Patents Assigned to J. M. Huber Corporation
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Patent number: 9051477Abstract: A composite comprising a silicate material, such as, a sodium aluminosilicate, and titanium dioxide disposed on the surface thereof is disclosed, together with formulations comprising the composite and methods for preparing the same.Type: GrantFiled: October 8, 2014Date of Patent: June 9, 2015Assignee: J.M. Huber CorporationInventors: Hilary Ellen Matthews, Ronald Louis Romer
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Patent number: 9045616Abstract: Aluminosilicate pigments enriched by zirconium treatment, and methods of making the pigments, are disclosed. Such zirconium-containing aluminosilicate pigments can have a unique combination of small particle size, high surface area, low oil absorption, and neutral pH. These pigments can be used in various paint and coating applications, such as a TiO2 extender, offering improved properties to the finished paint or coating.Type: GrantFiled: October 30, 2014Date of Patent: June 2, 2015Assignee: J.M. Huber CorporationInventor: Duen-Wu Hua
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Patent number: 9028605Abstract: Disclosed herein are architectural coating compositions comprising spheroid shaped silica or silicate. The compositions exhibit a number of improved properties and are useful on a variety of substrates.Type: GrantFiled: February 16, 2012Date of Patent: May 12, 2015Assignee: J.M. Huber CorporationInventors: William J. Hagar, Ronald L. Romer, William C. Fultz, Karl W. Gallis
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Patent number: 8987363Abstract: Calcium carbonate particles having very narrow particle sizes with a controlled D98 and minimal ultrafines (very small particles) are described. The particles are prepared by grinding a feedstock in a centrifugal grinding mill, which utilizes very high centrifugal forces to impact the particles with each other or grinding media.Type: GrantFiled: March 20, 2012Date of Patent: March 24, 2015Assignee: J.M. Huber CorporationInventors: Lane George Shaw, Gary Lee Hillebrenner
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Patent number: 8945517Abstract: Disclosed herein is a continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product. Silica products and dentifrice compositions comprising the silica products are also disclosed. A continuous loop reactor is also disclosed.Type: GrantFiled: November 13, 2013Date of Patent: February 3, 2015Assignee: J. M. Huber CorporationInventors: William J. Hagar, Karl W. Gallis
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Patent number: 8876965Abstract: A composite comprising a silicate material, such as, a sodium aluminosilicate, and titanium dioxide disposed on the surface thereof is disclosed, together with formulations comprising the composite and methods for preparing the same.Type: GrantFiled: March 11, 2013Date of Patent: November 4, 2014Assignee: J.M. Huber CorporationInventors: Hilary Ellen Matthews, Ronald Louis Romer
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Publication number: 20140271749Abstract: Disclosed herein are silica materials comprising an adduct on at least a portion of a surface thereof. The silica materials are capable of binding volatile sulfur compounds (VSC)s and thereby reducing oral malodor. Also disclosed are dentifrice compositions, oral care compositions comprising the silica materials, and methods of making and using the silica materials.Type: ApplicationFiled: May 29, 2014Publication date: September 18, 2014Applicant: J.M. Huber CorporationInventors: Karl W. Gallis, Terry W. Nassivera, William H. Pitcock, JR.
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Patent number: 8609068Abstract: Disclosed herein is a continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product. Silica products and dentifrice compositions comprising the silica products are also disclosed. A continuous loop reactor is also disclosed.Type: GrantFiled: February 24, 2010Date of Patent: December 17, 2013Assignee: J.M. Huber CorporationInventors: William J. Hagar, Karl W. Gallis
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Patent number: 8596468Abstract: New silica gel materials and novel methods of producing such are provided. The method itself entails a manner of mixing the reactants together in a one-pot process such that the time required for aging is reduced without compromising the ability to target pore size production. In such a way, the pH of the reaction drives pore size development, thereby permitting a more efficient process to be followed in terms of expensive drying/heating steps being reduced timewise, if not altogether. Furthermore, in one embodiment, the resultant gel materials exhibit a certain pore size minimum while simultaneously exhibiting a degree of softness heretofore unavailable. As such, not only is this novel method more efficient in silica gel manufacture, but the resultant materials are completely novel as well. The gel materials made therefrom may be utilized in a variety of different end uses, such as cooking oil filtration, soft skin cleansers, dental abrasives, and the like.Type: GrantFiled: June 27, 2007Date of Patent: December 3, 2013Assignee: J.M. Huber CorporationInventors: Duen-Wu Hua, Gary W. Loock
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Patent number: 8277703Abstract: The smoke suppressant comprises a molybdate precipitate on the surface of a borate core. The precipitate increases surface area of the core and provides improved smoke suppression relative to a mixture of the molybdate and borate core. The suppressants can be incorporated into polymer compositions to improve their smoke suppression capability.Type: GrantFiled: April 15, 2011Date of Patent: October 2, 2012Assignee: J. M. Huber CorporationInventors: Joseph K. Walker, Elmer D. Luke, Jr.
