Patents Assigned to J. M. Huber Corporation
  • Patent number: 9051477
    Abstract: A composite comprising a silicate material, such as, a sodium aluminosilicate, and titanium dioxide disposed on the surface thereof is disclosed, together with formulations comprising the composite and methods for preparing the same.
    Type: Grant
    Filed: October 8, 2014
    Date of Patent: June 9, 2015
    Assignee: J.M. Huber Corporation
    Inventors: Hilary Ellen Matthews, Ronald Louis Romer
  • Patent number: 9045616
    Abstract: Aluminosilicate pigments enriched by zirconium treatment, and methods of making the pigments, are disclosed. Such zirconium-containing aluminosilicate pigments can have a unique combination of small particle size, high surface area, low oil absorption, and neutral pH. These pigments can be used in various paint and coating applications, such as a TiO2 extender, offering improved properties to the finished paint or coating.
    Type: Grant
    Filed: October 30, 2014
    Date of Patent: June 2, 2015
    Assignee: J.M. Huber Corporation
    Inventor: Duen-Wu Hua
  • Patent number: 9028605
    Abstract: Disclosed herein are architectural coating compositions comprising spheroid shaped silica or silicate. The compositions exhibit a number of improved properties and are useful on a variety of substrates.
    Type: Grant
    Filed: February 16, 2012
    Date of Patent: May 12, 2015
    Assignee: J.M. Huber Corporation
    Inventors: William J. Hagar, Ronald L. Romer, William C. Fultz, Karl W. Gallis
  • Patent number: 8987363
    Abstract: Calcium carbonate particles having very narrow particle sizes with a controlled D98 and minimal ultrafines (very small particles) are described. The particles are prepared by grinding a feedstock in a centrifugal grinding mill, which utilizes very high centrifugal forces to impact the particles with each other or grinding media.
    Type: Grant
    Filed: March 20, 2012
    Date of Patent: March 24, 2015
    Assignee: J.M. Huber Corporation
    Inventors: Lane George Shaw, Gary Lee Hillebrenner
  • Patent number: 8945517
    Abstract: Disclosed herein is a continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product. Silica products and dentifrice compositions comprising the silica products are also disclosed. A continuous loop reactor is also disclosed.
    Type: Grant
    Filed: November 13, 2013
    Date of Patent: February 3, 2015
    Assignee: J. M. Huber Corporation
    Inventors: William J. Hagar, Karl W. Gallis
  • Patent number: 8876965
    Abstract: A composite comprising a silicate material, such as, a sodium aluminosilicate, and titanium dioxide disposed on the surface thereof is disclosed, together with formulations comprising the composite and methods for preparing the same.
    Type: Grant
    Filed: March 11, 2013
    Date of Patent: November 4, 2014
    Assignee: J.M. Huber Corporation
    Inventors: Hilary Ellen Matthews, Ronald Louis Romer
  • Publication number: 20140271749
    Abstract: Disclosed herein are silica materials comprising an adduct on at least a portion of a surface thereof. The silica materials are capable of binding volatile sulfur compounds (VSC)s and thereby reducing oral malodor. Also disclosed are dentifrice compositions, oral care compositions comprising the silica materials, and methods of making and using the silica materials.
    Type: Application
    Filed: May 29, 2014
    Publication date: September 18, 2014
    Applicant: J.M. Huber Corporation
    Inventors: Karl W. Gallis, Terry W. Nassivera, William H. Pitcock, JR.
  • Patent number: 8609068
    Abstract: Disclosed herein is a continuous process for preparing a silica product, comprising: (a) continuously feeding an acidulating agent and an alkali metal silicate into a loop reaction zone comprising a stream of liquid medium; wherein at least a portion of the acidulating agent and the alkali metal silicate react to form a silica product in the liquid medium of the loop reaction zone; (b) continuously recirculating the liquid medium through the loop reaction zone; and (c) continuously discharging from the loop reaction zone a portion of the liquid medium comprising the silica product. Silica products and dentifrice compositions comprising the silica products are also disclosed. A continuous loop reactor is also disclosed.
