Abstract: An object of the present invention is to provide a novel catalyst for olefin (co)polymer production, which has high activity without using a large amount of a cocatalyst and is aimed for obtaining a particulate olefin (co)polymer. The invention relates to an olefin polymerization catalyst which comprises: a solid carrier (1) that has been brought into contact with a specific compound; and a metal catalyst component (2) that contains a transition metal compound (C) containing a transition metal M belonging to Group 9, 10, or 11 of the periodic table and has a reactive group Ra.
Type:
Grant
Filed:
July 23, 2015
Date of Patent:
May 28, 2019
Assignees:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: The present invention provides a polyethylene, which has an excellent balance between rigidity and durability and is excellent in moldability and impact resistance, and a material useful as a material for hollow plastic products such as containers, bottles, tanks, especially fuel tanks for automobiles. The polyethylene of the invention is composed of one or two or more ethylene polymers selected from the group consisting of a homopolymer of ethylene and a copolymer of ethylene and an ?-olefin having 3 to 12 carbon atoms and satisfies specific requirements at the same time.
Abstract: An object of the present invention is to provide a novel catalyst for olefin (co)polymer production, which has high activity without using a large amount of a cocatalyst and is aimed for obtaining a particulate olefin (co)polymer. The invention relates to an olefin polymerization catalyst which comprises: a solid carrier (1) that has been brought into contact with a specific compound; and a metal catalyst component (2) that contains a transition metal compound (C) containing a transition metal M belonging to Group 9, 10, or 11 of the periodic table and has a reactive group Ra.
Type:
Grant
Filed:
July 23, 2015
Date of Patent:
April 16, 2019
Assignees:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: A method of producing a polar-group-containing olefin copolymer which comprises 99.999 to 80 mol % of structural units derived from at least one of ethylene and ?-olefin having 3 to 20 carbon atoms and 20 to 0.001 mol % of structural units derived from at least one polar-group-containing monomer which contains an epoxy group and is represented by structural formula (I) or (II), the method comprising random copolymerization in the presence of a transition metal catalyst to obtain a copolymer having a linear molecular structure.
Type:
Application
Filed:
November 26, 2018
Publication date:
March 28, 2019
Applicants:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: The metallocene compound represented by the following general formula (1): (the numerals and signs in the general formula (1) are as described in the description).
Abstract: The present invention relates to a polar group-containing olefin copolymer (A?) which is produced through polymerization using a transition metal catalyst, which has a weight-average molecular weight falling within a specific range and which contains a polar group-containing monomer within a specific range; a multinary polar olefin copolymer (A?) indispensably containing a polar monomer component that has a norbornene skeleton and a carboxyl group or an acid anhydride group and having three or more types of monomer units; and a resin composition (C) containing a specific amount of a polar group-containing olefin copolymer (A) and a specific amount of an olefin resin (B).
Type:
Application
Filed:
October 1, 2018
Publication date:
February 28, 2019
Applicants:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: The present invention provides a polyethylene-based resin composition for a foamable laminate which contains a polyethylene-based resin (A) satisfying the following properties (a-1) to (a-3): (a-1) MFR is 6 g/10 minutes or more and less than 20 g/10 minutes; (a-2) the density is from 0.920 to 0.930 g/cm3; and (a-3) the ratio of eluates at an elution temperature of 70° C. or higher is from 47 to 83% by weight in the elution curve obtained by a temperature rising elution fractionation (TREF) with o-dichlorobenzene.
Abstract: The metallocene compound represented by the following general formula (I): (the numerals and signs in the general formula (1) are as described in the description).
Abstract: The invention is a polyacetal resin composition containing a polyacetal resin (A) and a polyethylene resin (B), in which the blending proportion of the polyacetal resin (A) occupying in the total mass of the polyacetal resin (A) and the polyethylene resin (B) is 10 to 90 mass %, the melt flow rate of the polyacetal resin (A) measured at a condition of 190° C. and 2.16 kg load is 30 g/10 minutes or less, and the polyethylene resin (B) consists of a modified polyethylene resin and the modification rate is 0.01 mass % or more based on 100 mass % of the total mass of the polyethylene resin and the melt flow rate of the polyethylene resin (B) measured at a condition of 190° C. and 2.16 kg load is 2.5 g/10 minutes or less.
Type:
Grant
Filed:
August 1, 2013
Date of Patent:
November 20, 2018
Assignees:
MITSUBISHI ENGINEERING-PLASTICS CORPORATION, JAPAN POLYETHYLENE CORPORATION
Abstract: [Problem] To provide an ethylene-?-olefin copolymer that is highly effective in improving the molding properties of polyolefin resins, improving the balance between impact strength and stiffness, and improving transparency. [Solution] Provided is an ethylene-?-olefin copolymer having a specific MFR, a specific density, and a specific molecular weight distribution, containing a suitable amount of a long-chain branching structure characterized by a branching index, and having a specific composition distribution structure characterized by solvent fractionation behavior.
Abstract: [Problem] To provide an ethylene-?-olefin copolymer that is highly effective in improving the molding properties of polyolefin resins and at the same time highly effective improving the balance between impact strength and stiffness. [Solution] Provided is an ethylene-?-olefin copolymer having a specific MFR, a specific density, and a specific molecular weight distribution, containing a suitable amount of a long-chain branching structure characterized by a branching index, and having a specific composition distribution structure characterized by solvent fractionation behavior.