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Patent number: 8070990Abstract: The present invention is directed to smoke suppressants based on ammonium octamolybdate chemistry. According to this invention, the precipitation of ammonium octamolybdate in the presence of an inert mineral core produce a novel high surface area ammonium octamolybdate smoke suppressant. The high surface area significantly increases the smoke suppression performance over a standard ammonium octamolybdate. This invention is also directed to a process for making the high surface area ammonium octamolybdate smoke suppressant. The smoke suppressant of this invention is particularly suitable for smoke suppression in polyvinyl chloride (PVC) applications.Type: GrantFiled: November 2, 2007Date of Patent: December 6, 2011Assignee: J.M. Huber CorporationInventors: Wai-Kwong Ho, Joseph K. Walker
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Publication number: 20110206749Abstract: Disclosed herein are silica materials comprising an adduct on at least a portion of a surface thereof. The silica materials are capable of binding volatile sulfur compounds (VSC)s and thereby reducing oral malodor. Also disclosed are dentifrice compositions, oral care compositions comprising the silica materials, and methods of making and using the silica materials.Type: ApplicationFiled: February 14, 2011Publication date: August 25, 2011Applicant: J.M. Huber CorporationInventors: Karl W. Gallis, Terry W. Nassivera, William H. Pitcock, JR.
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Patent number: 7803343Abstract: New silica gel materials and novel methods of producing such are provided. The method itself entails a manner of mixing the reactants together in a one-pot process such that the time required for aging is reduced without compromising the ability to target pore size production. In such a way, the pH of the reaction drives pore size development, thereby permitting a more efficient process to be followed in terms of expensive drying/heating steps being reduced timewise, if not altogether. Furthermore, in one embodiment, the resultant gel materials exhibit a certain pore size minimum while simultaneously exhibiting a degree of softness heretofore unavailable. As such, not only is this novel method more efficient in silica gel manufacture, but the resultant materials are completely novel as well. The gel materials made therefrom may be utilized in a variety of different end uses, such as cooking oil filtration, soft skin cleansers, dental abrasives, and the like.Type: GrantFiled: June 27, 2007Date of Patent: September 28, 2010Assignee: J.M. Huber CorporationInventors: Duen-Wu Hua, Michael C. Withiam, Francis R. W. Godwin, Fitzgerald A. Sinclair
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Patent number: 7731110Abstract: A method of making abrasive compositions, and more particularly, it relates to a method of making precipitated silica abrasive compositions having excellent cleaning performance and lower abrasiveness with post-reactor sizing of the abrasive particles being performed directly via wet comminution and centrifugation, optionally followed by hydraulic chamber press filtering combined with vacuum dewatering and de-agglomeration is provided. By targeting a specific particle size range, it has been determined that higher pellicle film cleaning levels may be achieved without also increasing the dentin abrasion properties of the silica products themselves. As a result, dentifrices including such classified abrasive silica products, exhibiting particularly desirable cleaning benefits, can be provided for improved tooth polishing, whitening, and the like, without deleteriously affecting the hard tooth surfaces.Type: GrantFiled: June 29, 2005Date of Patent: June 8, 2010Assignee: J.M. Huber CorporationInventor: Yung-Hui Huang
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Patent number: 7718184Abstract: Coated particles of metal (such as calcium) silicate that exhibit excellent odor neutralization and sebum absorption properties when present within certain cosmetic and/or personal care formulations and suspensions are provided. Uncoated calcium silicate exhibits a high pH level that may have a deleterious effect upon such cosmetic and/or personal care compositions, thereby rendering the overall composition ineffective for its intended purpose, particularly if the calcium silicate is present in its usual state at high loading levels. Alternatively, if certain materials present within personal care compositions exhibit a sufficiently low pH level, the effectiveness of such calcium silicates may be compromised as well.Type: GrantFiled: June 26, 2007Date of Patent: May 18, 2010Assignee: J.M. Huber CorporationInventors: Michael C. Withiam, Donald P. Conley, Michael Simone
