Abstract: An improved coal deashing process wherein coal is mixed with a first dissolving solvent, heated, solubilized and flashed to provide a prepared mixture. The flashing is effected at a temperature below about 650.degree. F. to increase the amount of the first dissolving solvent in the prepared mixture. The prepared mixture then is mixed with a second dissolving solvent to produce a feed mixture which is subjected to two or more successive phase separations. Insoluble coal products present are separated from the feed mixture in a first separation zone and the soluble coal products are recovered from the first and the second dissolving solvents in a second separation zone. The second dissolving solvent is recovered from the first and the second heavy fractions and the second light fraction for recycling to aid in producing the feed mixture. The first dissolving solvent is recovered from the first and second flash zones.
Abstract: This invention relates to an improved process for the production of deashed coal which includes contacting coal with coal dissolving solvent at elevated temperature and pressure in a hydrogen atmosphere and thereafter passing the resulting mixture to a vacuum tower to remove coal dissolving solvent for recirculation and leave vacuum tower still bottoms, which are substantially free of coal dissolving solvent. Said still bottoms then are contacted with a solubilizing solvent to dissolve a substantial quantity of said still bottoms after which said dissolved still bottoms are separated from undissolved still bottoms. The separation procedure may be effected by settling, countercurrent decantation, or filtration using pressure precoated rotary and plate filters and the like.
Type:
Grant
Filed:
October 23, 1975
Date of Patent:
June 7, 1977
Assignee:
Kerr-McGee Corporation
Inventors:
Roger Allen Baldwin, Robert Elliott Davis
Abstract: A method of separating methylolphenols from an organic solution containing the methylolphenols by contacting the organic solution with an aqueous alkaline borate solution in which lithium ions are present in a quantity greater than any other single alkali metal ion for a period of time sufficient to form a solid complex of the lithium and boron with the methylolphenols which then are separated from the organic solution.The methylolphenols subsequently may be recovered from the complex by decomposing the complex with acid and dissolving the released methylolphenols in an organic solvent.
Type:
Grant
Filed:
May 16, 1974
Date of Patent:
September 21, 1976
Assignee:
Kerr-McGee Corporation
Inventors:
Robert Elliott Davis, Friedrich Josef Weck