Patents Assigned to L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés George Claude
  • Patent number: 11746959
    Abstract: The invention relates to a gas container equipped with a gas distribution valve having an electronic device for measuring gas autonomy. Flow selection means allow a desired gas flow to be selected. The electronic device includes a pressure sensor. Signal processing means allow gas autonomies to be determined on the basis of the pressure signal and of the selectable gas flows. A selection component cooperates with the signal processing means in order to successively display, on data display means and in response to successive digital activations by the user of the selection component, the various selectable flow values and the various corresponding autonomies, with each flow value being simultaneously displayed with a corresponding autonomy.
    Type: Grant
    Filed: January 13, 2021
    Date of Patent: September 5, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Federica Bellingeri, Adrien Campagnac, Alexis Mary
  • Patent number: 11740015
    Abstract: An air separation unit using cryogenic distillation comprises a first column, a second column thermally linked to the first column, a first argon column, a second argon column, means for sending cooled, compressed and purified air to at least the first column, means for sending at least one fluid enriched in nitrogen from the first column to the second column and at least one fluid enriched in oxygen from the first column to the second column, means for sending a gas enriched in argon from the second column to a first end of the first argon column, means for sending gas from a second end of the first argon column to a first end of the second argon column, means for removing argon rich fluid from a second end of the second argon column, a pump, means for removing argon enriched liquid from the first end of the second argon column and sending it to the second end of the first argon column via the pump, the first end of the first argon column being raised above the ground by a first supporting structure, the pum
    Type: Grant
    Filed: January 26, 2018
    Date of Patent: August 29, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Remy Kurtz, Patrice Cavagne, Delphine Vallier
  • Patent number: 11739220
    Abstract: A Si-containing film forming composition comprising a catalyst and/or a polysilane and a N—H free, C-free, and Si-rich perhydropolysilazane having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton and comprising N—H free repeating units having the formula [—N(SiH3)x(SiH2-)y], wherein x=0, 1, or 2 and y=0, 1, or 2 with x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 with x+y=3. Also disclosed are synthesis methods and applications for using the same.
    Type: Grant
    Filed: February 21, 2019
    Date of Patent: August 29, 2023
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.
    Inventors: Antonio Sanchez, Gennadiy Itov, Manish Khandelwal, Cole Ritter, Peng Zhang, Jean-Marc Girard, Zhiwen Wan, Glenn Kuchenbeiser, David Orban, Sean Kerrigan, Reno Pesaresi, Matthew Damien Stephens, Yang Wang, Guillaume Husson, Grigory Nikiforov
  • Publication number: 20230264162
    Abstract: Provided is a method for cooling a methanol r synthesis reactor effluent vapor stream in a methanol production plant, wherein the method comprises the steps of: receiving, using an inlet of a cooler, the methanol synthesis reactor effluent vapor stream from an interchanger or a methanol synthesis reactor of the methanol production plant; and spraying, using a recirculation pump connected to a spraying device, a liquid condensate received from a methanol synthesis loop onto a tube sheet of the cooler which enables direct contact of the liquid condensate with the methanol synthesis reactor effluent vapor stream and cools the methanol synthesis reactor effluent vapor stream.
    Type: Application
    Filed: January 20, 2023
    Publication date: August 24, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Bryce WILLIAMS, Tobias OELMANN
  • Patent number: 11732678
    Abstract: Device for supplying fluid to a user apparatus, in particular a cryogenic fuel such as hydrogen, to an engine, the device comprising a liquefied cryogenic fluid tank comprising a liquid phase and a gaseous phase, a user apparatus, a heating unit comprising a first end which is connected to the tank and a second end which is connected to the user apparatus, the drawing-off duct comprising a heater for the fluid drawn off, the device comprising a system for pressurising the tank comprising a pressurising duct comprising a first end which is connected to an upper end of the tank, a second end which is connected to a lower end of the tank, the pressurising duct comprising a fluid pumping unit and a heating unit, and being configured to draw off gaseous fluid from the tank, to heat it in the heating unit, and to re-inject this heated fluid into the low part in the liquid phase, characterised in that the pressurising duct and the drawing-off duct have a portion in common, and in that the heating unit and the heater
    Type: Grant
    Filed: February 1, 2022
    Date of Patent: August 22, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Yan Pennec
  • Patent number: 11724229
    Abstract: The invention relates to a process and plant for purifying a raw synthesis gas containing hydrogen and carbon monoxide as target components and carbon dioxide and sulfur components as disruptive components by gas scrubbing with a physically acting, liquid scrubbing medium selective for carbon dioxide and sulfur components. The process/the plant comprise an absorption apparatus, a hot regeneration apparatus, a preferably multistage flash regeneration apparatus and a reabsorber column supplied with the first portion of a stripping gas. According to the invention the flash regeneration apparatus is supplied with the second portion of the stripping gas.