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Patent number: 7670593Abstract: Unique abrasive and/or thickening materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial characteristics depending on the structure of the composite in situ generated material. With low structured composites (as measured via linseed oil absorption levels from 40 to 100 ml oil absorbed/100 g composite), simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels are possible in order to accord the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Increased amounts of high structure composite materials tend to accord greater viscosity build and thickening benefits together with such desirable abrasion and cleaning properties, albeit to a lesser extent than for the low structure types.Type: GrantFiled: November 24, 2004Date of Patent: March 2, 2010Assignee: J.M. Huber CorporationInventors: Patrick D. McGill, William C. Fultz
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Patent number: 7628844Abstract: Filtration materials comprising heat-treated metal-doped precipitated silica or silica gel materials with sulfur-containing functional silane surface treatments are provided. Such materials exhibit excellent mercury removal properties from flue gas emissions through the trapping of mercury vapors within a smokestack (or other like site). The metal dopant and the sulfur-containing functional silane components applied to the surface of the target metal-doped gels effectuate the desired mercury reactions to permit capture thereof. In combination, such components permit versatile utilization in either a fixed bed configuration or through a dynamic mercury removal procedure. Methods of using and specific filter apparatuses are also encompassed within this invention.Type: GrantFiled: October 17, 2007Date of Patent: December 8, 2009Assignee: J.M. Huber CorporationInventor: Duen-Wu Hua
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Patent number: 7585359Abstract: A filtration system including a novel combination of at least one metal-doped silica-based gel and zeolite materials to trap and/or modify, and remove undesirable gases (such as ammonia, ethylene oxide, formaldehyde, and nitrous oxide, as examples) from an enclosed environment is provided. The gel component exhibits specific porosity requirements and density measurements; the zeolite component is generally acidic and is preferably not reacted with any salts or like substances. Also included is the presence of an oxidizing agent on the gel materials to aid in capturing nitrogen dioxide and preventing conversion of such a product to NO. Methods of using and the application within specific filter apparatuses are also encompassed within this invention.Type: GrantFiled: December 27, 2006Date of Patent: September 8, 2009Assignee: J.M. Huber CorporationInventors: Michael C. Withiam, Fitzgerald A. Sinclair, David Friday, Terry Nassivera
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Publication number: 20090196929Abstract: New methods of treating silica wetcake during precipitated silica materials manufacturing are provided. Such methods permit a significant increase in high solids content processing while simultaneously reducing high viscosity of the resultant particles for transport facilitation. The resultant precipitated silica wetcake is treated with a borate-containing dispersant to impart the necessary low viscosity characteristics thereto. Such a dispersant accords not only such a viscosity result, but will not char or otherwise discolor the silica particles during evaporation of the liquids within the wetcake itself. Furthermore, such a dispersant, if left on the surfaces of such particles, will not deleteriously affect the abrasivity, fluoride compatibility, or other dentifrice properties of the precipitated silica materials themselves. Also encompassed within this invention are the resultant precipitated silica particles exhibiting borate residues and dentifrices including such materials.Type: ApplicationFiled: February 1, 2008Publication date: August 6, 2009Applicant: J.M. HUBER CORPORATIONInventors: Duen-Wu Hua, Michael William Mullahey, JR.
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Patent number: 7559981Abstract: An environmental control for use in air handling systems that are required to provide highly effective filtration of noxious gases is provided. In one embodiment, a filtration system utilizes a novel combination of at least one metal-doped silica-based gel and zeolite materials to trap and/or modify, and remove such undesirable gases (such as ammonia, ethylene oxide, formaldehyde, and nitrous oxide, as examples) from an enclosed environment. The gel component exhibits specific porosity requirements and density measurements; the zeolite component is generally acidic and is preferably not reacted with any salts or like substances. The novel combination of such gels and zeolites permits highly effective noxious gas filtration over a wide range of known toxic industrial chemicals such that excellent breakthrough results are attained, particularly in comparison with prior media filtration products.Type: GrantFiled: July 6, 2006Date of Patent: July 14, 2009Assignee: J.M. Huber CorporationInventors: David K. Friday, Fitzgerald A. Sinclair, Michael C. Withiam