Abstract: An object of the present invention is to provide a polyethylene-based resin composition excellent in the moldability and at the same time, excellent in the balance between impact strength and stiffness as well as in the transparency, and a molded product and a film, which are obtained by the molding of the polyethylene-based resin composition. The polyethylene-based resin composition of the present invention comprises from 41 to 99 wt % of (A) an ethylene-based polymer satisfying specific conditions and from 1 to 59 wt % of (B) an ethylene-based polymer satisfying specific conditions, wherein MFR of the composition as a whole is from 0.05 to 50 g/10 min and the density is from 0.910 to 0.960 g/cm3.
Abstract: A resin composition for a solar cell encapsulant containing an ethylene.?-olefin copolymer and an organic peroxide or a silane coupling agent or the like, and having superior heat resistance, transparency, flexibility and adhesion property to a glass substrate, as well as good balance between rigidity and cross-linking efficiency, the solar cell encapsulant and a solar cell module using the same. It is provided by a resin composition for the solar cell encapsulant characterized by containing the ethylene.?-olefin copolymer (A) having the characteristics of the following (a1) to (a5), and the organic peroxide (B) and/or the silane coupling agent (C). (a1) a density of 0.860 to 0.920 g/cm3 (a2) a ratio, (Mz/Mn), of Z average molecular weight (Mz) and number average molecular weight (Mn) determined by a gel permeation chromatography (GPC), of 8.0 or less (a3) a melt viscosity (?*1) measured at 100° C. under a shear rate of 2.43×10 s?1 of 1.2×105 poise or more (a4) a melt viscosity (?*2) measured at 100° C.
Abstract: Provided is a process of effectively producing an ethylene/unsaturated carboxylic acid copolymer having excellent mechanical and thermal properties. A process for producing an ethylene/unsaturated carboxylic acid copolymer comprises: producing an ethylene/unsaturated carboxylic acid ester copolymer from ethylene and unsaturated carboxylic acid ester using a late-transition-metal complex catalyst; and heating the ethylene/unsaturated carboxylic acid ester copolymer at a temperature capable of converting the ester group into a carboxylic acid group, thereby converting into the ethylene/unsaturated carboxylic acid copolymer.
Type:
Application
Filed:
January 11, 2018
Publication date:
July 19, 2018
Applicants:
JAPAN POLYETHYLENE CORPORATION, JAPAN POLYPROPYLENE CORPORATION
Abstract: The invention provides a specific metallocene compound and an olefin polymerization catalyst for use for a catalyst for producing an olefin polymer having a sufficiently high molecular weight while maintaining excellent copolymerizability at a polymerization temperature and under polymerization conditions industrially advantageous in polymerization of an olefin such as ethylene or the like, and provides a method for producing an olefin polymer using the catalyst.
Type:
Grant
Filed:
May 9, 2017
Date of Patent:
June 26, 2018
Assignee:
JAPAN POLYETHYLENE CORPORATION
Inventors:
Koji Itagaki, Tsutomu Sakuragi, Takayoshi Takahashi
Abstract: An object of the present invention is to provide a polyethylene-based resin composition excellent in the moldability and at the same time, excellent in the balance between impact strength and stiffness as well as in the transparency, and a molded product and a film, which are obtained by the molding of the polyethylene-based resin composition. The polyethylene-based resin composition of the present invention comprises from 41 to 99 wt % of (A) an ethylene-based polymer satisfying specific conditions and from 1 to 59 wt % (B) an ethylene-based polymer satisfying specific conditions, wherein MFR of the composition as a whole is from 0.05 to 50 g/10 min and the density is from 0.910 to 0.960 g/cm3.
Abstract: [Problem] To provide an ethylene-?-olefin copolymer having high mechanical strength and good molding properties. [Solution] Provided is an ethylene-?-olefin copolymer having a specific MFR, a specific density, and a specific molecular weight distribution, containing a suitable amount of a long-chain branching structure characterized by a branching index, and having a specific composition distribution structure characterized by solvent fractionation behavior.
Abstract: A polyethylene for a pipe and a joint of the present invention satisfies the following characteristics (1) to (5): Characteristic (1): a melt flow rate at a temperature of 190° C. and a load of 21.6 kg (HLMFR) is 5 to 20 g/10 minutes, Characteristic (2): a density (D) is 0.954 to 0.960 g/cm3, Characteristic (3): a ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mn) (Mw/Mn) measured by gel permeation chromatography (GPC) is 15 to 27, Characteristic (4): a rupture time at 80° C. and 5 MPa by a full notch creep test (FNCT) is 150 hours or more, and Characteristic (5): a Charpy impact strength (CIS) measured at ?20° C. is 8.5 kJ/m2 or more.
Abstract: An electroconductive polyethylene resin composition comprises: a resin component comprising a polar-group-containing polyethylene resin (A) and a polyethylene resin (B); and an electroconductive filler (E) incorporated into the resin component, wherein each of the proportions of the polar-group-containing polyethylene resin (A) and the polyethylene resin (B) in the resin component is the polar-group-containing polyethylene resin (A): 0.5 wt %-80 wt % and the polyethylene resin (B): 99.5 wt %-20 wt %, and the electroconductive polyethylene resin composition satisfies the following requirement (1): (1) surface resistivity: 10?/?-1010?/?.
Abstract: An object of the present invention is to provide a polyethylene for injection molding, which has an excellent balance between moldability and durability, and a molded article such as an injection-molded plastic fuel tank that has an excellent balance among injection moldability, durability, and impact resistance. The invention relates to a polyethylene for injection molding, the polyethylene comprising at least two types of specific polyethylenes, wherein the density, the high load melt flow rate, and the relationship between the weight ratio and the density of the polyethylene satisfy specific characteristics.