Abstract: A process is disclosed for separating closely-boiling chlorinated phenolic compounds from other chlorinated and unchlorinated phenolics by treating a mixture of the phenolics with a metal halide salt. The metal halide salt preferentially forms a complex with one of the phenolics over other related closely-boiling phenolics in the mixture. The preferentially-formed complex of one of the phenolics may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of, one phenolic. The process is particularly suitable for resolving a mixture comprising phenol or cresol from their closely-boiling ortho-chlorinated derivatives, or a mixture of two isomeric chlorinated phenols or cresols or a mixture of closely-boiling mono- and dichlorinated phenols or cresols.

Abstract: A process is disclosed for separating 5-isopropyl-m-cresol from other isopropylated m-cresols by treating a mixture of the isopropylated m-cresols with a metal halide salt. The metal halide salt preferentially forms a complex with 5-isopropyl-m-cresol over other related closely-boiling isopropylated m-cresols in the mixture. The preferentially-formed complex of 5-isopropyl-m-cresol may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of, 5-isopropyl-m-cresol. The process is particularly suitable for isolating 5-isopropyl-m-cresol from closely-boiling isomers, and di-isopropylated m-cresols.

Abstract: Water-borne preservative salts are used to impregnate wood by the empty-cell pressure impregnation method without the precipitation of water-borne salts such as chromium, copper and arsenic when wood sugars enter the treating solution during the kickback or pressure release phase of the empty-cell cycle. The lack of precipitation is obtained by maintaining the preservative salts solution at a temperature between about 40.degree. F. and about 70.degree. F.

Abstract: A process is disclosed for one-step preparation of sulfur-selenium fulvalenes by reaction of an acetylenic compound with carbon selenide sulfide or with a mixture of carbon diselenide and carbon disulfide under pressures of at least about 1,000 atmospheres. Fulvalene compounds made by the process are characterized in having at least one sulfur atom and at least one selenium atom in the ring structure of the fulvalene compound. Substituted diselenadithiafulvalenes made by this process are precursors to very pure diselenadithiafulvalene which is useful in preparing charge-transfer salts.

Abstract: Catalytic material is provided by a composition comprising the elements vanadium, non-water-contained hydrogen, phosphorus and non-water-contained oxygen. Freshly prepared catalytic material proxides relatively high yields upon its initial use in the catalytic oxidation of hydrocarbon feedstocks, such as n-butane and benzene to maleic anhydride.

Abstract: An improved gear type coupling wherein the sleeve thereof is a torsional shear element to provide torsional overload protection to the coupling and its connected equipment. The shear section of the shear element is an integral part thereof and all sections of the shear element conduct an equal share of the transmitted torque.

Abstract: Catalytic material is prepared by impregnating porous silica with an aqueous solution containing vanadyl oxalate (VOC.sub.2 O.sub.4), potassium sulfate (K.sub.2 SO.sub.4) and potassium bisulfate (KHSO.sub.4). A free-flowing dry-appearing powder is provided comprising particles having substantially all compounds deposited from the impregnating solution attached to the silica particles within pores of the particles. Subsequent calcining of the powder provides a mixture of compounds within the particle pores containing at least one oxide of vanadium and at least one sulfate of potassium. Catalytic material prepared by the disclosed process is characterized in having a substantially uniform concentration of deposited compounds within the pores of the silica support. The catalytic material is particularly useful in a process for fluid bed oxidation of naphthalene to phthalic anhydride, in which oxidation process the catalyst provides high product yield at a low catalyst attrition rate.

Abstract: Coal fines developed from the processing of coal through a preheating system are accumulated in a secondary cyclone system. The coal fines, at an elevated temperature, are mixed with a hydrocarbon organic binder and compressed into larger particles of sufficient structural integrity and mass to be fed directly through pneumatic pressure coke oven coal charging lines without significant size reduction, resulting in the elimination of fine coal build-up in one coke oven standpipes and charging mains as well as overloading of the charging liquor system.

Abstract: A disc type refiner, for paper pulp processing and the like, is provided with an automatic control mechanism to prevent contact-clashing of the refiner plates on short term losses of feed and to sense the long term losses of feed so as to open the refiner plates before contact-clashing occurs. The control mechanism includes a counter-force-producing means acting in opposition to the refining or attrition force-producing means such that, on either short or long term loss of feed, resistance to plate clashing is provided. Moreover, the counter-force-producing means is monitored and the monitor provides signals to actuate, in cooperation with other control devices, a desired sequence of operative steps to effectuate either the continuation or the discontinuation of the refining operation.