    Type: Grant
    Filed: June 29, 2021
    Date of Patent: August 15, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Robert Szabo, Sophia Schmidt
  • Publication number: 20230249151
    Abstract: The present invention relates to a device for inserting at least one packing section into a cylindrical shell, comprising a base provided with gripping means configured to grip hold of a packing section and arranged at regular intervals around a main axis, wherein the insertion device comprises at least two telescopic devices secured to the base and at least one pushing means secured to one end of each of the two telescopic devices, the telescopic devices being configured to extend and cause the pushing means to move.
    Type: Application
    Filed: February 7, 2023
    Publication date: August 10, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Cyrille BABINET, Eric GALLOPIN, Gilles LEBAIN
  • Publication number: 20230249097
    Abstract: The present invention relates to an insertion device for inserting at least one packing section for a gas/liquid separation column into a cylindrical casing, comprising a base provided with retaining means which are configured to grip a packing section and which are arranged uniformly around a main axis, characterized in that the insertion device comprises at least two fastening means secured to the base, said fastening means being configured to fasten the insertion device to the casing. The invention also covers an insertion system for inserting at least one packing section into a cylindrical casing, comprising such an insertion device, and a method for inserting at least one packing section into a cylindrical casing that is implemented by such an insertion system.
    Type: Application
    Filed: February 7, 2023
    Publication date: August 10, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Cyrille BABINET, Eric GALLOPIN, Gilles LEBAIN
  • Publication number: 20230251030
    Abstract: Certain embodiments of the invention relate to a facility for refrigerating hydrogen to cryogenic temperatures, and in particular for liquefying hydrogen, comprising a circuit for hydrogen to be refrigerated comprising an upstream end to be connected to a hydrogen source, and a downstream end connected to a refrigerated hydrogen collection member, the refrigeration facility comprising a set of one or more heat exchangers in thermal exchange with the circuit of hydrogen to be refrigerated, the facility comprising a device for refrigerating by heat exchange with the set of one or more heat exchangers, the refrigerating device comprising a refrigerator with a refrigeration cycle of a cycle gas such as hydrogen, at least one portion of the hydrogen circuit, of the set of one or more exchangers and of the refrigerating device being housed in a vacuum-insulated cold box, the facility comprising in the cold box, at least one ejector the suction inlet of which is connected to the gas phase of a fluid capacity and the
    Type: Application
    Filed: May 27, 2021
    Publication date: August 10, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Bertille GUENEGO, Patrick LE BOT, Axelle GAERTNER
  • Publication number: 20230249954
    Abstract: The present invention concerns a gripping device for gripping a packing section, having a support forming a chassis and retaining means connected to this support and distributed angularly so as to surround the packing section that is to be gripped, characterized in that at least one of the retaining means has movable shoes respectively intended to be in contact with a peripheral edge of the packing section and a plurality of platforms disposed in at least two stages, each platform bearing articulation means able to interact with a platform of a different stage or one of the movable shoes.
    Type: Application
    Filed: February 7, 2023
    Publication date: August 10, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Cyrille BABINET, Eric GALLOPIN, Gilles LEBAIN
  • Publication number: 20230249096
    Abstract: The present invention relates to an insertion device for inserting at least one section of packing for a gas/liquid separation column into a cylindrical casing, characterized in that a deployment module comprises a main member centred about a main axis of the insertion device, and a plurality of peripheral members arranged circumferentially and uniformly around the main axis, each of the peripheral members comprising an attachment means configured to grasp hold of a packing section, the deployment module comprising a plurality of branches arranged as pairs of branches connecting the main member to one of the peripheral members, the deployment module being able to modify the dimension of the insertion device by modifying a radial distance between the main member and each of the peripheral members.
    Type: Application
    Filed: February 7, 2023
    Publication date: August 10, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Cyrille BABINET, Eric GALLOPIN, Gilles LEBAIN
  • Patent number: 11718796
    Abstract: The invention relates to a process and a plant for staged separation of concomitants from a raw synthesis gas stream to produce synthesis gas and a sulfur-free naphtha product as a by-product, To remove naphtha compounds and sulfur-containing concomitants, raw synthesis gas is treated with a scrubbing medium in a prescrubbing stage and withdrawn from the prescrubbing stage, and the laden scrubbing medium is mixed with water to bring about a phase separation into a scrubbing medium-water mixture and naphtha, wherein sulfur-containing concomitants are in solution in naphtha. To remove the sulfur-containing concomitants the naphtha is heated to obtain sulfur-free naphtha as a by-product of the gas scrubbing.
    Type: Grant
    Filed: August 27, 2020
    Date of Patent: August 8, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Sophia Schmidt, Sharon Corbet
  • Patent number: 11717806
    Abstract: An adsorbent bed, including at least one elementary composite structure that includes adsorbent particles in a polymer matrix, wherein the adsorbent bed has a bed packing, ?bed, defined as a volume occupied by the at least one elementary composite structure Vecs divided by a volume of the adsorbent bed Vbed where ?bed is greater than 0.60.
