Abstract: This invention relates to hydrothermal treatment of silica-alumina cogels resulting in a reduction in the NH.sub.4 content of the gel and the generation of a gamma crystal phase and the employment of such gels as cracking catalysts.
Abstract: This invention relates silica-alumina cogels containing a crystalline phase and to hydrothermally treatment of silica-alumina cogels resulting in generation of a crystalline phase in the gel and the employment of such crystallized gels as hydrocarbon conversion catalysts.
Abstract: This invention relates to alpha (Si, Al)O.sub.4 crystalline complex, and to silica-alumina gel and crystalline alumino silicate host containing said alpha (Si, Al)O.sub.4 complex; both gels and crystalline alumina silicates containing a novel crystalline phase resulting from the hydrothermal treatment of the host (Si, Al)O.sub.4 complexes, both amorphous gel and crystalline alumino silicates, in the presence of rare earth cations.
Abstract: This invention relates to an improvement in the production of zeolites, particularly, zeolites of the faujasite type, employing clay based seeds derived from natural halloysite.
Abstract: This invention relates to zeolites of the faujasite type generally referred to as X or Y zeolites which contain both aluminum and NH.sub.4 in exchange position and catalysts employing the same.The zeolite of our invention is derived from the sodium form of the zeolite by first exchanging the sodium form with an aluminum ion to replace a substantial portion of the sodium and further reducing the sodium content of the zeolite by exchange with an ammonium ion.
Abstract: Exchanged zeolite of the faujasite type is produced by exchanging the sodium zeolite at super atmospheric pressures at temperatures below about 500.degree. F. with salt solutions in ratios of cations in excess of an equivalent of the cation per equivalent of the sodium in the zeolite.
Abstract: This invention relates to an improvement in the abrasion resistance of catalysts formulated from a mixture of an exchanged zeolite of the faujasite type, hydrated alumina and ammonium polysilicate or silica sol.
Type:
Grant
Filed:
January 15, 1979
Date of Patent:
June 3, 1980
Assignee:
Filtrol Corporation
Inventors:
John Lim, Dennis Stamires, Michael Brady
Abstract: This invention relates to zeolitic catalysts composed of an exchanged zeolite of the faujasite type and a matrix composed of clay and an alumina-silica component.
Abstract: This invention relates to a hydroprocessing catalyst particularly useful in hydrocracking comprising a low sodium faujasite zeolite produced by a high pressure exchange of Na cations with a solution of an ammonium salt as a substrate for incorporation of a hydrogenating metal compound.
Abstract: A rare earth exchanged zeolite of the faujasite type in which the equivalent of Na is less than 0.1 and the rare earth is at least 0.9 equivalents per gram atom of aluminum and catalysts including the same.
Abstract: This invention relates to the preparation of rare earth exchanged X type faujasite zeolites in which the Na content is reduced by exchange with rare earth cations to introduce in excess of about 0.9 equivalents of rare earth cations per gram atom of aluminum and catalysts employing the same.
Abstract: This invention relates to zeolitic catalysts composed of an exchanged zeolite of the faujasite type and a matrix composed of alumina and an alumina-silica component.
Abstract: A mechanically strong, thermally stable porous siliceous particle having a high pore volume and surface area with a major portion of the pore volume in pores of radii more than 20 Angstroms and the process of producing the particles by shaping a clay, acid-leached to a degree insufficient to destroy the plasticity of the clay, forming the leached clay into shaped particles, calcining the particles and further extracting the calcined clay particles without impairing their shape.
Abstract: This invention relates to production of improved zeolitic catalysts produced from mixtures of cation exchanged zeolites of the faujasite type incorporated into a matrix such as alumina, silica-alumina gels and clay or mixtures thereof.
Abstract: Catalysts containing a matrix and an ammonium zeolite of the faujasite type produced by exchanging the zeolite whose exchange sites are substantially entirely occupied by Na cations, with an ammonium salt solution to exchange substantially all of the Na cations with NH.sub.4 cations with substantially no impairment of crystallinity by a control of the relation of the equivalents of NH.sub.4 in the solution to equivalents of Na in the zeolite.
Abstract: A process of producing an ammonium zeolite of the faujasite type in which a zeolite of the faujasite type whose exchange sites are substantially entirely occupied by Na cations, is treated with an ammonium salt solution to exchange substantially all of the Na cations with NH.sub.4 cations with substantially no impairment of crystallinity by a control of the relation of the equivalents of NH.sub.4 in the solution to equivalents of Na in the zeolite.
Abstract: A shaped hydrodesulfurization catalyst comprising a nonzeolitic substrate impregnated with a Group VI and a Group VIII catalytic metal and with a Group IV-B promoter and having a high resistance to abrasion and a process of producing the same employing a substantially nonacid Group IV-B metal compound as the source of the Group IV-B promoter.
Abstract: This invention relates to a high-activity catalyst of improved thermal stability employing a zeolite of the faujasite type, pseudoboehmite alumina gel and a synthetic mica-montmorillonite and may also include a clay.
Type:
Grant
Filed:
October 15, 1974
Date of Patent:
March 1, 1977
Assignee:
Filtrol Corporation
Inventors:
Robert B. Secor, Robert A. Van Nordstrand, David R. Pegg