Abstract: Bromide ions when used as the redox intermediates in the oxidation of arsenic (III) oxide to arsenic (V) acid can be removed from a solution having a major proportion of arsenic acid by treatment with an oxidant selected from H.sub.2 O.sub.2, O.sub.3 or Cr(VI) to oxidize the bromide to bromine followed by purging with air, nitrogen or other inert gas to sweep out the resultant bromine. The bromine can be recovered and recycled to a fresh batch of arsenic (III) oxide.

Abstract: A process is disclosed for separating nitrated phenolic compounds from other nitrated and unnitrated phenolics by treating a mixture of the phenolics with a metal halide salt. The metal halide salt preferentially forms a complex with one of the phenolics over other related phenolics in the mixture. The preferentially-formed complex of one of the phenolics may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of, one phenolic. The process is particularly suitable for resolving a mixture comprising phenol or cresol from their ortho-nitrated derivatives, or a mixture of two isomeric nitrated phenols or cresols or a mixture of mono-and dinitrated phenols or cresols.

Abstract: A process is disclosed for separating 3,5-xylenol or 3,4-xylenol from other closely boiling polymethylated phenolics by treating a mixture of the phenolics with a metal halide salt. The metal halide salt preferentially forms a complex with the xylenol over other related phenolics in the mixture. The preferentially-formed complex of the xylenol may then be isolated from the mixture and the complex decomposed to provide a product substantially enriched in, or substantially entirely composed of the xylenol.

Abstract: A gravity operated conical hopper having a sliding closure plate which is pneumatically activated as soon as the hopper has been emptied. An apparatus and method is also disclosed for pneumatically detecting and automatically closing the hopper to stop the flow of contained material after material has been discharged to a particular level.

Abstract: Closed-cell phenolic foam having a uniform cell structure in which the cell walls are substantially free of both ruptures and perforations is disclosed. The phenolic foam has initial k values of less than 0.15 with substantially no increase of k value over time and good density and compressive strengths. The phenolic foam is prepared by foaming and curing a foamable phenolic resole composition containing an aqueous phenol formaldehyde resole, surfactant, fluorocarbon blowing agent, and optionally other additives with an acid foaming and curing catalyst in a substantially closed mold which exerts a restraining pressure on the foaming composition in excess of ambient atmosphericpressure of greater than about 3 pounds per square inch. The aqueous phenol formaldehyde resole is essentially a phenol formaldehyde condensation polymer having a molar ratio of formaldehyde to phenol of from about 1.7:1 to 2.3:1, preferably from 1.75:1 to 2.25:1 and most preferably about 2:1.

Abstract: Stress corrosion cracking which occurs in metallic portions of a high-temperature regenerative air heater can be alleviated by the disclosed methods. The methods include the step of storing a gas charge within a heated regenerative air heater, which gas charge is substantially devoid of free oxygen. The substantial absence of free oxygen from the gas charge prevents or reduces formation of nitrogen-containing oxides which typically form within an air-containing gas charge stored in a regenerative air heater held at high temperature. Conditions conducive to stress corrosion cracking are thereby alleviated by reduction of these nitrogen-containing oxides which are precursors to corrosive acids. The methods are particularly suitable for reducing stress corrosion cracking in blast furnace stoves.

Abstract: There is disclosed a process for removing tar bases and neutral oils from the Lurgi tar acids by treating the tar acids with aqueous sodium bisulfate to change the tar bases to salts and to hydrolyze the neutral oils to hydrolysis products and distilling the tar acids to obtain refined tar acid as the distillate while the tar base salts and neutral oil hydrolysis products remain as residue.

Abstract: A flexible coupling in which the torque is transmitted by elastomeric elements held in compression. The coupling includes a sleeve assembly comprised of a plurality of independent arcuate elements and a retainer ring assembly which maintain the elastomeric elements in operable contact with the blades of the hub during rotation of the coupling.

Abstract: A device for adjusting the position of a track mounted car from a first position where the car is initially spotted by conventional braking means to a second predetermined position on the track which must be reached within close tolerances. An arm which may be pivoted in a vertical arc parallel to the track is pivotally attached to the car at its one end and at its other end it has preferably cone-shaped feeler means which engages a protrusion fixed adjacent to the track. A preferably vertical gravity based reference position is selected for the arm, and a sensing means for producting a direct current output signal proportional in magnitude to angular displacement of the arm from this position and corresponding in polarity to direction of displacement is provided.

Abstract: A process is provided for recovering the crystallization medium used for separating a 2,6-disubstituted phenol (DSP) from a feedstock containing it and a phenol in which only one of the 2 or 6 carbon positions are substituted (MSP).

Abstract: A hot top casing for cooperation with an ingot mold body is provided having a depending portion from which a pair of trunnions extend away from the casing and a second pair of trunnions extend toward said casing whereby each of said pairs are displaced vertically with respect to the center of gravity with one pair above and one pair below said center.