Abstract: A process for separating a cis isomer from a mixture of the cis isomer and a trans isomer of an azolylmethylcyclopentanol derivative of the formula (I): ##STR1## wherein, R.sup.1 and R.sup.2 each independently represent a hydrogen atom or an alkyl group; each X represents a halogen atom, an alkyl group, a haloalkyl group, a phenyl group, a cyano group or a nitro group; n is an integer of from 0 to 5; A represents a nitrogen atom or a CH group; and each X may be identical or different when n is an integer of from 2 to 5, comprising the steps of dehydrating selectively the trans isomer in the presence of an acid and isolating the cis isomer.
Abstract: Disclosed herein are a polyvinyl alcohol product obtained by heat-treating a melt-molded polyvinyl alcohol product composed of a polyvinyl alcohol composition containing 0.01 to 3.0 mmol of a metal compound based on 1 g of polyvinyl alcohol; a polyvinyl alcohol product obtained by stretching a melt-molded polyvinyl alcohol product composed of a polyvinyl alcohol composition containing 0.01 to 3.0 mmol of a metal compound based on 1 g of polyvinyl alcohol; and a multi-layer product comprising at least one inner layer of a melt-molded product composed of a polyvinyl alcohol composition containing 0.01 to 3.0 mmol of a metal compound based on 1 g of polyvinyl alcohol.
Abstract: A composition is disclosed, comprising(1) a polyamide as a dispersed phase and(2) a polyarylene sulfide as a continuous phase, wherein at least a part of the polyarylene sulfide has at least one modifying group directly bonded to the aromatic ring thereof, where the modifying group is selected from the group consisting of a carboxyl group, an alkali metal salt of a carboxyl group, and an alkaline earth metal salt of a carboxyl group, and where the modifying group is present at a ratio of 10 or more millimoles of the modifying group per kilogram of the polyamide. The composition has improved mechanical strength.
Type:
Grant
Filed:
June 17, 1993
Date of Patent:
July 25, 1995
Assignee:
Kureha Kagaku Kogyo Kabushiki Kaisha
Inventors:
Ken Kashiwadate, Mitsuru Hoshino, Shuji Morinishi, Yukichika Kawakami
Abstract: Magnetic components having a higher permeability than those obtained from Ni-Zn-based ferrite powder can be obtained by molding a composition comprising 5-30 wt. parts of polyarylene sulfide resin and 70-95 wt. parts (providing 100 wt. parts with the resin) of Ni-Zn-Cu-based ferrite powder. The Ni-Zn-Cu-based ferrite has a composition represented by the following formula (1):Ni.sub.a Zn.sub.b Cu.sub.c Fe.sub.2 O.sub.d,wherein a, b, c and d are numbers satisfying 0.10.ltoreq.a .ltoreq.0.70, 0.10.ltoreq.b.ltoreq.0.80, 0.10.ltoreq.c.ltoreq.0.35 and 3.97.ltoreq.d .ltoreq.4.20.
Abstract: A wave-receiving piezoelectric device for use as, e.g., a hydrophone or a microphone, is constituted by a piezoelectric body having two surfaces sandwiching a thickness and including at least one surface provided with a recess (including a perforation communicating with the two surfaces) set in the thickness direction, and a rigid member having a contact surface and an outer surface opposite to the contact surface and disposed to cover said at least one surface with the contact surface so as to make the recess airtight. As a result, an acoustic pressure received by the outer surface is concentrated and applied onto said at least one surface of the piezoelectric body, thereby giving an improved wave-receiving sensitivity at an enhanced acoustic pressure.
Abstract: Core materials for strings for musical instruments of a twist of two or more multifilaments composed of a vinylidene fluoride resin. The multifilament core has a diameter of 0.1 to 5 mm, an elongation of 10 to 50%, a tensile strength of at least 30 kg/mm.sup.2, a creep elongation of at most 15% and a Young's modulus of at least 200 kg/mm.sup.2. The multifilament is made of monofilaments each having a diameter of 1 to 300 .mu.m, a dispersion diameter of at most 20%/m, a specific gravity of at least 1.6, an inherent viscosity of 0.85 to 1.6 dl/g, an apparent viscosity of 12,000 to 100,000 poise and a birefringence of 30.times.10.sup.-3. Strings for violins, cellos and the like are made by tightly wrapping the core with a metal string.
