÜHLEN, Annika REINHARDT, Armin Matthias RIX, Robert FRANKE, Dirk FRIDAG, Anna Chiara SALE, Ana MARKOVIC
Abstract: A process is developed for the hydroformylation of diisobutene, in which the diisobutene stream used is subjected to a distillation prior to the hydroformylation in order to enrich 2,4,4-trimethylpent-1-ene in the stream to be hydroformylated. The hydroformylation is carried out with synthesis gas in the presence of a homogeneous catalyst system that comprises at least Co or Rh and optionally a phosphorus-containing ligand.
Type:
Application
Filed:
June 11, 2024
Publication date:
December 19, 2024
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter Kucmierczyk, Robert Franke, Anna Chiara Sale, Dirk Fridag, Ana Markovic, Armin Matthias Rix, Maren Termühlen, Laura-Selin Harding, Jan Benedikt Metternich
Abstract: A process produces a target alcohol by hydrogenation of an ester formed by alkoxycarbonylation of diisobutene. The diisobutene stream used in the alkoxycarbonylation is subjected to a distillation prior to the alkoxycarbonylation in order to enrich 2,4,4-trimethylpent-1-ene in the stream to be alkoxycarbonylated. The alkoxycarbonylation is carried out with an alcohol and carbon monoxide in the presence of a homogeneous catalyst system that comprises at least one metal from group 8 to 10 of the periodic table of the elements or a compound thereof, a phosphorus-containing ligand and an acid.
Type:
Application
Filed:
June 11, 2024
Publication date:
December 19, 2024
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter Kucmierczyk, Robert Franke, Anna Chiara Sale, Dirk Fridag, Ana Markovic, Armin Matthias Rix, Maren Termühlen, Laura-Selin Harding, Jan Benedikt Metternich
Abstract: A process produces a carboxylic acid or salt thereof by hydrolysis or saponification of an ester formed by alkoxycarbonylation of diisobutene. The diisobutene stream used in the alkoxycarbonylation is subjected to a distillation prior to the alkoxycarbonylation in order to enrich 2,4,4-trimethylpent-1-ene in the stream to be alkoxycarbonylated. The alkoxycarbonylation is carried out with an alcohol and carbon monoxide in the presence of a homogeneous catalyst system that comprises at least one metal from group 8 to 10 of the periodic table of the elements or a compound thereof, a phosphorus-containing ligand and an acid.
Type:
Application
Filed:
June 11, 2024
Publication date:
December 19, 2024
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter Kucmierczyk, Robert Franke, Anna Chiara Sale, Dirk Fridag, Ana Markovic, Armin Matthias Rix, Maren Termühlen, Laura-Selin Harding, Jan Benedikt Metternich
Abstract: A process isomerizes 2,4,4-trimethylpent-2-ene to 2,4,4-trimethylpent-1-ene over a heterogeneous catalyst based on a zeolite or an ion-exchange resin. The process includes providing an input stream containing 2,4,4-trimethylpent-2-ene and 2,4,4-trimethylpent-1-ene and performing the isomerization with the input stream using a heterogeneous catalyst based on a zeolite or an ion-exchange resin. A proportion of 2,4,4-trimethylpent-2-ene in the total stream is at least 25 mol % based on the total input stream.
Type:
Application
Filed:
June 10, 2024
Publication date:
December 19, 2024
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter Kucmierczyk, Robert Franke, Anna Chiara Sale, Dirk Fridag, Ana Markovic, Armin Matthias Rix, Maren Termühlen, Laura-Selin Harding, Jan Benedikt Metternich
Abstract: A process is developed for the alkoxycarbonylation of diisobutene, in which the diisobutene stream used is subjected to a distillation prior to the alkoxycarbonylation in order to enrich 2,4,4-trimethylpent-1-ene in the stream to be alkoxycarbonylated. The alkoxycarbonylation is carried out with an alcohol and carbon monoxide in the presence of a homogeneous catalyst system that comprises at least one metal from group 8 to 10 of the periodic table of the elements or a compound thereof, a phosphorus-containing ligand and an acid.
Type:
Application
Filed:
June 11, 2024
Publication date:
December 19, 2024
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter Kucmierczyk, Robert Franke, Anna Chiara Sale, Dirk Fridag, Ana Markovic, Armin Matthias Rix, Maren Termühlen, Laura-Selin Harding, Jan Benedikt Metternich
Abstract: A process provides a tops stream K containing more than 85% by weight of 2,4,4-trimethylpent-1-ene, wherein both an isomerization of 2,4,4-trimethylpont-2-ene to 2,4,4-trimethylpont-1-ene and a distillation to obtain the tops stream K are performed. The isomerization is at least partially fed with the bottoms stream of the distilation where a tops stream K is withdrawn overhead.
Type:
Application
Filed:
June 10, 2024
Publication date:
December 19, 2024
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter Kucmierczyk, Robert Franke, Anna Chiara Sale, Dirk Fridag, Ana Markovic, Armin Matthias Rix, Maren Termühlen, Laura-Selin Harding, Jan Benedikt Metternich
Abstract: A catalyst for the total hydrogenation of an olefin-containing hydrocarbon stream can be made. The catalyst has a support material and platinum as a catalytically active metal. A process for the total hydrogenation of an olefin-containing hydrocarbon stream in at least one reactor with addition of hydrogen and using the catalyst can be performed.
Type:
Application
Filed:
April 10, 2024
Publication date:
October 17, 2024
Applicant:
Evonik Oxeno GmbH & Co. KG
Inventors:
Ralf Meier, Guido Stochniol, Stephan Peitz, Armin Matthias Rix
Abstract: The invention relates to a process for separating one or more components from a mixture by a membrane separation in which—depending on the component to be separated—an acid or a base is added to the mixture before the membrane separation.
Type:
Grant
Filed:
June 1, 2020
Date of Patent:
August 20, 2024
Assignee:
Evonik Oxeno GmbH & Co. KG
Inventors:
Peter Kucmierczyk, Robert Franke, Dirk Fridag, Johannes Knossalla, Marc Schäpertöns, Frederik Gluth