    Type: Grant
    Filed: July 11, 2020
    Date of Patent: August 8, 2023
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Philippe A. Coignet, Dean W. Kratzer, Antoine Pruvot, Matthew Metz
  • Patent number: 11702336
    Abstract: The invention relates to a process and a plant for producing pure hydrogen from an input gas containing hydrogen and hydrocarbons, in particular from a hydrogen-containing refinery off-gas, by steam reforming in a steam reforming stage and multi-stage hydrogen enrichment. According to the invention the input gas containing hydrogen and hydrocarbons is separated in a first hydrogen enrichment stage into a hydrogen-enriched substream and a hydrogen-depleted substream, wherein at least a portion of the hydrogen-enriched substream is supplied to a second hydrogen enrichment stage or introduced into the pure hydrogen product stream and at least a portion of the hydrogen-depleted substream is supplied to the steam reforming stage as a reforming feed stream or as part thereof and/or to the burners as a fuel gas stream.
    Type: Grant
    Filed: November 24, 2020
    Date of Patent: July 18, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Swatantra Kumar Shrivastava, Mirko Huebel, Mrityunjoy Samaddar
  • Publication number: 20230221067
    Abstract: A single compressor is used to separately compress permeate from cascaded first and second gas separation membrane-based separation units and residue from a fourth gas separation membrane-based separation unit in order to avoid too high a CO2 partial pressure in the compressed permeate. After the permeates from the first and second stages are compressed, the compressed stream is fed to a third gas separation membrane-based separation unit.
    Type: Application
    Filed: January 13, 2022
    Publication date: July 13, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Sandeep KARODE, Paul TERRIEN, Cyril DEFAYE
  • Publication number: 20230221068
    Abstract: A heat exchanger for indirect heat exchange between a first and a second fluids to be cooled and at least a third fluid to be heated, made up of a plurality of passages, namely a first series of passages for the flow at least of the first and of the second fluids, a second series of passages for the flow of the third fluid to be placed in a heat exchange relationship with the first and second fluids, the exchanger comprising three sections, the second section being between the first and third sections and means for introducing the first fluid into only a portion of the passages of the first series in the second section.
    Type: Application
    Filed: January 6, 2023
    Publication date: July 13, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Benoit DAVIDIAN
  • Publication number: 20230213273
    Abstract: An integrated industrial unit is provided, which can include: a nitrogen source configured to provide liquid nitrogen; a hydrogen source; a hydrogen liquefaction unit, wherein the hydrogen liquefaction unit comprises a precooling system, and a liquefaction system; and a liquid hydrogen storage tank, wherein the precooling system is configured to receive the gaseous hydrogen from the hydrogen source and cool the gaseous hydrogen to a temperature between 75 K and 100 K, wherein the precooling system comprises a primary refrigeration system and a secondary refrigeration system, wherein the liquefaction system is in fluid communication with the precooling system and is configured to liquefy the gaseous hydrogen received from the precooling system to produce liquid hydrogen, wherein the liquid hydrogen storage tank is in fluid communication with the liquefaction system and is configured to store the liquid hydrogen received from the liquefaction system.
    Type: Application
    Filed: August 26, 2022
    Publication date: July 6, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Michael A. TURNEY, Alain GUILLARD, Bobby Mon-Flan CHAN
  • Publication number: 20230213278
    Abstract: An integrated industrial unit is provided, which can include: a nitrogen source comprising an air separation unit that is configured to provide pressurized gaseous nitrogen and liquid nitrogen; a hydrogen source; a hydrogen liquefaction unit, wherein the hydrogen liquefaction unit comprises a precooling system, and a liquefaction system; and a liquid hydrogen storage tank, wherein the precooling system is configured to receive the gaseous hydrogen from the hydrogen source and cool the gaseous hydrogen to a temperature between 70K and 100K, wherein the precooling system comprises a primary refrigeration system and a secondary refrigeration system, wherein the liquefaction system is in fluid communication with the precooling system and is configured to liquefy the gaseous hydrogen received from the precooling system to produce liquid hydrogen, wherein the liquid hydrogen storage tank is in fluid communication with the liquefaction system and is configured to store the liquid hydrogen received from the liquefact
    Type: Application
    Filed: December 16, 2022
    Publication date: July 6, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Michael A. TURNEY, Alain GUILLARD, Bobby CHAN
  • Publication number: 20230211281
    Abstract: A single compressor is used to separately compress permeate from cascaded first and second gas separation membrane-based separation units and residue from a fourth gas separation membrane-based separation unit in order to avoid too high a CO2 partial pressure in the compressed permeate. After the permeates from the first and second stages are compressed, the compressed stream is fed to a third gas separation membrane-based separation unit.
    Type: Application
    Filed: December 31, 2021
    Publication date: July 6, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Sandeep KARODE, Paul TERRIEN, Cyril DEFAYE
  • Publication number: 20230212007
    Abstract: A method for producing hydrogen in a steam methane reformer with reduced carbon emissions that can include the steps of: heating a feed stream comprising methane in a first heat exchanger to produce a heated feed stream, wherein the heated feed stream is at a temperature above 500° C.
    Type: Application
    Filed: December 23, 2022
    Publication date: July 6, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Alexander ROESCH, Richard DUBETTIER, Dieter ULBER, Florian PONTZEN, Guillaume LODIER, Michael LUTZ