Abstract: A vinylidene fluoride copolymer containing a carboxyl group or a carbonate group is formed by copolymerizing a monomer principally comprising vinylidene fluoride with a relatively small amount of an unsaturated dibasic acid monoester or vinylene carbonate. The copolymer has a large adhesion to various substrates or fillers and is excellent in chemical resistance, so that it is useful as a basic substance constituting a binder, an adhesive, a paint, etc. The copolymer is particularly effectively used as a binder for constituting an electrode for a non-aqueous solvent-type secondary battery together with an active substance, or an active substance and an electroconductive material, respectively in a particulate form.
Abstract: Disclosed herein are an azole derivative represented by the formula (I): ##STR1## wherein R.sup.1 and R.sup.2 respectively represent a (C.sub.1 -C.sub.5) alkyl group or a hydrogen atom; X represents a halogen atom, a (C.sub.1-C.sub.5) alkyl group or a phenyl group; n represents an integer of from 0 to 2 and A represents a nitrogen atom or a CH, provided that R.sup.1 is not a hydrogen atom when R.sup.2 is a hydrogen atom, a process for producing the azole derivative represented by the formula (I), and an agricultural and horticultural composition containing the azole derivative represented by the formula (I).
Abstract: A sheet-form piezoelectric device having improved mechanical strengths as represented by an electrode peel strength while retaining flexibility and piezoelectric performances of a polymer-type piezoelectric device, is obtained by embedding a perforated sheet electrode into at least one surface layer of a polymer piezoelectric film treated with a solvent in advance. The sheet-form piezoelectric device may be wound or curved about a certain central axis to provide a tubular or curved piezoelectric device having wave-transmitting and/or -receiving characteristics suitable for wave-transmitting and/or -receiving devices, such as a hydrophone and microphone.
Abstract: Disclosed herein are 4,5,6,7-tetrahydro-1H-imidazo[4,5-c]pyridine-6-carboxylic acid amide derivatives having a high antagonistic activity against angiotensin II and a high specificity to angiotensin II receptors, intermediates for preparing the derivatives, and antagonists against angiotensin II comprising the derivatives.
Abstract: The Langelier index and pH of city drinking water are improved by mixing and reacting a slurry of calcium carbonate and slaked lime covered with calcium carbonate produced in a slaked lime dissolving vessel with carbonic acid-containing water in a mixing and reacting vessel to make a calcium hydrogen carbonate aqueous solution which in turn is continuously added to water in a water-receiving vessel together with the aqueous solution of slaked lime. As a result, unused undissolved matter is decreased, and the Langelier index of drinking water can be improved.
Abstract: A method for roughening the surface of a resin molded article to make it susceptible to metallizing is disclosed, comprising contacting a resin molded article at least the surface of which to be toughened mainly comprises a block copolymer comprising 100 parts by weight of a polyphenylene sulfide resin and from 30 to 100 parts by weight of a polyphenylene sulfide ketone resin with a solvent capable of dissolving a polyphenylene sulfide ketone resin more than a polyphenylene sulfide resin.
Abstract: A ribbed porous carbon material (1) is a one piece molded product containing carbon fibers (5) and having a rib portion ( 2) and a web portion (3), in which the carbon fibers (5) are oriented in the rib portion (2) along the direction of the thickness of the web portion (3), while the carbon fibers (5) are oriented in the web portion (3) along the direction of the plane of the web portion (3) and along the direction perpendicular to the rib portion (2).
Abstract: Disclosed herein is a biaxially oriented laminated film comprising at least a surface layer of a polyester containing not less than 88 mol. % of terephthalic acid as an acid ingredient, an intermediate layer of a polyamide having a melting point of higher than 160.degree. C. and lower than 210.degree. C. and a heat-sealing layer or a polyolefin, the thickness of the polyester layer being lower than the thickness of the polyamide layer.