    Type: Grant
    Filed: February 24, 2010
    Date of Patent: December 17, 2013
    Assignee: J.M. Huber Corporation
    Inventors: William J. Hagar, Karl W. Gallis
  • Patent number: 8596468
    Abstract: New silica gel materials and novel methods of producing such are provided. The method itself entails a manner of mixing the reactants together in a one-pot process such that the time required for aging is reduced without compromising the ability to target pore size production. In such a way, the pH of the reaction drives pore size development, thereby permitting a more efficient process to be followed in terms of expensive drying/heating steps being reduced timewise, if not altogether. Furthermore, in one embodiment, the resultant gel materials exhibit a certain pore size minimum while simultaneously exhibiting a degree of softness heretofore unavailable. As such, not only is this novel method more efficient in silica gel manufacture, but the resultant materials are completely novel as well. The gel materials made therefrom may be utilized in a variety of different end uses, such as cooking oil filtration, soft skin cleansers, dental abrasives, and the like.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: December 3, 2013
    Assignee: J.M. Huber Corporation
    Inventors: Duen-Wu Hua, Gary W. Loock
  • Patent number: 8277703
    Abstract: The smoke suppressant comprises a molybdate precipitate on the surface of a borate core. The precipitate increases surface area of the core and provides improved smoke suppression relative to a mixture of the molybdate and borate core. The suppressants can be incorporated into polymer compositions to improve their smoke suppression capability.
    Type: Grant
    Filed: April 15, 2011
    Date of Patent: October 2, 2012
    Assignee: J. M. Huber Corporation
    Inventors: Joseph K. Walker, Elmer D. Luke, Jr.
  • Patent number: 8070990
    Abstract: The present invention is directed to smoke suppressants based on ammonium octamolybdate chemistry. According to this invention, the precipitation of ammonium octamolybdate in the presence of an inert mineral core produce a novel high surface area ammonium octamolybdate smoke suppressant. The high surface area significantly increases the smoke suppression performance over a standard ammonium octamolybdate. This invention is also directed to a process for making the high surface area ammonium octamolybdate smoke suppressant. The smoke suppressant of this invention is particularly suitable for smoke suppression in polyvinyl chloride (PVC) applications.
    Type: Grant
    Filed: November 2, 2007
    Date of Patent: December 6, 2011
    Assignee: J.M. Huber Corporation
    Inventors: Wai-Kwong Ho, Joseph K. Walker
  • Publication number: 20110206749
    Abstract: Disclosed herein are silica materials comprising an adduct on at least a portion of a surface thereof. The silica materials are capable of binding volatile sulfur compounds (VSC)s and thereby reducing oral malodor. Also disclosed are dentifrice compositions, oral care compositions comprising the silica materials, and methods of making and using the silica materials.
    Type: Application
    Filed: February 14, 2011
    Publication date: August 25, 2011
    Applicant: J.M. Huber Corporation
    Inventors: Karl W. Gallis, Terry W. Nassivera, William H. Pitcock, JR.
  • Patent number: 7803343
    Abstract: New silica gel materials and novel methods of producing such are provided. The method itself entails a manner of mixing the reactants together in a one-pot process such that the time required for aging is reduced without compromising the ability to target pore size production. In such a way, the pH of the reaction drives pore size development, thereby permitting a more efficient process to be followed in terms of expensive drying/heating steps being reduced timewise, if not altogether. Furthermore, in one embodiment, the resultant gel materials exhibit a certain pore size minimum while simultaneously exhibiting a degree of softness heretofore unavailable. As such, not only is this novel method more efficient in silica gel manufacture, but the resultant materials are completely novel as well. The gel materials made therefrom may be utilized in a variety of different end uses, such as cooking oil filtration, soft skin cleansers, dental abrasives, and the like.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: September 28, 2010
    Assignee: J.M. Huber Corporation
    Inventors: Duen-Wu Hua, Michael C. Withiam, Francis R. W. Godwin, Fitzgerald A. Sinclair
  • Patent number: 7731110
    Abstract: A method of making abrasive compositions, and more particularly, it relates to a method of making precipitated silica abrasive compositions having excellent cleaning performance and lower abrasiveness with post-reactor sizing of the abrasive particles being performed directly via wet comminution and centrifugation, optionally followed by hydraulic chamber press filtering combined with vacuum dewatering and de-agglomeration is provided. By targeting a specific particle size range, it has been determined that higher pellicle film cleaning levels may be achieved without also increasing the dentin abrasion properties of the silica products themselves. As a result, dentifrices including such classified abrasive silica products, exhibiting particularly desirable cleaning benefits, can be provided for improved tooth polishing, whitening, and the like, without deleteriously affecting the hard tooth surfaces.
    Type: Grant
    Filed: June 29, 2005
    Date of Patent: June 8, 2010
    Assignee: J.M. Huber Corporation
    Inventor: Yung-Hui Huang
  • Patent number: 7718184
    Abstract: Coated particles of metal (such as calcium) silicate that exhibit excellent odor neutralization and sebum absorption properties when present within certain cosmetic and/or personal care formulations and suspensions are provided. Uncoated calcium silicate exhibits a high pH level that may have a deleterious effect upon such cosmetic and/or personal care compositions, thereby rendering the overall composition ineffective for its intended purpose, particularly if the calcium silicate is present in its usual state at high loading levels. Alternatively, if certain materials present within personal care compositions exhibit a sufficiently low pH level, the effectiveness of such calcium silicates may be compromised as well.