Abstract: A resin for bonding polyarylene sulfides is disclosed, comprising a copolymer wherein a main constituent element of the repeating unit of the copolymer is --A--Z--R--Z--, wherein --Z--is an ester linkage; A is an arylene sulfide oligomer component block comprising one or more arylene groups; and R is an organic compound residue formed by removing one atom or one group attached to each of two carbon atoms among carbon atoms constituting either an aliphatic main chain or an aromatic ring and has at most a molecular weight corresponding to an oligomer, but is different from A. An adhesive comprising the resin and a pyrrolidone solvent is also disclosed.
Abstract: A pair of tubular products of polyarylene sulfide having end faces to be welded are welded to each other by heating the end faces by a hot plate in no contact with the end faces to a surface temperature which is at least the melting heat-absorption peak temperature and at most 80.degree. C. above the melting initiation temperature of the polyarylene sulfide, and abutting the end faces under a pressure of 50-1500 kPa when the end faces are at a surface temperature which is at least 10.degree. C. above the melting initiation temperature and not exceeding the melting heat-absorption peak temperature of the polyarylene sulfide. As a result, a welded tubular structure having a weld with a small inside bead but having a sufficiently large weld strength can be obtained with substantially no thermal degradation and at a good operating efficiency.
Type:
Grant
Filed:
December 9, 1992
Date of Patent:
July 12, 1994
Assignee:
Kureha Kagaku Kogyo Kabushiki Kaisha
Inventors:
Satoshi Usui, Kouichi Kodama, Yoichiro Yamanobe, Ken Kashiwadate
Abstract: A method for roughening the surface of a resin molded article to make it susceptible to metallizing is disclosed, including contacting a resin molded article at least the surface portion of which to be roughened mainly includes a block copolymer including 100 parts by weight of a polyarylene sulfide component block and from 100 to 200 parts by weight of a polyarylene sulfide ketone component block with a solvent capable of dissolving a polyarylene sulfide ketone more than a polyarylene sulfide.
Abstract: Disclosed herein are polyvinyl alcohol products obtained by heat-treating a melt-molded polyvinyl alcohol product composed of a polyvinyl alcohol composition containing 0.01 to 3.0 mmol of a metal compound based on 1 g of polyvinyl alcohol;a polyvinyl alcohol product obtained by stretching a melt-molded polyvinyl alcohol product composed of a polyvinyl alcohol composition containing 0.01 to 3.0 mmol of a metal compound based on 1 g of polyvinyl alcohol; anda multi-layer product comprising at least one inner layer of a melt-molded product composed of a polyvinyl alcohol composition containing 0.01 to 3.0 mmol of a metal compound based on 1 g of polyvinyl alcohol.
Abstract: A laminated piezoelectric device is formed by sandwiching a relatively rigid central electrode layer with a pair of piezoelectric polymer films and then with a pair of outer electrode layers which are less rigid than the central electrode layer. The laminated piezoelectric device, as a whole, has a good flexibility and shows good piezoelectric characteristics represented by a hydrostatic piezoelectric constant d.sub.h and a symmetrical vibration characteristic. The outer electrode layers may preferably be constituted as a sprayed coating electrode which shows good solderability and peel strength.
Abstract: This invention provides a method of inhibiting aromatase and treating of estrogen-dependent diseases in a patient by administering azole derivatives as nonsteroidal inhibitors. The azole derivative has the formula ##STR1## where R.sub.1 a is hydrogen or a (C.sub.1 -C.sub.5) alkyl; R.sub.2 is a hydrogen or a (C.sub.1 -C.sub.5) alkyl; R.sub.3 is any of a halogen, a (C.sub.1 -C.sub.5)alkyl, a haloalkyl, a phenyl, a cyano, or nitro; n is 0 to 5; and Y is a nitrogen atom or CH.