    Type: Grant
    Filed: June 26, 2007
    Date of Patent: May 18, 2010
    Assignee: J.M. Huber Corporation
    Inventors: Michael C. Withiam, Donald P. Conley, Michael Simone
  • Patent number: 7670593
    Abstract: Unique abrasive and/or thickening materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial characteristics depending on the structure of the composite in situ generated material. With low structured composites (as measured via linseed oil absorption levels from 40 to 100 ml oil absorbed/100 g composite), simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels are possible in order to accord the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Increased amounts of high structure composite materials tend to accord greater viscosity build and thickening benefits together with such desirable abrasion and cleaning properties, albeit to a lesser extent than for the low structure types.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: March 2, 2010
    Assignee: J.M. Huber Corporation
    Inventors: Patrick D. McGill, William C. Fultz
  • Patent number: 7628844
    Abstract: Filtration materials comprising heat-treated metal-doped precipitated silica or silica gel materials with sulfur-containing functional silane surface treatments are provided. Such materials exhibit excellent mercury removal properties from flue gas emissions through the trapping of mercury vapors within a smokestack (or other like site). The metal dopant and the sulfur-containing functional silane components applied to the surface of the target metal-doped gels effectuate the desired mercury reactions to permit capture thereof. In combination, such components permit versatile utilization in either a fixed bed configuration or through a dynamic mercury removal procedure. Methods of using and specific filter apparatuses are also encompassed within this invention.
    Type: Grant
    Filed: October 17, 2007
    Date of Patent: December 8, 2009
    Assignee: J.M. Huber Corporation
    Inventor: Duen-Wu Hua
  • Patent number: 7585359
    Abstract: A filtration system including a novel combination of at least one metal-doped silica-based gel and zeolite materials to trap and/or modify, and remove undesirable gases (such as ammonia, ethylene oxide, formaldehyde, and nitrous oxide, as examples) from an enclosed environment is provided. The gel component exhibits specific porosity requirements and density measurements; the zeolite component is generally acidic and is preferably not reacted with any salts or like substances. Also included is the presence of an oxidizing agent on the gel materials to aid in capturing nitrogen dioxide and preventing conversion of such a product to NO. Methods of using and the application within specific filter apparatuses are also encompassed within this invention.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: September 8, 2009
    Assignee: J.M. Huber Corporation
    Inventors: Michael C. Withiam, Fitzgerald A. Sinclair, David Friday, Terry Nassivera
  • Publication number: 20090196929
    Abstract: New methods of treating silica wetcake during precipitated silica materials manufacturing are provided. Such methods permit a significant increase in high solids content processing while simultaneously reducing high viscosity of the resultant particles for transport facilitation. The resultant precipitated silica wetcake is treated with a borate-containing dispersant to impart the necessary low viscosity characteristics thereto. Such a dispersant accords not only such a viscosity result, but will not char or otherwise discolor the silica particles during evaporation of the liquids within the wetcake itself. Furthermore, such a dispersant, if left on the surfaces of such particles, will not deleteriously affect the abrasivity, fluoride compatibility, or other dentifrice properties of the precipitated silica materials themselves. Also encompassed within this invention are the resultant precipitated silica particles exhibiting borate residues and dentifrices including such materials.
    Type: Application
    Filed: February 1, 2008
    Publication date: August 6, 2009
    Applicant: J.M. HUBER CORPORATION
    Inventors: Duen-Wu Hua, Michael William Mullahey, JR.
  • Patent number: 7559981
    Abstract: An environmental control for use in air handling systems that are required to provide highly effective filtration of noxious gases is provided. In one embodiment, a filtration system utilizes a novel combination of at least one metal-doped silica-based gel and zeolite materials to trap and/or modify, and remove such undesirable gases (such as ammonia, ethylene oxide, formaldehyde, and nitrous oxide, as examples) from an enclosed environment. The gel component exhibits specific porosity requirements and density measurements; the zeolite component is generally acidic and is preferably not reacted with any salts or like substances. The novel combination of such gels and zeolites permits highly effective noxious gas filtration over a wide range of known toxic industrial chemicals such that excellent breakthrough results are attained, particularly in comparison with prior media filtration products.
    Type: Grant
    Filed: July 6, 2006
    Date of Patent: July 14, 2009
    Assignee: J.M. Huber Corporation
    Inventors: David K. Friday, Fitzgerald A. Sinclair, Michael C. Withiam